This work introduces into the chemistry, materials science and technology of Rare Earth Elements. The chapters by experienced lecturers describe comprehensively the recent studies of their characteristics, properties and applications in functional materials. Due to the broad range of covered topics as hydrogen storage materials, LEDs or permanent magnets this work gives an up-to-date presentation of this fascinating research.

This textbook addresses the chemical and physicochemical principles of supramolecular host-guest chemistry in solution. It covers the thermodynamics and dynamics of inclusion and highlights several types of organic hosts. Various applications of host-guest chemistry in analytical and environmental chemistry as well as pharmaceutical and chemical industry demonstrate the versatile usability of molecular cages.

The second edition of Metal Ions in Biochemistry deals with the multidisciplinary subject of bio-inorganic chemistry, encompassing the disciplines of inorganic chemistry, biochemistry and medicine. The book deals with the role of metal ions in biochemistry, emphasising that biochemistry is mainly the chemistry of metal-biochemical complexes. Hence, the book starts with the structures of biochemicals and the identification of their metal binding sites. Thermodynamic and kinetic properties of the complexes are explained from the point of view of the nature of metal-ligand bonds. Various catalytic and structural roles of metal ions in biochemicals are discussed in detail. Features The role of Na+ and K+ in brain chemistry. The role of zinc insulin in glucose metabolism and its enhancement by vanadium and chromium compounds. Discussion of the role of zinc signals, zinc fingers and cascade effect in biochemistry. Haemoglobin synthesis and the role of vitamin B12 in it. The role of lanthanides in biochemical systems. A detailed discussion of the role of non-metals in biochemistry, a topic missing in most of the books on bio-inorganic chemistry. The study of bio-inorganic chemistry makes biochemists rethink the mechanistic pathways of biochemical reactions mediated by metal ions. There is a realisation of the role of metal complexes and inorganic ions as therapeutics such as iron in leukaemia, thalassemia and sickle cell anaemia, iodine in hypothyroidism and zinc, vanadium and chromium in glucose metabolism. The most recent realisation is of the use of zinc in the prevention and treatment of COVID-19.

Framework Science.- Polymers for Multifunctional Applications: Some General Considerations.- An Objective for Polymers with Unusual Properties: Polymers with Delocalized Electronic States.- Ceramics from Organometallic Polymers: Industrial Perspectives.- The Current State of the Art in the Synthesis of Inorganic and Organometallic Polymers.- Polymer Synthesis.- Polymerization of Liquid Crystalline Monomers.- Electrosynthesis, A New Route to Disilanes, Polysilanes and Polycarbosilanes.- Catalytic Dehydro-and Dehydrosilyl-coupling: New Routes to Inorganic and Hybrid Organic/Inorganic Polymers.- Synthesis of Penta-alkoxy-and Penta-aryloxy Silicates Directly from SiO2.- Magnetic Materials.- Molecular Composites of the MPS3 Layered Inorganic Polymers: Chemistry, Magnetic, and Dielectric Properties.- Chemistry, Structures and Magnetic Properties of Mn(II)Cu(II) Molecular Compounds: Heterobinuclear Species, Ferrimagnetic Chains and Molecular-Based Ferromagnets..- Magnetic Molecular Materials.- Conducting And Electronic Materials.- Molecular Solids with Organic Conducting Chains and Inorganic Magnetic Chains: The (Per)2(mnt)2 Family. (M = Ni, Cu, Pd, Pt, Au, Fe and Co)..- Selective Synthesis and Some Electroconductive Properties of Organosilicon Polymers Containing Aromatic Units.- Crystal and Electronic Structure of Cobaltacene Intercalates of the Host Lattices SnS2-xSex (x=O, 0.3, 0.5, 1.3, 1.85, 2).- Approaches to Stacked, Semi-conducting Organometallics.- Supramolecular Organization of Phthalocyanines. Design and Synthesis of Low Dimensional Conductors.- Preceramic Materials.- Synthesis and Pyrolysis Chemistry of Polymeric Precursors to SiC and Si3N4.- A Catalytic Preparation of a New Preceramic Polymer: Transformation into SiC.- Transition Metal Oxo Polymers Synthesized via Sol-Gel Chemistry.- Organically Modified Silicates as Inorganic-Organic Polymers.- Nonlinear Optical Materials.- Resonant Nonlinear Optical Excitations in Glassy Polymers.- Rigid-Rod Transition Metal Acetylide Complexes, Oligomers, and Polymers for Nonlinear Optics.- Characterization.- Spectroscopic Characterization of the Pyrolysis Process of Pre-Ceramics Polymers.- Characterisation of Metallophthalocyanine Polymers for Application as Semiconductor Gas Sensor Material.- Aspects of Polyphosphazene Photochemistry.- Characterizing the Microstructures of New Polymers.- Report To Nato.- Inorganic and Organometallic Polymer with Special Properties. Progress, Potential and Problems.

When was radium discovered? Who are Dmitri Mendeleev and Glenn T. Seaborg? Who discovered uranium’s radioactivity? Which element is useful for dating the age of Earth? And why doesn’t gold have a scientific name?

30-Second Elements presents you with the very foundations of chemical knowledge, explaining concisely the 50 most significant chemical elements.

This book uses helpful glossaries and tables to fast track your knowledge of the other 68 elements and the relationships between all of them.

With the development of science and technology,more and more complex materials such as porous materials, ion liquid, liquid crystals, thin ?lms and colloids etc. are being developed in laboratories. However, it is dif?cult to prepare these advanced materials and use them on a large scale without some experience. Therefore, mo- cular thermodynamics, a method that laid emphasis on correlating and interpreting the thermodynamic properties of a variety of ?uids in the past, has been recently employed to study the equilibrium properties of complex materials and establish thermodynamic models to analyse the evolution process of their components, - crostructures and functions during the preparation process. In this volume, some important progress in this ?eld, from fundamental aspects to practical applications, is reviewed. In the ?rst chapter of this volume, Prof. Jianzhong Wu presents the application of Density Functional theory (DFT) for the study of the structure and thermodynamic properties of both bulk and inhomogeneous ?uids. This chapter presents a tut- ial overview of the basic concepts of DFT for classical systems, the mathematical relations linking the microstructure and correlation functions to measurable th- modynamic quantities, and the connections of DFT with conventional liquid-state theories. While for pedagogythe discussion is limited to one-componentsimple - ids, similar ideas and concepts are directly applicable to mixtures and polymeric systems of practical concern. This chapter also covers a few theoretical approaches to formulate the thermodynamic functional.

The current textbook is an excellent inroduction to the chemistry of the non-metallic elements. The book begins by reviewing the key theoretical concepts of chemical bonding and the properties of different bonding types. Subsequent chapters are focused on reactions, structures and applications of the non-metallic compounds. Combining careful pedagogy and clear writing style, the textbook is a must-have for students studying inorganic chemistry.

This is the second volume in the series of books covering practical aspects of synthesis and characterization of various categories of nanomaterials taking into consideration the most up to date research publications. The aim of the book series is to provide students and researchers practical information such as synthetic procedures, characterization protocols and mechanistic insights to enable them to either reproduce well established methods or plan for new syntheses of size and shaped controlled nanomaterials. The second volume focuses on multifunctional nanomaterials.

The incredible ""glowing"" history of the ""Devil's element ""phosphorus
Discovered by alchemists, prescribed by apothecaries, exploited by ninth-century industrialists, and abused by twentieth-century combatants, the chemical element phosphorus has fascinated us for more than three centuries. It may even be the cause of will-o'-the wisps and spontaneous human combustion Now John Emsley has written an enthralling account of this eerily luminescent element. Shining with wonderful nuggets-from murders-by-phosphorus to a match factory strike; from the firebombing of Hamburg to the deadly compounds derived from phosphorus today-The 13th Element weaves together a rich tableau of brilliant and oddball characters, social upheavals, and bizarre events.

Organic LEDs (OLEDs) in mobile displays have been in large-scale production for over a decade, and OLED-based televisions are rapidly gaining traction in the marketplace. OLEDs are on the verge of entering the solid-state lighting market in a big way. The OLED technology gives higher color purity and is more efficient than any of the competing technologies. When produced at scale, OLEDs are also economical. A key limitation in the development of OLEDs was the efficient conversion of all of the electrical energy put into the device into light. Until the late 1990s, the maximum efficiency of OLEDs was limited to 25% (photons/electrons), but this limitation was removed and OLEDs with 100% efficiency were reported in the early 2000s. This advance in OLED technology was driven by the author of this book. He and his collaborators developed electrophosphorescence, which is essential in reaching the 100% efficiency that is now commonplace in commercial devices.

This book provides an in-depth introduction to the sol to gel transition in inorganic and hybrid organic-inorganic systems, one of the most important chemical-physical transitions and the basis of the sol-gel process. Familiarity with the fundamental chemistry and physics of this transition is essential for students in chemistry and materials science through academic and industry researchers working on sol-gel-related applications. The book features a didactic approach, using simple and clear language to explain the sol to gel transition and the accompanying processes. The text is also suitable for use in short courses and workshops for graduate students as well as professionals.This fully revised and updated new edition contains a wealth of new content. In particular, it includes a detailed discussion of the chemistry of transition metal alkoxides and organosilanes, and an extended discussion of the sol to gel transition models.

Finalist for the Los Angeles Times Book Prize for Science and Technology "Very well-written and rewarding … an excellent account of the story." —Nature Ten years ago, the discovery of buckminsterfullerene, a previously unknown form of carbon, stunned the scientific community, as much for the discovery itself as for the manner in which it came about. In the words of author Hugh Aldersey-Williams. it was an example of "classic bootleg science. The work was done on the back of other, funded projects, and when time would allow. Yet its commercial implications are probably immense." Now, in a lively account, The Most Beautiful Molecule chronicles the events leading up to this momentous discovery and the ongoing, often frenzied aftermath. Hugh Aldersey-Williams leads us on a thrilling expedition to the very forefront of modern chemistry research.

Chapter contribution from John B Goodenough, Nobel Laureate in Chemistry 2019.This book provides a unique look at the chemistry and properties of complex metal oxides from the perspectives of some of the most active researchers on this class of materials. Applications of complex oxide materials are highly varied. Topics reviewed in this volume include solid-state battery research, the chemistry of transparent conductors, ternary uranium oxides, magnetic perovskites, non-linear optical materials, complex molybdenum-vanadium bronzes and other complex materials used in selective oxidation catalysis. It is written to serve as an introduction to the subject for and those beginning to work on these materials, particularly new graduate students.

This is the first volume (Part A) in the series of books covering practical aspects of synthesis and characterization of various categories of nanomaterials taking into consideration the most up to date research publications. The aim of the book series is to provide students and researchers practical information such as synthetic procedures, characterization protocols and mechanistic insights to enable them to either reproduce well established methods or plan for new syntheses of size and shape controlled nanomaterials based on both batch and continuous flow reactions. The first Volume (Part A) focuses on metallic nanomaterials.

This book provides a comprehensive review of the current state of the art in silicon compounds for thermoelectric applications. Silicides are materials with good initial thermoelectric properties, which can be enhanced through tuning of their micro- and macrostructure. These compounds present various conduction mechanisms and complex band structures. Moreover, some are isotropic, and others anisotropic, which is highly beneficial for device tailoring. Silicides are a particularly attractive material for sensors, thermoelectric generators, and other applications because they are environmentally friendly, abundant, and low cost. This concise volume covers fundamentals and applications for an audience of materials scientists, chemists, solid-state physicists, and engineers.

This brief introduces the classification and mechanism of density gradient ultracentrifugation (DGUC) method with rich examples showing the versatility of such an efficient separation technique. It also gives a strict mathematical description and a computational optimization model to predict the best separation parameters for a given colloidal system. The concept of "Lab in a tube" is proposed in the last chapter, which allows the size-property relationship investigation, synthetic optimization and reaction/assembly mechanism exploration etc.

This reference offers an overview of the bulk and surface properties of perovskite-like structures, and provides the latest discussions on the applications of these materials and processes. It also introduces ceramic methods for the processing of perovskite-derived high Tc cuprates.;Examining every available procedure for synthesizing high-surface-area perovskite oxides, this book: delineates processing techniques for preparing perovskite-derived high-critical-temperature superconductors; illustrates the relevance of physiochemical methods to investigate bulk and surface structures of perovskite compounds; explicates the importance of surface composition in the context of catalytic behaviour; summarizes methods of changing stoichiometry; shows how to design perovskite oxides for a given purpose; reviews key solid-state properties; and presents the major applications.

Historically, technological developments that have made use of the acidity/basicity of solids have often preceded an understanding of the phenomena involved. This, of course, is very expensive, and a far less efficient process than research based on a fundamental understanding of the science. For the last 50 years, therefore, a vast amount of research has been devoted to the subject: the rewards, in terms of technological advantage, were seen to be high. In the last few years, however, significant advances in the field have been achieved, in terms of our theoretical understanding, in instrumentation that allows research to be conducted "in situ" and under conditions appropriate to industrial processes, and in the realization that a closer coupling between science and technology can improve our quest. It is against such a background that "Acidity and Basicity of Solids" presents work in the field. This text should be suitable for specialized workers in the field and university teachers of introductory as well as graduate courses. The more general reader may find the reviews interesting.

This book introduces the principles and techniques of crystal growth by the flux method, which is arguably the most useful way to obtain millimeter- to centimeter-sized single crystals for physical research. As it is possible to find an appropriate solvent ("flux") for nearly all inorganic materials, the flux method can be applied to the growth of many crystals ranging from transition metal oxides to intermetallic compounds. Both important principles and experimental procedures are described in a clear and accessible manner. Practical advice on various aspects of the experiment, which is not readily available in the literature, will assist the beginning graduate students in setting up the lab and conducting successful crystal growth. The mechanisms of crystal growth at an elementary level are also provided to better understand the techniques and to help in assessing the quality of the crystals. The book also contains many photographs of beautiful crystals with important physical properties of current interest, such as high-temperature superconductors, strongly correlated electronic systems, topological insulators, relaxor ferroelectrics, low-dimensional quantum magnets, non-linear optical materials, and multiferroics.

The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students Special offer for all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.

As one of the most recognisable images in science, the periodic table is ingrained in our culture. First drawn up in 1869 by Dmitri Mendeleev, its 118 elements make up not only everything on our planet but also everything in the entire universe. The periodic table looks at the fascinating story and surprising uses of each of those elements, whether solid, liquid or gas. From the little-known uses of gold in medicine to the development of the hydrogen bomb, each entry is accompanied by technical data (category, atomic number, weight, boiling point) presented in easy-to-read headers, and a colour-coding system that helps the reader to navigate through the different groups of elements. A remarkable display of thought-provoking science and beautiful photography, this guide will allow the reader to discover the world afresh.

This book covers the latest progress in the field of transparent ceramics, emphasizing their processing as well as solid-state lasers. It consists of 10 chapters covering the synthesis, characterization and compaction, fundamentals of sintering, densification of transparent ceramics by different methods as well as transparent ceramic applications. This book can be used as a reference for senior undergraduate to postgraduate students, researchers, engineers and material scientists working in solid-state physics.

Troy Townsend's thesis explores the structure, energetics and activity of three inorganic nanocrystal photocatalysts. The goal of this work is to investigate the potential of metal oxide nanocrystals for application in photocatalytic water splitting, which could one day provide us with clean hydrogen fuel derived from water and solar energy. Specifically, Townsend's work addresses the effects of co-catalyst addition to niobium oxide nanotubes for photocatalytic water reduction to hydrogen, and the first use of iron oxide 'rust' in nanocrystal suspensions for oxygen production. In addition, Townsend studies a nickel/oxide-strontium titanate nanocomposite which can be described as one of only four nanoscale water splitting photocatalysts. He also examines the charge transport for this system. Overall, this collection of studies brings relevance to the design of inorganic nanomaterials for photocatalytic water splitting while introducing new directions for solar energy conversion.

Given the recent expansion in materials chemistry, this revised edition of a highly successful book addresses several of the vigorous areas of research in this field where inorganic materials are central to that research. Each chapter provides an introduction to the subject under discussion and then develops the field to provide a sensible overview, with certain topics being expanded. Comments on the First Edition 'This...timely book...covers a wide range of material, using the multi-author format, with the advantage that each chapter is written by an expert in the field...The editors have deliberately used authors who are actively researching the areas they describe, which helps to convey the author's enthusiasm to the reader'-Chemistry in Britain '...the individual reviews are timely, self contained and up-to-date and will be of value to researchers in chemistry, physics and materials science'-Science 'This excellently designed and produced book gives a valuable introduction to inorganic materials chemistry...an interesting, readable and up-to-date account of the present status of this field'-Polymer News