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Books > Science & Mathematics > Chemistry > Inorganic chemistry > General

Mechanochemical Synthesis of Composite Materials (Hardcover): Zulkhair A. Mansurov, Nina N. Mofa, Tlek A. Ketegenov, Bakhtiyar... Mechanochemical Synthesis of Composite Materials (Hardcover)
Zulkhair A. Mansurov, Nina N. Mofa, Tlek A. Ketegenov, Bakhtiyar S. Sadykov
R4,078 Discovery Miles 40 780 Ships in 10 - 15 working days

A stand-alone, monograph present results on mechanochemical synthesis of nanostructured composite materials on the base of inorganic and organic components The book summarizes and systematizes the results of a fundamentally new complex approach to the creation of composite polymer-inorganic systems by mechanochemical treatment, both as a result of the traditional approach with the use of dynamic mills (mechanical reactors) and ultrasonic action on powder mixtures In addition, the book will present a chapter that will focus on the method of mechanochemical preparation of materials for high-energy systems, which are the most promising, since it allows the most productive management of the formation of new structural compositions that increase the energy intensity of the system.

Molecular Design in Inorganic Biochemistry (Hardcover, 2014 ed.): Daniel Rabinovich Molecular Design in Inorganic Biochemistry (Hardcover, 2014 ed.)
Daniel Rabinovich
R5,737 Discovery Miles 57 370 Ships in 18 - 22 working days

Chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors.

Elements Old and New - Discoveries, Developments, Challenges, and Environmental Implications (Hardcover): Mark a. Benvenuto,... Elements Old and New - Discoveries, Developments, Challenges, and Environmental Implications (Hardcover)
Mark a. Benvenuto, Tracy Williamson
R4,020 Discovery Miles 40 200 Ships in 10 - 15 working days

The Periodic Table of the Elements remains a living, growing document that attempts to map out all of the most primal matter known to humankind. This book preserves our current knowledge and understanding of the Periodic Table of the Elements as it exists at this specific moment in time. The heavy elements have recently been verified and named, and thus complete the seventh row of the Periodic Table, with oganesson being the name of the final element, which had formerly been known as Element 118 or Eka-radon. One can say honestly that it is a rare moment in time when a row of the Periodic Table of the Elements is completed.

Synthetic Fluorine Chemistry (Hardcover): GA Olah Synthetic Fluorine Chemistry (Hardcover)
GA Olah
R8,231 Discovery Miles 82 310 Ships in 18 - 22 working days

Leading investigators in their fields present a broad perspective of recent major research trends in synthetic fluorine chemistry. Coverage includes: various aspects of organic and inorganic fluorine chemistry, fluorination methods, organometallic fluorine chemistry and its use in synthesis, the synthesis of perfluoropolyethers (an extraordinary class of new fluorinated compounds) and much more.

Polyoxometalates - Advances, Properties, and Applications (Hardcover): Benat Artetxe, Jose Luis Vilas Vilela, Juan Manuel... Polyoxometalates - Advances, Properties, and Applications (Hardcover)
Benat Artetxe, Jose Luis Vilas Vilela, Juan Manuel Gutierrez-Zorrilla, Leire Ruiz Rubio
R4,067 Discovery Miles 40 670 Ships in 10 - 15 working days

Polyoxometalates are anionic metal-oxo nanoclusters, which constitute a unique class of compounds owing to their rich solution equilibria and their unique compositional, electronic, reactive, and structural diversity. This book reviews metal-oxide cluster chemistry by covering topics ranging from fundamental aspects (i.e., structure, properties, self-assembly processes, derivatization) to functional materials that incorporate these molecular units, as well as their applications in the fields of current socioeconomic interest, such as energy storage systems, catalysis, molecular electronics, and biomedicine. Edited by prominent researchers in the field of polymer and polyoxometalate chemistries, the book compiles contributions from some of the most distinguished and promising scientists worldwide in such a way that it will appeal to a general readership involved in research areas related to chemistry and materials science.

Deuteride Materials (Hardcover, 1st ed. 2019): Jiping Liu, Xiaobo Liu Deuteride Materials (Hardcover, 1st ed. 2019)
Jiping Liu, Xiaobo Liu
R2,910 Discovery Miles 29 100 Ships in 18 - 22 working days

This is the very first book that offers an up-to-date and comprehensive overview on deuteride. It not only includes the concept, existing forms, key characteristics, but also reviews the preparation and characterization technologies and the latest research developments of deuteride. The special properties such as the nuclear properties, isotropic and neutron effect, poisonousness, radioactivity, volume expansion are systematically discussed to build up the sound understanding of the materials. In particular, this work reviews a number of commercial and scientific uses of the materials including nuclear reactors, NMR spectroscopy and medicines. Researchers and industrial professionals in medicine, chemistry, biochemistry, environmental sciences and defense sciences will benefit from this work.

Activated Carbon - Progress and Applications (Hardcover): Chandrabhan Verma, Mumtaz A. Quraishi Activated Carbon - Progress and Applications (Hardcover)
Chandrabhan Verma, Mumtaz A. Quraishi
R4,568 Discovery Miles 45 680 Ships in 18 - 22 working days

Activated carbon has long been used for filtering contaminants, thanks to its large surface area for adsorption. This, and other properties has led to a growing interest in activated carbon and a broader range of applications. This book explores the various forms of activated carbon, detailing how they can be prepared and characterised. The editors bring together a global team of authors from industry and academia. Their contributions include environmental and medical applications, as well as various industries. Future directions are also considered. The editors are at the Interdisciplinary Center for Research in Advanced Materials, King Fahd University of Petroleum and Minerals, Saudi Arabia. They present an up-to-date and comprehensive reference aimed at all career levels in chemistry and materials science, engineering and research across the diverse industries finding a use for activated carbon.

Uranium Dioxide, UO2, Preparation and Crystallographic Properties (Hardcover, 8th ed. 1984): Dieter Vollath Uranium Dioxide, UO2, Preparation and Crystallographic Properties (Hardcover, 8th ed. 1984)
Dieter Vollath; Edited by (editors-in-chief) Rudolf Keim, Cornelius Keller; Horst Wedemeyer
R15,382 Discovery Miles 153 820 Ships in 18 - 22 working days
Transition Metal Oxides - An Introduction to their Electronic Structure and Properties (Paperback, New Ed): P.A. Cox Transition Metal Oxides - An Introduction to their Electronic Structure and Properties (Paperback, New Ed)
P.A. Cox
R2,791 Discovery Miles 27 910 Ships in 10 - 15 working days

Transition metal oxides form a series of compounds with a uniquely wide range of electronic properties. They have important applications as dielectrics,semiconductors, and metals, and as materials for magnetic and optical uses. The recent discovery of `high temperature' superconductors has brought the attention of a wide scientific community to this area and has highlighted the problems involved in trying to understand transition metal oxides. The present book is not primarily about Tc superconductors, although their main properties are discussed in the final sections. The main aim is to describe the varied electronic behaviour shown by transition metal oxides, and to discuss the different types of theoretical model that have been proposed to interpret it. It is intended to provide an introduction to this fascinating and difficult field, at a level suitable for graduate students and other research workers with a background in solid- state chemistry or physics.

Chemistry: The Key to our Sustainable Future (Hardcover, 2014 ed.): Minu Gupta-Bhowon, Sabina Jhaumeer-Laulloo, Henri Li Kam... Chemistry: The Key to our Sustainable Future (Hardcover, 2014 ed.)
Minu Gupta-Bhowon, Sabina Jhaumeer-Laulloo, Henri Li Kam Wah, Ponnadurai Ramasami
R5,946 R4,814 Discovery Miles 48 140 Save R1,132 (19%) Ships in 10 - 15 working days

Chemistry: The Key to our Sustainable Future is a collection of selected contributed papers by participants of the International Conference on Pure and Applied Chemistry (ICPAC 2012) on the theme of "Chemistry: The Key for our Future" held in Mauritius in July 2012. In light of the significant contribution of chemistry to benefit of mankind, this book is a collection of recent results generated from research in chemistry and interdisciplinary areas. It covers topics ranging from nanotechnology, natural product chemistry to analytical and environmental chemistry. Chemistry: The Key to our Sustainable Future is written for graduates, postgraduates, researchers in industry and academia who have an interest in the fields ranging from fundamental to applied chemistry.

Mechanical Behaviour of Metal-Organic Framework Materials (Hardcover): Jin-Chong Tan Mechanical Behaviour of Metal-Organic Framework Materials (Hardcover)
Jin-Chong Tan
R3,170 Discovery Miles 31 700 Ships in 18 - 22 working days

In the first book dedicated to this rapidly expanding research area, Mechanical Behaviour of Metal-Organic Framework Materials, provides a convenient introduction to how chemistry determines structure-mechanical property relationships and functional performance. Much of the research efforts in metal-organic framework (MOF) and hybrid framework materials focus on synthesis and adsorption related properties. But practical applications of MOFs require a precise understanding of mechanical properties and knowledge of structure-property relationships, to ensure robustness in device manufacturing and mechanical resilience for long-term performance. Readers will learn through key experimental and theoretical techniques for studying MOF mechanical properties including elastic and plastic behaviour, framework dynamics, high-pressure response, rate effects, anomalous mechanical behaviour and failure mechanisms. Edited by a pioneer of the field and with contributions by leading researchers developing the new science of "MOF Mechanics", this book is suitable for both students and researchers who are new to the field.

Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells (Paperback): Kenneth... Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells (Paperback)
Kenneth Kam-Wing Lo
R3,102 Discovery Miles 31 020 Ships in 10 - 15 working days

Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells provides a complete overview of this important research area that is perfect for both newcomers and expert researchers in the field. Through concise chapters written and edited by esteemed experts, this book brings together a comprehensive treatment of the area previously only available through scattered, lengthy review articles in the literature. Advanced topics of research are covered, with particular focus on recent advances in the biological applications of transition metal complexes, including inorganic medicine, enzyme inhibitors, antiparasital agents, and biological imaging reagents.

Inorganic Chemistry (Hardcover): Dennis Close Inorganic Chemistry (Hardcover)
Dennis Close
R3,048 R2,764 Discovery Miles 27 640 Save R284 (9%) Ships in 18 - 22 working days
Biomedical Engineering (Hardcover): Akihiro Miyauchi, Yuji Miyahara Biomedical Engineering (Hardcover)
Akihiro Miyauchi, Yuji Miyahara
R3,419 Discovery Miles 34 190 Ships in 10 - 15 working days

Presents cutting-edge research in biomedical engineering from materials, devices, imaging, and information perspectives All chapters are results of collaborative research in engineering and life sciences Useful resource for researchers, students, and general readers in biomedical engineering

Chalcogen Chemistry - Fundamentals and Applications (Hardcover): Vito Lippolis, Claudio Santi, Eder J. Lenardao, Antonio L.... Chalcogen Chemistry - Fundamentals and Applications (Hardcover)
Vito Lippolis, Claudio Santi, Eder J. Lenardao, Antonio L. Braga
R3,987 Discovery Miles 39 870 Ships in 18 - 22 working days

Up until a few decades ago, chalcogen chemistry was mainly represented by the chemistry of sulfur-containing compounds. However, with the rise in research around selenium and tellurium compound chemistry, the field has developed significantly as it continues to uncover and understand the peculiarities chalcogens exhibit. Taking an introductory approach, this book is the foundation to the subject that has been long needed. Covering organic and inorganic synthesis, structural properties, coordination chemistry and computational modelling, all key classes of chalcogen compounds are illustrated. Applications across materials science, biology, pharmaceutical science and environmental topics highlight to readers the impact of chalcogen chemistry in many aspects of research. Edited by international leaders in the field, Chalcogen Chemistry brings together contributions from acclaimed researchers around the world. This book is ideal for newcomers and established researchers, and provides the first building block to uncovering this fascinating field.

Handbook on the Physics and Chemistry of Rare Earths, Volume 49 - Including Actinides (Hardcover): Jean-Claude G. Bunzli,... Handbook on the Physics and Chemistry of Rare Earths, Volume 49 - Including Actinides (Hardcover)
Jean-Claude G. Bunzli, Vitalij K Pecharsky
R5,660 Discovery Miles 56 600 Ships in 10 - 15 working days

Handbook on the Physics and Chemistry of Rare Earths is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science, and physics. The book's main emphasis is on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but whenever relevant, information is also included on the closely related actinide elements. Individual chapters are comprehensive, broad, up-to-date critical reviews written by highly experienced, invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines and integrates both the fundamentals and applications of these elements and publishes two volumes a year.

Unusual Structures & Physical Properties in Organometallic Chemistry (Hardcover): M. Gielen Unusual Structures & Physical Properties in Organometallic Chemistry (Hardcover)
M. Gielen
R11,426 Discovery Miles 114 260 Ships in 18 - 22 working days

The principal idea of this volume is to offer a Capita Selecta of unconventional and thought-provoking topics in organometallic chemistry, presented by experts in each field. As intended, this approach leads either to reviews covering a specific uncommon class of organometallic compounds or to overviews which relate uncommon physical properties with various classes of organometallic compounds. The contributions are streamlined thus onto two main axes - unusual properties reflecting structures and bonding situations, on the one hand, and uncommon structural features or structure-reactivity relationships, on the other. Extensive cross-referencing of useful information is provided, making this volume accessible for people working in rather different areas of organometallic chemistry.

The synthesis of molecules with 'extreme' properties is a challenge for all those working in organometallic chemistry, irrelevant of theoretical/computational, synthetic or application interests. This book presents case studies at the interface of these overlapping interests.

Unusual Structures and Physical Properties in Organometallic Chemistry:

  • Provides test cases for computational and theoretical models
  • Presents a challenge for synthetic chemists
  • Provides ideal show cases for analytical techniques
This volume will be an invaluable reference for researchers in organometallic chemistry, computational and theoretical chemistry, NMR and other spectroscopic methods.
Biobased Materials - Recent Developments and Industrial Applications (Hardcover, 1st ed. 2023): Ajay Kumar Mishra, Chaudhery... Biobased Materials - Recent Developments and Industrial Applications (Hardcover, 1st ed. 2023)
Ajay Kumar Mishra, Chaudhery Mustansar Hussain
R2,687 Discovery Miles 26 870 Ships in 18 - 22 working days

This book discusses the extraction, purification, modification, and processing of biobased materials and their various industrial applications, across biomedical, pharmaceutical, construction, and other industries. It includes contributions from experts on hybrid biopolymers and bio-composites, bioactive and biodegradable materials, bio-inert polymers, natural polymers and composites, and metallic natural materials. Therefore, this encyclopedia is a useful reference for scientists, academicians, research scholars, and technologists. Major challenges of biobased materials are their efficient development, cost-effective, and green & environment friendly production/applications. This encyclopedia answers these challenges to professionals and scientists for proper utilization of biobased materials. It presents the recent practices of biobased materials technology in different scientific and engineering domains. It helps the bounded industrial outcomes to reach the general readership of different domains. This encyclopedia bridges the technological gaps between the industrial and academic professionals and the novice young students/scholars. The interdisciplinarity of this encyclopedia makes it unique for a wide readership. The topic of biobased materials is currently popular in the scientific community, working in such following areas as Recycled materials, Renewable materials, Materials for efficiency, Materials for waste treatment, Materials for reduction of environmental load, Materials for easy disposal or recycle, Hazardous free materials, Materials for reducing human health impact, Materials for energy efficiency, Materials for green energy, etc. This is a relatively hot topic in materials science and has strong demands for energy, material and money savings, as well as heavy contamination problems, despite that the area of biobased materials belongs to most important fields of modern science & technology, no important encyclopedias have been published in the area of "biobased materials"

Photonic and Electronic Properties of Fluoride Materials - Progress in Fluorine Science Series (Hardcover): Alain Tressaud,... Photonic and Electronic Properties of Fluoride Materials - Progress in Fluorine Science Series (Hardcover)
Alain Tressaud, Kenneth R. Poeppelmeier
R3,549 Discovery Miles 35 490 Ships in 10 - 15 working days

Photonic and Electronic Properties of Fluoride Materials: Progress in Fluorine Science, the first volume in this new Elsevier series, provides an overview of the important optical, magnetic, and non-linear properties of fluoride materials. Beginning with a brief review of relevant synthesis methods from single crystals to nanopowders, this volume offers valuable insight for inorganic chemistry and materials science researchers. Edited and written by leaders in the field, this book explores the practical aspects of working with these materials, presenting a large number of examples from inorganic fluorides in which the type of bonding occurring between fluorine and transition metals (either d- or 4f-series) give rise to peculiar properties in many fundamental and applicative domains. This one-of-a-kind resource also includes several chapters covering functional organic fluorides used in nano-electronics, in particular in liquid crystal devices, in organic light-emitting diodes, or in organic dyes for sensitized solar cells. The book describes major advances and breakthroughs achieved by the use of fluoride materials in important domains such as superconductivity, luminescence, laser properties, multiferroism, transport properties, and more recently, in fluoro-perovskite for dye-sensitized solar cells and inorganic fluoride materials for NLO, and supports future development in these varied and key areas. The book is edited by Alain Tressaud, past chair and founder of the CNRS French Fluorine Network. Each book in the collection includes the work of highly-respected volume editors and contributors from both academia and industry to bring valuable and varied content to this active field.

Physical Chemistry of Natural Waters (Hardcover): F.J. Millero Physical Chemistry of Natural Waters (Hardcover)
F.J. Millero
R6,329 Discovery Miles 63 290 Ships in 18 - 22 working days

An in-depth discussion of the thermodynamics and kinetics of natural waters

Divided into three major parts–structure of matter, chemical thermodynamics, and chemical kinetics– physical chemistry is concerned with the measurement, description, and prediction of the characteristics of chemical systems and their interaction with each other with respect to the transfer of mass and energy. Physical Chemistry of Natural Waters explores how the basic concepts of physical chemistry can be used to understand the chemistry of natural waters, with most of the text confined to chemical thermodynamics and kinetics.

The extensive material in this book is the result of a course in marine physical chemistry that the author has taught over the past decade. Dr. Millero incorporates his own personal interest in solution physical chemistry and his approach to understanding the physical chemistry of seawater with the text’s vast coverage of the physical chemistry of liquid phases. In addition, detailed reviews of the basics of thermodynamics and kinetics provide a comprehensive overview for a clearer understanding of the topics covered.

Environmental and physical chemists conducting research on water, seawater, rivers, lakes, and groundwater as well as graduate students studying environmental chemistry will find Physical Chemistry of Natural Waters a solid foundation on the subject of the physical chemistry of natural waters.

Molecular Clusters - A Bridge to Solid-State Chemistry (Hardcover): Thomas Fehlner, Jean-Francois Halet, Jean-Yves Saillard Molecular Clusters - A Bridge to Solid-State Chemistry (Hardcover)
Thomas Fehlner, Jean-Francois Halet, Jean-Yves Saillard
R3,929 Discovery Miles 39 290 Ships in 10 - 15 working days

Clusters can be viewed as solids at the nano-scale, yet molecular cluster chemistry and solid state chemistry have traditionally been considered as separate topics. This treatment has made it conceptually difficult to appreciate commonalities of structure and bonding between the two. Using analogous models, this is the first book to form a connecting bridge. Although the focus is on clusters, sufficient attention is paid to solid-state compounds at each stage of the development to establish the interrelationship between the two topics. Comprehensive coverage of cluster types by composition, size and ligation, is provided, as is a synopsis of selected research. Written in an accessible style and highly illustrated to aid understanding, this book is suitable for researchers in inorganic chemistry, physical chemistry, materials science, and condensed matter physics.

Handbook of Isotopes in the Cosmos - Hydrogen to Gallium (Paperback): Donald Clayton Handbook of Isotopes in the Cosmos - Hydrogen to Gallium (Paperback)
Donald Clayton
R2,409 Discovery Miles 24 090 Ships in 10 - 15 working days

Each naturally occurring isotope has a tale to tell about the history of matter, and each has its own special place in cosmic evolution. This volume aims to grasp the origins of our material world by looking at the abundance of the elements and their isotopes, and how this is interpreted within the theory of nucleosynthesis. Each isotope of elements from Hydrogen to Gallium is covered in detail. For each, there is an historical and chemical introduction, and a table of those isotopes that are abundant in the natural world. Information given on each isotope includes its nuclear properties, solar system abundance, nucleosynthesis in stars, astronomical observations, and isotopic anomalies in premolar grains and solar-system solids. The book is suitable for astronomers, physicists, chemists, geologists and planetary scientists, and contains a glossary of essential technical terms.

Spectral Methods in Transition Metal Complexes (Paperback): K. Sridharan Spectral Methods in Transition Metal Complexes (Paperback)
K. Sridharan
R1,286 Discovery Miles 12 860 Ships in 10 - 15 working days

Spectral Methods in Transition Metal Complexes provides a conceptual understanding on how to interpret the optical UV-vis, vibrational EPR, and NMR spectroscopy of transition metal complexes. Metal complexes have broad applications across chemistry in the areas of drug discovery, such as anticancer drugs, sensors, special materials for specific requirements, and catalysis, so a thorough knowledge in preparation and characterization of metal complexes, while niche, is critical. Accessible to both the seasoned researcher and the graduate student alike, this book provides readers with a single source of content that addresses spectral methods in transition metal complexes.

Global Atmospheric Phenomena Involving Water - Water Circulation, Atmospheric Electricity, and the Greenhouse Effect... Global Atmospheric Phenomena Involving Water - Water Circulation, Atmospheric Electricity, and the Greenhouse Effect (Hardcover, 1st ed. 2020)
Boris M. Smirnov
R2,665 Discovery Miles 26 650 Ships in 18 - 22 working days

This book covers the role of water in global atmospheric phenomena, focussing on the physical processes involving water molecules and water microparticles. It presents the reader with a detailed look at some of the most important types of global atmospheric phenomena involving water, such as water circulation, atmospheric electricity and the greenhouse effect. Beginning with the cycle of water evaporation and condensation, and the important roles played by the nucleation and growth processes of water microdroplets, the book discusses atmospheric electricity as a secondary phenomenon of water circulation in the atmosphere, comprising a chain of processes involving water molecules and water microdroplets. Finally, the book discusses aspects of the molecular spectroscopy of greenhouse atmospheric components, showing how water molecules and water microdroplets give the main contribution to atmospheric emission in the infrared spectrum range. Featuring numerous didactic schematics and appendices detailing all necessary unit conversion factors, this book is useful to both active researchers and doctoral students working in the fields of atmospheric physics, climate science and molecular spectroscopy.

Early Transition Metal Clusters with Pi-Donor Ligands (Hardcover): MH Chisholm Early Transition Metal Clusters with Pi-Donor Ligands (Hardcover)
MH Chisholm
R8,193 Discovery Miles 81 930 Ships in 18 - 22 working days

The discovery and evolution of oranometallic cluster chemistry is a major event in the development of inorganic chemistry. This is the second volume in the series 'The Chemistry of Metal Clusters' edited by Du Shriver, Herb Kaesz, and Richard Adams.
This volume focuses on the chemistry of the early transition elements in their lower and middle oxidation states, i.e., halide, sulfide, oxide, phosphate, alkoxide, and related o-donor ligands. The key feature linking all these complexes in metal-metal bonding is the presence of pi-donor ligands.

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