This volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species involved in catalytic oxidations. The series contains critical reviews of the present position and future trends, and short and concise reports written by the world's renowned experts.

The field of atomic clusters continues to attract great interest amongst physicists and chemists alike. This is in part due to their intrinsic properties and potential industrial applications. The first part of Binary Clusters is devoted to recent developments in experimental techniques, the second part covers a variety of theoretical approaches. Different theoretical methods based on group/graph theories and quantum chemical computational methods as well as various spectroscopy techniques (such as mass, laser, infrared, photoelectron etc.) are applied to the determination of the existence of geometrical and electronic structures, chemical bonding phenomena, and the thermodynamic stabilities of several classes of binary clusters. All chapters within this review volume have been contributed by experts in chemistry, physics, and material sciences based at the University of Leuven, Belgium. This book is aimed at professionals and students working in cluster science.

This book describes a series of research topics investigated during the 6 years from 2010 through 2015 in the project "Advanced Materials Development and Integration of Novel Structured Metallic and Inorganic Materials". Every section of the book is aimed at understanding the most advanced research by describing details starting with the fundamentals as often as possible. Because both fundamental and cutting-edge topics are contained in this book, it provides a great deal of useful information for chemists as well as for materials scientists and engineers who wish to consider future prospects and innovations. The contents of Novel Structured Metallic and Inorganic Materials are unique in materials science and technology. The project was carried out through the cooperation of research groups in the following six institutes in Japan: the Institute for Materials Research (IMR), Tohoku University; the Materials and Structures Laboratory (MSL), Tokyo Institute of Technology; the Joining and Welding Research Institute (JWRI), Osaka University; the Eco-Topia Science Institute (EST), Nagoya University; the Institute of Biomaterials and Bioengineering (IBB), Tokyo Medical and Dental University; and the Institute for Nanoscience and Nanotechnology (INN), Waseda University. Major objectives of the project included creation of advanced metallic and inorganic materials with a novel structure, as well as development of materials-joining technologies for development of cutting-edge applications as environmental and energy materials, biomedical materials, and electronic materials for contributing to the creation of a safer and more secure society.

Magnetic nanocatalysts are garnering attention for development of greener catalytic processes due to their ease of recovery from a reaction medium. This book delves into a variety of magnetic nanocatalysts, their use in the industrial context, and recyclability. Topics covered include wastewater treatment, drug delivery, and industrial catalysis; another available volume focuses on the use of magnetic nanocatalysts in synthetic appliances and transformations.

This volume of the Handbook illustrates the rich variety of topics covered by rare earth science. Three chapters are devoted to the description of solid state compounds: skutterudites (Chapter 211), rare earth -antimony systems (Chapter 212), and rare earth-manganese perovskites (Chapter 214). Two other reviews deal with solid state properties: one contribution includes information on existing thermodynamic data of lanthanide trihalides (Chapter 213) while the other one describes optical properties of rare earth compounds under pressure (Chapter 217). Finally, two chapters focus on solution chemistry. The state of the art in unraveling solution structure of lanthanide-containing coordination compounds by paramagnetic nuclear magnetic resonance is outlined in Chapter 215. The potential of time-resolved, laser-induced emission spectroscopy for the analysis of lanthanide and actinide solutions is presented and critically discussed in Chapter 216.

Spectrophotometry enables one to determine, with good precision and sensitivity, almost all the elements present in small and trace quantities of any material. The method is particularly useful in the determination of non-metals and allows the determination elements in a large range of concentrations (from single % to low ppm levels) in various materials.

In "Separation, Preconcentration and Spectrophotometry in Inorganic Analysis," much attention has been paid to separation and preconcentration methods, since they play an essential role in increasing the selectivity and sensitivity of spectrophotometric methods. Separation and preconcentration methods have also been utilised in other determination techniques.

Spectrophotometric methods which are widely used for the determination of the elements in a large variety of inorganic materials are presented in the book whilst separation and preconcentration procedures combined with spectrophotometry are also described.

This book contains recent advances in spectrophotometry, detailed discussion of the instrumentation, and the techniques and reagents used for spectrophotometric determination of elements in a wide range of materials as well as a detailed discussion of separation and preconcentration procedures that precede the spectrophotometric detection.

Lead-based paint has become a national issue and will continue to be a hi- priority focus ofnational, state, and local agencies until there is no lead-based paint in the United States. Lead-based paint has become a tremendous health hazard for people and animals. Lead-based paint has been in widespread use throughout Europe and the United States. Lead has been known to be a health hazard since the time ofPliny the Elder (A. D. 23-79), but it was deemed that the advantages of lead in paint outweighed the health hazards. There has been a change in outlook, and in 1973 the U. S. Congress banned all lead paint from residential structures. A voluminous number of law suits have been initiated since, and continue to be litigated with the purpose of determining the parties responsible for the lead poisoning of children and others and to exact the indemnities. Lead-based paint is still authorized for use on bridges and nonresidential structures, and thousands of city, state, military, and federal government housing projects still contain lead-based paint. This paint must be removed if these dwellings are to be safe living quarters, especially for children. Aba- ment techniques continue to be evaluated; some have been used successfully. Lead-based paint abatement will continue into the next century, and it is hoped that this comprehensive volume will serve as a guide for those seriously interested in this important subject.

Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.

Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.

This book presents an original investigation into alternative photovoltaic absorbers. Solar power is a highly promising renewable energy solution; however, its success is hampered by the limited cost-effectiveness of current devices. The book assesses the photovoltaic performance of over 20 materials using state-of-the-art, first-principles methods. Adopting a computational approach, it investigates atomic-scale properties at a level of accuracy that is difficult to achieve using laboratory-based experimental techniques. Unlike many theoretical studies, it provides specific advice to those involved in experimental investigations. Further, it proposes directions for future research. This book advances the field of photovoltaics in three crucial ways: firstly, it identifies why one class of proposed materials cannot achieve high efficiency, while at the same time gaining insights that can be used to design future absorbers. Secondly, it shows that poor performance in the bismuth chalcohalides is not due to fundamental limitations, and can be overcome by finely controlling synthesis conditions. Lastly, it describes a range of new stable materials that are expected to show excellent photovoltaic performance.

This book introduces readers to the preparation of two-dimensional metal sulfide/oxide for CO2 photoreduction. Based on two-dimensional metal sulfide/oxide materials, this book establishes the structure-to-property relationships of photocatalyst for CO2 photoreduction, and reveals the intrinsic mechanism of the CO2 photoreduction by virtue of the in situ characterization techniques and the density functional theory calculations. It is anticipated that this book will help to identify empirical guidelines for designing and fabricating high-performance catalysts of solar-driven CO2 reduction.

During the past 30 years materials science has developed into a full-fledged field for basic and applied scientific enquiry. Indeed, materials scientists have devoted their efforts to creating new materials with improved electronic, magnetic, thermal, mechanical, and optical properties. Often unnoticed, these new materials are rapidly invading our homes and automobiles, and may be found in our utensils, electronic equipment, textiles, home appliances, and electric motors. Even though they may go unnoticed, these new materials have either improved the efficiency and lifetime of these items or have reduced their weight or cost. In particular, magnetically ordered materials are useful in various applications, such as motors, magnetic imaging, magnetic recording, and magnetic levitation. Hence, much effort has been devoted to the development of better hard magnetic materials, magnetic thin films, and molecular magnets. During the same period of time, Mossbauer-effect spectroscopy has grown from a laboratory curiosity to a mature spectroscopic technique, a technique that probes solid-state materials at specific atomic sites and yields microscopic information on the magnetic and electronic properties of these materials. Iron-57 is the most commonly and easily used Mossbauer-effect isotope and, of course, is particularly relevant for the study of magnetic materials. Various applications of Mossbauer spectroscopy to magnetic materials are discussed in the first six chapters of this volume. Other isotopes such as zinc-67 and gadolinium-ISS have recently been used to study the electronic properties of zinc compounds and the electronic and magnetic properties of rare-earth transition metal compounds.

Phosphate Fibers is a singular detailed account of the discovery, chemistry, synthesis, properties, manufacture, toxicology, and uses of calcium and sodium calcium polyphosphate fibers. Author Edward J. Griffith-the inventor and developer of this safe, biodegradable material-takes a multidisciplinary approach to this subject, considering the social, legal, medical, and industrial issues surrounding the use of asbestos and other mineral fibers. This compelling study is a beneficial resource to both readers interested in mineral fibers as well as those who want to understand the complexities of bringing new substances into the modern marketplace.

Contemporary Aspects of Boron: Chemistry and Biological Applications highlights the biological activity and applications of boron containing compounds. The authors specific approach surveys general features of the subject, while exploring new and novel strategies for preparing certain chemical and natural boron products that are of significant substance in medicinal chemistry. For example, cancer treatment is one of the most important issues related to such products. In addition to contributing to the development of new drugs by addressing biological applications in medicinal and industrial fields, the book provides a comprehensive review of the most relevant components that comprise the pharmaceutical, medicinal and environmental applications of boron containing compounds.
* Timely and comprehensive
* Provides new insights to active researchers in the field
* Presents concepts and methods in simple scientific terms

This collection addresses new research and technology for increased efficiency, energy reduction, and waste minimization in mineral processing, extractive metallurgy, and recycling. Professor Patrick R. Taylor and his students have been studying these topics for the past 45 years. Chapters include new directions in:* Mineral Processing * Hydrometallurgy * Pyrometallurgy * Electrometallurgy * Metals and E waste recycling * Waste minimization (including by-product recovery) * Innovations in metallurgical engineering education and curriculum development

The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant.
The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors.
Readership: research scientists at universities or in industry, graduate students
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For all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.

Boron-Doped Diamond Electrodes for Electroorganic Chemistry, by Siegfried R. Waldvogel, Stamo Mentizi und Axel Kirste.- Modern Developments in Aryl Radical Chemistry, by Gerald Pratsch und Markus R. Heinrich.- Radical Additions to Chiral Hydrazones: Stereoselectivity and Functional Group Compatibility, by Gregory K. Friestad.- Hydrogen Atom Donors: Recent Developments, by Andreas Gansauer, Lei Shi, Matthias Otte, Inga Huth, Antonio Rosales, Iris Sancho-Sanz, Natalia M. Padial und J. Enrique Oltra.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? - A Fruitful Interplay Anyway Part 1. Radical Catalysis by Group 4 to Group 7 Elements, by Ullrich Jahn.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? - A Fruitful Interplay Anyway Part 2. Radical Catalysis by Group 8 and 9 Elements, by Ullrich Jahn.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?: A Fruitful Interplay Anyway Part 3: Catalysis by Group 10 and 11 Elements and Bimetallic Catalysis, by Ullrich Jahn.-"

Using potassium as an example, this work presents a unique approach to the anomalous effects in metals, resulting in knowledge that can be applied to similar materials.
Most theoretical predictions on the electric, magnetic, optical, and thermal properties of a simple metal do - surprisingly - not agree with experimental behavior found in alkali metals. The purpose of this volume is to document the many phenomena that have violated expectations. It collects in one place the research by Albert Overhauser, one of the pioneers of the field. His and his collaborators work has led to a unified synthesis of alkali metal peculiarities. The unique collection of 65 reprint papers, commented where necessary to explain the context and perspective, is preceded by a thorough and well paced introduction.
The book is meant to advanced solid state physics and science historians.
It might also serve as additional reading in advanced solid state physics courses.
With a foreword by Mildred and Gene Dresselhaus

Almost all contemporary organic synthesis involve transition metal complexes as catalysts or particular reagents. The aim of this book is to provide the reader with detailed accounts of elementary processes within molecular catalysis to allow its development and as an aid in designing novel catalytic systems. The book comprises authoritative reviews on elementary processes from experts working at the forefront of organometallic chemistry.
.This is the first book that focuses on elementary processes in transition metal complexes for understanding catalytic mechanisms
.Provides detailed description of elementary processes involved in catalytic cycles by experts in the field
.Provides an overview of the mechanisms of various homogeneous catalyses

The. first edition of this work appeared almost thirty years ago, when, as we can see in retrospect, the study of the actinide elements was in its first bloom. Although the broad features of the chemistry of the actinide elements were by then quite weil delineated, the treatment of the subject in the first edition was of necessity largely descriptive in nature. A detailed understanding ofthe chemical consequences of the characteristic presence of 5f electrons in most of the members ofthe actinide se ries was still for the future, and many ofthe systematic features ofthe actinide elements were only dimly apprehended. In the past thirty years all this has changed. The application of new spectroscopic techniques, which came into general use during this period, and new theoretical insights, which came from a better understanding of chemical bonding, inorganic chemistry, and solid state phenomena, were among the important factors that led to a great expansion and maturation in actinide element research and a large number of new and important findings. The first edition consisted of aserial description of the individual actinide elements, with a single chapter devoted to the six heaviest elements (lawrencium, the heaviest actinide, was yet to be discovered). Less than 15 % of the text was devoted to a consideration of the systematics of the actinide elements.

This collection explores state-of-the-art methods and protocols for research on photodynamic therapy (PDT) and its use in a wide range of medical applications, from antiviral to anticancer. Beginning with an extensive section on in vitro and in vivo models, the volume continues with chapters on oxygen-independent photosensitizers, next-generation photosensitization strategies, contemporary insights into the immunomodulatory effects of PDT, antimicrobial effects of PDT, as well as a variety of general biochemical and molecular biological techniques. Written for the highly successful Methods in Molecular Biology series, chapters include the kind of detailed implementation advice that ensures successful results in the lab. Thorough and authoritative, Photodynamic Therapy: Methods and Protocols serves as an ideal source of inspiration for both new and established PDT scientists and a guide for designing innovative research programs in this continuously advancing and multidisciplinary field.

The current volume includes articles on the elementary processes in nonsymmetric collisions of inert gas atoms, the parameters of gaseous dimers, and the physical properties of strongly coupled plasmas.

Xiao-Ming Jiang, Sheng-Ping Guo, Hui-Yi Zeng, Ming-Jian Zhang, Guo-Cong Guo: Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials.- Kechen Wu: Simulation and Design of Infrared Second-Order Nonlinear Optical Materials in Metal Cluster Compounds.- Chaoyang Tu: The Recent Development Of SRS and SRS SF- conversion Laser Crystal.- Hua-Jun Zhao, Xin-Tao Wu, Li-Ming Wu: Exploration of New Second-Order Nonlinear Optical Compounds Containing Main Group Elements.

KrAtschmer and Huffman's revolutionary discovery of a new solid phase of carbon, solid C60, in 1990 opened the way to an entire new class of materials with physical properties so diverse that their richness has not yet been fully exploited. Moreover, as a by-product of fullerene research, carbon nanotubes were later identified, from which novel nanostructures originated that are currently fascinating materials scientists worldwide. Rivers of words have been written on both fullerenes and nanotubes, in the form of journal articles, conference proceedings and books. The present book offers, in a concise and self-contained manner, the basics of the science of these materials as well as detailed information on those aspects that have so far been better explored. Structural, electronic and dynamical properties are described as obtained from various measurements and state-of-the-art calculations. Their interrelation emerges as well as their possible dependence on, for example, preparation conditions or methods of investigation. By presenting and comparing data from different sources, experiment and theory, this book helps the reader to rapidly master the basic knowledge, to grasp important issues and critically discuss them. Ultimately, it aims to inspire him or her to find novel ways to approach still open questions. As such, this book is addressed to new researchers in the field as well as experts.

1 Oxford and Webster's dictionaries,2 give trans-Atlantic agreement in English with a common definition for 'Quality' as 'degree of excellence'. Compared with the many words taken up by other authors' definitions, this is remarkably brief and no doubt unsatisfactory to many people. Yet if 'degree' means a stage in an ascending or descending series, in intensity or in amount, then measurement is by definition explicitly required if terms such as 'quality level', 'good quality', 'high quality' etc. are to have any real meaning. Using measurement is inherent in the methods of all the major writers on the achievement of business improvement through quality. Results from measurements allow improvement by using tools commonly grouped under the heading Statistical Process Control (SPC). Results also form part of the judging criteria of Total Quality Management (TQM) models such as the Malcolm Baldrige National Quality Award in the USA and the more recent European Quality Award. Future revisions of the ISO 9000 series of quality management system standards will specifically require measure ment of defects. However, it is not easy for quality professionals or line managers to find examples of what they should measure and how to do it in their own particular functions in their own particular industries; case st\}dies always seem to refer to others."