This volume collects the contributions to the NATO Advanced Study Institute (ASI); "Computer Simulation in Materials Science -NanolMesolMacroscopic Space and Time Scales", held on lIe d'OIeron (France) June 6-16, 1995.1his event was intended to present the state of the art in simulation techniques in Materials Science. For decades to come the limits of computing power will not allow for atomistic simulations of macroscopic specimens. Simulations can only be performed on various scales (nano, meso, micro, macro) with the constitutive input provided by simulations (or data) on the next smaller scale. The resulting hierarchy has been the main topic of many of lectures and seminars. Necessarily, special emphasis was placed on mesoscopic simulations bridging the gaps between nano (atomic) and micro space and time scales. During the ASI, lecturers and participants did not only consider fundamental problems, but also applications. Papers on the evolution of morphological patterns in phase transformations and plastic deformation, irradiation effects, mass transport and mechanical properties of materials in general, highlighted what has already been achieved. It was concluded that computer simulations must be based on realistic and efficient models, the fundamental equations controlling the dynamical evolution of microstructures, stochastic field kinetic models being a case in point.

The attractive physical and mechanical properties of ordered intermetallic alloys have been recognized since early in this century. However, periodic attempts to develop intermetallics for structural applications were unsuc cessful, due in major part to the twin handicaps of inadequate low-temper ature ductility or toughness, together with poor elevated-temperature creep strength. The discovery, in 1979, by Aoki and Izumi in Japan that small additions of boron caused a dramatic improvement in the ductility of Ni3Al was a major factor in launching a new wave of fundamental and applied research on intermetallics. Another important factor was the issuance in 1984 of a National Materials Advisory Board reported entitled "Structural Uses for Ductile Ordered Alloys," which identified numerous potential defense-related applications and proposed the launching of a coordinated development program to gather engineering property and processing data. A substantial research effort on titanium aluminides was already underway at the Air Force Materials Laboratory at Wright Patterson Air Force Base in Ohio and, with Air Force support, at several industrial and university laboratories. Smaller programs also were under way at Oak Ridge National Laboratory, under Department of Energy sponsorship. These research efforts were soon augmented in the United States by funding from Department of Defense agencies such as Office of Naval Research and Air Force Office of Scientific Research, and by the National Science Foundation."

This volume records the proceedings of an international symposium on "ME CHANICS OF SHEET METAL FORMING: Material Behavior and Deformation Analysis." It was sponsored and held at the General Motors Research Labora tories on October 17-18, 1977. This symposium was the twenty-first in an annual series. The objective of this symposium was to discuss the research frontiers in experimental and theoretical methods of sheet metal forming analysis and, also, to determine directions of future research to advance technology that would be useful in metal stamping plants. Metal deformation analyses which provide guide lines for metal flanging are already in use. Moreover, recent advances in computer techniques for solving plastic flow equations and in measurements of material parameters are leading to dynamic models of many stamping operations. These models would accurately predict the stresses and strains in the sheet as a function of punch travel. They would provide the engineer with the knowledge he needs to improve die designs. The symposium papers were organized into five sessions: the state of the art, constitutive relations of sheet metal, role of friction, sheet metal formability, and deformation analysis of stamping operations. We believe this volume not only summarizes the various viewpoints at the time of the symposium, but also pro vides an outlook for materials and mechanics research in the future.

In this vivid and comprehensible introduction to materials science, the author expands the modern concepts of metal physics to formulate basic theory applicable to other engineering materials, such as ceramics and polymers. Written for engineering students and working engineers with little previous knowledge of solid-state physics, this textbook enables the reader to study more specialized and fundamental literature of materials science. Dozens of illustrative photographs, many of them transmission electron microscopy images, plus line drawings, aid developing a firm appreciation of this complex topic. Hard-to-grasp terms such as "textures" are lucidly explained - not only the phenomenon itself, but also its consequences for the material properties. This excellent book makes materials science more transparent.

The scientific understanding of high-velocity deformation has advanced substantially during the past decade. On the one hand, the framework for a theory explaining the metallurgical effects of shock waves is beginning to take shape; on the other hand, the technological applications of high strain-rate processes have found their way into industries in countries around the world. Ex plosive cladding, welding, forming, compaction and consolidation, cutting, and hardening, in addition to high energy-rate deformation processes using other energy sources, are some of the topics of contemporary technological importance. Metallurgical effects are of the utmost importance in both the scientific understanding of the phenomena involved, and in the successful development and utilization of the associated applications. The international conference upon which this book is based had as its major objectives the acceleration of progress in the field of high-strain rate deformation and fabrication, including applications, by providing a forum for the exchange of state-of-the art information on the metallurgical effects of high strain-rate deformation and fabrication; and the organization of this informa tion into a timely and coherent body of knowledge focused around significant areas and applications. This volume is a manifestation of these objectives. In addition, the contents of this book were organized to provide for a somewhat logical perspective of the fundamentals, development, and state-of-the-art applications of high strain-rate and shock phenomena."

Corrosion due to water is one of the most significant and complex causes of damage to metallic products. Written from the viewpoint of physical chemistry, this authoritative and established text deals with the aqueous corrosion of metals. Available for the first time in English, Corrosion of Metal addressing engineers, metallurgists, physicists and chemists. This self-contained, valuable reference comprehensively organizes and makes readily accessible the accumulated wealth of fundamental and applied knowledge. The concentration is on the underlying essentials of corrosion and failure, and the material is consistently presented in relation to practical applications to corrosion protection. The first chapters introducing the physicochemical principles are ideal for students. The following chapters provide an overview of the state of research for those familiar with the fundamentals. An exhaustive bibliography and appendices conclude the volume.

Basic research and new manufacturing methods have led to high nitrogen steels (HNS), a promising new group of materials for use in advanced applications in mechanical and chemical engineering. The book deals with the atomic structure, constitution, properties, manufacturing and application of martensitic, austenitic, duplex and dualphase steels of superior strength and corrosion resistance. Combining metallurgy and engineering aspects. It gives a detailed overview and presents new results on HNS. The book is intended for scientists as well as technologists, who will find stimulating information.

Crystal growth, casting, soldering, welding, high-energy surface treatment, nuclear safety systems and geophysical flows are just a few examples where solidification and convection occur together. These processes are interactive on micro- and macroscales: flow affects the distribution of heat and species and hence the freezing process, while solidification evolves flow boundaries, as in crusting, for example, and hence can radically alter the convection. Mathematical modellers, experimentalists and applied scientists were invited to this colloquium with the aim of consolidating our understanding of such interactions, of identifying key outstanding issues, and of developing new approaches in this important area of fundamental research. Both invited and contributed papers focus on both fundamental and technologically relevant problems.

The classical, phenomenological theory of plastically anisotropic materials has passed a long way: from the work of von Mises presented in 1928, and the HilI formulation given in 1948, to the latest papers on large elastic-plastic deformations of anisotropic metal sheets. A characteristic feature of this approach is a linear flow rule and a quadratic yield criterion. Mathematical simplicity of the theory is a reason of its numerous applications to the analysis of engineering structures during the onset of plastic deformations. However, such an approach is not sufficient for description of the metal forming processes, when a metal element undergoes very large plastic strains. If we take an initially isotropic piece of metal, it becomes plastically anisotropic during the forming process, and the induced anisotropy progressively increases. This fact strongly determines directions of plastic flow, and it leads to an unexpected strain localization in sheet elements. To explain the above, it is necessary to take into account a polycrystalline structure of the metal, plastic slips on slip systems of grains, crystallographic lattice rotations, and at last, a formation of textures and their evolution during the whole deformation process. In short, it is necessary to introduce the plasticity of crystals and polycrystals. The polycrystal analysis shows that, when the advanced plastic strains take place, some privileged crystallographic directions, called a crystallographic texture, occur in the material. The texture formation and evolution are a primary reason for the induced plastic anisotropy in pure metals.

Little do we reliably know about the Mott transition, and we are far from a complete understanding of the metal --insulator transition due to electr- electron interactions. Mott summarized his basic ideas on the subject in his wonderful book Metal--Insulator nansitions that first appeared in 1974 11. 1). In his view, a Motk insulator displays a gap for charge-carrying excitations due to electron cowelations, whose importance is expressed by the presence of local magnetic moments regardless of whether or not they are ordered. Since the subject is far from being settled, different opinions on specific aspects of the Mott transition still persist. This book naturally embodies my own understanding of the phenomenon, inspired by the work of the late Sir Kevill Mott. The purpose of this book is twofold: first, to give a detailed presen- tion of the basic theoretical concopts for Mott insulators and, second, to test these ideas against the results from model calculations. For this purpose the Hubbard model and some of its derivatives are best suited. The Hubbard model describes a Mott transition with a mere minimum of tunable par- eters, and various exact statements and even exact solutions exist in certain limiting cases. Exact solutions not only allow us to test our basic ideas, but also help to assess the quality of approxin ate theories for correlated electron systems.

The present monograph is mainly focused on the behaviour of ductile ma terials at cryogenic temperatures, stability issues concerning application of corrugated shells at cryogenic conditions and reliability oriented parametric optimisation of compensation systems containing the corrugated bellows. As there are relatively few publications on combined material and structural be haviour at very low temperatures, the monograph aims at filling this gap. It is worth pointing out that within the class of publications dedicated to low temperature behaviour of materials and structures the majority is based on testing down to the temperature of liquid nitrogen (77 K). Rare publications deal with the analysis of material and structural response at the temperature of liquid helium (4. 5 K) or superfluid helium (below the point T>., = 2. 17 K). This can be explained by the fact that an (by its nature complex) installation for testing at such low temperatures is very expensive. Only the large research centres and universities, working in the domain of superconductivity, cryogen ics or developing superconducting magnets for particle accelerators, can afford such installations. A significant part of the present monograph is dedicated to the analy sis of the phenomena associated with plastic yielding in stainless steels at cryogenic temperatures. Generally, three phenomena are distinguished: plas tic strain induced phase transformations, serrated yielding and evolution of ductile damage."

This monograph assimilates new research in the field of low-dimensional metals. It provides a detailed overview of the current status of research on quasi-one- and two-dimensional molecular metals, describing normal-state properties, magnetic field effects, superconductivity, and the phenomena of interacting p and d electrons. It includes a number of findings likely to become standard material in future textbooks on solid-state physics.

The fundamental physics of metallic magnetism is not yet satisfactorily understood and continues to be interesting. For instance, although the detail is yet to be clarified, magnetism is anticipated to be playing a principal role in producing the high Tc superconductivity of the oxides. This book has two major objectives. First, it intends to provide an introduction to magnetism of metals in a broad sense. Besides pursuing the mechanism of metallic magnetism itself, it attempts to fmd and actively analyze magnetic causes hidden hitherto unnoticed behind various physical phenomena. My foremost goal is to expose the fundamental role played by phonons in the mechanism of metallic magnetism. I demonstrate how such a view also helps to elucidate a broad spectrum of other observations. The second objective is to concisely introduce the standard many-body points of view and techniques necessary in studying solid physics in general. The book is intended to be self-contained and starts with Chapter I containing a brief summary on the rudiments of quantum mechanics and statistical mechanics including the method of second quantization. In the same spirit, the foundation of magnetism in general is summarized in Chapter 2 and that for metals in particular, the Stoner theory, in Chapter 3. In Chapter 4, various linear responses of metallic electrons are systematically discussed with emphasis on the role of magnetism in them.

Over the past decade, important advances have been made in the development of nanostructured materials for solid state hydrogen storage used to supply hydrogen to fuel cells in a clean, inexpensive, safe and efficient manner. Nanomaterials for Solid State Hydrogen Storage focuses on hydrogen storage materials having high volumetric and gravimetric hydrogen capacities, and thus having the highest potential of being applied in the automotive sector.

Written by leading experts in the field, Nanomaterials for Solid State Hydrogen Storage provides a thorough history of hydrides and nanomaterials, followed by a discussion of existing fabrication methods. The authors own research results in the behavior of various hydrogen storage materials are also presented. Covering fundamentals, extensive research results and recent advances in nanomaterials for solid state hydrogen storage, this book serves as a comprehensive reference."

This book is a unique collection of experimental data in the field of internal friction, anelastic relaxation, and damping properties of metallic materials. It reviews virtually all anelastic relaxation phenomena ever published. The reader is also supplied with explanations of the basic physical mechanisms of internal friction, a summary of typical effects for different groups of metals, and more than 2000 references to original papers.

Metals have been vital to human civilization for many thousands of years. Their durability and recyclability should make them ideal materials for a sustainable economy. This book assembles experts from many fields to discuss the conditions and limits of sustainable metals management. The contributors examine the theoretical ideas and goals of sustainability, and apply them across the metal making and trading process.

Detailed analyses of failures of material components have proved to be valuable in many ways; by preventing further failures, by assessing the validity of designs and the selection of materials, by uncovering shortcomings in the processing of the materials in volved through characterizations of defects, and by revealing problems introduced during the manufacture or fabrication of the component. Increased recognition of the value of performing failure analyses has caused the field to develop into a very active area of tech nical endeavor. Failure analysis has been employed in numerous different technical dis ciplines and has proven beneficial. The increased activity has caused many new and im proved methods for performing these analyses to be developed. Among these are many methods which can be characterized as generally belonging to the field of metallography. In recognition of the important role that metallography plays in the performance of failure analyses, the absence of a text that specifically discusses this subject, and the be lief that communication of information on the subject would be of technical interest, The American Society for Metals and The International Metallographic Society co sponsored a symposium. The intent was to bring together world-recognized authorities working in various aspects of the failure analysis and metallographic fields to share meth ods they use, results they have obtained, and the purposes to which they utilized these results. The symposium, entitled "Metallography in Failure Analysis," was held in Hous ton, Texas, USA, July 17-18, 1977."

This volume contains papers presented at the NATO Advanced Research Workshop on the Structure and Dynamics of Partially Solidified Systems held at Stanford Sierra Lodge, Tahoe, California, May 12-16, 1986. This work shop grew out of a realization that there was a significant amount of interest and activity in this topic in several unrelated disciplines, and that it would be mutually beneficial to bring together those mathemati' cians, scientists and engineers interested in this subject to share their knowledge and ideas with each other. Partially solidified systems occur in a variety of natural and man made environments. Perhaps the most well-known occurrence involves the solidification of metallic alloys. Typically as a molten alloy is cooled, the solid phase advances from the cold boundary into the liquid as a branching forest of dendritic crystals. This creates a region of mixed solid and liquid phases, commonly referred to as a mushy zone, in which the solid forms a rigidly connected framework with the liquid occurring in the intercrystalline gaps. In addition to the casting of metallic alloys, mushy zones can occur in weld pools, the Earth's core and. mantle, magma chambers, temperate glaciers, frozen soils, frozen lakes and sea ice. A second mechanical configuration for the solid phase is as a suspension of small crystals within the liquid; this is referred to as a slurry."

Stefanescu here attempts to describe solidification theory through the complex mathematical apparatus required for a fundamental treatment of the problem. The mathematics is however restricted to the elements essential to attain a working knowledge in the field. This is in line with the main goal of the book, which is to educate the reader in the fast moving area of computational modeling of solidification of castings. A special effort has been made to introduce the reader to the latest developments in solidification theory including, in this second edition, a new chapter on semi-solid casting.

Solder Joint Reliability Prediction for Multiple Environments will provide industry engineers, graduate students and academic researchers, and reliability experts with insights and useful tools for evaluating solder joint reliability of ceramic area array electronic packages under multiple environments. The material presented here is not limited to ceramic area array packages only, it can also be used as a methodology for relating numerical simulations and experimental data into an easy-to-use equation that captures the essential information needed to predict solder joint reliability. Such a methodology is often needed to relate complex information in a simple manner to managers and non-experts in solder joint who work with computer server applications as well as for harsh environments such as those found in the defense, space, and automotive industries.

The expansion of the application of ferroelectric crystals in engineering as well as of a number of fundamental problems of solid-state physics, which have not yet been solved and which bear a direct relation to ferro electricity, has lately stimulated much interest in the problem of ferroelectricity. In courses of solid-state physics ferroelectricity is studied today along with traditional disciplines, such as magnetism, superconductivity, and 'semiconducting phe nomena. Moreover, new specialities have been born concerned directly with the development and utilization of ferroelectric material in optics, acous tics, computer technology, and capacitor engineering. Special courses in the physics of ferroelectrics are read in a number of colleges and universities. The study of the nature of ferro electricity has currently reached such a level of development that we may speak of having gained a rather deep insight into the physical essence of a number of phenomena, which contribute to the generation of a spontaneous electric polarization in crystals. It is exactly at this level that it has become possible to single out that part of the problem, the physical picture of which can be depicted in a rather unsophisticated manner and which is the foundation for the construction of a building of "complete understanding.""

Chemistry of Powder Production focuses on the solid-state chemistry of powder materials and relates this to the structure, properties and preparation, and characterization techniques for these important industrial products. Additionally, the properties of the particles are discussed in relation to their surface structure and characteristics. This book describes the fundamentals of statistical methods for measuring the characteristics of particles. New advanced materials being developed in powder technology manufacturing techniques are also emphasised, including powdered materials for advanced ceramics as well as magnetic and pigment materials.

Bulk metallic glasses are a new emerging field of materials with many desirable and unique properties, such as high strength, good hardness, good wear resistance, and high corrosion resistance that can be produced in near net shape components. These amorphous materials have many diverse applications from structural applications to biomedical implants.

A complete overview of bulk metallic glasses is presented: the principles of alloy design, glass formation, processing, atomistic modeling, computer simulations, mechanical properties and microstructures.

Even though the effect of lead contamination on human health has been known for decades, very little attention has been paid to lead-based solders used in electronics until recently. This comprehensive book examines all the important issues associated with lead-free electronic solder. It collects the work of researchers recognized for their significant scientific contributions in the area.

This book can be viewed as a scientific investigation combined with methodological studies. For practical reasons each of the methods is described in the following general manner including: the uses and the scientific investigation tasks; methods of sampling; testing equipment; test preparation; tests; data processing; controversial issues and conclusions. Each of the 37 methods contains a range of 1 to 8 variants. As far as we know, the book is the first publication in the field.