This comprehensive book offers a clear account of the theory and applications of advanced metal forming. It provides a detailed discussion of specific forming processes, such as deep drawing, rolling, bending extrusion and stamping. The author highlights recent developments of metal forming technologies and explains sound, new and powerful expert system techniques for solving advanced engineering problems in metal forming. In addition, the basics of expert systems, their importance and applications to metal forming processes, computer-aided analysis of metalworking processes, formability analysis, mathematical modeling and case studies of individual processes are presented.

This thesis presents recent developments in magnetic coupling phenomena of ferrimagnetic rare-earth transition-metal Tb-Fe alloys and coupled systems consisting of ferri-/ferromagnetic heterostructures. Taking advantage of the tunability of the exchange coupling between ferrimagnetic and ferromagnetic layers by means of stoichiometry of the Tb-Fe layer, the variable number of repetitions in the Co/Pt multilayer as well as the thickness of an interlayer spacer, it is demonstrated that large perpendicular unidirectional anisotropy can be induced at room temperature. This robust perpendicular exchange bias at room temperature opens up a path towards applications in spintronics.

Tin (Sn) whiskers are electrically conductive, single crystal eruptions that grow from Sn film surfaces. Their high aspect ratio presents reliability problems for the electronics industry due to bridging and metal arcing, leading to malfunctions and catastrophic failures in many electronic systems (including satellite and defense sectors). Due to legislation in the EU, Japan, and the U.S., mandating a gradual shift from lead (Pb)-based to lead-free solders and board finishes, there has been a reemergence of Sn whiskers. Continuing reports of Sn whisker induced failures coupled with the lack of an industry-accepted understanding of whisker growth and/or test methods to identify whisker prone products has made pure/high Sn substitutes a risky proposition in high reliability systems. This thesis is designed to clarify and control the fundamental mechanisms that govern whisker formation. The research focuses on reproducible "laboratory" created whiskers under a variety of rigorously controlled environmental factors such as film thickness, film stress, substrate material, gas environment, and humidity exposure, which are known to play a significant role in whisker production. The ultimate question of how to impede and/or prevent whisker growth is also addressed and shows that whisker prevention is possible via hard metal capping films, which are impenetrable by whiskers.

This book covers the Resistivity Recovery (RR) technique, underlying its physical principles, performance and problematic. A concise review on the state of the art is provided, showing the advances in radiation modelling, linking both experimental and theoretical fields. The reader will find a data compilation and comparison of up-to-date results obtained from the European Fusion Development Agreement model alloys.

High-temperature structural intermetallics continue to be an active field of research because they offer the promise of structural properties, oxidation resistance and service temperatures exceeding those of conventional metals and alloys. However, they also present problems with respect to their understanding and processing. Current research into aluminide- and silicide-based materials illustrates this point very well. Continuing advances require basic studies to support alloy development as well as the identification and exploration of applications. This book, first published in 2001, provides a representative cross-section of research carried out and should be of interest to a wide range of readers. The most 'popular' material continues to be TiAl, which is beginning to find applications as a light-weight, high-strength, oxidation resistant structural material. There is renewed interest in structural silicides with melting points on the order of 2000%C. Examples include intermetallics with thermoelectric properties as well as intermetallics with shape memory effects at unusually high temperatures above 1000 DegreesC.

Problems of fatigue under multiaxial fatigue loads have been addressed in a very large number of research publications. The present publication is primarily a survey of biaxial fatigue under constant amplitude loading on metal specimens. It starts with the physical understanding of the fatigue phenomenon under biaxial fatigue loads. Various types of proportional and non-proportional biaxial fatigue loads and biaxial stress distributions in a material are specified. Attention is paid to the fatigue limit, crack nucleation, initial micro crack growth and subsequent macro-crack in different modes of crack growth. The interference between the upper and lower surfaces of a fatigue crack is discussed. Possibilities for predictions of biaxial fatigue properties are analysed with reference to the similarity concept. The significance of the present understanding for structural design problems is considered. The book is completed with a summary of major observations.

This Brief focuses on the synthesis, functionalization techniques, optical properties and biomedical application of gold nanostars (GNS). Various facilities of gold nanostars synthesis as well as functionalization of GNS with PEG, organic dyes, bioactive compounds are discussed. The authors discuss physical origin of the Localized Surface Plasmon Resonances and the way the nano-environment affects them. The implication of the LSPR of gold nanostars surface enhanced Raman scattering is also discussed. The emphasis has been done on the application of GNS for current and emerge needs of medicine, biology and pharmacy. Moreover, properties of gold nanostars as contrast agents for in vivo imaging and interaction of GNS with cells are also discussed in this Brief.

This book guides readers through the systematic analysis of Arc Spraying: one of the most widespread and important thermal spraying methods. Along the way, readers from industry and research laboratories become familiar with the features of the process and physical-chemical regulations of particles in flight, coating formation, internal coating properties, and their output parameters. The book is ideal for engineers, technicians, and scientists engaged in welding and thermal spraying and stands as an excellent reference for students interested in advanced coatings technology.

This book gives detailed information about the fabrication, properties and applications of nanoporous alumina. Nanoporous anodic alumina prepared by low-cost, simple and scalable electrochemical anodization process due to its unique structure and properties have attracted several thousand publications across many disciplines including nanotechnology, materials science, engineering, optics, electronics and medicine. The book incorporates several themes starting from the understanding fundamental principles of the formation nanopores and theoretical models of the pore growth. The book then focuses on describing soft and hard modification techniques for surface and structural modification of pore structures to tailor specific sensing, transport and optical properties of nano porous alumina required for diverse applications. These broad applications including optical biosensing, electrochemical DNA biosensing, molecular separation, optofluidics and drug delivery are reviewed in separated book chapters. The book appeals to researchers, industry professionals and high-level students.

Inorganic nanoparticles are among the most investigated objects nowadays, both in fundamental science and in various technical applications. In this book the physical properties of nanowires formed by nanoparticles with elongated shape, i.e. rod-like or wire-like, are described. The transition in the physical properties is analyzed for nanorods and nanowires consisting of spherical and rod-like nanoparticles. The physical properties of nanowires and elongated inorganic nanoparticles are reviewed too. The optical, electrical, magnetic, mechanical and catalytic properties of nanowires consisting of semiconductors, noble and various other metals, metal oxides properties and metal alloys are presented. The applications of nanorods and nanowires are discussed in the book.

With China becoming a major force in steel research and development, this book highlights the work of a group from the Chinese Academy of Sciences, led by the first four authors. This group has the ideal knowledge base for writing this updated book on heat-resistant steels. The fifth author, Sha, based in the UK, has been collaborating with the Chinese group since 2009 and is the lead or sole author of four research books, all published in English. The last book, “Steels: from materials science to structural engineering,� was published by Springer in 2013. Within two months of its publication, researchers at the University of Science and Technology Liaoning had requested translation of the book into Chinese. Springer obliged, and the Chinese version was published by the Metallurgical Industry Press, Beijing, in August 2014. Sha has organized and completed the writing of the proposed book, though the main research was done in China.

This book shows how severe plastic deformation techniques could be used to enhance the hydrogen storage properties of metal hybrides. The mechanochemical techniques of ball-milling (BM), Cold Rolling (CR), Equal Chanel Angular Pressing (ECAP) and High Pressure Torsion (HPT) are covered. Each technique is described and critically assessed with respect to its usefulness to process metal hybrides at an industrial scale.

An uncomfortable observation in the Shift Logs and Process Control records of most aluminum smelting plants is that process control failures, large and small, happen every day. Although only a small fraction of these failures give rise to catastrophic events, the difference between a disaster we read about and a failure which, although expensive, has no irreversible consequences, is only chance. Control for Aluminum Production and Other Processing Industries exemplifies new control thinking fused with an understanding of process variability, and how to diagnose abnormalities and their causes in aluminum production plants. Many real life examples in the book demonstrate the importance of human behavior and a scientific, questioning approach in the control of a technologically complex process. Written from the perspective of production staff and management, the book also gives readers a view into the human aspects of accidents and their analogy with failures in control of production. Production plants regularly experience more control failures than successes and staff must continuously strive to establish stability and control of their process. Through on-the-job experiences of the authors and their industry colleagues, the control experiences described in this book provide readers with a foundation for building their own robust control rationale and a framework for avoidance of plant control problems.

These are the proceedings of the International Conference on Design, Fabrication and Economy of Metal Structures held on 24-26 April 2013 in Miskolc, Hungary which contain 99 papers covering: Structural optimization Thin-walled structures Stability Fatigue Frames Fire Fabrication Welding technology Applications Steel-concrete composite Special problems The authors are from 23 different countries, ensuring that the themes covered are of worldwide interest and importance. The International Institute of Welding (IIW), the International Society of Structural and Multidisciplinary Optimization (ISSMO), the TAMOP 4.2.1.B-10/2/KONV-2010-0001 project entitled "Increasing the quality of higher education through the development of research - development and innovation program at the University of Miskolc supported by the European Union, co-financed by the European Social Fund" and many other sponsors helped organizers to collect these valuable studies, the results of which will provoke discussion, and provide an important reference for civil and mechanical engineers, architects, researchers and structural designers and fabricators, as well as managers in a range of industries including building, transport, shipbuilding, aircraft, chemical and offshore engineering.

This book collects several examples of research in machining processes. Chapter 1 provides information on polycrystalline diamond tool material and its emerging applications. Chapter 2 is dedicated to the analysis of orthogonal cutting experiments using diamond-coated tools with force and temperature measurements. Chapter 3 describes the estimation of cutting forces and tool wear using modified mechanistic models in high performance turning. Chapter 4 contains information on cutting under gas shields for industrial applications. Chapter 5 is dedicated to the machinability of magnesium and its alloys. Chapter 6 provides information on grinding science. Finally, chapter 7 is dedicated to flexible integration of shape and functional modelling of machine tool spindles in a design framework.

This thesis deals with Rare Earth Elements (REE), especially with neodymium used in permanent magnets, from a very scientific basis by providing basic research data. Despite the fact that REE are newsworthy and very important elements for a considerable bandwidth of todays' technologies, accompanied by the monopolistic supply-situation and Chinese politics, there are inexplicable data discrepancies about REE which have been recognized frequently but usually have not been addressed accordingly. So this analysis started with the hypothesis that the four application areas, namely computer hard disk drives (HDD), mobile phones, wind turbines and e-mobility (automotive traction), account for about 80% of the global annual neodymium-demand. The research methodology was a laboratory analysis of the composition of used magnets for HDDs and mobile phones and a literature and official report analysis of wind turbine and automotive neodymium use. The result was amazing and the hypothesis had to be withdrawn as these four areas only account for about 20% of neodymium use. This result raises some questions concerning actual use and thus potential recycling options.

The fundamental properties of deep luminescence centres in Si associated with transition metals such as Cu, Ag, Au, and Pt have been a focus of interest for decades, both as markers for these deleterious contaminants, and also in the quest for efficient Si-based light emission. This dissertation presents the results of ultra-high resolution photoluminescence studies of these centres in specially prepared, highly enriched 28-Si samples. The greatly improved spectral resolution due to this enrichment led to the discovery of isotopic fingerprints. These fingerprints have revealed that the detailed constituents of all of the centres previously studied had been identified incorrectly. They also revealed the existence of several different families of impurity complexes containing either four or five atoms chosen from Li, Cu, Ag, Au, and Pt. These centres' constituents have been determined, together with no-phonon transition energies, no-phonon isotope shifts, local vibrational mode energies, and the isotope shifts of the local vibrational mode energies. The data presented here for these centres should prove useful for the currently sought theoretical explanations of their formation, stability, and properties.

Laser shock processing (LSP) is a new and promising surface treatment technique for improving the fatigue durability, corrosion, wear resistance and other mechanical properties of metals and alloys. During LSP, the generated shock wave can introduce a deep compressive residual stress into the material, due to its high-pressure (GPa-TPa), ultra-fast (several tens nanoseconds), ultra-high strain-rate and high-energy. The overall properties and behavior of metal materials subjected to LSP were significantly improved because a refined surface layer was successfully obtained. Nevertheless, up to now, a clear scenery between micro-structure and macro-property of the refined surface layer, especially formation of sub-micrometer grains from coarse grains during severe plastic deformation, is still pending. Therefore, the basic studies of the underlying mechanism for grain refinement by ultra-high strain-rate presented in this book becomes more and more crucial.

Die Casting: An Analytical Approach will refresh knowledge of the governing laws of the fluid dynamics that have an effect on die cast die and die cast process design. It will be bought by product designers that design die cast parts and die cast die and process engineers and designers.

In the last few years, a significant increase in applications of MMCs has taken place, particularly in the areas of automotive, aerospace, electronics, and recreation. These include continuous fiber reinforced MMCs for cables in power transmission, high temperature superconducting wires, particulate MMCs in civilian aircraft and automotive applications, and high volume fraction, high thermal conductivity substrates for electronic packaging. Nevertheless, as with any novel material systems, there is a lack of fundamental understanding on the part of practicing engineers and designers. This book would seek to address these issues, in a thorough and cohesive manner, as well as to provide students and scientists with a basic understanding of MMCs. This book will emphasize the synergistic relationships among processing, structure, and properties of metal matrix composites.

William Hosford's book is ideal for those involved in designing sheet metal forming processes. Knowledge of plasticity is essential for the computer simulation of metal forming processes and understanding the advances in plasticity theory is key to formulating sound analyses. The author makes the subject simple by avoiding notations used by specialists in mechanics. R. Hill's authoritative book, Mathematical Theory of Plasticity (1950), presented a comprehensive treatment of continuum plasticity theory up to that time; much of the treatment in this book covers the same ground, but focuses on more practical topics. Hosford has included recent developments in continuum theory, including a newer treatment of anisotropy that has resulted from calculations of yielding based on crystallography, analysis of the role of defects, and forming limit diagrams. A much greater emphasis is placed on deformation mechanisms and the book also includes chapters on slip and dislocation theory and twinning.

One of the key aspects of this volume is to cut across the traditional taxonomy of disciplines in the study of alloys. Hence there has been a deliberate attempt to integrate the different approaches taken towards alloys as a class of materials in different fields, ranging from geology to metallurgical engineering. The emphasis of this book is to highlight commonalities between different fields with respect to how alloys are studied. The topics in this book fall into several themes, which suggest a number of different classification schemes. We have chosen a scheme that classifies the papers in the volume into the categories Microstructural Considerations, Ordering, Kinetics and Diffusion, Magnetic Considerations and Elastic Considerations. The book has juxtaposed apparently disparate approaches to similar physical processes, in the hope of revealing a more dynamic character of the processes under consideration. This monograph will invigorate new kinds of discussion and reveal challenges and new avenues to the description and prediction of properties of materials in the solid state and the conditions that produce them.

Theuseoflasersinmaterialsprocessinghasbecomewidespreadinrecent years,sothatanunderstandingofthenatureofheatandmasstransferin thisbranchofmoderntechnologyisofincreasingimportance. Theaimofthe authorsofthisbookistoconcentrateonthephysicalprocesses;thesecanbe developedfromamathematicalpointofview,orfromdirectexperimental- derivedobservation. Thetwoapproachesarecomplementary;eachcanprovide insightsandthesynthesisofthetwocanleadtoaverypowerfulunderstanding oftheprocessesinvolved. Mathematicalmodellingofphysicalprocesseshas hadanimportantroletoplayinthedevelopmentoftechnologyoverthe centuriesandparticularlysointhelastonehundredand?ftyyearsorso. Itcanbearguedthatitismoreimportanttodaythaneverbeforesincethe availabilityofhigh-speedcomputersallowsaccuratenumericalsimulationof industrialprocessesatafractionofthecostofthecorrespondingexperiments. Thisisoneaspectofmathematicalmodelling,highpro?leandmuchvalued, butitisnottheonlyone. Inthepastmathematicalmodellinghadtorelyonqualitativeinves- gation,veryspecialanalyticalsolutions,orinaccurateandtime-consuming calculationsperformedwithlittleinthewayoftabulatedormechanical assistance. Logtablesandsliderulesarestillrememberedbypeopleworking today,thoughtherearesurelyfewwhoregrettheirdisappearance. Thevalueanddistinctivefunctionofmethodsbasedontheanalytical approachisnowbecomingmuchclearer,nowthattheyarenolongerexpected toproducedetailedimitationsofwhathappensinrealexperimentsofind- trialprocesses,afunctionnowful?lledmostlybynumericalmethods,c- sideredbelow. Theemphasistodayisontheirabilitytocon?rmandextend ourunderstandingofthebasicphysicalmechanismsinvolvedintheprocesses of interest. These are essential for any intelligent use of numerical simulation. Theargumentaboutthevalueofteachingpeoplehowtodoarithmetic themselveswithouttheaidofacalculatorseemstobepassingintohistory, vi Preface butitisanimportantoneandprovidesasimpleanalogy. Ifsomeonedoes nothaveafeelingfornumbersandthewayarithmeticworks,theywillalltoo easilyfailtospotanerrorproducedbyamachine. Computersarenotinfallible -andneitherarethosewhobuildorprogramthem. Computersarenow takingonlessmundanemathematicaltasksandthesamecontroversiesare appearinginconnectionwithalgebraicmanipulation. Equally,andwitheven greaterpenaltiesintermsofcostintheeventoferrors,thesameconsiderations applytonumericalsimulationofmajorindustrialprocesses. Awarenessofthe analyticalsolutionscanbeinvaluableindistinguishingtherightfromthe wrong,i. e. forthepractitionertounderstandthebasisofthework,andto haveanideaofthekindsofoutcomesthatareplausible-andtorecognise thosewhicharenot. Thephrase"mathematicalmodelling"is,however,ambiguous,perhaps morenowthanithaseverbeen. Thereisanenormousamountofworkdone todayonsimulationbasedontheuseofverypowerfulcomputerprograms, anditisquitecorrectlyreferredtoasmathematicalmodelling. Theprograms aresometimesconstructedin-housebutareusuallycommercialpackages. This isanentirelyvalidapproachwithspeci?c(generallycommercial)objectives. Ingeneraltherearetwouses. Thedominantobjectiveisnumericalagreement withaparticularexperimentinthe?rstinstance,leadingtopredictivec- mercialuseinthesecondinstance. Thesecondobjectiveistheclari?cation ofphysicalmechanisms,aimedatthegenerationofunderstandingofcomplex interconnectedprocesses,ratherthantheexactreproductionofaparticular experiment. Itissometimesoverlookedthat,withsu?cientcare,anum- icalapproachisequallyvalidintheinvestigationofphysicalfundamentals. Numericalsimulationisnotacentraltopicofthisbook,butbecauseofits crucialimportancetoeachofthetwousestowhichnumericalmodellingcan beput,itisvitalthatthecomputationalbasisoftheworkshouldbec- pletelysound. Inaddition,thelevelofprocessdetailwhichcanbeconsidered bythenumericalapproachusuallyexceedswhatispossiblewiththeanaly- calapproachsigni?cantly,leavinglittlechoicebuttoreverttothenumerical treatmentwheninvestigatingtheinterconnectionsbetweenprocesses. Itis forthesereasonsthatthebookconcludeswithachapteroncomprehensive numericalsimulation. Inmanyways,theapproachadoptedhereiscomplementarytothemore phenomenologicalapproach. Itisalwaysimportantina?eldwhichhasvery directindustrialapplicationstobearinmindhowtechniquessuchasthose describedherewillbeused,butitisessentialnottolosesightofthef- damentals. Thereareserioussafetyimplications;therearecostimplications; therearemoralimplications;thereareconsiderationsoftheappropriateness ofthetechnologytotheapplicationunderconsideration. Aproperrespectfor alltheserequiresanunderstandingofthefundamentals. Wearealltoowellawarethatthisbookdoeslittlemorethanscratch thesurfaceoftheproblemsinvolvedinafundamentalunderstandingofthese phenomena. Ifwehaveprovidedideasandinformationthatcauseothersto Preface vii testthemexperimentallyorintellectually,agreewiththemordisputethem vigorously,anddevelopthemfurther,wewillconsiderthatwehaveachieved ouraim. Colchester April,2008 JohnDowden Contents 1MathematicsinLaserProcessing JohnDowden...1 1. 1 MathematicsanditsApplication...1 1. 2 FormulationinTermsofPartialDi?erentialEquations...3 1. 2. 1 LengthScales...3 1. 2. 2 ConservationEquationsandtheirGeneralisations...4 1. 2. 3 GoverningEquationsofGeneralised ConservationType...7 1. 2. 4 Gauss'is,however,ambiguous,perhaps morenowthanithaseverbeen. Thereisanenormousamountofworkdone todayonsimulationbasedontheuseofverypowerfulcomputerprograms, anditisquitecorrectlyreferredtoasmathematicalmodelling. Theprograms aresometimesconstructedin-housebutareusuallycommercialpackages. This isanentirelyvalidapproachwithspeci?c(generallycommercial)objectives. Ingeneraltherearetwouses. Thedominantobjectiveisnumericalagreement withaparticularexperimentinthe?rstinstance,leadingtopredictivec- mercialuseinthesecondinstance. Thesecondobjectiveistheclari?cation ofphysicalmechanisms,aimedatthegenerationofunderstandingofcomplex interconnectedprocesses,ratherthantheexactreproductionofaparticular experiment. Itissometimesoverlookedthat,withsu?cientcare,anum- icalapproachisequallyvalidintheinvestigationofphysicalfundamentals. Numericalsimulationisnotacentraltopicofthisbook,butbecauseofits crucialimportancetoeachofthetwousestowhichnumericalmodellingcan beput,itisvitalthatthecomputationalbasisoftheworkshouldbec- pletelysound. Inaddition,thelevelofprocessdetailwhichcanbeconsidered bythenumericalapproachusuallyexceedswhatispossiblewiththeanaly- calapproachsigni?cantly,leavinglittlechoicebuttoreverttothenumerical treatmentwheninvestigatingtheinterconnectionsbetweenprocesses. Itis forthesereasonsthatthebookconcludeswithachapteroncomprehensive numericalsimulation. Inmanyways,theapproachadoptedhereiscomplementarytothemore phenomenologicalapproach. Itisalwaysimportantina?eldwhichhasvery directindustrialapplicationstobearinmindhowtechniquessuchasthose describedherewillbeused,butitisessentialnottolosesightofthef- damentals. Thereareserioussafetyimplications;therearecostimplications; therearemoralimplications;thereareconsiderationsoftheappropriateness ofthetechnologytotheapplicationunderconsideration. Aproperrespectfor alltheserequiresanunderstandingofthefundamentals. Wearealltoowellawarethatthisbookdoeslittlemorethanscratch thesurfaceoftheproblemsinvolvedinafundamentalunderstandingofthese phenomena. Ifwehaveprovidedideasandinformationthatcauseothersto Preface vii testthemexperimentallyorintellectually,agreewiththemordisputethem vigorously,anddevelopthemfurther,wewillconsiderthatwehaveachieved ouraim. Colchester April,2008 JohnDowden Contents 1MathematicsinLaserProcessing JohnDowden...1 1. 1 MathematicsanditsApplication...1 1. 2 FormulationinTermsofPartialDi?erentialEquations...3 1. 2. 1 LengthScales...3 1. 2. 2 ConservationEquationsandtheirGeneralisations...4 1. 2. 3 GoverningEquationsofGeneralised ConservationType...7 1. 2. 4 Gauss'Theuseoflasersinmaterialsprocessinghasbecomewidespreadinrecent years,sothatanunderstandingofthenatureofheatandmasstransferin thisbranchofmoderntechnologyisofincreasingimportance. Theaimofthe authorsofthisbookistoconcentrateonthephysicalprocesses;thesecanbe developedfromamathematicalpointofview,orfromdirectexperimental- derivedobservation. Thetwoapproachesarecomplementary;eachcanprovide insightsandthesynthesisofthetwocanleadtoaverypowerfulunderstanding oftheprocessesinvolved. Mathematicalmodellingofphysicalprocesseshas hadanimportantroletoplayinthedevelopmentoftechnologyoverthe centuriesandparticularlysointhelastonehundredand?ftyyearsorso. Itcanbearguedthatitismoreimportanttodaythaneverbeforesincethe availabilityofhigh-speedcomputersallowsaccuratenumericalsimulationof industrialprocessesatafractionofthecostofthecorrespondingexperiments. Thisisoneaspectofmathematicalmodelling,highpro?leandmuchvalued, butitisnottheonlyone. Inthepastmathematicalmodellinghadtorelyonqualitativeinves- gation,veryspecialanalyticalsolutions,orinaccurateandtime-consuming calculationsperformedwithlittleinthewayoftabulatedormechanical assistance. Logtablesandsliderulesarestillrememberedbypeopleworking today,thoughtherearesurelyfewwhoregrettheirdisappearance. Thevalueanddistinctivefunctionofmethodsbasedontheanalytical approachisnowbecomingmuchclearer,nowthattheyarenolongerexpected toproducedetailedimitationsofwhathappensinrealexperimentsofind- trialprocesses,afunctionnowful?lledmostlybynumericalmethods,c- sideredbelow. Theemphasistodayisontheirabilitytocon?rmandextend ourunderstandingofthebasicphysicalmechanismsinvolvedintheprocesses of interest. These are essential for any intelligent use of numerical simulation. Theargumentaboutthevalueofteachingpeoplehowtodoarithmetic themselveswithouttheaidofacalculatorseemstobepassingintohistory, vi Preface butitisanimportantoneandprovidesasimpleanalogy. Ifsomeonedoes nothaveafeelingfornumbersandthewayarithmeticworks,theywillalltoo easilyfailtospotanerrorproducedbyamachine. Computersarenotinfallible -andneitherarethosewhobuildorprogramthem. Computersarenow takingonlessmundanemathematicaltasksandthesamecontroversiesare appearinginconnectionwithalgebraicmanipulation. Equally,andwitheven greaterpenaltiesintermsofcostintheeventoferrors,thesameconsiderations applytonumericalsimulationofmajorindustrialprocesses. Awarenessofthe analyticalsolutionscanbeinvaluableindistinguishingtherightfromthe wrong,i. e. forthepractitionertounderstandthebasisofthework,andto haveanideaofthekindsofoutcomesthatareplausible-andtorecognise thosewhicharenot. Thephrase"mathematicalmodelling"is,however,ambiguous,perhaps morenowthanithaseverbeen. Thereisanenormousamountofworkdone todayonsimulationbasedontheuseofverypowerfulcomputerprograms, anditisquitecorrectlyreferredtoasmathematicalmodelling. Theprograms aresometimesconstructedin-housebutareusuallycommercialpackages. This isanentirelyvalidapproachwithspeci?c(generallycommercial)objectives. Ingeneraltherearetwouses. Thedominantobjectiveisnumericalagreement withaparticularexperimentinthe?rstinstance,leadingtopredictivec- mercialuseinthesecondinstance. Thesecondobjectiveistheclari?cation ofphysicalmechanisms,aimedatthegenerationofunderstandingofcomplex interconnectedprocesses,ratherthantheexactreproductionofaparticular experiment. Itissometimesoverlookedthat,withsu?cientcare,anum- icalapproachisequallyvalidintheinvestigationofphysicalfundamentals. Numericalsimulationisnotacentraltopicofthisbook,butbecauseofits crucialimportancetoeachofthetwousestowhichnumericalmodellingcan beput,itisvitalthatthecomputationalbasisoftheworkshouldbec- pletelysound. Inaddition,thelevelofprocessdetailwhichcanbeconsidered bythenumericalapproachusuallyexceedswhatispossiblewiththeanaly- calapproachsigni?cantly,leavinglittlechoicebuttoreverttothenumerical treatmentwheninvestigatingtheinterconnectionsbetweenprocesses. Itis forthesereasonsthatthebookconcludeswithachapteroncomprehensive numericalsimulation. Inmanyways,theapproachadoptedhereiscomplementarytothemore phenomenologicalapproach. Itisalwaysimportantina?eldwhichhasvery directindustrialapplicationstobearinmindhowtechniquessuchasthose describedherewillbeused,butitisessentialnottolosesightofthef- damentals. Thereareserioussafetyimplications;therearecostimplications; therearemoralimplications;thereareconsiderationsoftheappropriateness ofthetechnologytotheapplicationunderconsideration. Aproperrespectfor alltheserequiresanunderstandingofthefundamentals. Wearealltoowellawarethatthisbookdoeslittlemorethanscratch thesurfaceoftheproblemsinvolvedinafundamentalunderstandingofthese phenomena. Ifwehaveprovidedideasandinformationthatcauseothersto Preface vii testthemexperimentallyorintellectually,agreewiththemordisputethem vigorously,anddevelopthemfurther,wewillconsiderthatwehaveachieved ouraim. Colchester April,2008 JohnDowden Contents 1MathematicsinLaserProcessing JohnDowden...1 1. 1 MathematicsanditsApplication...1 1. 2 FormulationinTermsofPartialDi?erentialEquations...3 1. 2. 1 LengthScales...3 1. 2. 2 ConservationEquationsandtheirGeneralisations...4 1. 2. 3 GoverningEquationsofGeneralised ConservationType...7 1. 2. 4 Gauss'sLaw...10 1. 3 BoundaryandInterfaceConditions...11 1. 3. 1 GeneralisedConservationConditions...11 1. 3. 2 TheKinematicConditioninFluidDynamics...13 1. 4 Fick'sLaws...15 1. 5 Electromagnetism...15 1. 5. 1 Maxwell'sEquations...15 1. 5. 2 Ohm'sLaw...18 References...19 2SimulationofLaserCutting WolfgangSchulz,MarkusNiessen,UrsEppelt,KerstinKowalick...21 2. 1 Introduction...22 2. 1. 1 PhysicalPhenomenaandExperimentalObservation...23 2. 2 MathematicalFormulationandAnalysis...26 2. 2. 1 TheOne-PhaseProblem...29 2. 2. 2 TheTwo-PhaseProblem...42 2. 2. 3 Three-PhaseProblem...51 2. 3 Outlook...64 2. 4 Acknowledgements...65 References...65 x Contents 3KeyholeWelding:TheSolidandLiquidPhases AlexanderKaplan...71 3. 1 HeatGenerationandHeatTransfer...71 3. 1. 1 Absorption...

This book presents a state-of-the-art summary and critical analysis of work recently performed in leading research laboratories around the world on the implementation of metal oxide nanomaterial research methodologies for the discovery and optimization of new sensor materials and sensing systems. The book provides a detailed description and analysis of (i) metal oxide nanomaterial sensing principles, (ii) advances in metal oxide nanomaterial synthesis/deposition methods, including colloidal, emulsification, and vapor processing techniques, (iii) analysis of techniques utilized for the development of low temperature metal oxide nanomaterial sensors, thus enabling a broader impact into sensor applications, (iv) advances, challenges and insights gained from the in situ/ex situ analysis of reaction mechanisms, and (v) technical development and integration challenges in the fabrication of sensing arrays and devices.

This book serves both as a textbook and a scientific work. As a textbook, the work gives a clear, thorough and systematic presentation of the fundamental postulates, theorems and principles and their applications of the classical mathematical theories of plasticity and creep. In addition to the mathematical theories, the physical theory of plasticity, the book presents the Budiansky concept of slip and its modification by M. Leonov. Special attention is given to the analysis of the advantages and shortcomings of the classical theories. In its main part, the book presents the synthetic theory of irreversible deformations, which is based on the mathematical Sanders flow plasticity theory and the physical theory, the Budiansky concept of slip. The main peculiarity of the synthetic theory is that the formulae for both plastic and creep deformation, as well their interrelations, can be derived from the single constitutive equation. Furthermore, the synthetic theory, as physical one, can take into account the real processes that take place in solids at irreversible deformation. This widens considerably the potential of the synthetic theory. In the framework of the synthetic theory such problems as creep delay, the Hazen-Kelly effect, the deformation at the break of the load trajectory, the influence of the rate of loading on the stress-strain diagram, creep at the changes of load, creep at unloading and reversed creep, have been analytically described. In the last chapter, the book shows the solution of some contemporary problems of plasticity and creep: Creep deformation at cyclic abrupt changes of temperature, The influence of irradiation on the plastic and creep deformation, Peculiarities of deformation at the phase transformation of some metals.