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Books > Professional & Technical > Industrial chemistry & manufacturing technologies > Metals technology / metallurgy
Metal matrix composites are making tangible inroads into the "real"
world of engineering. They are used in engineering components such
as brake rotors, aircraft parts, combustion engines, and heat sinks
for electronic systems. Yet, outside a relatively limited circle of
specialists, these materials are mostly unknown. Designers do not
as a rule think of using these materials, in part because access to
information is difficult as these materials have not really entered
engineering handbooks. Metal Matrix Composites in Industry is thus
useful to engineers who wish to gain introductory knowledge of
these materials and who want to know where "to find" them.
Additionally, it provides researchers and academics with a survey
of current industrial activity in this area of technology.
By drawing together the current theoretical and experimental
understanding of the phenomena of delayed hydride cracking (DHC) in
zirconium alloys, The Effect of Hydrogen and Hydrides on the
Integrity of Zirconium Alloy Components: Delayed Hydride Cracking
provides a detailed explanation focusing on the properties of
hydrogen and hydrides in these alloys. Whilst the emphasis lies on
zirconium alloys, the combination of both the empirical and
mechanistic approaches creates a solid understanding that can also
be applied to other hydride forming metals. This up-to-date
reference focuses on documented research surrounding DHC, including
current methodologies for design and assessment of the results of
periodic in-service inspections of pressure tubes in nuclear
reactors. Emphasis is placed on showing how our understanding of
DHC is supported by progress in general understanding of such broad
fields as the study of hysteresis associated with first order phase
transformations, phase relationships in coherent crystalline
metallic solids, the physics of point and line defects, diffusion
of substitutional and interstitial atoms in crystalline solids, and
continuum fracture and solid mechanics. Furthermore, an account of
current methodologies is given illustrating how such understanding
of hydrogen, hydrides and DHC in zirconium alloys underpins these
methodologies for assessments of real life cases in the Canadian
nuclear industry. The all-encompassing approach makes The Effect of
Hydrogen and Hydrides on the Integrity of Zirconium Alloy
Component: Delayed Hydride Cracking an ideal reference source for
students, researchers and industry professionals alike.
The mineral resources of the industrialized countries, especially
the member nations of the North Atlantic Treaty Organiza tion, are
being depleted at such a rate that more and more of these count
ries are beginning to depend on ore imported from other coun tries.
To sustain the economic and strategie well-being of these member
countries, it becomes imperative that a program of developing and
exploiting other non-conventional mineral resources and a con
servation program where metal values from waste dumps and scrap
metals and alloys are recycled must be initiated and implemented.
In order to meet this challenge, new processes and technology must
be available for consideration in the design and operation of the
new plants. One of the possible routes of extracting the metals
from their ores, especially for multimetal complex ores and very
low grade ores, is by hydrometallurgical processing. The
hydrometallurgical route of metal recovery where dissolution
(leaching), separation and concentration (ion exchange, solvent
extraction, and membrane separation) and reduction to metal
(cementation, precipitation by gaseous reduction, and electrolysis)
is carried out at near ambient temperature is becoming more competi
tive with the conventional high temperature processes used in the
smelting of metals from high grade and beneficiated ores.
Jonathan Scragg documents his work on a very promising material
suitable for use in solar cells. Copper Zinc Tin Sulfide (CZTS) is
a low cost, earth-abundant material suitable for large scale
deployment in photovoltaics. Jonathan pioneered and optimized a low
cost route to this material involving electroplating of the three
metals concerned, followed by rapid thermal processing (RTP) in
sulfur vapour. His beautifully detailed RTP studies - combined with
techniques such as XRD, EDX and Raman - reveal the complex
relationships between composition, processing and photovoltaic
performance. This exceptional thesis contributes to the development
of clean, sustainable and alternative sources of energy
This monograph describes mathematical models that enable
prediction of phase compositions for various technological
processes, as developed on the base of a complex physico-chemical
analysis of reaction. It studies thermodynamics and kinetics of
specific stages of complex pyrometallurgical processes involving
boron, carbon, sulfur, tungsten, phosphorus, and many more, as well
as their exposure to all sorts of factors.
First and foremost, this enables to optimize processes and
technologies at the stage of design, while traditional empirical
means of development of new technologies are basically incapable of
providing an optimal solution. Simulation results of metals and
alloys production, welding and coating technologies allow obtaining
materials with pre-given composition, structure and properties in a
cost-saving and conscious manner. Moreover, a so-called "inverse
problem," i.e., selecting source materials which would ensure the
required results, cannot be solved by any other means.
The book describes the valorization of biomass-derived compounds
over gold catalysts. Since biomass is a rich renewable feedstock
for diverse platform molecules, including those currently derived
from petroleum, the interest in various transformation routes has
become intense. Catalytic conversion of biomass is one of the main
approaches to improving the economic viability of biorefineries. In
addition, Gold catalysts were found to have outstanding activity
and selectivity in many key reactions. This book collects
information about transformations of the most promising and
important compounds derived from cellulose, hemicelluloses, and
woody biomass extractives. Since gold catalysts possess high
stability under oxidative conditions, selective oxidation reactions
were discussed more thoroughly than other critical reactions such
as partial hydrogenation, acetalization, and isomerization. The
influence of reaction conditions, the role of the catalyst, and the
advantages and disadvantages of using gold are presented for all of
the reactions mentioned above. This book provides an overview of
the recent research results focusing on application of gold
catalysts for synthesis of valuable chemicals using renewable
feedstocks.
The first International Conference on Thermoelectric Properties of
Metallic Conductors was held at Michigan State University on August
10-12, 1977. The conference was sponsored and supported by the
National Science Foundation, the Office of Naval Research and the
Ford Motor Company. Although the topic may appear, at first glance,
rather narrow and of limited interest, it impacts significantly on
numerous fields of research, in each instance providing a unique
and fru- ful technique for securing important data that is
frequently difficult to obtain by other means. Thus, though
thermoelectricity is the thread that binds these pages together,
the papers constitute a patchwork quilt that includes critical
phenomena, superconductivity, many-body theory, quasi
one-dimensional systems, liquid metals, to mention only a few. This
volume contains the 12 invited and 31 contributed papers, arranged
in the order in which they were presented, as well as much of the
frequently spirited and always illuminating discussion that
followed these papers. Regrettably, not all of the discussion is
included. Difficulties with the recording system during the first
session (Wednesday morning) did not become apparent before the end
of that session, and, consequently, none of the discussion--some of
it fairly heated--appears in the proceedings; other remarks were
lost to posterity through occasional malfunctioning of the record
ing facilities and/or failure of speakers to come near a
microphone."
The rare earths have a unique place among the elements. Although
very much alike chemically and in most phy ical properties they
each have very different and striking magnetic properties. The
reason, of course, lies in their 4f electrons which determine the
magnetic properties but have little effect on other chemical and
physical behaviour. Although they are not rare, some indeed are
among the more common heavy elements in the earth's crust, the
difficulty of separation has meant that their intricate magnetic
properties have only recently been unravelled. Now, however, the
general pattern of their magnetism is well charted and the
underlying theory is well understood. Both are thoroughly
summarised in this book. It provides an excellent example of the
kind of extensive synthesis which is possible with modem solid
state physics. it represents only a high plateau in the ascent to
complete understanding. But It will become clear to the reader that
while the overall position is satisfactory there are many details
still to be elucidated experimentally and much to be done
theoretically before all the underlying forces are identified and
estimated from a priori calculations. It is hoped that the book
will provide a useful stimulus in this direction. It should also be
of use to those who are interested in related disciplines, for
example the rare earth compounds, or the transition metals. In
addition rare earths promise to be important technologically as
alloy constituents.
Industrial advances frequently depend on the development of new,
special-purpose ma terials possessing specific magnetic,
electrical, optical, strength, friction, antifriction, and other
properties. Metal alloys produced by the conventional technique of
metallurgical reduc tion often do not meet these new requirements.
Powder metallurgy, therefore, is of consider able importance in
solving many problems of present-day materials science. Its
production techniques-solid-phase and liquid-phase sintering,
impregnation, hot pressing - make it pos, ... sible to obtain
materials from metallic components which are immiscible in the
liquid state and also materials in which metals are combined with
nonmetallic components such as refract ory compounds- oxides,
carbides, nitrides, borides, sUicides, sulfides, etc. The
properties of sintered parts depend essentially on the processes
occurring during their formation. One of the most promising methods
of producing sintered materials of high density with the best
combination of various properties is liquid-phase sintering. In
recent years, many publications have appeared concerning processes
of sintering specific combinations of com ponents, the theoretical
basis of liquid-phase sintering, and the laws governing this
process. The present work examines liquid-phase sintering processes
and the action of capillary forces in models of dispersed
solid-liquid systems, and also gives data from theoretical and
experi mental studies of liquid-phase sintering in various metal
and metal-ceramic systems. Some theoretical generalizations on the
principles of sintering processes are presented, and the driv ing
forces of sintering and the effect of different conditions on
liquid-phase sintering processes are considered."
Fermi Surfaces of Low-Dimensional Organic Metals and
Superconductors is an introduction to quasi-one- and
quasi-two-dimensional organic metals and a review of the current
knowledge on the electronic structure of these materials. The
principal structural, electronic, and superconducting properties
are described and illustrated with many examples. The book
introduces the basic theoretical concepts necessary for the
understanding of the experimental techniques and reviews in detail
recent results in the investigation of the Fermi surface topology.
The book is intended both as an introduction and as a reference
book for active researchers.
Electrometallurgy is a broad field but it is not a new one. It was
the great Faraday in the 1830s who discovered laws covering the
electrodeposition of metals and its relation to the current passed
and equivalent weight of the metal undergoing depo- tion. Since
that time, applications and developments of his discoveries have
spread to many areas of technology. Electrowinning is the most well
known, partly because it embraces the process by which aluminum is
extracted from its ores. In electrorefining, the impure metal is
made into anode and the pure metal dissolved therefrom is deposited
on a cathode. Electroplating is exemplified by its use in the
manufacture of car bumpers. Finally, in electroreforming, objects
may be metallized, often with a very thin layer of the coating
desired. The numerous technologies vary greatly in the degree to
which they are intell- tualized. Until the work of Popov et al. ,
electrometallurgy has been regarded as largely empirical, an
activity in which there was much art and little science. This will
all change with the publication of this book. Several aspects of
the background of its senior author, Konstantin Popov, make him
uniquely suited to the job of intellectual- ing electrometallurgy.
First, he had as his mentor the great surely the leading
electrochemist in Eastern Europe since the death of Frumkin.
Second, he has had ample experience with the leading
electrochemical engineer in America, Ralph White.
The increasing use of powder metallurgy techniques to make an
almost infinite variety of materials and products places greater
emphasis on utilization of sophisticated experimental techniques.
Usually research and development efforts initiate the use of newly
developed equipment and analytical procedures. Indeed, the contents
of this book are strongly linked to research endeavors, in both the
academic and industrials worlds. However, this volume can serve a
much needed function in industrial applied powder metallurgy.
Although many research ers will find the contents of great value,
the technical personnel more involved with production, quality
control, customer services and product design now have at their
dispo sal a means to learn about the potential uses of several very
important techniques. With today's "knowledge explosion" the
present set of papers greatly facilitates the comprehension and
adoption of new procedures. If powder metallurgy is to continue its
rapid rate of growth in virtually all segments of industry, then
the transition of modern equipment and procedures from tools of
research and development laboratories to everyday plant operations
and applications must be hastened. The editors hope that this
volume aids in this process, as well as assisting students and
researchers by providing a ready source of up-to-date useful
information.
Stereology is the science that relates three-dimensional structure
to the two-dimensional images that can be measured. The most common
field of application is in microscopy, both of man-made materials
(metals, ceramics, composites, etc.) and of biological tissue
samples. This book covers the applications and terminology of both
fields. Recent emphasis in stereology is concerned with sampling
strategies to avoid bias due to directionality and non-uniformity,
and these methods are fully covered. So are the classic techniques
that measure size distributions, surface curvature, etc., which are
widely useful but not discussed in other recent texts. Finally,
most stereology is taught as manual procedures using counting and
grids, but this text also covers the use of modern desktop
computers for image analysis and processing to obtain and interpret
the stereological data.
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