Palladacycles: Catalysis and Beyond provides an overview of recent research in palladacycles in catalysis for cross-coupling and similar reactions. In the quest for developing highly efficient and robust palladium-based catalysts for C-C bond formation via cross-coupling reactions, palladacycles have played a significant role. In recent years, they have found a wide variety of applications, ranging from catalysts for cross-coupling and related reactions, to their more recent application as anticancer agents. This book explores early examples of the use of palladacyclic complexes in catalysis employing azobenzene and hydrazobenzene as coordinating ligands. Its applications in processes such as selective reduction of alkenes, alkynes, or nitroalkanes are also covered. Palladacycles: Catalysis and Beyond reveals the tremendous advances that have taken place in the potential applications of palladacycles as versatile catalysts in academia and industry. It is a valuable resource for synthetic chemists, organometallic chemists, and chemical biologists.

During September 24-26, 2001, the Faculty of Aerospace Engineering of the Delft University of Technology in the Netherlands organised the Glare - the New Material for Aircraft Conference, an international conference on the relationship between design, material choice and application of aircraft materials with respect to new developments in industry. Eminent representatives from the aircraft manufacturing world, including manufacturers, airlines, airports, universities, governments and aviation authorities, were present at this conference to meet and exchange ideas - see the group photo on the next two pages. The fact that the conference was held just two weeks after 'September 11, 2001' put things in a rather unique perspective. The aim of the conference was to illustrate the many unique applications of the Glare family of fibre metal laminates and to provide for the exchange and distribution of information regarding this material in order to stimulate their acceptance and promote further application. The introduction of fibre metal laminates into the commercial aviation market took about 20 years' time. Introducing new technologies should not be taken lightly, however; the aircraft industry is by nature rather conservative and innovations must therefore be proven - a paradox actually - in all possible ways before they can be introduced in real aircraft structures. Not only do technical aspects play a role in this respect; historical, cultural, economical and political issues are equally important.

This textbook is a revised and enlarged version of notes for a one-semester course on electromagnetism. It covers the theory of electromagnetic phenomena in vacuum and in material media. The book includes a CD-ROM with didactic software, to solve boundary value problems in electrostatics and magnetostatics.

Christian Heinemann explores a unifying model which couples phase separation and damage processes in a system of partial differential equations. The model has technological applications to solder materials where interactions of both phenomena have been observed and cannot be neglected for a realistic description. The author derives the equations in a thermodynamically consistent framework and presents suitable weak formulations for various types of this coupled system. In the main part, he proves the existence of weak solutions and investigates degenerate limits.

The concept of virtual manufacturing has been developed in order to increase the industrial performances, being one of the most ef cient ways of reducing the m- ufacturing times and improving the quality of the products. Numerical simulation of metal forming processes, as a component of the virtual manufacturing process, has a very important contribution to the reduction of the lead time. The nite element method is currently the most widely used numerical procedure for s- ulating sheet metal forming processes. The accuracy of the simulation programs used in industry is in uenced by the constitutive models and the forming limit curves models incorporated in their structure. From the above discussion, we can distinguish a very strong connection between virtual manufacturing as a general concept, ?nite element method as a numerical analysis instrument and constitutive laws,aswellas forming limit curves as a speci city of the sheet metal forming processes. Consequently, the material modeling is strategic when models of reality have to be built. The book gives a synthetic presentation of the research performed in the eld of sheet metal forming simulation during more than 20 years by the members of three international teams: the Research Centre on Sheet Metal Forming-CERTETA (Technical University of Cluj-Napoca, Romania); AutoForm Company from Zurich, Switzerland and VOLVO automotive company from Sweden. The rst chapter presents an overview of different Finite Element (FE) formu- tions used for sheet metal forming simulation, now and in the past.

"Biomimetics in Materials Science" provides a comprehensive theoretical and practical review of biomimetic materials with self-healing, self-lubricating and self-cleaning properties. These three topics are closely related and constitute rapidly developing areas of study. The field of self-healing materials requires a new conceptual understanding of this biomimetic technology, which is in contrast to traditional engineering processes such as wear and fatigue. "Biomimetics in Materials Science" is the first monograph to be devoted to these materials. A new theoretical framework for these processes is presented based on the concept of multi-scale structure of entropy and non-equilibrium thermodynamics, together with a detailed review of the available technology. The latter includes experimental, modeling, and simulation results obtained on self-healing/lubricating/cleaning materials since their emergence in the past decade."

Fatigue of structures and materials covers a wide scope of different topics. The purpose of the present book is to explain these topics, to indicate how they can be analyzed, and how this can contribute to the designing of fatigue resistant structures and to prevent structural fatigue problems in service. Chapter 1 gives a general survey of the topic with brief comments on the signi?cance of the aspects involved. This serves as a kind of a program for the following chapters. The central issues in this book are predictions of fatigue properties and designing against fatigue. These objectives cannot be realized without a physical and mechanical understanding of all relevant conditions. In Chapter 2 the book starts with basic concepts of what happens in the material of a structure under cyclic loads. It illustrates the large number of variables which can affect fatigue properties and it provides the essential background knowledge for subsequent chapters. Different subjects are presented in the following main parts: * Basic chapters on fatigue properties and predictions (Chapters 2-8) * Load spectra and fatigue under variable-amplitude loading (Chapters 9-11) * Fatigue tests and scatter (Chapters 12 and 13) * Special fatigue conditions (Chapters 14-17) * Fatigue of joints and structures (Chapters 18-20) * Fiber-metal laminates (Chapter 21) Each chapter presents a discussion of a speci?c subject.

Machining of Metal Matrix Composites provides the fundamentals and recent advances in the study of machining of metal matrix composites (MMCs). Each chapter is written by an international expert in this important field of research. Machining of Metal Matrix Composites gives the reader information on machining of MMCs with a special emphasis on aluminium matrix composites. Chapter 1 provides the mechanics and modelling of chip formation for traditional machining processes. Chapter 2 is dedicated to surface integrity when machining MMCs. Chapter 3 describes the machinability aspects of MMCs. Chapter 4 contains information on traditional machining processes and Chapter 5 is dedicated to the grinding of MMCs. Chapter 6 describes the dry cutting of MMCs with SiC particulate reinforcement. Finally, Chapter 7 is dedicated to computational methods and optimization in the machining of MMCs. Machining of Metal Matrix Composites can serve as a useful reference for academics, manufacturing and materials researchers, manufacturing and mechanical engineers, and professionals involved with MMC applications. It can also be used to teach modern manufacturing engineering or as a textbook for advanced undergraduate and postgraduate engineering courses in machining, manufacturing or materials.

Metal matrix composites are making tangible inroads into the "real" world of engineering. They are used in engineering components such as brake rotors, aircraft parts, combustion engines, and heat sinks for electronic systems. Yet, outside a relatively limited circle of specialists, these materials are mostly unknown. Designers do not as a rule think of using these materials, in part because access to information is difficult as these materials have not really entered engineering handbooks. Metal Matrix Composites in Industry is thus useful to engineers who wish to gain introductory knowledge of these materials and who want to know where "to find" them. Additionally, it provides researchers and academics with a survey of current industrial activity in this area of technology.

By drawing together the current theoretical and experimental understanding of the phenomena of delayed hydride cracking (DHC) in zirconium alloys, The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Components: Delayed Hydride Cracking provides a detailed explanation focusing on the properties of hydrogen and hydrides in these alloys. Whilst the emphasis lies on zirconium alloys, the combination of both the empirical and mechanistic approaches creates a solid understanding that can also be applied to other hydride forming metals. This up-to-date reference focuses on documented research surrounding DHC, including current methodologies for design and assessment of the results of periodic in-service inspections of pressure tubes in nuclear reactors. Emphasis is placed on showing how our understanding of DHC is supported by progress in general understanding of such broad fields as the study of hysteresis associated with first order phase transformations, phase relationships in coherent crystalline metallic solids, the physics of point and line defects, diffusion of substitutional and interstitial atoms in crystalline solids, and continuum fracture and solid mechanics. Furthermore, an account of current methodologies is given illustrating how such understanding of hydrogen, hydrides and DHC in zirconium alloys underpins these methodologies for assessments of real life cases in the Canadian nuclear industry. The all-encompassing approach makes The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Component: Delayed Hydride Cracking an ideal reference source for students, researchers and industry professionals alike.

The mineral resources of the industrialized countries, especially the member nations of the North Atlantic Treaty Organiza tion, are being depleted at such a rate that more and more of these count ries are beginning to depend on ore imported from other coun tries. To sustain the economic and strategie well-being of these member countries, it becomes imperative that a program of developing and exploiting other non-conventional mineral resources and a con servation program where metal values from waste dumps and scrap metals and alloys are recycled must be initiated and implemented. In order to meet this challenge, new processes and technology must be available for consideration in the design and operation of the new plants. One of the possible routes of extracting the metals from their ores, especially for multimetal complex ores and very low grade ores, is by hydrometallurgical processing. The hydrometallurgical route of metal recovery where dissolution (leaching), separation and concentration (ion exchange, solvent extraction, and membrane separation) and reduction to metal (cementation, precipitation by gaseous reduction, and electrolysis) is carried out at near ambient temperature is becoming more competi tive with the conventional high temperature processes used in the smelting of metals from high grade and beneficiated ores.

Jonathan Scragg documents his work on a very promising material suitable for use in solar cells. Copper Zinc Tin Sulfide (CZTS) is a low cost, earth-abundant material suitable for large scale deployment in photovoltaics. Jonathan pioneered and optimized a low cost route to this material involving electroplating of the three metals concerned, followed by rapid thermal processing (RTP) in sulfur vapour. His beautifully detailed RTP studies - combined with techniques such as XRD, EDX and Raman - reveal the complex relationships between composition, processing and photovoltaic performance. This exceptional thesis contributes to the development of clean, sustainable and alternative sources of energy

Erosive wear is characterized by successive loss of material from the surface due to the continuous impact of solid particles. This type of wear affects numerous industries, such as power generation, mining, and the pneumatic transportation of solids. The worst case scenario normally occurs where there is a combination of both erosion and oxidation, especially at high temperatures. In order to minimize damage caused by erosive wear, many authors propose the use of better bulk materials or surface coatings, and generally cermets are suggested. Various researchers have conducted experiments to study the wear mechanisms occurring in this kind of materials, but most of these experiments do not lead to similar results; in fact, there is no accordance among the authors, and moreover, some wear variables are ignored. In this book, studies undertaken in this field by several investigators have been discussed extensively. At the end of it, table reviews are suggested to summarize the most important mechanisms of the erosive wear in bulk and coating cermets.

Charge density analysis of materials provides a firm basis for the evaluation of the properties of materials. The design and engineering of a new combination of metals requires a firm knowledge of intermolecular features. Recent advances in technology and high-speed computation have made the crystal X-ray diffraction technique a unique tool for the determination of charge density distribution in molecular crystal. Methods have been developed to make experimental probes capable of unraveling the features of charge densities in the intra- and inter-molecular regions of crystal structures. In Metal and Alloy Bonding - An Experimental Analysis, the structural details of materials are elucidated with the X-ray diffraction technique. Analyses of the charge density and the local and average structure are given to reveal the structural properties of technologically important materials. Readers will gain a new understanding of the local and average structure of existing materials. The electron density, bonding, and charge transfer studies in Metal and Alloy Bonding - An Experimental Analysis contain useful information for researchers in the fields of physics, chemistry, materials science, and metallurgy. The properties described in these studies can contribute to the successful engineering of these technologically important materials.