This book provides an introduction to fundamental concepts of solid mechanics for the uninitiated. It also includes a concise review of fundamentals for those who have been away from the field for a time or are studying for a final exam or engineering license exam. The coverage ranges from fundamental definitions through constitutive equations, axial loading, torsion, bending, thermal effects, stability, pressure vessels, plates and shells, computational mechanics, and fibrous composite materials.

This thesis reports a rare combination of experiment and theory on the role of geometry in materials science. It is built on two significant findings: that curvature can be used to guide crack paths in a predictive way, and that protected topological order can exist in amorphous materials. In each, the underlying geometry controls the elastic behavior of quasi-2D materials, enabling the control of crack propagation in elastic sheets and the control of unidirectional waves traveling at the boundary of metamaterials. The thesis examines the consequences of this geometric control in a range of materials spanning many orders of magnitude in length scale, from amorphous macroscopic networks and elastic continua to nanoscale lattices.

This book presents experimental studies on emergent transport and magneto-optical properties in three-dimensional topological insulators with two-dimensional Dirac fermions on their surfaces. Designing magnetic heterostructures utilizing a cutting-edge growth technique (molecular beam epitaxy) stabilizes and manifests new quantization phenomena, as confirmed by low-temperature electrical transport and time-domain terahertz magneto-optical measurements. Starting with a review of the theoretical background and recent experimental advances in topological insulators in terms of a novel magneto-electric coupling, the author subsequently explores their magnetic quantum properties and reveals topological phase transitions between quantum anomalous Hall insulator and trivial insulator phases; a new topological phase (the axion insulator); and a half-integer quantum Hall state associated with the quantum parity anomaly. Furthermore, the author shows how these quantum phases can be significantly stabilized via magnetic modulation doping and proximity coupling with a normal ferromagnetic insulator. These findings provide a basis for future technologies such as ultra-low energy consumption electronic devices and fault-tolerant topological quantum computers.

This book describes how advances in recording and printing technologies have influenced the research and teaching style of succeeding generations of physicists, chemists, and astronomers, particularly from the boom of spectrum analysis in the 1860s until the advent of quantum mechanics. Seemingly disparate strands such as spectrochemistry and cartography, instrument-design and science education are woven into the rich tapestry of one of the most fascinating and influential research-technologies of the late 19th and early 20th century.

Solid-State NMR Characterization of Heterogeneous Catalysts and Catalytic Reactions provides a comprehensive account of state-of-the-art solid-state NMR techniques and the application of these techniques in heterogeneous catalysts and related catalytic reactions. It includes an introduction to the basic theory of solid-state NMR and various frequently used techniques. Special emphasis is placed on characterizing the framework and pore structure, active site, guest-host interaction, and synthesis mechanisms of heterogeneous catalysts using multinuclear one- and two-dimensional solid-sate NMR spectroscopy. Additionally, various in-situ solid-state NMR techniques and their applications in investigation of the mechanism of industrially important catalytic reactions are also discussed. Both the fundamentals and the latest research results are covered, making the book suitable as a reference guide for both experienced researchers in and newcomers to this field. Feng Deng is a Professor at Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences.

This book highlights the power and elegance of algebraic methods of solving problems in quantum mechanics. It shows that symmetries not only provide elegant solutions to problems that can be solved exactly, but also substantially simplify problems that must be solved approximately. Furthermore, the book provides an elementary exposition of quantum electrodynamics and its application to low-energy physics, along with a thorough analysis of the role of relativistic, magnetic, and quantum electrodynamic effects in atomic spectroscopy. Included are essential derivations made clear through detailed, transparent calculations. The book's commitment to deriving advanced results with elementary techniques, as well as its inclusion of exercises will enamor it to advanced undergraduate and graduate students.

Nanomaterials in Chromatography: Current Trends in Chromatographic Research Technology and Techniques provides recent advancements in the wide variety of chromatographic techniques applied to nanotechnology. As nanomaterials' unique properties can improve detection sensitivity and miniaturize the devices used in analytical procedures, they can substantially affect the evaluation and analysis ability of scientists and researchers and foster exciting developments in separation science. The book includes chapters on such crucial topics as the use of nanomaterials in sample preparation and the legalization of nanomaterials, along with a section on reducing the cost of the analysis process, both in terms of chemicals and time consumption.

This book features the essential material for any graduate or advanced undergraduate course covering solid-state electrochemistry. It provides the reader with fundamental course notes and numerous solved exercises, making it an invaluable guide and compendium for students of the subject. The book places particular emphasis on enhancing the reader's expertise and comprehension of thermodynamics, the Kroeger-Vink notation, the variation in stoichiometry in ionic compounds, and of the different types of electrochemical measurements together with their technological applications. Containing almost 100 illustrations, a glossary and a bibliography, the book is particularly useful for Master and PhD students, industry engineers, university instructors, and researchers working with inorganic solids in general.

Covers application of Deep Eutectic Solvents (DES) in extraction of aromatics and polyaromatics from fuel oil by Liquid-Liquid extraction Studies eutectic behavior with respect to hydrocarbon and aqueous solutions Describes molecular dynamics insights of extraction by DES Explores possible industrial applicability of potential DES Includes results from Gaussian, NAMD and PACKMOL software packages

Beginning with a review of the important areas of mathematics, this book then covers many of the underlying theoretical and practical aspects of NMR and MRI spectroscopy from a maths point of view. Competence in algebra and introductory calculus is needed but all other maths concepts are covered. It will bridge a gap between high level and introductory titles used in NMR or MRI spectroscopy. Uniquely, it takes a very careful and pedagogical approach to the mathematics behind NMR and MRI. It leaves out very few steps, which distinguishes it from other books in the field. The author is an NMR laboratory manager and is sympathetic to the frustrations of trying to understand where some of the fundamental equations come from hence his desire to either explicitly derive all equations for the reader or direct them to derivations. This is an essential text aimed at graduate students who are beginning their careers in NMR or MRI spectroscopy and laboratory managers if they need an understanding of the theoretical foundations of the technique.

This thesis extends our understanding of systems of independent electrons by developing a generalization of Bloch's Theorem which is applicable whenever translational symmetry is broken solely due to arbitrary boundary conditions. The thesis begins with a historical overview of topological condensed matter physics, placing the work in context, before introducing the generalized form of Bloch's Theorem. A cornerstone of electronic band structure and transport theory in crystalline matter, Bloch's Theorem is generalized via a reformulation of the diagonalization problem in terms of corner-modified block-Toeplitz matrices and, physically, by allowing the crystal momentum to take complex values. This formulation provides exact expressions for all the energy eigenvalues and eigenstates of the single-particle Hamiltonian. By precisely capturing the interplay between bulk and boundary properties, this affords an exact analysis of several prototypical models relevant to symmetry-protected topological phases of matter, including a characterization of zero-energy localized boundary excitations in both topological insulators and superconductors. Notably, in combination with suitable matrix factorization techniques, the generalized Bloch Hamiltonian is also shown to provide a natural starting point for a unified derivation of bulk-boundary correspondence for all symmetry classes in one dimension.

This book reports on the development and application of a new uniaxial pressure apparatus that is currently generating considerable interest in the field of materials physics. The author provides practical guidelines for performing such experiments, backed up by finite element simulations. Subsequently, the book reports on two uses of the device. In the first, high pressures are used to tune to a Van Hove singularity in Sr2RuO4, while the effects on the unconventional superconductivity and the normal state properties are investigated. In the second experiment, precise and continuous strain control is used to probe symmetry breaking and novel phase formation in the vicinity of a quantum critical point in Sr3Ru2O7.

This monograph deals with theoretical aspects and numerical simulations of the interaction of electromagnetic fields with nonlinear materials. It focuses in particular on media with nonlinear polarization properties. It addresses the direct problem of nonlinear Electrodynamics, that is to understand the nonlinear behavior in the induced polarization and to analyze or even to control its impact on the propagation of electromagnetic fields in the matter. The book gives a comprehensive presentation of the results obtained by the authors during the last decade and put those findings in a broader, unified context and extends them in several directions.It is divided into eight chapters and three appendices. Chapter 1 starts from the Maxwell's equations and develops a wave propagation theory in plate-like media with nonlinear polarizability. In chapter 2 a theoretical framework in terms of weak solutions is given in order to prove the existence and uniqueness of a solution of the semilinear boundary-value problem derived in the first chapter. Chapter 3 presents a different approach to the solvability theory of the reduced frequency-domain model. Here the boundary-value problem is reduced to finding solutions of a system of one-dimensional nonlinear Hammerstein integral equations. Chapter 4 describes an approach to the spectral analysis of the linearized system of integral equations. Chapters 5 and 6 are devoted to the numerical approximation of the solutions of the corresponding mathematical models. Chapter 7 contains detailed descriptions, discussions and evaluations of the numerical experiments. Finally, chapter 8 gives a summary of the results and an outlook for future work.

Designed to sit alongside more conventional established condensed matter physics textbooks, this compact volume offers a concise presentation of the principles of solid state theory, ideal for advanced students and researchers requiring an overview or a quick refresher on a specific topic. The book starts from the one-electron theory of solid state physics, moving through electron-electron interaction and many-body approximation schemes, to lattice oscillations and their interactions with electrons. Subsequent chapters discuss transport theory and optical properties, phase transitions and some properties of low-dimensional semiconductors. This extensively expanded second edition includes new material on adiabatic perturbation theory, kinetic coefficients, the Nyquist theorem, Bose condensation, and the field-theoretical approach to non-relativistic quantum electrodynamics. Throughout the text, mathematical proofs are often only sketched, and the final chapter of the book reviews some of the key concepts and formulae used in theoretical physics. Aimed primarily at graduate and advanced undergraduate students taking courses on condensed matter theory, the book serves as a study guide to reinforce concepts learned through conventional solid state texts. Researchers and lecturers will also find it a useful resource as a concise set of notes on fundamental topics.

The interaction of electromagnetic waves with matter in the frequency range between 10-6 and 1012 Hz is the domain of broadband dielectric spectroscopy. In this extraordinarily extended dynamic range molecular and collective dipolar fluctuations, charge transport and polarisation effects at inner and outer boundaries take place and determine the dielectric properties of the material being studied. Hence, broadband dielectric spectroscopy enables one to gain a wealth of information on the dynamics of bound (dipoles) and mobile charge carriers depending on the details of a molecular system. It is the intention of this book to be both an introductory course to broadband dielectric spectroscopy as well as a monograph describing recent dielectric contributions to current topics. In this respect the book will correspond to the needs of graduate students but also to specialized researchers, molecular physicists, polymer scientists and materials scientists in academia and in industry.

Synchrotron radiation has been a revolutionary and invaluable research tool for a wide range of scientists, including chemists, biologists, physicists, materials scientists, geophysicists. It has also found multidisciplinary applications with problems ranging from archeology through cultural heritage to paleontology. The subject of this book is x-ray spectroscopy using synchrotron radiation, and the target audience is both current and potential users of synchrotron facilities. The first half of the book introduces readers to the fundamentals of storage ring operations, the qualities of the synchrotron radiation produced, the x-ray optics required to transport this radiation, and the detectors used for measurements. The second half of the book describes the important spectroscopic techniques that use synchrotron x-rays, including chapters on x-ray absorption, x-ray fluorescence, resonant and non-resonant inelastic x-ray scattering, nuclear spectroscopies, and x-ray photoemission. A final chapter surveys the exciting developments of free electron laser sources, which promise a second revolution in x-ray science. Thanks to the detailed descriptions in the book, prospective users will be able to quickly begin working with these techniques. Experienced users will find useful summaries, key equations, and exhaustive references to key papers in the field, as well as outlines of the historical developments in the field. Along with plentiful illustrations, this work includes access to supplemental Mathematica notebooks, which can be used for some of the more complex calculations and as a teaching aid. This book should appeal to graduate students, postdoctoral researchers, and senior scientists alike.

This thesis addresses elementary dislocation processes occurring in single-crystalline alloys based on Fe-Al, and investigates correspondences between dislocation distribution inside crystals characterized by transmission electron microscopy (TEM) and surface patterns observed using atomic force microscopy (AFM). Fe-Al alloys with different degrees of ordering were prepared and deformed in compression at ambient temperature in-situ inside the AFM device. The evolution of slip line structures was captured in the sequences of AFM images and wavy slip bands, while cross slip at the tip of the slip band and homogeneous fine slip lines were also identified. Further, the thesis develops a technique for constructing 3D representations of dislocations observed by TEM without the prohibitive difficulties of tomography, and creates 3D models of dislocation structures. Generally speaking, the thesis finds good agreement between AFM and TEM observations, confirming the value of AFM as a relevant tool for studying dislocations.

This book presents not only the simultaneous combination of optical methods based on holographic principles for marker-free imaging, real-time trapping, identification and tracking of micro objects, but also the application of substantial low coherent light sources and non-diffractive beams. It first provides an overview of digital holographic microscopy (DHM) and holographic optical tweezers as well as non-diffracting beam types for minimal-invasive, real-time and marker-free imaging as well as manipulation of micro and nano objects. It then investigates the design concepts for the optical layout of holographic optical tweezers (HOTs) and their optimization using optical simulations and experimental methods. In a further part, the book characterizes the corresponding system modules that allow the addition of HOTs to commercial microscopes with regard to stability and diffraction efficiency. Further, based on experiments and microfluidic applications, it demonstrates the functionality of the combined setup, and discusses several types of non-diffracting beams and their application in optical manipulation. The book shows that holographic optical tweezers, including several non-diffracting beam types like Mathieu beams, combined parabolic and Airy beams, not only open up the possibility of generating efficient multiple dynamic traps for micro and nano particles with forces in the pico and nano newton range, but also the opportunity to exert optical torque with special beams like Bessel beams, which can facilitate the movement and rotation of particles by generating microfluidic flows. The last part discusses the potential use of a slightly modified DHM-HOT-system to explore the functionality of direct laser writing based on a two photon absorption process in a negative photoresist with a continuous wave laser

This book covers virtually all aspects of semiconductor nanowires, from growth to related applications, in detail. First, it addresses nanowires' growth mechanism, one of the most important topics at the forefront of nanowire research. The focus then shifts to surface functionalization: nanowires have a high surface-to-volume ratio and thus are well-suited to surface modification, which effectively functionalizes them. The book also discusses the latest advances in the study of impurity doping, a crucial process in nanowires. In addition, considerable attention is paid to characterization techniques such as nanoscale and in situ methods, which are indispensable for understanding the novel properties of nanowires. Theoretical calculations are also essential to understanding nanowires' characteristics, particularly those that derive directly from their special nature as one-dimensional nanoscale structures. In closing, the book considers future applications of nanowire structures in devices such as FETs and lasers.

The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science. The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics. Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist. Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned. Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students

This book presents recent advances in the design, fabrication and implementation of flexible printed sensors. It explores a range of materials for developing the electrode and substrate parts of the sensors, on the basis of their electrical and mechanical characteristics. The sensors were processed using laser cutting and 3D printing techniques, and the sensors developed were employed in a number of healthcare, environmental and industrial applications, including: monitoring of physiological movements, respiration, salinity and nitrate measurement, and tactile sensing. The type of sensor selected for each application depended on its dimensions, robustness and sensitivity. The sensors fabricated were also embedded in an IoT-based system, allowing them to be integrated into real-time applications.

Annual Reports on NMR Spectroscopy, Volume 93 provides a thorough and in-depth accounting of progress in nuclear magnetic resonance (NMR) spectroscopy and its many applications. This updated volume in this premier resource for both specialists and non-specialists focuses on NMR at Giga-Pascal Pressures, Ultrafast 2D NMR: Methods and Applications, Perspective on the Hyperpolarization Technique Signal Amplification by Reversible Exchange (SABRE) in NMR Spectroscopy and MR Imaging, and Recent Advances in 11B Solid-State Nuclear Magnetic Resonance Spectroscopy of Crystalline Solids, and Progress in Our Understanding of 19F Chemical Shifts, amongst other timely topics.

The reader is provided with information about methods of calibration of light sources and photodetectors as well as responsiveness of spectral instruments ranging from near infrared to vacuum UV spectral, 1200 - 100 nm, and radiation intensities of up to several quanta per second in absolute and arbitrary units. The author describes for the first time original methods of measurements they created and draws upon over 40 years of experience in working with light sources and detectors to provide accurate and precise measurements. This book is the first to cover these aspects of radiometry and is divided into seven chapters thatexamine information about terminology, units, light sources and detectors, methods, including author's original ones, of absolute calibration of detectors, spectral instruments responsiveness, absolute measurements of radiation intensity of photoprocesses, and original methods of their study. Of interest to researchers measuring; luminescence spectra, light intensities from IR to vacuum UV, spectral range in wide-light intensity ranges, calibrate light sources and detectors, absolute or relative quantum yields of photoprocess determination.

This book provides knowledge of the basic theory, spectral analysis methods, chemometrics, instrumentation, and applications of near-infrared (NIR) spectroscopy-not as a handbook but rather as a sourcebook of NIR spectroscopy. Thus, some emphasis is placed on the description of basic knowledge that is important in learning and using NIR spectroscopy. The book also deals with applications for a variety of research fields that are very useful for a wide range of readers from graduate students to scientists and engineers in both academia and industry. For readers who are novices in NIR spectroscopy, this book provides a good introduction, and for those who already are familiar with the field it affords an excellent means of strengthening their knowledge about NIR spectroscopy and keeping abreast of recent developments.

In the last 500 years, the worldwide community of chemistry has produced individuals who attempted to synthesize a coherent view of chemistry that could be taught to actual students. This book attempts to define the characteristics of good chemical preceptors. Even chemical geniuses can become so focused on their own work that they are not understood by the bulk of their contemporaries and cannot contribute to the synoptic view of chemistry needed for effective teaching. It is hoped that the insights presented in this work will be of benefit to all current preceptors in chemistry.