During my professional career, I developed a strong interest in sol-gel technology, and worked on both xerogel and aerogel systems. My fascination with aerogels has driven me to explore their commercial potential, which is currently an important component of my company's business plan. Together with my co-workers, I have also worked on the preparation of controlled PZT and silica xerogels as well as thin film coatings of metals by the sol-gel technology, These experiences convinced me of the tremendous potentials of this technology. A conviction that is shared by many scientists, engineers, and business leaders around the globe. Many sol-gel derived products are already articles of commerce. However, to expand the commercial potential of sol-gel technology, two challenges must be met: (1) the quality of sol-gel derived products must continue to meet or exceed the quality of competing products, (2) the production cost of sol-gel products (specially aerogels) must continued to decline. A key to lowering the costs of sol-gel products is finding inexpensive precursors.

Interfacial science impacts on our lives in diverse and surprising ways. Without it, we would face bubble bath without the bubbles, detergents which don't clean, cappuccinos without the froth. It has also fuelled some of the most ground-breaking and throught-provoking advances in research in recent times, from biosciences to nanotechnology. Introduction to Interfacial Science offers an engaging insight into the study of the physical and chemical properties of interfaces, how they behave, why they behave as they do, and how this behavior can be harnessed and exploited in novel and exciting ways.
Interfacial Science: An Introduction is an accessible text introducing readers to the chemistry of interfaces, a subject of increasing relevance and popularity due to the emergence of nanoscience.
Opening with an overview of the key principles of capilliarity and adsorption, the book goes on to explore liquid/gas, solid/gas, and liquid/liquid interfaces, before examining biological interfaces, one of the most stimulating areas of current research. With the careful explanation of essential mathematical and physical concepts, and description of real world applications of the material presented, the book helps the student to build confidence in, and see the relevance of, the topics covered.
Striking a careful balance between the highly mathematical treatments of the subject by more specialist texts, and the rudimentary treatment offered by general physical chemistry texts, Interfacial Science: An Introduction offers a breadth and depth of treatment which is perfect for any advanced undergraduate course on this exciting, dynamic subject.

Online Resource Center
The Online Resource Center to accompany Interfacial Science: An Introduction features the following resources for registered adopters of the text:
- Downloadable figures
- Solutions manual, containing worked solutions to the exercises appearing in the textbook
- Protocols for around five laboratory experiments, appearing as MS Word documents, for lecturers to modify to suit their own particular setups

This book describes solid surfaces and their properties on both small and large scales. It look at how atoms and molecules interact with surfaces and how and why they subsequently react and/or behave. The book is written for undergraduates, and builds on their knowledge from their first year. It reflects the striking advances made in recent years through the study of well defined single crystal surfaces.

This book introduces the fascinating world of self-assembly in mesoporous ordered silica films. Beginning from a single droplet, it guides the reader, in a step-by-step learning process, how to obtain and control ordered porous mesophases in thin films by varying only the precursor chemistry and the process. It explains, in great detail, how order control is achieved through chemical design and post-deposition processing, the latter of which is a unique property in materials science. The book places a special focus on silica, whose particularly complex chemistry enables order control over a range of different length scales. This book is suitable for students and researchers in the fields of sol-gel or colloidal chemistry and interested in the topics of self-assembly and mesoporous phases.

This book focuses on the use of natural surfactants in enhanced oil recovery, providing an overview of surfactants, their types, and different physical-chemical properties used to analyse the efficiency of surfactants. Natural surfactants discuss the history of the surfactants, their classification, and the use of surfactants in petroleum industry. Special attention has been paid to natural surfactants and their advantages over synthetic surfactants, including analysing their properties such as emulsification, interfacial tension, and wettability and how these can be used in EOR. This book offers an overview for researchers and graduate students in the fields of petroleum and chemical engineering, as well as oil and gas industry professionals.

This book provides a general overview and current state of the art of different types of metal oxide nanomaterials, either in nanoparticles or thin film structure. It covers from the development and optimization of different nanofabrication/synthesis techniques for nanostructures which are currently the attention of the research community, the study of the structure and interactions by different characterization techniques of heterostructured materials and the final impact in different applications such as nanotherapy, data storage, super magnets, high-frequency devices. The book's 13 chapters provide deep insight into the intriguing science of oxide materials and include contributions on novel technologies to fabricate nanomaterials with a broad range of functional properties (semiconducting, magnetic, ferroelectric, thermoelectric, optical, flexible and mechanical). This book is intended to the experts for consolidation of their knowledge but also for students who aim to learn and get basics of nanostructured metal oxides in diverse forms.

This book presents contributions on a wide range of computational research applied to fields ranging from molecular systems to bulk structures. This volume highlights current trends in modern computational chemistry and discusses the development of theoretical methodologies, state-of-the-art computational algorithms and their practical applications. This volume is part of a continuous effort by the editors to document recent advances by prominent researchers in the area of computational chemistry. Most of the chapters are contributed by invited speakers and participants to International annual conference "Current Trends in Computational Chemistry", organized by Jerzy Leszczynski, one of the editors of the current volume. This conference series has become an exciting platform for eminent theoretical and computational chemists to discuss their recent findings and is regularly honored by the presence of Nobel laureates. Topics covered in the book include reactive force-field methodologies, coarse-grained modeling, DNA damage radiosensitizers, modeling and simulation of surfaces and interfaces, non-covalent interactions, and many others. The book is intended for theoretical and computational chemists, physical chemists, material scientists and those who are eager to apply computational chemistry methods to problems of chemical and physical importance. It is a valuable resource for undergraduate, graduate and PhD students as well as for established researchers.

This book presents the optimal auxiliary functions method and applies it to various engineering problems and in particular in boundary layer problems. The cornerstone of the presented procedure is the concept of "optimal auxiliary functions" which are needed to obtain accurate results in an efficient way. Unlike other known analytic approaches, this procedure provides us with a simple but rigorous way to control and adjust the convergence of the solutions of nonlinear dynamical systems. The optimal auxiliary functions are depending on some convergence-control parameters whose optimal values are rigorously determined from mathematical point of view. The capital strength of our procedure is its fast convergence, since after only one iteration, we obtain very accurate analytical solutions which are very easy to be verified. Moreover, no simplifying hypothesis or assumptions are made. The book contains a large amount of practical models from various fields of engineering such as classical and fluid mechanics, thermodynamics, nonlinear oscillations, electrical machines, and many more. The book is a continuation of our previous books "Nonlinear Dynamical Systems in Engineering. Some Approximate Approaches", Springer-2011 and "The Optimal Homotopy Asymptotic Method. Engineering Applications", Springer-2015.

Small solid particles adsorbed at liquid interfaces arise in many industrial products and process, such as anti-foam formulations, crude oil emulsions and flotation. They act in many ways like traditional surfactant molecules, but offer distinct advantages. However, the understanding of how these particles operate in such systems is minimal. This book brings together the diverse topics actively being investigated, with contributions from leading experts in the field. After an introduction to the basic concepts and principles, the book divides into two sections. The first deals with particles at planar liquid interfaces, with chapters of an experimental and theoretical nature. The second concentrates on the behaviour of particles at curved liquid interfaces, including particle-stabilised foams and emulsions and new materials derived from such systems. This unique collection will be of interest to academic researchers and graduate students in chemistry, physics, chemical engineering, pharmacy, food science and materials science.

This book aims at identifying novel advanced materials of extreme wetting properties (MEWP) for practical, industrial applications. The state-of-the art superhdyrophobic, superhdyrophilic, superoleophobic, superoleophilic, and superomniphobic materials, that are MEWP, with respect to their technological and emerging industrial applications are discussed in this book. MEWP offer new perspectives providing numerous potential applications. Hence, these advanced MEWP have the potential to lead to a new generation of products and devices with unique properties and functionalities. Despite the large scientific progress on MEWP there are still some obstacles which have to be solved to make these materials available for real life applications. Recent advances on the production strategies, including methods and materials, of MEWP has shown that the durability and sustainability obstacles can be addressed thus offering the possibility for industrial exploitation. MEWP with wettabilities ranging from superhydrophobicity to superhydrophilicity provide promising avenues for several and important applications, which sometimes are crucial for the humankind. This book also discusses a large variety of other potential applications of MEWP, thus providing new ideas to scientists and engineers for further exploitation of these novel materials. Moreover, the whole spectrum of the recent technological developments, current research progress, future outlook, and the modern trends in the applications of MEWP are discussed in a consistent approach.

This book takes an interface science approach to describe and understand the behavior of the dispersions we call emulsions, microemulsions and foams. The one thing all these dispersions have in common is the presence of surface-active species (surfactants) adsorbed at the interfaces between the two fluid phases that make up the emulsions, microemulsions or foams. The interfacial layers formed by the surfactants control most of the properties of the dispersions. The book describes the properties of interfacial layers, thin films and bulk fluids used in the elaboration of the various dispersions and it explains how such properties relate to the dispersion properties of these soft matter systems: structure, rheology and stability. These dispersion properties are far from being fully understood, in particular foam and emulsion stability. In discussing the state of the art of the current knowledge, the author draws interesting parallels between emulsions, microemulsions and foams that enlighten the interpretation of previous observations and point to a deeper understanding of the behavior of these materials in the future.

This book covers the fundamentals of conventional transmission electron microscopy (CTEM) as applied to crystalline solids. In addition to including a large selection of worked examples and homework problems, the volume is accompanied by a supplementary website (http://ctem.web.cmu.edu/) containing interactive modules and over 30,000 lines of free Fortran 90 source code. The work is based on a lecture course given by Marc De Graef in the Department of Materials Science and Engineering at Carnegie Mellon University.

This book presents the select proceedings of the International Conference on Functional Material, Manufacturing and Performances (ICFMMP) 2019. The book covers broad aspects of several topics involved in the metrology and measurement of engineering surfaces and their implementation in automotive, bio-manufacturing, chemicals, electronics, energy, construction materials, and other engineering applications. The contents focus on cutting-edge instruments, methods and standards in the field of metrology and mechanical properties of advanced materials. Given the scope of the topics, this book can be useful for students, researchers and professionals interested in the measurement of surfaces, and the applications thereof.

This volume documents the proceedings of the 8th International Symposium on Particles on Surfaces: Detection, Adhesion and Removal held in Providence, Rhode Island, June 2426, 2002.
The study of particles on surfaces is extremely crucial in a host of diverse technological areas, ranging from microelectronics to optics to biomedical. In a world of shrinking dimensions and with the tremendous interest in various nanotechnologies, the need to understand the physics of nanoparticles becomes quite patent. With the interest in and concern with nanoparticles comes the need for new and more sensitive metrological and analysis techniques to detect, quantitate, analyze and characterize very small particles on a host of substrates.
This volume contains a total of 21 papers covering many ramifications of particles on surfaces. All manuscripts were rigorously peer-reviewed and all were revised and properly edited before inclusion in this volume. The book is divided into two parts: Particle Analysis/Characterization and General Cleaning-Related Topics and Particle Adhesion and Removal. The topics covered include: nature and characterization of small particles; surface and micro-analytical methods for particle identification; haze as a new method to monitor nano-sized particles; particle transport and adhesion in ion-beam sputter deposition process; particle deposition during immersion rinsing; ice-air blast cleaning; rectangular jets for surface decontamination; factors important in particle adhesion and removal; mechanics of nanoparticle adhesion; particle adhesion on nanoscale rough surfaces; various techniques for cleaning or removal of particles from different substrates including wetcleaning, use of modified SC-1 solutions, use of surfactants, ozonated DI water, ultrasonic, megasonic, laser, energetic clusters; and post-CMP cleaning.
This volume, together with its predecessors, will be of immense value to anyone interested in the world of particles on surfaces, and will serve as a resource for information on contemporary R&D activity in this extremely technologically important area.

This book presents recent material science-based and mechanical analysis-based advances in joining processes. It includes all related processes, e.g. friction stir welding, joining by plastic deformation, laser welding, clinch joining, and adhesive bonding, as well as hybrid joints. It gathers selected full-length papers from the 1st Conference on Advanced Joining Processes.

This book provides comprehensive coverage of the materials characteristics, process technologies, and device operations for memory field-effect transistors employing inorganic or organic ferroelectric thin films. This transistor-type ferroelectric memory has interesting fundamental device physics and potentially large industrial impact. Among various applications of ferroelectric thin films, the development of nonvolatile ferroelectric random access memory (FeRAM) has been most actively progressed since the late 1980s and reached modest mass production for specific application since 1995. There are two types of memory cells in ferroelectric nonvolatile memories. One is the capacitor-type FeRAM and the other is the field-effect transistor (FET)-type FeRAM. Although the FET-type FeRAM claims the ultimate scalability and nondestructive readout characteristics, the capacitor-type FeRAMs have been the main interest for the major semiconductor memory companies, because the ferroelectric FET has fatal handicaps of cross-talk for random accessibility and short retention time. This book aims to provide the readers with development history, technical issues, fabrication methodologies, and promising applications of FET-type ferroelectric memory devices, presenting a comprehensive review of past, present, and future technologies. The topics discussed will lead to further advances in large-area electronics implemented on glass, plastic or paper substrates as well as in conventional Si electronics. The book is composed of chapters written by leading researchers in ferroelectric materials and related device technologies, including oxide and organic ferroelectric thin films.

This volume documents the proceedings of the "International Symposium on Surface Contamination and Cleaning, held in Newark, New Jersey, May 23-25, 2001.
Because of the importance of this topic in many technological areas, tremendous efforts have been devoted to devise novel and more efficient ways to monitor, analyse and characterize contamination on surfaces as well as ways to remove such contamination from a wide variety of surfaces. The technological areas where surface contamination has always been a bete noire and thus surface cleaning is of cardinal importance are too many and range from aerospace to microelectronics to biomedical.
This volume contains a total of 24 papers, all rigorously peer reviewed and revised before inclusion, which deal with all kinds of contaminations on a host of surfaces. The topics covered include: mapping of surface contaminants; various techniques for cleaning surfaces; various techniques for monitoring level of cleanliness; acceptable cleanliness levels; ionic contamination; pharmaceutical cleaning validations; cleaning of glass surfaces; decontamination of sensitive equipment; no-chemistry process cleaning; waterjet cleaning; cleaning with solid carbon dioxide pellet blasting; cleanroom wipers; dust removal from solar panels and spacecraft on Mars; laser cleaning of silicon surfaces; particle removal; implications of surface contamination and cleaning; and future of industrial cleaning and related public policy-making.

This book represents a significant advance in our understanding of the synthesis and properties of two-dimensional (2D) materials. The author's work breaks new ground in the understanding of a number of 2D crystals, including atomically thin transition metal dichalcogenides, graphene, and their heterostructures, that are technologically important to next-generation electronics. In addition to critical new results on the direct growth of 2D heterostructures, it also details growth mechanisms, surface science, and device applications of "epi-grade" 2D semiconductors, which are essential to low-power electronics, as well as for extending Moore's law. Most importantly, it provides an effective alternative to mechanically exfoliate 2D layers for practical applications.

This book provides a comprehensive overview of the latest developments in the field of spin dynamics and magnetic damping. It discusses the various ways to tune damping, specifically, dynamic and static control in a ferromagnetic layer/heavy metal layer. In addition, it addresses all optical detection techniques for the investigation of modulation of damping, for example, the time-resolved magneto-optical Kerr effect technique.

This book investigates the adsorption dynamics of water, methanol, ethanol, and ammonia vapor on loose and consolidated adsorbent beds, as well as the impact of this aspect on the overall performance of adsorption systems for heat transformation. In particular, it presents the results of kinetic measurements made using the large temperature jump (LTJ) method, the most efficient way to study adsorption dynamics under realistic operating conditions for adsorptive heat transformers. The information provided is especially beneficial for all those working on the development of novel adsorbent materials and advanced adsorbers for heating and cooling applications. Today, technologies and systems based on adsorption heat transformation (AHT) processes offer a fascinating option for meeting the growing worldwide demand for air conditioning and space heating. Nevertheless, considerable efforts must still be made in order to enhance performance so as to effectively compete with commonly used electrical compression and absorption machines. For this purpose, intelligent design for adsorption units should above all focus on finding a convenient choice of adsorbent material by means of a comprehensive analysis that takes into account both thermodynamic and dynamic aspects. While the thermodynamic properties of the AHT cycle have been studied extensively, the dynamic optimization of AHT adsorbers is still an open issue. Several efforts have recently been made in order to analyze AHT dynamics, which greatly influence overall AHT performance.

This SpringerBrief utilizes a surface chemistry/physical chemistry approach toward the study of aqueous corrosion processes. The book starts with a timely and in-depth review of Acid-Base Properties of Surface Oxide Films. Acid-base properties are significant in various surface phenomena such as general and localized corrosion, corrosion inhibition by organic molecules, and the adhesion of organic polymers to oxide-covered metals. This review also discusses the relationship between the two measures of surface charge, the isoelectric point of the oxide film and the potential of zero charge of the oxide-covered metal. Other topics included are capillarity and corrosion, corrosion inhibition, passivity of Fe-Cr and Fe-Cr-Ni alloys, the uptake of chloride Ions and the pitting of aluminum, and the formation of water films on the iron oxide surface.

This book covers the development of both experiment and theory in natural surface particle chemistry. It emphasizes insights gained over the past few years, and concentrates on molecular spectroscopy, kinetics, and equilibrium as they apply to natural particle surface reactions in aqueous media. The discussion, divided among five chapters, is complemented by lengthy annotations, reading suggestions, and end-of-chapter problem sets that require a critical reading of important technical journal articles.

Rapid population growth, urbanisation and industrialisation have caused serious problems in terms of water pollution and the supply of safe water. Solutions for monitoring pollutants in water and for removing them are urgently needed and they must be both efficient and sustainable. Recent advances in emerging environmental nanotechnologies provide promising solutions for these issues. The physical and chemical properties of nanomaterials can be tailored by controlling attributes such as their size, shape, composition, and surface, so that they can be both highly specific and highly efficient. This makes them perfect platforms for a variety of environmental applications including sensing, treatment and remediation. Providing an array of cutting-edge nanotechnology research in water applications, including sensing, treatment, and remediation, as well as a discussion of progress in the rational design and engineering of nanomaterials for environmental applications, this book is a valuable reference for researchers working in applications for nanotechnology, environmental chemistry and environmental engineering as well as those working in the water treatment industry.

Membrane technology has received great popularity in many industrial sectors and significantly enhanced our abilities to restructure production processes, protect the environment and public health, and provide competitive strategies for separation and purification. However, the need for sustainable development has imposed new targets for this technology, such as more effective/precise separation and stricter admissible limits for the discharge of contaminants into the environment. Focusing on hot topic environment-related applications, Advances in Functional Separation Membranes introduces emerging membranes nanoengineered with attractive functions and discusses their key features. It also provides a comprehensive guide to various design strategies for such functional membranes, making it useful reference for environmental chemists and membrane engineers alike.

With principles that are shaping today's most advanced technologies, from nanomedicine to electronic nanorobots, colloid and interface science has become a truly interdisciplinary field, integrating chemistry, physics, and biology. Colloid and Surface Chemistry: Exploration of the Nano World- Laboratory Guide explains the basic principles of colloid and interface science through experiments that emphasize the fundamentals. It bridges the gap between the underlying theory and practical applications of colloid and surface chemistry. Separated into five chapters, the book begins by addressing research methodology, how to design successful experiments, and ethics in science. It also provides practical information on data collection and analysis, keeping a laboratory notebook, and writing laboratory reports. With each section written by a distinguished researcher, chapter 2 reviews common techniques for the characterization and analysis of colloidal structures, including surface tension measurements, viscosity and rheological measurements, electrokinetic methods, scattering and diffraction techniques, and microscopy. Chapters 3-5 provide 19 experiments, each including the purpose of the experiment, background information, pre-laboratory questions, step-by-step procedures, and post-laboratory questions. Chapter 3 contains experiments about colloids and surfaces, such as sedimentation, exploration of wetting phenomena, foam stability, and preparation of miniemulsions. Chapter 4 covers various techniques for the preparation of nanoparticles, including silver, magnetic, and silica nanoparticles. Chapter 5 demonstrates daily-life applications of colloid science, describing the preparation of food colloids, body wash, and body cream.