This book provides comprehensive coverage of the materials characteristics, process technologies, and device operations for memory field-effect transistors employing inorganic or organic ferroelectric thin films. This transistor-type ferroelectric memory has interesting fundamental device physics and potentially large industrial impact. Among various applications of ferroelectric thin films, the development of nonvolatile ferroelectric random access memory (FeRAM) has been most actively progressed since the late 1980s and reached modest mass production for specific application since 1995. There are two types of memory cells in ferroelectric nonvolatile memories. One is the capacitor-type FeRAM and the other is the field-effect transistor (FET)-type FeRAM. Although the FET-type FeRAM claims the ultimate scalability and nondestructive readout characteristics, the capacitor-type FeRAMs have been the main interest for the major semiconductor memory companies, because the ferroelectric FET has fatal handicaps of cross-talk for random accessibility and short retention time. This book aims to provide the readers with development history, technical issues, fabrication methodologies, and promising applications of FET-type ferroelectric memory devices, presenting a comprehensive review of past, present, and future technologies. The topics discussed will lead to further advances in large-area electronics implemented on glass, plastic or paper substrates as well as in conventional Si electronics. The book is composed of chapters written by leading researchers in ferroelectric materials and related device technologies, including oxide and organic ferroelectric thin films.

This book represents a significant advance in our understanding of the synthesis and properties of two-dimensional (2D) materials. The author's work breaks new ground in the understanding of a number of 2D crystals, including atomically thin transition metal dichalcogenides, graphene, and their heterostructures, that are technologically important to next-generation electronics. In addition to critical new results on the direct growth of 2D heterostructures, it also details growth mechanisms, surface science, and device applications of "epi-grade" 2D semiconductors, which are essential to low-power electronics, as well as for extending Moore's law. Most importantly, it provides an effective alternative to mechanically exfoliate 2D layers for practical applications.

This book provides a comprehensive overview of the latest developments in the field of spin dynamics and magnetic damping. It discusses the various ways to tune damping, specifically, dynamic and static control in a ferromagnetic layer/heavy metal layer. In addition, it addresses all optical detection techniques for the investigation of modulation of damping, for example, the time-resolved magneto-optical Kerr effect technique.

The third volume in a series dedicated to colloids and interfaces, Drops and Bubbles in Contact with Solid Surfaces presents an up-to-date overview of the fundamentals and applications of drops and bubbles and their interaction with solid surfaces. The chapters cover the theoretical and experimental aspects of wetting and wettability, liquid-solid interfacial properties, and spreading dynamics on different surfaces, including a special section on polymers. The book examines issues related to interpretation of contact angle from nano to macro systems. Expert contributors discuss interesting peculiarities, such as the phenomena of super-spreading and super-hydrophobicity. They discuss specific solid surfaces-for example, reactions and wetting of liquid metals at high temperatures-and the interaction between nano-bubbles at solid surface and nano-particles at liquid interfaces. The book also includes a chapter on electro-wetting. Given the range of topics covered in this volume, the state-of-art content is useful to readers looking for an introductory overview as well as those looking for in-depth exploration of material related to the interaction of fluids with solid surfaces. It is a valuable contribution to the field of characterization of solid surfaces and can be used as a working tool or to stimulate further study for researchers and students.

This work covers topics ranging from fundamental studies of solubilization to practical technological applications of the phenomenon. It reviews the solubilization of organic materials into surfactant aggregates, including micelles, vesicles and admicelles. The book also details methods of measuring solubilization that utilize both classical and newer instrumental techniques. It is intended for physical, surface, colloid and surfactant chemists; chemical, environmental and civil engineers; and upper-level undergraduate and graduate students in these disciplines.

Continued and systematic analysis of the mechanics of flexible fibre assemblies dates from about 1945, although the growth of research into textiles after 1920 had included studies of fabric structure and the measurement of mechanical properties. The subject is thus a young one, although this NATO Advanced Study Institute is a sign of developing maturity. However there is an earlier tradition. Relevant, even if somewhat loosely connected, quotations can be found in the works of the engineers of the ancient civilisations, recurring during the llenaissance with Leonardo da Vinci and Galileo. But the glorious libk is with Euler and the Bernoulli family, with their theories of the mechanics of flexible slender rods. While mathematicians have admired the beauty of this work, the invention of elliptic integrals, and the grace of the different classes of planar elastica, it is in the technology of textile materials, composed of flexible fibres and yarns, that the subject has found its more direct application. All this, and much more such as Max Born's doctoral thesis, was brought to our attention in a delightful discourse by Milos Konopasek, who is not only fascinated by the mathematics of Euler and the modern movement of the solutions of bending curves from two dimensions into three by the use of the computer, but also feels a personal link through having lived and studied within sight of the scene of Euler's triumphs in St. Petersburg.

During the Koln meeting (August 28-31, 1984), Irdia was chosen as the venue for the next International Conference on Valence Fluctuations. lhis was in recognition ard appreciation of the work done, both experimental ard theoretical, by the Irdian scientists in this area during the last decade. We decided to hold this Conference in the month of January, 1987 at Bangalore. lhe subject of Valence Fluctuations has kept itself alive ard active as it has provided many shocks ard suprises particularly among the Ce- ard U-based intermetallies. lhe richness of many interesting physical phenomena occurring in mixed valent materials, the flexibility of modifying their physical properties (by alloying, for example) ard the possibility of synthesizing a wide variety of new such materials seem to be the key factors in this regard. Barely six months before this Conference, an International Conference on Anomalous Rare Earths and Actinides (ICAREA) had been held at Grenoble (July, 1986) which also focussed on mixed valence ard heavy fermion phenomena. In spite of this, the response to this' Conference was very enthusiastic and encouraging. Many interesting ard important results were presented at this Conference which have been included in this volume.

In an earlier book, Rheological Measurement (A. A. Collyer & D. W. Clegg, Elsevier Applied Science, 1988), the basic rheological methods of measurement presently used were discussed in the light of the basic underlying principles and current theories. The same approach is adopted in this companion book, which is concerned with some newer or more sophisticated techniques that have resulted from a fresh understanding of the subject, or as a result of improvement in computer control, data acquisition and computational power, or more simply from an industrial need, particularly with regard to process control. The first two chapters deal with the extensional flow properties of fluids and their measurement. This inclusion is in response to a greater awareness in industry of the importance of these flows. Chapter 3 intro duces and develops the subject of surface rheology and the measurement of its properties, again a subject of increasing significance. The methods of measurement of the dynamic mechanical properties of fluids and the calculation of the resulting rheological parameters are discussed in Chap ters 4-7 inclusive. The subject areas covered are: large-amplitude oscilla tory shear, a model for viscoelastic fluids and solids, a new method of measuring dynamic mechanical properties, particularly for curing sys tems, and the use of complex waveforms in dynamic mechanical analysis."

The European Conference on Composite Materials (ECCM-4) will be held for the first time, in Germany after the successes of previous meetings in France and England. The meeting will take place in Stuttgart which is capital of B aden-Wtirttemberg and a centre for new technologies in Germany. Amongst these new technologies, composite materials play a dominant role and it is the aim of the conference to promote scientific discussion of these materials. Polymer matrix composites are well established and lie at the centre of interest so that a great number of contributions forms on plastic matrix and high temperature resin matrix composites. New developments in the area of reinforcement fibres will be discussed in a special section of the poster session. Metal matrix and ceramic matrix composites as well as carbon fibre reinforced carbon are strong candidates for future structural materials. These classes of composites receive wide interest at the conference. The conference organisers received more than 250 abstracts, from which about 160 contributed papers from 20 countries were accepted. In addition to the' 80 oral presentations five invited papers on topics of special interest will be given. The recycling problem of fiber reinforced composites will be discussed in a plenary paper. In the name of all those who were involved in preparation and organisation of this conference, we hope that fruitful discussions but also the social gathering will contribute to further steps in deepening the European cooperation in this fascinating composite research field.

Providing the "tricks of the trade" in surface science, this book describes hundreds of techniques, methods, instruments, and tools in common use from the worlds of physics, chemistry, and engineering. The methods are arranged in topical groupings for easy reference, and each is described succinctly, with a clear sketch of the apparatus involved. Covering all the basic methods of surface science, this source book will serve not only as a useful reference to those just starting on experimental research in surface science, but also as a "vade mecum" for established researchers.

This third edition has been thoroughly revised and updated. In particular it now includes an extensive discussion of the band lineup at semiconductor interfaces. The unifying concept is the continuum of interface-induced gap states.

Since the publication of the first edition of Interfacial Phenomena, the interest in interfaces and surfactants has multiplied, along with their applications. Experimental and theoretical advances have provided scientists with greater insight into the structure, properties, and behavior of surfactant and colloid systems. Emphasizing equilibrium phenomena, flow, transport, and stability, Interfacial Phenomena: Equilibrium and Dynamic Effects, Second Edition presents a concise and current summary of the fundamental principles governing interfacial interactions. This new edition features updated and expanded topics in every chapter. It highlights key experimental techniques that have expanded the scope of our understanding, such as in mass transfer, microstructure determination in colloidal dispersions, and surfactant-polymer interactions. Interfacial Phenomena, Second Edition reflects the progress scientists have made in understanding the surface chemistry and interfacial dynamics of colloid and surfactant systems. The book also illustrates the growing applicability of these systems in a variety of fields including pharmaceuticals, cosmetics, detergents, paints, agricultural chemicals, and foods.

Dynamics of Surfactant Self-Assemblies explains the dynamics of micellar equilibria, tracking surfactant exchange, and micelle formation/breakdown processes. Highlighting the structural similarities of amphiphilic block copolymers to surfactants, this volume elucidates the dynamics of more complex self-assemblies that surfactants and amphiphilic block copolymers form in solutions. The book first discusses self-assembling processes taking place in aqueous surfactant solutions and the dynamic character of surfactant self-assemblies. The next chapter reviews methods that permit the study of the dynamics of self-assemblies. The dynamics of micelles of surfactants and block copolymers, solubilized systems, microemulsions, vesicles, and lyotropic liquid crystals/mesophases are reviewed successively. The authors point out the similarities and differences in the behavior of these different self-assemblies. Much emphasis is put on the processes of surfactant exchange and of micelle formation/breakdown that determine the surfactant residence time in micelles, and the micelle lifetime. The last three chapters cover topics for which the dynamics of surfactant self-assemblies can be important for a better understanding of observed behaviors: dynamics of surfactant adsorption on surfaces, rheology of viscoelastic surfactant solutions, and kinetics of chemical reactions performed in surfactant self-assemblies used as microreactors. Dynamics of Surfactant Self-Assemblies offers a unique and comprehensive review of the literature that exists on the dynamics of the various surfactant self-assemblies and a unified perspective on this topic. It provides researchers with a useful guide for the dynamics of the surfactant systems that they wish to investigate.

Principles of Adsorption and Reaction on Solid Surfaces

As with other books in the field, Principles of Adsorption and Reaction on Solid Surfaces describes what occurs when gases come in contact with various solid surfaces. But, unlike all the others, it also explains why. While the theory of surface reactions is still under active development, the approach Dr. Richard Masel takes in this book is to outline general principles derived from thermodynamics and reaction rate theory that can be applied to reactions on surfaces, and to indicate ways in which these principles may be applied. The book also provides a comprehensive treatment of the latest quantitative surface modeling techniques with numerous examples of their use in the fields of chemical engineering, physical chemistry, and materials science. A valuable working resource and an excellent graduate-level text, Principles of Adsorption and Reaction on Solid Surfaces provides readers with:

• A detailed look at the latest advances in understanding and quantifying reactions on surfaces
• In-depth reviews of all crucial background material
• 40 solved examples illustrating how the methods apply to catalysis, physical vapor deposition, chemical vapor deposition, electrochemistry, and more
• 340 problems and practice exercises
• Sample computer programs
• Universal plots of many key quantities
• Detailed, class-tested derivations to help clarify key results

The recent development of quantitative techniques for modeling surface reactions has led to a number of exciting breakthroughs in our understanding of what happens when gases come in contact with solid surfaces. While many books have appeared describing various experimental modeling techniques and the results obtained through their application, until now, there has been no single-volume reference devoted to the fundamental principles governing the processes observed.

The first book to focus on governing principles rather than experimental techniques or specific results, Principles of Adsorption and Reaction on Solid Surfaces provides students and professionals with a quantitative treatment of the application of principles derived from the fields of thermodynamics and reaction rate theory to the investigation of gas adsorption and reaction on solid surfaces. Writing for a broad-based audience including, among others, chemical engineers, chemists, and materials scientists, Dr. Richard I. Masel deftly balances basic background in areas such as statistical mechanics and kinetics with more advanced applications in specialized areas.

Principles of Adsorption and Reaction on Solid Surfaces was also designed to provide readers an opportunity to quickly familiarize themselves with all of the important quantitative surface modeling techniques now in use. To that end, the author has included all of the key equations involved as well as numerous real-world illustrations and solved examples that help to illustrate how the equations can be applied. He has also provided computer programs along with universal plots that make it easy for readers to apply results to their own problems with little computational effort.

Principles of Adsorption and Reaction on Solid Surfaces is a valuable working resource for chemical engineers, physical chemists, and materials scientists, and an excellent text for graduate students in those disciplines.

Small solid particles adsorbed at liquid interfaces arise in many industrial products and process, such as anti-foam formulations, crude oil emulsions and flotation. They act in many ways like traditional surfactant molecules, but offer distinct advantages. However, the understanding of how these particles operate in such systems is minimal. This book brings together the diverse topics actively being investigated, with contributions from leading experts in the field. After an introduction to the basic concepts and principles, the book divides into two sections. The first deals with particles at planar liquid interfaces, with chapters of an experimental and theoretical nature. The second concentrates on the behaviour of particles at curved liquid interfaces, including particle-stabilised foams and emulsions and new materials derived from such systems. This unique collection will be of interest to academic researchers and graduate students in chemistry, physics, chemical engineering, pharmacy, food science and materials science.

This volume is based on lectures given at the NATO-Advanced Study Institute on Structure and Dynamics of Polymer and Colloid Systems held in Les Houches, France from September 14-24, 1999. The meeting arose from a perceived need to bring together scientists studying the polymer and colloid fields. Although these fields are intertwined and share many techniques (e. g. , light, neutron and x-ray scattering), it is remarkable how little the approaches and concepts used by the one field penetrate the other. For instance, the theory of spherical colloids is very highly developed and many of the concepts developed for these systems can be extended to those with non-spherical morphology, such as solutions of rigid rod polymers. In addition, mixtures of polymers and colloids, both in the bulk and at interfaces, are the basis for many industrial products. Methods are now rapidly being developed for understanding the structure and dynamics in polymer/colloid mixtures at the molecular level, but the point of view of the colloid scientist is often rather different from that of the polymer scientist. The NATO-ASI brought together polymer and colloid scientists, including many young researchers, who presented and discussed recent developments in these fields and the possibilities for cross-fertilization This volume contains articles on a wide variety of topics at the research forefront of the polymer and colloid fields by some of the world's foremost experts at a level accessible to graduate students, post-docs and researchers.

During my professional career, I developed a strong interest in sol-gel technology, and worked on both xerogel and aerogel systems. My fascination with aerogels has driven me to explore their commercial potential, which is currently an important component of my company's business plan. Together with my co-workers, I have also worked on the preparation of controlled PZT and silica xerogels as well as thin film coatings of metals by the sol-gel technology, These experiences convinced me of the tremendous potentials of this technology. A conviction that is shared by many scientists, engineers, and business leaders around the globe. Many sol-gel derived products are already articles of commerce. However, to expand the commercial potential of sol-gel technology, two challenges must be met: (1) the quality of sol-gel derived products must continue to meet or exceed the quality of competing products, (2) the production cost of sol-gel products (specially aerogels) must continued to decline. A key to lowering the costs of sol-gel products is finding inexpensive precursors.

Surfactants... today you have probably eaten some, or rubbed others on your body. Plants, animals (including you) and microorganisms make them, and many everyday products (e.g. detergents, cosmetics, foodstuffs) contain them. Surfactant molecules have one part which is soluble in water and another which is not. This gives surfactant molecules two valuable properties: 1) they adsorb at surfaces (e.g. of an oil droplet in water), and 2) they stick together (aggregate) in water. The aggregates (micelles) are able to dissolve materials not soluble in water alone, and adsorbed surfactant layers, at the surfaces of particles or (say) oil droplets in water, stop the particles or drops sticking together. This is why stable emulsions such as milk do not separate into layers. This book treats the basic physical chemistry and physics underlying the behaviour of surfactant systems. In this book, you will first learn about some background material including hydrophobic hydration, interfacial tension and capillarity (Section I). Discussion of surfactant adsorption at liquid/fluid and solid/liquid interfaces is given in Section II, and includes thermodynamics of adsorption, dynamic and rheological aspects of liquid interfaces and the direct characterisation of surfactant monolayers. In Section III, a description is given of surfactant aggregation to give micelles, lyotropic liquid crystals, microemulsions and Winsor systems. There follows a discussion of surface forces and the way they confer stability on lyophobic colloids and thin liquid films (Section IV). Various dispersions stabilised by adsorbed surfactant or polymer (including solid in liquid dispersions, emulsions and foams) are considered in Section V. The wetting of solids and liquids is explored in Section VI. Like surfactants, small solid particles can adsorb at liquid/fluid interfaces, form monolayers and stabilise emulsions and foams. Such behaviour is covered in Section VII. It is assumed the reader has a knowledge of undergraduate physical chemistry, particularly chemical thermodynamics, and of simple physics. Mathematics (elementary algebra and calculus) is kept at a level consistent with the straightforward derivation of many of the equations presented.

With the voluminous research being published, it is difficult, if not impossible, to stay abreast of current developments in a given area. The review articles in this book consolidate information to provide an alternative way to follow the latest research activity and developments in adhesion science and adhesives. With the ever-increasing amount of research being published, it is a Herculean task to be fully conversant with the latest research developments in any field, and the arena of adhesion and adhesives is no exception. Thus, topical review articles provide an alternate and very efficient way to stay abreast of the state-of-the-art in many subjects representing the field of adhesion science and adhesives. The 19 chapters in this Volume 6 follow the same order as the review articles originally published in RAA in the year 2020 and up to June 2021. The subjects of these 19 chapters fall in the following areas: Adhesives and adhesive joints Contact angle Reinforced polymer composites Bioadhesives Icephobic coatings Adhesives based on natural resources Polymer surface modification Superhydrophobic surfaces The topics covered include: hot-melt adhesives; adhesively-bonded spar-wingskin joints; contact angle hysteresis; fiber/matrix adhesion in reinforced thermoplastic composites; bioadhesives in biomedical applications; mucoadhesive pellets for drug delivery applications; bio-inspired icephobic coatings; wood adhesives based on natural resources; adhesion in biocomposites; vacuum UV surface photo-oxidation of polymers and other materials; vitrimers and their relevance to adhesives; superhydrophobic surfaces by microtexturing; structural acrylic adhesives; mechanically durable water-repellent surfaces; mussel-inspired underwater adhesives; and cold atmospheric pressure plasma technology for modifying polymers. Audience This book will be valuable and useful to researchers and technologists in materials science, nanotechnology, physics, surface and colloid chemistry in multiple disciplines in academia, industry, various research institutes and other organizations.

In this book, the authors present current research in the study of adhesions. Topics discussed in this compilation include surface analysis techniques for root canal filling adhesion studies; polysialylated-neural cell adhesion molecules in the human nervous system at prenatal, postnatal and adult ages; surgical adhesives; interaction of diamond-transition metal substrates and interfacial adhesion enhancement/failure mechanisms; inhibition and impairment of cell adhesions; and effects of anti-cell adhesion molecules to prevent heart transplant rejection.

This book introduces the fascinating world of self-assembly in mesoporous ordered silica films. Beginning from a single droplet, it guides the reader, in a step-by-step learning process, how to obtain and control ordered porous mesophases in thin films by varying only the precursor chemistry and the process. It explains, in great detail, how order control is achieved through chemical design and post-deposition processing, the latter of which is a unique property in materials science. The book places a special focus on silica, whose particularly complex chemistry enables order control over a range of different length scales. This book is suitable for students and researchers in the fields of sol-gel or colloidal chemistry and interested in the topics of self-assembly and mesoporous phases.

This book presents contributions on a wide range of computational research applied to fields ranging from molecular systems to bulk structures. This volume highlights current trends in modern computational chemistry and discusses the development of theoretical methodologies, state-of-the-art computational algorithms and their practical applications. This volume is part of a continuous effort by the editors to document recent advances by prominent researchers in the area of computational chemistry. Most of the chapters are contributed by invited speakers and participants to International annual conference "Current Trends in Computational Chemistry", organized by Jerzy Leszczynski, one of the editors of the current volume. This conference series has become an exciting platform for eminent theoretical and computational chemists to discuss their recent findings and is regularly honored by the presence of Nobel laureates. Topics covered in the book include reactive force-field methodologies, coarse-grained modeling, DNA damage radiosensitizers, modeling and simulation of surfaces and interfaces, non-covalent interactions, and many others. The book is intended for theoretical and computational chemists, physical chemists, material scientists and those who are eager to apply computational chemistry methods to problems of chemical and physical importance. It is a valuable resource for undergraduate, graduate and PhD students as well as for established researchers.

This book provides a general overview and current state of the art of different types of metal oxide nanomaterials, either in nanoparticles or thin film structure. It covers from the development and optimization of different nanofabrication/synthesis techniques for nanostructures which are currently the attention of the research community, the study of the structure and interactions by different characterization techniques of heterostructured materials and the final impact in different applications such as nanotherapy, data storage, super magnets, high-frequency devices. The book's 13 chapters provide deep insight into the intriguing science of oxide materials and include contributions on novel technologies to fabricate nanomaterials with a broad range of functional properties (semiconducting, magnetic, ferroelectric, thermoelectric, optical, flexible and mechanical). This book is intended to the experts for consolidation of their knowledge but also for students who aim to learn and get basics of nanostructured metal oxides in diverse forms.

This new book covers the physics and chemistry of surfaces. The scope includes the structure, thermodynamics, and mobility of clean surfaces, as well as the interaction of gas molecules with solid surfaces. The energetic particle interactions that are the basis for the majority of techniques developed to reveal the structure and chemistry of surfaces are explored including auger electron spectroscopy, photoelectron spectroscopy, inelastic scattering of electrons and ions, low energy electron diffraction, scanning probe microscopy, and interfacial segregation. Crystal nucleation and growth are also considered. Principles such as adsorption, desorption and reactions between adsorbates are examined, with coverage also of new developments in the growth of epitaxial, and Langmuir-Blodgett films, as well as treatment of the etching of surfaces. Modern analytical techniques and applications to thin films and nanostructures are included. The latest in-depth research from around the world is presented.

This book focuses on the use of natural surfactants in enhanced oil recovery, providing an overview of surfactants, their types, and different physical-chemical properties used to analyse the efficiency of surfactants. Natural surfactants discuss the history of the surfactants, their classification, and the use of surfactants in petroleum industry. Special attention has been paid to natural surfactants and their advantages over synthetic surfactants, including analysing their properties such as emulsification, interfacial tension, and wettability and how these can be used in EOR. This book offers an overview for researchers and graduate students in the fields of petroleum and chemical engineering, as well as oil and gas industry professionals.