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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
Approach your problems from the right end It isn't that they can't see the solution. It is and begin with the answers. Then one day, that they can't see the problem. perhaps you will find the final question. G. K. Chesterton. The Scandal of Father 'The Hermit Clad in Crane Feathers' in R. Brown 'The point of a Pin'. van Gulik's The Chif1ese Maze Murders. Growing specialization and diversification have brought a host of monographs and textbooks on increasingly specialized topics. However, the "tree" of knowledge of mathematics and related fields does not grow only by putting forth new branches. It also happens, quite often in fact, that branches which were thought to be completely disparate are suddenly seen to be related. Further, the kind and level of sophistication of mathematics applied in various sciences has changed drastically in recent years: measure theory is used (non trivially) in regional and theoretical economics; algebraic geometry interacts with physics; the Minkowsky lemma, coding theory and the structure of water meet one another in packing and covering theory; quantum fields, crystal defects and mathematical programming profit from homotopy theory; Lie algebras are relevant to filtering; and prediction and electrical engineering can use Stein spaces. And in addition to this there are such new emerging subdisciplines as "experimental mathematics," "CFD," "completely integrable systems," "chaos, synergetics and large-scale order," which are almost impossible to fit into the existing classification schemes. They draw upon widely different sections of mathematics."
The spectacular success of the scientific enterprise over the last four hundred years has led to the promise of an all encompassing vision of the natural world. In this elegant picture, everything we observe is based upon just a few fundamental processes and entities. The almost infinite variety and complexity of the world is thus the product of emergence. But the concept of emergence is fraught with controversy and confusion. This book ponders the question of how emergence should be understood within the scientific picture, and whether a complete vision of the world can be attained that includes consciousness.
This book provides a comprehensive introduction to the theory of phase transitions and critical phenomena. The content covers a period of more than 100 years of theoretical research of condensed matter phases and phase transitions providing a clear interrelationship with experimental problems. It starts from certain basic University knowledge of thermodynamics, statistical physics and quantum mechanics. The text is illustrated with classic examples of phase transitions. Various types of phase transition and (multi)critical points are introduced and explained. The classic aspects of the theory are naturally related with the modern developments. This interrelationship and the field-theoretical renormalization group method are presented in details. The main applications of the renormalization group methods are presented. Special attention is paid to the description of quantum phase transitions. This edition contains a more detailed presentation of the renormalization group method and its applications to particular systems.
This book presents quantum kinetic theory in a comprehensive way. The focus is on density operator methods and on non-equilibrium Green functions. The theory allows to rigorously treat nonequilibrium dynamics in quantum many-body systems. Of particular interest are ultrafast processes in plasmas, condensed matter and trapped atoms that are stimulated by rapidly developing experiments with short pulse lasers and free electron lasers. To describe these experiments theoretically, the most powerful approach is given by non-Markovian quantum kinetic equations that are discussed in detail, including computational aspects.
This third edition of one of the most important and best selling textbooks in statistical physics, is a graduate level text suitable for students in physics, chemistry, and materials science.The discussion of strongly interacting condensed matter systems has been expanded. A chapter on stochastic processes has also been added with emphasis on applications of the Fokker-Planck equation.The modern theory of phase transitions occupies a central place. The chapter devoted to the renormalization group approach is largely rewritten and includes a detailed discussion of the basic concepts and examples of both exact and approximate calculations. The development of the basic tools includes a chapter on computer simulations in which both Monte Carlo method and molecular dynamics are introduced, and a section on Brownian dynamics added.The theories are applied to a number of important systems such as liquids, liquid crystals, polymers, membranes, Bose condensation, superfluidity and superconductivity. There is also an extensive treatment of interacting Fermi and Bose systems, percolation theory and disordered systems in general.
Potts Models and Related Problems in Statistical Mechanics
How can one construct dynamical systems obeying the first and second laws of thermodynamics: mean energy is conserved and entropy increases with time? This book answers the question for classical probability (Part I) and quantum probability (Part II). A novel feature is the introduction of heat particles which supply thermal noise and represent the kinetic energy of the molecules. When applied to chemical reactions, the theory leads to the usual nonlinear reaction-diffusion equations as well as modifications of them. These can exhibit oscillations, or can converge to equilibrium. In this second edition, the text is simplified in parts and the bibliography has been expanded. The main difference is the addition of two new chapters; in the first, classical fluid dynamics is introduced. A lattice model is developed, which in the continuum limit gives us the Euler equations. The five Navier???Stokes equations are also presented, modified by a diffusion term in the continuity equation. The second addition is in the last chapter, which now includes estimation theory, both classical and quantum, using information geometry.
The availability of large data sets has allowed researchers to uncover complex properties such as large-scale fluctuations and heterogeneities in many networks, leading to the breakdown of standard theoretical frameworks and models. Until recently these systems were considered as haphazard sets of points and connections. Recent advances have generated a vigorous research effort in understanding the effect of complex connectivity patterns on dynamical phenomena. This book presents a comprehensive account of these effects. A vast number of systems, from the brain to ecosystems, power grids and the internet, can be represented as large complex networks. This book will interest graduate students and researchers in many disciplines, from physics and statistical mechanics to mathematical biology and information science. Its modular approach allows readers to readily access the sections of most interest to them, and complicated maths is avoided so the text can be easily followed by non-experts in the subject.
The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail."
This book is a collection of papers contributed by some of the greatest names in the areas of chaos and nonlinear dynamics. Each paper examines a research topic at the frontier of the area of dynamical systems. As well as reviewing recent results, each paper also discusses the future perspectives of each topic. The result is an invaluable snapshot of the state of the ?eld by some of the most important researchers in the area. The ?rst contribution in this book (the section entitled "How did you get into Chaos?") is actually not a paper, but a collection of personal accounts by a number of participants of the conference held in Aberdeen in September 2007 to honour Celso Grebogi's 60th birthday. At the instigation of James Yorke, many of the most well-known scientists in the area agreed to share their tales on how they got involved in chaos during a celebratory dinner in Celso's honour during the conference. This was recorded in video, we felt that these accounts were a valuable historic document for the ?eld. So we decided to transcribe it and include it here as the ?rst section of the book.
In this unique book, Arieh Ben-Naim invites the reader to experience the joy of appreciating something which has eluded understanding for many years -- entropy and the Second Law of Thermodynamics. The book has a two-pronged message: first, that the Second Law is not "infinitely incomprehensible" as commonly stated in textbooks of thermodynamics but can, in fact, be comprehended through sheer common sense; and second, that entropy is not a mysterious quantity that has "resisted understanding" but a simple, familiar and easily comprehensible concept. Written in an accessible style, the book guides the reader through an abundance of dice games and examples from everyday life. The author paves the way for readers to discover for themselves what entropy is, how it changes, and most importantly, why it always changes in one direction in a spontaneous process.
Thermostable Proteins: Structural Stability and Design provides a comprehensive, updated account of the physical basis of enhanced stability of thermophilic proteins and the design of tailor-made thermostable proteins, paving the way for their possible industrial applications. This book is devoted to understanding the survival mechanisms of "thermophilic life forms" at the molecular level with an emphasis on design strategies. The review chapters presented in Thermostable Proteins span a wide range of protein thermostability research. Basic structural, thermodynamic, and kinetic principles are explained and molecular strategies for the adaptation to high temperatures are delineated. In addition, this book covers:
Understanding the molecular basis of how thermostable and hyperthermostable proteins gain and maintain their stability and biological function at high temperatures remains an important scientific challenge. A more detailed knowledge of protein stability not only deepens our understanding of protein structure but also helps in obtaining insights into processes that drive protein activities folding, unfolding, and misfolding essential to biological function.
* Materials are presented to guide the reader with ease through a difficult subject by providing extra help whenever needed to overcome the more demanding technical and conceptual aspects * Active reading strategies (conceptual problems, discussion questions, worked examples with comments, end of chapter problems, further reading etc.) to stimulate engagement with the text through active, critical thought * Well-balanced textbook design (including introductions, illustrations, keywords defined, highlights, notes in margins, summary of key ideas and concepts, boxes with additional topics that complement the materials presented in the main text)
Thermal and statistical physics has established the principles and procedures needed to understand and explain the properties of systems consisting of macroscopically large numbers of particles. By developing microscopic statistical physics and macroscopic classical thermodynamic descriptions in tandem, Statistical and Thermal Physics: An Introduction provides insight into basic concepts and relationships at an advanced undergraduate level. This second edition is updated throughout, providing a highly detailed, profoundly thorough, and comprehensive introduction to the subject and features exercises within the text as well as end-of-chapter problems. Part I of this book consists of nine chapters, the first three of which deal with the basics of equilibrium thermodynamics, including the fundamental relation. The following three chapters introduce microstates and lead to the Boltzmann definition of the entropy using the microcanonical ensemble approach. In developing the subject, the ideal gas and the ideal spin system are introduced as models for discussion. The laws of thermodynamics are compactly stated. The final three chapters in Part I introduce the thermodynamic potentials and the Maxwell relations. Applications of thermodynamics to gases, condensed matter, and phase transitions and critical phenomena are dealt with in detail. Initial chapters in Part II present the elements of probability theory and establish the thermodynamic equivalence of the three statistical ensembles that are used in determining probabilities. The canonical and the grand canonical distributions are obtained and discussed. Chapters 12-15 are concerned with quantum distributions. By making use of the grand canonical distribution, the Fermi-Dirac and Bose-Einstein quantum distribution functions are derived and then used to explain the properties of ideal Fermi and Bose gases. The Planck distribution is introduced and applied to photons in radiation and to phonons on solids. The last five chapters cover a variety of topics: the ideal gas revisited, nonideal systems, the density matrix, reactions, and irreversible thermodynamics. A flowchart is provided to assist instructors on planning a course. Key Features: Fully updated throughout, with new content on exciting topics, including black hole thermodynamics, Heisenberg antiferromagnetic chains, entropy and information theory, renewable and nonrenewable energy sources, and the mean field theory of antiferromagnetic systems Additional problem exercises with solutions provide further learning opportunities Suitable for advanced undergraduate students in physics or applied physics. Michael J.R. Hoch spent many years as a visiting scientist at the National High Magnetic Field Laboratory at Florida State University, USA. Prior to this, he was a professor of physics and the director of the Condensed Matter Physics Research Unit at the University of the Witwatersrand, Johannesburg, where he is currently professor emeritus in the School of Physics.
Nonlinear elliptic problems play an increasingly important role in
mathematics, science and engineering, creating an exciting
interplay between the subjects. This is the first and only book to
prove in a systematic and unifying way, stability, convergence and
computing results for the different numerical methods for nonlinear
elliptic problems. The proofs use linearization, compact
perturbation of the coercive principal parts, or monotone operator
techniques, and approximation theory. Examples are given for linear
to fully nonlinear problems (highest derivatives occur nonlinearly)
and for the most important space discretization methods: conforming
and nonconforming finite element, discontinuous Galerkin, finite
difference, wavelet (and, in a volume to follow, spectral and
meshfree) methods. A number of specific long open problems are
solved here: numerical methods for fully nonlinear elliptic
problems, wavelet and meshfree methods for nonlinear problems, and
more general nonlinear boundary conditions. We apply it to all
these problems and methods, in particular to eigenvalues, monotone
operators, quadrature approximations, and Newton methods.
Adaptivity is discussed for finite element and wavelet methods.
This second part of Continuum Thermodynamics is designed to match almost one-to-one the chapters of Part I. This is done so that the reader studying thermodynamics will have a deepened understanding of the subjects covered in Part I. The aims of the book are in particular: the illustration of basic features of some simple thermodynamical models such as ideal and viscous fluids, non-Newtonian fluids, nonlinear solids, interactions with electromagnetic fields, and diffusive porous materials. A further aim is the illustration of the above subjects by examples and simple solutions of initial and boundary problems as well as simple exercises to develop skills in the construction of interdisciplinary macroscopic models.
Statistical Mechanics: Fundamentals and Model Solutions, Second Edition Fully updated throughout and with new chapters on the Mayer expansion for classical gases and on cluster expansion for lattice models, this new edition of Statistical Mechanics: Fundamentals and Model Solutions provides a comprehensive introduction to equilibrium statistical mechanics for advanced undergraduate and graduate students of mathematics and physics. The author presents a fresh approach to the subject, setting out the basic assumptions clearly and emphasizing the importance of the thermodynamic limit and the role of convexity. With problems and solutions, the book clearly explains the role of models for physical systems, and discusses and solves various models. An understanding of these models is of increasing importance as they have proved to have applications in many areas of mathematics and physics. Features Updated throughout with new content from the field An established and well-loved textbook Contains new problems and solutions for further learning opportunity Author Professor Teunis C. Dorlas is at the Dublin Institute for Advanced Studies, Ireland.
This book explores the challenges our society faces in making the transition to renewable resource use in a way that is truly sustainable - environmentally, economically and socially. After exploring the physical limits the laws of thermodynamics impose on resource exploitation, the book outlines options for managing resources within these limits. It then moves on to look at the resources themselves (from fossil fuels, through minerals to renewable resources such as timber) and the salient question of how the relentless increase in consumption is putting untenable strain on resource use. Case studies investigate what is being done across a range of sectors - and what is and isn't working. The second half of the book turns to solutions, from the promise of industrial ecology to a new economy based on renewable resources such as biobased materials from agricultural crops and forests. Suitable for under- and postgraduate courses on environmental limits and resource use, and continuing professional development - particularly resource management, materials, industrial ecology, energy, resource economics and engineering.
The wide application of technologies in new mechanical, electronic and biomedical systems calls for materials and structures with non-conventional properties (e.g materials with 'memory'). Of equal importance is the understanding of the physical behaviour of these materials and consequently developing mathematical modelling techniques for prediction. This self contained text discusses the mathematical modelling used with these types of electromagnetic materials. It provides a carefully structured, coherent, and comprehensive treatment of electromagnetism of continuous media. The authors provide a systematic review of known subjects along with original results about thermodynamics of electromagnetic materials, well-posedness of initial boundary-value problems, variational settings, and wave propagation. Models of non-linear materials, non-local materials (superconductors), and hysteretic (magnetic) materials are also developed in detail.
This book explores the challenges our society faces in making the transition to renewable resource use in a way that is truly sustainable - environmentally, economically and socially. After exploring the physical limits the laws of thermodynamics impose on resource exploitation, the book outlines options for managing resources within these limits. It then moves on to look at the resources themselves (from fossil fuels, through minerals to renewable resources such as timber) and the salient question of how the relentless increase in consumption is putting untenable strain on resource use. Case studies investigate what is being done across a range of sectors - and what is and isn't working. The second half of the book turns to solutions, from the promise of industrial ecology to a new economy based on renewable resources such as biobased materials from agricultural crops and forests. Suitable for under- and postgraduate courses on environmental limits and resource use, and continuing professional development - particularly resource management, materials, industrial ecology, energy, resource economics and engineering.
This book summarizes the most recent theoretical, computational and experimental results dealing with homogeneous turbulence dynamics. A large class of flows is covered: flows governed by anisotropic production mechanisms (e.g. shear flows) and flows without production but dominated by waves (e.g. homogeneous rotating or stratified turbulence). Compressible turbulent flows are also considered. In each case, main trends are illustrated using computational and experimental results, while both linear and nonlinear theories and closures are discussed. Details about linear theories (e.g. Rapid Distortion Theory and variants) and nonlinear closures (e.g. EDQNM) are provided in dedicated chapters, following a fully unified approach. The emphasis is on homogeneous flows, including several interactions (rotation, stratification, shear, shock waves, acoustic waves, and more) which are pertinent to many applications fields - from aerospace engineering to astrophysics and Earth sciences.
This classic book marks the beginning of an era of vigorous mathematical progress in equilibrium statistical mechanics. Its treatment of the infinite system limit has not been superseded, and the discussion of thermodynamic functions and states remains basic for more recent work. The conceptual foundation provided by the Rigorous Results remains invaluable for the study of the spectacular developments of statistical mechanics in the second half of the 20th century.
This book provides an introduction to nonequilibrium statistical physics via lattice models. Beginning with an introduction to the basic driven lattice gas, the early chapters discuss the relevance of this lattice model to certain natural phenomena, examining simulation results in detail. Later chapters discuss absorbing-state transitions, and examine a variety of systems subject to dynamic disorder. The book discusses the effects of multiparticle rules, nonunique absorbing-states and conservation laws, as well as the use of methods such as mean-field theory, Monte Carlo simulation and the concept of universality. It also includes detailed references and examples using simple respresentations of nature to describe real systems.
The thermodynamic limit is a mathematical technique for modeling crystals or other macroscopic objects by considering them as infinite periodic arrays of molecules. The technique allows models in solid state physics to be derived directly from models in quantum chemistry. This book presents new results, many previously unpublished, for a large class of models and provides a survey of the mathematics of thermodynamic limit problems. The authors both work closely with Fields Medal-winner Pierre-Louis Lion, and the book will be a valuable tool for applied mathematicians and mathematical physicists studying nonlinear partial differential equations. |
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