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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
This monograph discusses the essential principles of the evaporationprocess by looking at it at the molecular and atomic level. In the first part methods of statistical physics, physical kinetics andnumerical modeling are outlined including the Maxwell's distributionfunction, the Boltzmann kinetic equation, the Vlasov approach, and theCUDA technique. The distribution functions of evaporating particles are then defined.Experimental results on the evaporation coefficient and the temperaturejump on the evaporation surface are critically reviewed and compared tothe theory and numerical results presented in previous chapters. The book ends with a chapter devoted to evaporation in differentprocesses, such as boiling and cavitation.This monograph addressesgraduate students and researchers working on phase transitions andrelated fields.
This monograph attempts to provide a systematic and consistent survey of the fundamentals of the theory of free, linear, isentropic oscillations in spherically symmetric, gaseous equilibrium stars, whose structure is affected neither by axial rotation, nor by the tidal action of a companion, nor by a magnetic eld. Three parts can be distinguished. The rst part, consisting of Chaps.1-8, covers the basic concepts and equations, the distinction between spheroidal and toroidal normal modes, the solution of Poisson's differential equation for the perturbation of the gravitational potential, and Hamilton's variational principle. The second part, consisting of Chaps.9-13, is devotedto the possible existenceof waves propagating in the radial direction, the origin and classi cation of normal modes, the comple- ness of the normal modes, and the relation between the local stability with respect to convection and the global stability of a star. In the third part, Chaps.14-18 c- tain asymptoticrepresentationsof normalmodes. Chapter 19 deals with slow period changes in rapidly evolving pulsating stars. The theory is developed within the framework of the Newtonian theory of gr- itation and the hydrodynamics of compressible uids. It is described in its present status, with inclusion of open questions. We give preference to the use of the adjective "isentropic" above that of the adjective "adiabatic," since, from a thermodynamic point of view, these stellar - cillations are described as reversible adiabatic processes and thus as processes that take place at constant entropy.
Kondo Semiconductors: Kondo Semiconductor CeNiSn (T. Takabatake et al.). Non Fermi-Liquid Ground State in the Heavy Fermion Compounds (F.G. Aliev). 4f and 5f Compounds: Specific Heat of Some Uranium Based Ternary Compounds (T. Fujita et al.). Magnetic Ordering of 122 U and Ce Intermetallic Compounds Described Via an fd Hybridization Model (J.A. Mydosh et al.). Supercoductivity of f electron Systems: Transport and Thermal Properties of Some Selected Heavy Fermion Materials (A. de Visser). Thermal Properties of Heavy Fermion Superconductors (J.P. Brison et al.). Theory: The Ground State of the One Dimensional Kondo Lattice Model (M. Sigrist et al.). Anisotropic Transport Properties of Cerium Kondo Compounds (A.K. Bhattacharjee et al.). Short Presentations: Specific Heat in a Low Carrier Concentration Compound (N. Sato et al.). 23 additional articles. Index.
This graduate-level meteorology text and reference provides a scientifically rigorous description of the many types of convective circulations in the Earth's atmosphere. These range from small-scale, convectively driven turbulences in the boundary layer to precipitating systems covering many thousands of square kilometers. The text introduces the principal techniques used in understanding and predicting convective motion: theory, field experiment, and numerical modelling. Part I explores dry convection, including turbulent plumes and thermals from isolated buoyancy sources, Raleigh-Benard convection, and turbulent convection in the planetary boundary layer. Emphasis is placed on applying theoretical understanding and lessons from experiments. Part II offers a complete treatment of the thermodynamics of moist and cloudy air, including fundamental laws, conserved quantities, graphical techniques, and stability. Part III explores the characteristics of individual convective clouds, thunderstorms, squall lines, mesoscale convective systems, and slantwise convection. Part IV studies the ensemble effects of convective clouds, including stratocumulus at trade cumulus boundary layers and the representation of convective clouds in numerical models. Each chapter is followed by a set of exercises.
This book gives the definitive mathematical answer to what thermodynamics really is: a variational calculus applied to probability distributions. Extending Gibbs's notion of ensemble, the Author imagines the ensemble of all possible probability distributions and assigns probabilities to them by selection rules that are fairly general. The calculus of the most probable distribution in the ensemble produces the entire network of mathematical relationships we recognize as thermodynamics. The first part of the book develops the theory for discrete and continuous distributions while the second part applies this thermodynamic calculus to problems in population balance theory and shows how the emergence of a giant component in aggregation, and the shattering transition in fragmentation may be treated as formal phase transitions. While the book is intended as a research monograph, the material is self-contained and the style sufficiently tutorial to be accessible for self-paced study by an advanced graduate student in such fields as physics, chemistry, and engineering.
This book presents a theoretical study of heat transfer due to laminar natural convection of nanofluids, using Al2O3-water nanofluid as an example. An innovative method of similarity transformation of velocity fields on laminar boundary layers is applied for the development of a mathematical governing model of natural convection with actual nanofluids, and a novel model of the nanofluid's variable thermophysical properties is derived by a mathematical analysis based on the developed model of variable physical properties of fluids combined with the model of the nanofluid's thermal conductivity and viscosity. Based on these, the physical property factors of nanofluids are produced, which leads to a simultaneous solution for deep investigations of hydrodynamics and heat transfer of nanofluid's natural convection. The book also proposes novel predictive formulae for the evaluation of heat transfer of Al2O3-water nanofluid's natural convection. The formulae have reliable theoretical and practical value because they are developed by rigorous theoretical analysis of heat transfer combined with full consideration of the effects of the temperature-dependent physical properties of nanofluids and the nanoparticle shape factor and concentration, as well as variations of fluid boundary temperatures. The conversion factors proposed help to turn the heat transfer coefficient and rate of fluid natural convection into those of nanofluid natural convection. Furthermore, several calculation examples are provided to demonstrate the heat transfer application of the proposed predictive formulae.
The idea of this book is to present the up-to-date research results on Nitrate Esters as explosive materials. It covers many aspects including the material structures, nitrating agent, chemical synthesis devices, preparation technology, and applications etc. In particular, this work sheds light on the comprehensive utilization and thorough destruction of the used Nitrate Easters which is crucial for preventing repeated pollution. This is a highly informative and instructive book providing insight for the researchers working on nitrating theory, energetic materials and chemical equipments.
This book pays tribute to two pioneers in the field of Mathematical physics, Jiri Patera and Pavel Winternitz of the CRM. Each has contributed more than forty years to the subject of mathematical physics, particularly to the study of algebraic methods.
This introduction to thermodynamics discusses typical phase diagrams features and presents the wide range of techniques such as Differential Scanning Calorimetry, Thermogravimetry and others. In the last part the author brings many examples for typical practical problems often solved by thermal analysis. As an instructive guideline for practitioners the work reveals the connection between experimental data and theoretical model and vice versa.
This book presents the physical science experiments in a space microgravity environment conducted on board the SJ-10 recoverable satellite, which was launched on April 6th, 2016 and recovered on April 18th, 2016. The experiments described were selected from ~100 proposals from various institutions in China and around the world, and have never previously been conducted in the respective fields. They involve fluid physics and materials science, and primarily investigate the kinetic properties of matter in a space microgravity environment. The book provides a comprehensive review of these experiments, as well as the mission's execution, data collection, and scientific outcomes.
The aim of this Book is to give an overview, based on the results of nearly three decades of intensive research, of transient chaos. One belief that motivates us to write this book is that, transient chaos may not have been appreciated even within the nonlinear-science community, let alone other scientific disciplines.
After a short introduction to the fundamentals, this book provides a detailed account of major advances in applying fractional calculus to dynamical systems. Fractional order dynamical systems currently continue to gain further importance in many areas of science and engineering. As with many other approaches to mathematical modeling, the first issue to be addressed is the need to couple a definition of the fractional differentiation or integration operator with the types of dynamical systems that are analyzed. As such, for the fundamentals the focus is on basic aspects of fractional calculus, in particular stability analysis, which is required to tackle synchronization in coupled fractional order systems, to understand the essence of estimators for related integer order systems, and to keep track of the interplay between synchronization and parameter observation. This serves as the common basis for the more advanced topics and applications presented in the subsequent chapters, which include an introduction to the 'Immersion and Invariance' (I&I) methodology, the masterslave synchronization scheme for partially known nonlinear fractional order systems, Fractional Algebraic Observability (FAO) and Fractional Generalized quasi-Synchronization (FGqS) to name but a few. This book is intended not only for applied mathematicians and theoretical physicists, but also for anyone in applied science dealing with complex nonlinear systems.
Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for students in chemical engineering and the chemical sciences.
Thisbook traces the history of the concept of work from its earliest stages and shows that its further formalization leads to equilibrium principle and to the principle of virtual works, and so pointing the way ahead for future research and applications. The idea that something remains constant in a machine operation is very old and has been expressed by many mathematicians and philosophers such as, for instance, Aristotle. Thus, a concept of energy developed. Another importantidea in machine operation is Archimedes'lever principle. In modern times the concept of work is analyzed in the context of applied mechanics mainly in Lazare Carnot mechanics and the mechanics of the new generation of polytechnical engineers like Navier, Coriolis and Poncelet. In this context the word "work" is finally adopted. These engineers are also responsible for the incorporation of the concept of work into the discipline of economics when they endeavoured to combine the studyof the work of machines and men together."
Predicting thermodynamic quantities for chemically realistic systems on the basis of atomistic calculations is still, even today, a nontrivial task. Nonetheless, accurate treatment of inter-particle interactions, in terms of quantum chemical first principles methods, is a prerequisite for many applications, because of the complexity of both reactants and solvents in modern molecular sciences. Currently, a straightforward calculation of thermodynamic properties from these methods is only possible for high-temperature and low- density systems. Although the enthalpy of a system can often be predicted to a good level of precision with this ideal gas approach, calculating the entropy contribution to the free energy is problematic, especially as the density of the system increases. This thesis contains a compact and coherent introduction of basic theoretical features. The foundations are then laid for the development of approaches suitable for calculation of condensed phase entropies on the basis of well-established quantum chemical methods. The main emphasis of this work is on realistic systems in solution, which is the most important environment for chemical synthesis. The presented results demonstrate how isolated molecular concepts typically employed in modern quantum chemistry can be extended for the accurate determination of thermodynamic properties by means of scale- transferring approaches.
An introductory textbook exploring the subject of Lagrangian and Hamiltonian dynamics, with a relaxed and self-contained setting. Lagrangian and Hamiltonian dynamics is the continuation of Newton's classical physics into new formalisms, each highlighting novel aspects of mechanics that gradually build in complexity to form the basis for almost all of theoretical physics. Lagrangian and Hamiltonian dynamics also acts as a gateway to more abstract concepts routed in differential geometry and field theories and can be used to introduce these subject areas to newcomers. Journeying in a self-contained manner from the very basics, through the fundamentals and onwards to the cutting edge of the subject, along the way the reader is supported by all the necessary background mathematics, fully worked examples, thoughtful and vibrant illustrations as well as an informal narrative and numerous fresh, modern and inter-disciplinary applications. The book contains some unusual topics for a classical mechanics textbook. Most notable examples include the 'classical wavefunction', Koopman-von Neumann theory, classical density functional theories, the 'vakonomic' variational principle for non-holonomic constraints, the Gibbs-Appell equations, classical path integrals, Nambu brackets and the full framing of mechanics in the language of differential geometry.
This textbook brings together the fundamentals of the macroscopic and microscopic aspects of thermal physics by presenting thermodynamics and statistical mechanics as complementary theories based on small numbers of postulates. The book is designed to give the instructor flexibility in structuring courses for advanced undergraduates and/or beginning graduate students and is written on the principle that a good text should also be a good reference. The presentation of thermodynamics follows the logic of Clausius and Kelvin while relating the concepts involved to familiar phenomena and the modern student's knowledge of the atomic nature of matter. Another unique aspect of the book is the treatment of the mathematics involved. The essential mathematical concepts are briefly reviewed before using them, and the similarity of the mathematics to that employed in other fields of physics is emphasized. The text gives in depth treatments of low density gases, harmonic solids, magnetic and dielectric materials, phase transitions, and the concept of entropy. The microcanonical, canonical, and grand canonical ensembles of statistical mechanics are derived and used as the starting point for the analysis of fluctuations, blackbody radiation, the Maxwell distribution, Fermi-Dirac statistics, Bose-Einstein condensation, and the statistical basis of computer simulations. Supplementary material including PowerPoint slides and detailed worked solutions can be downloaded online at http://booksupport.wiley.com
This book presents a careful selection of the most important developments of the \phi^4 model, offering a judicious summary of this model with a view to future prospects and the challenges ahead. Over the past four decades, the \phi^4 model has been the basis for a broad array of developments in the physics and mathematics of nonlinear waves. From kinks to breathers, from continuum media to discrete lattices, from collisions of solitary waves to spectral properties, and from deterministic to stochastic models of \phi^4 (and \phi^6, \phi^8, \phi^12 variants more recently), this dynamical model has served as an excellent test bed for formulating and testing the ideas of nonlinear science and solitary waves.
The Ising model provides a detailed mathematical description of ferromagnetism and is widely used in statistical physics and condensed matter physics. In this Student's Guide, the author demystifies the mathematical framework of the Ising model and provides students with a clear understanding of both its physical significance, and how to apply it successfully in their calculations. Key topics related to the Ising model are covered, including exact solutions of both finite and infinite systems, series expansions about high and low temperatures, mean-field approximation methods, and renormalization-group calculations. The book also incorporates plots, figures, and tables to highlight the significance of the results. Designed as a supplementary resource for undergraduate and graduate students, each chapter includes a selection of exercises intended to reinforce and extend important concepts, and solutions are also available for all exercises.
Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition presents a comprehensive introduction to 20th century thermodynamics that can be applied to both equilibrium and non-equilibrium systems, unifying what was traditionally divided into thermodynamics and kinetics into one theory of irreversible processes. This comprehensive text, suitable for introductory as well as advanced courses on thermodynamics, has been widely used by chemists, physicists, engineers and geologists. Fully revised and expanded, this new edition includes the following updates and features: * Includes a completely new chapter on Principles of Statistical Thermodynamics. * Presents new material on solar and wind energy flows and energy flows of interest to engineering. * Covers new material on self-organization in non-equilibrium systems and the thermodynamics of small systems. * Highlights a wide range of applications relevant to students across physical sciences and engineering courses. * Introduces students to computational methods using updated Mathematica codes. * Includes problem sets to help the reader understand and apply the principles introduced throughout the text. * Solutions to exercises and supplementary lecture material provided online at http://sites.google.com/site/modernthermodynamics/. Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition is an essential resource for undergraduate and graduate students taking a course in thermodynamics.
This book focuses on theoretical thermotics, the theory of transformation thermotics and its extended theories for the active control of macroscopic thermal phenomena of artificial systems, which is in sharp contrast to classical thermodynamics comprising the four thermodynamic laws for the passive description of macroscopic thermal phenomena of natural systems. The book covers the basic concepts and mathematical methods, which are necessary to understand thermal problems extensively investigated in physics, but also in other disciplines of engineering and materials. The analyses rely on models solved by analytical techniques accompanied with computer simulations and laboratory experiments. This book serves both as a reference work for senior researchers and a study text for zero beginners.
Fundamentals of the Finite Element Method for Heat and Mass Transfer, Second Edition is a comprehensively updated new edition and is a unique book on the application of the finite element method to heat and mass transfer. Addresses fundamentals, applications and computer implementation Educational computer codes are freely available to download, modify and use Includes a large number of worked examples and exercises Fills the gap between learning and research
Instantons, or pseudoparticles, are solutions to the equations of motion in classical field theories on a Euclidean spacetime. Instantons are found everywhere in quantum theories as they have many applications in quantum tunnelling. Diverse physical phenomena may be described through quantum tunnelling, for example: the Josephson effect, the decay of meta-stable nuclear states, band formation in tight binding models of crystalline solids, the structure of the gauge theory vacuum, confinement in 2+1 dimensions, and the decay of superheated or supercooled phases. Drawing inspiration from Sidney Coleman's Erice lectures, this volume provides an accessible, detailed introduction to instanton methods, with many applications, making it a valuable resource for graduate students in many areas of physics, from condensed matter, particle and nuclear physics, to string theory. This title, first published in 2017, has been reissued as an Open Access publication on Cambridge Core.
Fundamentals of Classical and Statistical Thermodynamics provides a comprehensive introduction to this pivotal subject. Starting from basics, the book begins with a thorough introduction to the field, providing concise definitions and an overview of thermodynamics and its applications. The book discusses the fundamentals of classical equilibrium thermodynamics, thermal physics, kinetic theory and statistical mechanics. This comprehensive coverage enables the reader to understand not only the interrelationships between these subjects but also encourages an ability to interpret the thermodynamic quantities and laws in terms of statistical mechanics. Beginning with a detailed discussion of the four laws of thermodynamics the text introduces more advanced topics in later chapters, such as applications of the first and second laws, free energy and chemical equilibria, and equilibrium statististical mechanics and applications. Uniquely, this text includes a large number of worked examples throughout, with a range of problems at the end of each chapter and their solutions all at the end of the book. The most fundamental concepts of the subject are emphasised throughout and new derivations of many of the standard formulae have been developed to avoid excessive mathematical rigour. Fundamentals of Classical and Statistical Thermodynamics:
Written by leading experts in their respective fields,
Solidification and Casting provides a comprehensive review of
topics fundamental to metallurgy and materials science as well as
indicates recent trends. |
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