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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
The aim of this book is to comment on, and clarify, the mathematical aspects of the theory of thermodynamics. The standard presentations of the subject are often beset by a number of obscurities associated with the words "state," "reversible," "irreversible," and "quasi-static." This book is written in the belief that such obscurities are best removed not by the formal axiomatization of thermodynamics, but by setting the theory in the wider context of a genuine field theory which incorporates the effects of heat conduction and intertia, and proving appropriate results about the governing differential equations of this field theory. Even in the simplest one-dimensional case it is a nontrivial task to carry through the details of this program, and many challenging problems remain open.
This book offers a compact tutorial on basic concepts and tools in quantum many-body physics, and focuses on the correlation effects produced by mutual interactions. The content is divided into three parts, the first of which introduces readers to perturbation theory. It begins with the simplest examples-hydrogen and oxygen molecules-based on their effective Hamiltonians, and looks into basic properties of electrons in solids from the perspective of localized and itinerant limits. Readers will also learn about basic theoretical methods such as the linear response theory and Green functions. The second part focuses on mean-field theory for itinerant electrons, e.g. the Fermi liquid theory and superconductivity. Coulomb repulsion among electrons is addressed in the context of high-Tc superconductivity in cuprates and iron pnictides. A recent discovery concerning hydride superconductors is also briefly reviewed. In turn, the third part highlights quantum fluctuation effects beyond the mean-field picture. Discussing the dramatic renormalization effect in the Kondo physics, it provides a clear understanding of nonperturbative interaction effects. Further it introduces readers to fractionally charged quasi-particles in one and two dimensions. The last chapter addresses the dynamical mean field theory (DMFT). The book is based on the author's long years of experience as a lecturer and researcher. It also includes reviews of recent focus topics in condensed matter physics, enabling readers to not only grasp conventional condensed matter theories but also to catch up on the latest developments in the field.
This is an introduction to the dynamics of fluids at small scales, the physical and mathematical underpinnings of Brownian motion, and the application of these subjects to the dynamics and flow of complex fluids such as colloidal suspensions and polymer solutions. It brings together continuum mechanics, statistical mechanics, polymer and colloid science, and various branches of applied mathematics, in a self-contained and integrated treatment that provides a foundation for understanding complex fluids, with a strong emphasis on fluid dynamics. Students and researchers will find that this book is extensively cross-referenced to illustrate connections between different aspects of the field. Its focus on fundamental principles and theoretical approaches provides the necessary groundwork for research in the dynamics of flowing complex fluids.
This long-awaited, physics-first and design-oriented text describes and explains the underlying flow and heat transfer theory of secondary air systems. An applications-oriented focus throughout the book provides the reader with robust solution techniques, state-of-the-art three-dimensional computational fluid dynamics (CFD) methodologies, and examples of compressible flow network modeling. It clearly explains elusive concepts of windage, non-isentropic generalized vortex, Ekman boundary layer, rotor disk pumping, and centrifugally-driven buoyant convection associated with gas turbine secondary flow systems featuring rotation. The book employs physics-based, design-oriented methodology to compute windage and swirl distributions in a complex rotor cavity formed by surfaces with arbitrary rotation, counter-rotation, and no rotation. This text will be a valuable tool for aircraft engine and industrial gas turbine design engineers as well as graduate students enrolled in advanced special topics courses.
This is an introduction to the dynamics of fluids at small scales, the physical and mathematical underpinnings of Brownian motion, and the application of these subjects to the dynamics and flow of complex fluids such as colloidal suspensions and polymer solutions. It brings together continuum mechanics, statistical mechanics, polymer and colloid science, and various branches of applied mathematics, in a self-contained and integrated treatment that provides a foundation for understanding complex fluids, with a strong emphasis on fluid dynamics. Students and researchers will find that this book is extensively cross-referenced to illustrate connections between different aspects of the field. Its focus on fundamental principles and theoretical approaches provides the necessary groundwork for research in the dynamics of flowing complex fluids.
This thesis deals with two main procedures performed with the ATLAS detector at the Large Hadron Collider (LHC). The noise description in the hadronic calorimeter TileCal represents a very valuable technical job. The second part presents a fruitful physics analysis - the cross section measurement of the process p+p Z0 + . The Monte Carlo simulations of the TileCal are described in the first part of the thesis, including a detailed treatment of the electronic noise and multiple interactions (so-called pile-up). An accurate description of both is crucial for the reconstruction of e.g. jets or hadronic tau-jets. The second part reports a Standard Model measurement of the Z0 + process with the emphasis on the final state with an electron and a hadronically decaying tau-lepton. The Z0 + channel forms the dominant background in the search for Higgs bosons decaying into tau lepton pairs, and thus the good understanding achieved here can facilitate more sensitive Higgs detection."
This book introduces and discusses the analysis of interacting many-body complex systems exhibiting spontaneous synchronization from the perspective of nonequilibrium statistical physics. While such systems have been mostly studied using dynamical system theory, the book underlines the usefulness of the statistical physics approach to obtain insightful results in a number of representative dynamical settings. Although it is intractable to follow the dynamics of a particular initial condition, statistical physics allows to derive exact analytical results in the limit of an infinite number of interacting units. Chapter one discusses dynamical characterization of individual units of synchronizing systems as well as of their interaction and summarizes the relevant tools of statistical physics. The latter are then used in chapters two and three to discuss respectively synchronizing systems with either a first- or a second-order evolution in time. This book provides a timely introduction to the subject and is meant for the uninitiated as well as for experienced researchers working in areas of nonlinear dynamics and chaos, statistical physics, and complex systems.
Designed for the course in thermodynamics or for use as a reference for practicing engineers, this book includes the theoretical underpinnings and derivations necessary for advanced study. The book focuses on the mechanical and power engineering applications of thermodynamics. Mathematics is utilized as required, serving as a tool to formulate the concepts, solve problems and applications. Furthermore, numerous examples are provided to demonstrate the applications of thermodynamics for engineering problems and to enhance the use of concepts. It also includes statistical thermodynamic examples when relevant and pertinent. These examples are shown either conceptually or numerically. Features: Numerous examples are provided to demonstrate the applications of thermodynamics for engineering problems; Includes a comprehensive and generalist view of thermodynamics, along with historical developments in the field; Presents mathematical tools such as the Legendre transformation, the Euler chain rule, the Jacobian methodology and applications for thermodynamic derivatives.
Partition functions arise in combinatorics and related problems of statistical physics as they encode in a succinct way the combinatorial structure of complicated systems. The main focus of the book is on efficient ways to compute (approximate) various partition functions, such as permanents, hafnians and their higher-dimensional versions, graph and hypergraph matching polynomials, the independence polynomial of a graph and partition functions enumerating 0-1 and integer points in polyhedra, which allows one to make algorithmic advances in otherwise intractable problems. The book unifies various, often quite recent, results scattered in the literature, concentrating on the three main approaches: scaling, interpolation and correlation decay. The prerequisites include moderate amounts of real and complex analysis and linear algebra, making the book accessible to advanced math and physics undergraduates.
This advanced text presents a unique approach to studying transport phenomena. Bringing together concepts from both chemical engineering and physics, it makes extensive use of nonequilibrium thermodynamics, discusses kinetic theory, and sets out the tools needed to describe the physics of interfaces and boundaries. More traditional topics such as diffusive and convective transport of momentum, energy and mass are also covered. This is an ideal text for advanced courses in transport phenomena, and for researchers looking to expand their knowledge of the subject. The book also includes: * Novel applications such as complex fluids, transport at interfaces and biological systems, * Approximately 250 exercises with solutions (included separately) designed to enhance understanding and reinforce key concepts, * End-of-chapter summaries.
This Brief concerns heat transfer and pressure drop in heat transfer enhancement for boiling and condensation. The authors divide their topic into six areas: abrasive treatment and coatings, combined structured and porous surfaces, basic principles of boiling mechanism, vapor space condensation, convective vaporization, and forced condensation inside tubes. Within this framework, the book examines range of specific phenomena including abrasive treatment, open grooves, 3D cavities, etched surfaces, electroplating, pierced 3D cover sheets, attached wire and screen promoters, non-wetting coatings, oxide and ceramic coatings, porous surfaces, structured surfaces (integral roughness), combined structured and porous surfaces, composite surfaces, single-tube pool boiling tests, theoretical fundamentals like liquid superheat, effect of cavity shape and contact angle on superheat, entrapment of vapor in cavities, nucleation at a surface cavity, effect of dissolved gases, bubble departure diameter, bubble dynamics, boiling hysteresis and orientation effects, basic principles of boiling mechanism, visualization and mechanism of boiling in subsurface tunnels, and Chien and Webb parametric boiling studies.
As a companion to the undergraduate textbook "Physical Chemistry from a Different Angle", this workbook offers an excellent opportunity to deepen the understanding of the concepts presented in the textbook by addressing specific problems. The workbook is divided into two parts: a first part with nearly 200 exercises and a second part providing the corresponding detailed solutions with helpful comments, enabling students to learn independently.
This text presents an intuitive and robust mathematical image of fundamental particle physics based on a novel approach to quantum field theory, which is guided by four carefully motivated metaphysical postulates. In particular, the book explores a dissipative approach to quantum field theory, which is illustrated for scalar field theory and quantum electrodynamics, and proposes an attractive explanation of the Planck scale in quantum gravity. Offering a radically new perspective on this topic, the book focuses on the conceptual foundations of quantum field theory and ontological questions. It also suggests a new stochastic simulation technique in quantum field theory which is complementary to existing ones. Encouraging rigor in a field containing many mathematical subtleties and pitfalls this text is a helpful companion for students of physics and philosophers interested in quantum field theory, and it allows readers to gain an intuitive rather than a formal understanding.
Arturo Carsetti According to molecular Biology, true invariance (life) can exist only within the framework of ongoing autonomous morphogenesis and vice versa. With respect to this secret dialectics, life and cognition appear as indissolubly interlinked. In this sense, for instance, the inner articulation of conceptual spaces appears to be linked to an inner functional development based on a continuous activity of selection and "anchorage" realised on semantic grounds. It is the work of "invention" and g- eration (in invariance), linked with the "rooting" of meaning, which determines the evolution, the leaps and punctuated equilibria, the conditions related to the unfo- ing of new modalities of invariance, an invariance which is never simple repetition and which springs on each occasion through deep-level processes of renewal and recovery. The selection perpetrated by meaning reveals its autonomy aboveall in its underpinning, in an objective way, the ongoing choice of these new modalities. As such it is not, then, concerned only with the game of "possibles," offering itself as a simple channel for pure chance, but with providing a channel for the articulation of the " le" in the humus of a semantic (and embodied) net in order to prepare the necessary conditionsfor a continuousrenewal and recoveryof original creativity. In effect, it is this autonomy in inventing new possible modules of incompressibility whichdeterminestheactualemergenceofnew(andtrue)creativity, whichalsotakes place through the "narration" of the effected construction.
This motivating textbook gives a friendly, rigorous introduction to fundamental concepts in equilibrium statistical mechanics, covering a selection of specific models, including the Curie-Weiss and Ising models, the Gaussian free field, O(n) models, and models with Kac interactions. Using classical concepts such as Gibbs measures, pressure, free energy, and entropy, the book exposes the main features of the classical description of large systems in equilibrium, in particular the central problem of phase transitions. It treats such important topics as the Peierls argument, the Dobrushin uniqueness, Mermin-Wagner and Lee-Yang theorems, and develops from scratch such workhorses as correlation inequalities, the cluster expansion, Pirogov-Sinai Theory, and reflection positivity. Written as a self-contained course for advanced undergraduate or beginning graduate students, the detailed explanations, large collection of exercises (with solutions), and appendix of mathematical results and concepts also make it a handy reference for researchers in related areas.
This book presents a vivid argument for the almost lost idea of a unity of all natural sciences. It starts with the "strange" physics of matter, including particle physics, atomic physics and quantum mechanics, cosmology, relativity and their consequences (Chapter I), and it continues by describing the properties of material systems that are best understood by statistical and phase-space concepts (Chapter II). These lead to entropy and to the classical picture of quantitative information, initially devoid of value and meaning (Chapter III). Finally, "information space" and dynamics within it are introduced as a basis for semantics (Chapter IV), leading to an exploration of life and thought as new problems in physics (Chapter V). Dynamic equations - again of a strange (but very general) nature - bring about the complex familiarity of the world we live in. Surprising new results in the life sciences open our eyes to the richness of physical thought, and they show us what can and what cannot be explained by a Darwinian approach. The abstract physical approach is applicable to the origins of life, of meaningful information and even of our universe.
This book is based on many years of teaching statistical and thermal physics. It assumes no previous knowledge of thermodynamics, kinetic theory, or probability---the only prerequisites are an elementary knowledge of classical and modern physics, and of multivariable calculus. The first half of the book introduces the subject inductively but rigorously, proceeding from the concrete and specific to the abstract and general. In clear physical language the book explains the key concepts, such as temperature, heat, entropy, free energy, chemical potential, and distributions, both classical and quantum. The second half of the book applies these concepts to a wide variety of phenomena, including perfect gases, heat engines, and transport processes. Each chapter contains fully worked examples and real-world problems drawn from physics, astronomy, biology, chemistry, electronics, and mechanical engineering.
Finite element methods have become ever more important to engineers as tools for design and optimization, now even for solving non-linear technological problems. However, several aspects must be considered for finite-element simulations which are specific for non-linear problems: These problems require the knowledge and the understanding of theoretical foundations and their finite-element discretization as well as algorithms for solving the non-linear equations. This book provides the reader with the required knowledge covering the complete field of finite element analyses in solid mechanics. It is written for advanced students in engineering fields but serves also as an introduction into non-linear simulation for the practising engineer.
This book gives a rigorous treatment of entanglement measures in the general context of quantum field theory. It covers a broad range of models and the use of fields allows us to properly take the localization of systems into account. The required mathematical techniques are introduced in a self-contained way.
Written by two specialists with over twenty-five years of experience in the field, this valuable text presents a wide range of topics within the growing field of nonequilibrium molecular dynamics (NEMD). It introduces theories which are fundamental to the field - namely, nonequilibrium statistical mechanics and nonequilibrium thermodynamics - and provides state-of-the-art algorithms and advice for designing reliable NEMD code, as well as examining applications for both atomic and molecular fluids. It discusses homogenous and inhomogenous flows and pays considerable attention to highly confined fluids, such as nanofluidics. In addition to statistical mechanics and thermodynamics, the book covers the themes of temperature and thermodynamic fluxes and their computation, the theory and algorithms for homogenous shear and elongational flows, response theory and its applications, heat and mass transport algorithms, applications in molecular rheology, highly confined fluids (nanofluidics), the phenomenon of slip and how to compute it from basic microscopic principles, and generalized hydrodynamics.
This book touches upon various aspects of a very interesting, and growing in popularity category of models of dynamical systems. These are the so-called fractional-order systems. Such models are not only relevant for many fields of science and technology, but may also find numerous applications in other disciplines applying the mathematical modelling tools. Thus, the book is intended for a very wide audience of professionals who want to expand their knowledge of systems modelling and its applications. The book includes the selections of papers presented at the International Conference on Fractional Calculus and its Applications organized by the Warsaw University of Technology and was held online on 6-8 September 2021. The International Conference on Fractional Calculus and its Applications (ICFDA) has an almost twenty years history. It started in Bordeaux (France) in 2004, followed by Porto (Portugal) 2006, Istanbul (Turkey) 2008, Badajoz (Spain) 2010, Nanjing (China) 2012, Catania (Italy) 2014, Novi Sad (Serbia) 2016, Amman (Jordan) 2018. Next ICFDA was planned in 2020 in Warsaw (Poland), but COVID-19 pandemic shifted it to 6-8 September 2021. Hence, the organizers were forced to change the form of the conference to the online one. In the volume twenty eight high-quality research papers presented during the ICFDA 2021 eleven Regular Sessions with an additional online Discussion Session are presented. The presented papers are scientifically inspiring, leading to new fruitful ideas. They cover a very broad range of many disciplines. Nowadays, and especially in such a subject as fractional calculus, it is very difficult to assign papers to specific scientific areas. So, many of the papers included have an interdisciplinary character.
This book offers a unified perspective on the study of complex systems for scholars of various disciplines, including mathematics, physics, computer science, biology, economics and social science. The contributions, written by leading scientists, cover a broad set of topics, including new approaches to data science, the connection between scaling limits and conformal field theories, and new ideas on the Legendre duality approach in statistical mechanics of disordered systems. The volume moreover explores results on extreme values of correlated random variables and their connection with the Riemann zeta functions, the relation between diffusion phenomena and complex systems, and the Brownian web, which appears as the universal scaling limit of several probabilistic models. Written for researchers from a broad range of scientific fields, this text examines a selection of recent developments in complex systems from a rigorous perspective.
Thermodynamics Problem Solving in Physical Chemistry: Study Guide and Map is an innovative and unique workbook that guides physical chemistry students through the decision-making process to assess a problem situation, create appropriate solutions, and gain confidence through practice solving physical chemistry problems. The workbook includes six major sections with 20 - 30 solved problems in each section that span from easy, single objective questions to difficult, multistep analysis problems. Each section of the workbook contains key points that highlight major features of the topic to remind students of what they need to apply to solve problems in the topic area. Key Features: Provides instructor access to a visual map depicting how all equations used in thermodynamics are connected and how they are derived from the three major energy laws. Acts as a guide in deriving the correct solution to a problem. Illustrates the questions students should ask themselves about the critical features of the concepts to solve problems in physical chemistry Can be used as a stand-alone product for review of Thermodynamics questions for major tests.
Thermodynamics is fundamental to university and college curricula in chemistry, physics, engineering and many life sciences around the world. It is also notoriously difficult for students to understand, learn and apply. What makes this book different, and special, is the clarity of the text. The writing style is fluid, natural and lucid, and everything is explained in a logical and transparent manner. Thermodynamics is a deep, and important, branch of science, and this book does not make it "easy". But it does make it intelligible. This book introduces a new, 'Fourth Law' of Thermodynamics' based on the notion of Gibbs free energy, which underpins almost every application of thermodynamics and which the authors claim is worthy of recognition as a 'law'. The last four chapters bring thermodynamics into the twenty-first century, dealing with bioenergetics (how living systems capture and use free energy), macromolecule assembly (how proteins fold), and macromolecular aggregation (how, for example, virus capsids assemble). This is of great current relevance to students of biochemistry, biochemical engineering and pharmacy, and is covered in very few other texts on thermodynamics. The book also contains many novel and effective examples, such as the explanation of why friction is irreversible, the proof of the depression of the freezing point, and the explanation of the biochemical standard state.
This book focuses on the development and set-up of fibre Bragg grating (FBG) and no-core fibre (NCF) sensors. It discusses the properties of the sensors and modelling of the resulting devices, which include electronic, optoelectronic, photovoltaic, and spintronic devices. In addition to providing detailed explanations of the properties of FBG and NCF sensors, it features a wealth of instructive illustrations and tables, helping to visualize the respective devices' functions. |
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