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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
Modern structural applications of crystallography make extensive use of statistical methods, in particular the probability density function (pdf) of the magnitude of the structure factor. Similarly, direct methods of phase determination have been responsible for much of the success of crystallography - methods based on properties of joint pdfs. This monograph, from two authorities in the field of structure factor statics, presents a survey of techniques and theories in this field of research in a self-contained and consistent way, with an emphasis on the probabilistic principles involved.
Stability conditions for functional differential equations can be obtained using Lyapunov functionals. Lyapunov Functionals and Stability of Stochastic Functional Differential Equations describes the general method of construction of Lyapunov functionals to investigate the stability of differential equations with delays. This work continues and complements the author's previous book Lyapunov Functionals and Stability of Stochastic Difference Equations, where this method is described for difference equations with discrete and continuous time. The text begins with both a description and a delineation of the peculiarities of deterministic and stochastic functional differential equations. There follows basic definitions for stability theory of stochastic hereditary systems, and the formal procedure of Lyapunov functionals construction is presented. Stability investigation is conducted for stochastic linear and nonlinear differential equations with constant and distributed delays. The proposed method is used for stability investigation of different mathematical models such as: * inverted controlled pendulum; * Nicholson's blowflies equation; * predator-prey relationships; * epidemic development; and * mathematical models that describe human behaviours related to addictions and obesity. Lyapunov Functionals and Stability of Stochastic Functional Differential Equations is primarily addressed to experts in stability theory but will also be of interest to professionals and students in pure and computational mathematics, physics, engineering, medicine, and biology.
This monograph gives a systematic presentation of ideas, methods and results of the modern statistical theory of open systems -- systems capable of exchanging matter, energy and information with the surrounding world. The resulting self-organization can lead to more sophisticated and advanced structures. Central to this work are the statistical criteria of self-organization. The feasibility of a unified description of kinetic, hydrodynamic and diffusion processes in passive and active macroscopic systems without resorting to the methods of perturbation theory is demonstrated. On this basis, a general definition of thermal flux is given in terms of the entropy gradient. Moreover, a consistent method for calculating both kinetic and hydrodynamic fluctuations is proposed. This approach is then used to construct a theory of classical and anomalous Brownian motion in nonlinear media. This theory makes it possible to treat in an original way the phenomenon of turbulence, and to propose a unified kinetic description of laminar and turbulent motion. The proposed methods are also applied to the statistical description of quantum macroscopic open systems. This provides answers as to whether or not the quantum mechanical description is complete, and whether or not there are hidden parameters in quantum mechanics. The book has no analogy in the existing literature. It is both a monograph and a textbook, and is based largely on the author's original research. The book will be useful to postgraduate students and researchers in chemistry, physics, mathematics, economics, sociology, and engineering.
- It provides a rigorous mathematical and physical basis to techniques that are often introduced on empirical basis - While the book covers a broad range of techniques, it starts at a basic theoretical level. This gives the book a strong foundation and makes it accessible to students from various backgrounds. - Has a computational focus unlike many competing titles
The book is designed for students taking introduction and intermediate thermodynamics courses in degrees and HNDs in Mechanical Engineering, Chemical Engineering and Process Engineering. The text provides a progressive development of ideas together with progress questions placed at regular intervals throughout the material. In the main, these questions are designed to be worked through before the student moves on through the text. This allows the assimilation of material at a rate which suits the individual.
This is one of the few books on the subject of mathematical materials science. It discusses the dynamics of two-phase systems within the framework of modern continuum thermodynamics, stressing fundamentals. Two general theories are discussed: a mechanical theory that leads to a generalization of the classical curve-shortening equation and a theory of heat conduction that broadly generalizes the classical Stefan theory. This original survey includes simple solutions that demonstrate the instabilities inherent in two-phase problems. The free-boundary problems that form the basis of the subject should be of great interest to mathematicians and physical scientists.
Unlike the traditional approach to thermodynamics, this book begins with a brief exposition of hydrodynamics. At this stage, the development is limited to potential flows, because, until recently, that is all that could be done, but also for didactic reasons. However, the reader will find that the situation has changed radically with the discovery of Conservative Hydrodynamics.At the core of thermodynamics is the Gibbsean minimum energy principle. In this book, it is generalized to include the hydrodynamical degrees of freedom; that is, localized as a field theory of density, pressure, temperature and entropy. The theory is referred to as local thermodynamics, as opposed to traditional, global thermodynamics where the main foundation is the variational principle of Gibbs, with a modification recommended by Prigogine.This book exists because there is (or was) no satisfactory theory of the dynamical metric interacting with extended distributions of matter. It will be shown that any theory of interacting fields that includes the Einsteinian metric must be based on an action principle.This allows us, for the first time, to use 'energy' as a precise concept in vortex dynamics. Sample applications include rotating planets, Couette flow, stresses in fluids (inside the meniscus, negative pressures), immiscible fluids, amongst others.
Proceedings of the NATO Advanced Study Institute on Propagation of Correlations in Constrained Systems, Cargese, Corsica, France, July 2-14, 1990
The book explores several open questions in the philosophy and the foundations of statistical mechanics. Each chapter is written by a leading expert in philosophy of physics and/or mathematical physics. Here is a list of questions that are addressed in the book:
This book provides a comprehensive yet short description of the basic concepts of Complex Network theory. In contrast to other books the authors present these concepts through real case studies. The application topics span from Foodwebs, to the Internet, the World Wide Web and the Social Networks, passing through the International Trade Web and Financial time series. The final part is devoted to definition and implementation of the most important network models. The text provides information on the structure of the data and on the quality of available datasets. Furthermore it provides a series of codes to allow immediate implementation of what is theoretically described in the book. Readers already used to the concepts introduced in this book can learn the art of coding in Python by using the online material. To this purpose the authors have set up a dedicated web site where readers can download and test the codes. The whole project is aimed as a learning tool for scientists and practitioners, enabling them to begin working instantly in the field of Complex Networks.
Das Buch bietet eine kompakte Zusammenstellung der wichtigsten Ph nomene in der Tieftemperaturphysik, die sowohl Studenten (mit dieser Vertiefungsrichtung im Hauptstudium), als auch Doktoranden, Wissenschaftlern und Ingenieuren, die auf diesem Gebiet t tig sind, als Lehrbuch dienen kann. Es eignet sich als Grundlage f r entsprechende Vorlesungen.
The statistical mechanical theory of liquids and solutions is a fundamental area of physical sciences with important implications in other fields of science and for many industrial applications. This book introduces equilibrium statistical mechanics in general, and statistical mechanics of liquids and solutions in particular. A major theme is the intimate relationship between forces in a fluid and the fluid structure - a relationship that is paramount for the understanding of the subject of interactions in dense fluids. Using this microscopic, molecular approach, the text emphasizes clarity of physical explanations for phenomena and mechanisms relevant to fluids, addressing the structure and behavior of liquids and solutions under various conditions. A notable feature is the author's treatment of forces between particles that include nanoparticles, macroparticles, and surfaces. The book provides an expanded, in-depth treatment of simple liquids and electrolytes in the bulk and in confinement. Provides an introduction to statistical mechanics of liquids and solutions with special attention to structure and interactions. Offers an extensive presentation starting with the basics of statistical mechanics to modern aspects of the theory of liquids and solutions, including intermolecular interactions in fluids. Treats both homogeneous bulk fluids and inhomogeneous fluids near surfaces and in confinement. Takes a microscopic, molecular approach that combines physical transparency, theoretical sharpness and a pedagogical and accessible style. Gives explicit and clear textual explanations and physical interpretations for any mathematical relationships and derivations. Goes deeper than the available texts on interactions in fluids, by taking the discussion beyond simple approximations and mean field approaches. The book will be an invaluable resource for advanced undergraduate, graduate, and postgraduate students in physics, chemistry, soft matter science, surface and colloid science and related fields, as well as professionals and instructors in those areas of science.
Concise yet thorough, accessible, authoritative, and affordable. These are the hallmarks of books in the remarkable Physics and its Applications series. Thermodynamics is an essential part of any physical sciences education, but it is so full of pitfalls and subtleties, that many students fail to appreciate its elegance and power. In Thermal Physics, the author emphasizes understanding the basic ideas and shows how the important thermodynamics results can be simply obtained from the fundamental relations without getting lost in a maze of partial differentials. In this second edition, the author incorporated new sections on scales of temperature, availability, the degradation of energy, and lattice defects. The text contains ample illustrations and examples of applications of thermodynamics in physics, engineering, and chemistry.
This volume contains a selection of expository articles on quantum field theory and statistical mechanics by James Glimm and Arthur Jaffe. They include a solution of the original interacting quantum field equations and a description of the physics which these equations contain. Quantum fields were proposed in the late 1920s as the natural framework which combines quantum theory with relativ ity. They have survived ever since. The mathematical description for quantum theory starts with a Hilbert space H of state vectors. Quantum fields are linear operators on this space, which satisfy nonlinear wave equations of fundamental physics, including coupled Dirac, Max well and Yang-Mills equations. The field operators are restricted to satisfy a "locality" requirement that they commute (or anti-commute in the case of fer mions) at space-like separated points. This condition is compatible with finite propagation speed, and hence with special relativity. Asymptotically, these fields converge for large time to linear fields describing free particles. Using these ideas a scattering theory had been developed, based on the existence of local quantum fields."
This proceedings volume gathers together original articles and survey works that originate from presentations given at the conference Transient Transcendence in Transylvania, held in Brasov, Romania, from May 13th to 17th, 2019. The conference gathered international experts from various fields of mathematics and computer science, with diverse interests and viewpoints on transcendence. The covered topics are related to algebraic and transcendental aspects of special functions and special numbers arising in algebra, combinatorics, geometry and number theory. Besides contributions on key topics from invited speakers, this volume also brings selected papers from attendees.
The equations which we are going to study in these notes were first presented in 1963 by E. N. Lorenz. They define a three-dimensional system of ordinary differential equations that depends on three real positive parameters. As we vary the parameters, we change the behaviour of the flow determined by the equations. For some parameter values, numerically computed solutions of the equations oscillate, apparently forever, in the pseudo-random way we now call "chaotic"; this is the main reason for the immense amount of interest generated by the equations in the eighteen years since Lorenz first presented them. In addition, there are some parameter values for which we see "preturbulence," a phenomenon in which trajectories oscillate chaotically for long periods of time before finally settling down to stable stationary or stable periodic behaviour, others in which we see "intermittent chaos," where trajectories alternate be tween chaotic and apparently stable periodic behaviours, and yet others in which we see "noisy periodicity," where trajectories appear chaotic though they stay very close to a non-stable periodic orbit. Though the Lorenz equations were not much studied in the years be tween 1963 and 1975, the number of man, woman, and computer hours spent on them in recent years - since they came to the general attention of mathematicians and other researchers - must be truly immense."
Dieses in sich abgeschlossene Lehrbuch enthalt eine moderne und ausfuhrliche Darstellung der Grundlagen der phanomenologischen Thermodynamik. Der Schwerpunkt liegt auf der grossen Zahl aktueller Beispiele und Anwendungen aus allen Bereichen der Naturwissenschaften wie Chemie, Physik, chemische Verfahrenstechnik, Biologie, nachhaltige Energietechnik, Geophysik, Astrophysik, Umweltchemie, Medizin und nicht zuletzt dem Alltagsleben. Dadurch wird es in besonderer Weise der wachsenden Bedeutung der Thermodynamik als Querschnittswissenschaft gerecht. Das Buch ist geeignet zum Selbststudium, zum Nachschlagen wie auch zum Gebrauch in Grund- und Spezialvorlesungen aller naturwissenschaftlichen Studienfacher.
Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.
This book provides an accessible yet thorough introduction to thermodynamics, crafted and class-tested over many years of teaching. Suitable for advanced undergraduate and graduate students, this book delivers clear descriptions of how to think about the mathematics and physics involved. The content has been carefully developed in consultation with a large number of instructors, teaching courses worldwide, to ensure wide applicability to modules on thermodynamics. Modern applications of thermodynamics (in physics and related areas) are included throughout-something not offered to the same degree by existing texts in the field. Features: A sophisticated approach to the subject that is suitable for advanced undergraduate students and above Modern applications of thermodynamics included throughout To be followed by volumes on statistical mechanics, which can be used in conjunction with this book on courses which cover both thermodynamics and statistical mechanics
This volume defends a novel approach to the philosophy of physics: it is the first book devoted to a comparative study of probability, causality, and propensity, and their various interrelations, within the context of contemporary physics -- particularly quantum and statistical physics. The philosophical debates and distinctions are firmly grounded upon examples from actual physics, thus exemplifying a robustly empiricist approach. The essays, by both prominent scholars in the field and promising young researchers, constitute a pioneer effort in bringing out the connections between probabilistic, causal and dispositional aspects of the quantum domain. The book will appeal to specialists in philosophy and foundations of physics, philosophy of science in general, metaphysics, ontology of physics theories, and philosophy of probability.
Stochastic processes and diffusion theory are the mathematical underpinnings of many scientific disciplines, including statistical physics, physical chemistry, molecular biophysics, communications theory and many more. Many books, reviews and research articles have been published on this topic, from the purely mathematical to the most practical. This book offers an analytical approach to stochastic processes that are most common in the physical and life sciences, as well as in optimal control and in the theory of filltering of signals from noisy measurements. Its aim is to make probability theory in function space readily accessible to scientists trained in the traditional methods of applied mathematics, such as integral, ordinary, and partial differential equations and asymptotic methods, rather than in probability and measure theory.
This book is the second edition of Numerical methods for diffusion phenomena in building physics: a practical introduction originally published by PUCPRESS (2016). It intends to stimulate research in simulation of diffusion problems in building physics, by providing an overview of mathematical models and numerical techniques such as the finite difference and finite-element methods traditionally used in building simulation tools. Nonconventional methods such as reduced order models, boundary integral approaches and spectral methods are presented, which might be considered in the next generation of building-energy-simulation tools. In this reviewed edition, an innovative way to simulate energy and hydrothermal performance are presented, bringing some light on innovative approaches in the field.
'The four laws that do not drive the universe: elements of thermodynamics for the curious and intelligent. The second purpose of Ben-NaimaEURO (TM)s book is to explain thermodynamics and show its relationship to information theory. This explanation makes the present book worth reading in its own right. Ben-NaimaEURO (TM)s discussion of the information basis of the second law is lucid and well worth reading.'CHOICEThis book provides a clear and mystery-free presentation of the central concepts in thermodynamics - probability, entropy, Helmholtz energy and Gibbs energy. It presents the concepts of entropy, free energy and various formulations of the Second Law in a friendly, simple language. It is devoid of all kinds of fancy and pompous statements made by authors of popular science books who write on this subject.The book focuses on the Four Laws of Thermodynamics. As it is said in the dedication page, this book is addressed to readers who might have already been exposed to Atkins' book having a similar title. It challenges both the title, and the contents of Atkins' book, Four Laws That Drive The Universe. One can glean from the title of this new book that the author's views are diametrically opposed to the views of Atkins.The book is addressed to any curious and intelligent reader. It aims to tickle, and hopefully to satisfy your curiosity. It also aims to challenge your gray matter, and to enrich your knowledge by telling you some facts and ideas regarding the Four Laws of Thermodynamics.
Die Neuauflage halt am bewahrten und anerkannten Konzept der Vorauflage fest: ein Grundlagenwerk zum Einsatz in der universitaren Lehre, aber vor allem ein Nachschlagewerk fur den Beruf zum tieferen Verstandnis der verfahrenstechnischen Zusammenhange. Gegenuber der Vorauflage wurde das Werk allerdings erheblich erweitert sowie durch aktuelle Forschungsergebnisse und ein Kapitel zur konzeptuellen Prozessentwicklung erganzt. Die Grundverfahren werden auf der Basis der Thermodynamik, der Warme- und Stoffubertragung und der Fluiddynamik ubergreifend dargestellt. Damit erhalt der Praktiker erste Informationen uber die Auswahl, die Auslegung und den Betrieb von Apparaten. Nach einer komprimierten Darstellung wichtiger Grundlagen werden u.a. das Destillieren, die Rektifikation, die Absorption, die Kristallisation und die Adsorption behandelt. Es wird aufgezeigt, wie sich grundlagenorientierte Berechnungsansatze fur fluiddynamische und kinetische Vorgange in bekannten und neuen Apparaten finden lassen."
Because classical thermodynamics evolved into many branches of science and engineering, most undergraduate courses on the subject are taught from the perspective of each area of specialization. General Thermodynamics combines elements from mechanical and chemical engineering, chemistry (including electrochemistry), materials science, and biology to present a unique and thorough treatment of thermodynamics that is broader in scope than other fundamental texts. This book contains classroom-tested materials designed to meet the academic requirements for students from a variety of scientific and engineering backgrounds in a single course. The first half focuses on classical concepts of thermodynamics, whereas the latter half explores field-specific applications, including a unique chapter on biothermodynamics. The book's methodology is unified, concise, and multidisciplinary, allowing students to understand how the principles of thermodynamics apply to all technical fields that touch upon this most fundamental of scientific theories. It also offers a rigorous approach to the quantitative aspects of thermodynamics, accompanied by clear explanations to help students transition smoothly from the physical concepts to their mathematical representations. Each chapter contains numerous worked examples taken from different engineering applications, illustrations, and an extensive set of exercises to support the material. A complete solutions manual is available to professors with qualifying course adoptions. |
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