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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
This book addresses the application of methods used in statistical physics to complex systems-from simple phenomenological analogies to more complex aspects, such as correlations, fluctuation-dissipation theorem, the concept of free energy, renormalization group approach and scaling. Statistical physics contains a well-developed formalism that describes phase transitions. It is useful to apply this formalism for damage phenomena as well. Fractals, the Ising model, percolation, damage mechanics, fluctuations, free energy formalism, renormalization group, and scaling, are some of the topics covered in Statistical Physics of Phase Transitions.
This book systematically interprets and documents new, unifying principles and basic laws describing the most relevant aspects of hierarchy. To do so, it discusses recent experiments and models that are simple and realistic enough to reproduce the observations, and develops concepts for a better understanding of the complexity of systems consisting of many organisms. The book covers systems ranging from flocks of birds to groups of people. Although it focuses on hierarchical collective behavior in general, two aspects pop up in the majority of cases: collective motion and dynamically changing, partially directed networks (and the natural relation between the two). In addition, it offers a brief description of the most relevant definitions and concepts involved in the context of hierarchies, presenting both a review of the current literature and a number of new experimental and computational results in more detail. It is a valuable resource for students and scholars pursuing research on the structure of interactions within the collectives of animals and humans.
This book presents a solution for direct and inverse heat conduction problems, discussing the theoretical basis for the heat transfer process and presenting selected theoretical and numerical problems in the form of exercises with solutions. The book covers one-, two- and three dimensional problems which are solved by using exact and approximate analytical methods and numerical methods. An accompanying CD-Rom includes computational solutions of the examples and extensive FORTRAN code.
The book provides a systematic view on flammability and a collection of solved engineering problems in the fields of dilution and purge, mine gas safety, clean burning safety and gas suppression modeling. For the first time, fundamental principles of energy conservation are used to develop theoretical flammability diagrams and are then explored to understand various safety-related mixing problems. This provides the basis for a fully-analytical solution to any flammability problem. Instead of the traditional view that flammability is a fundamental material property, here flammability is discovered to be a result of the explosibility of air and the ignitability of fuel, or a process property. By exploring the more fundamental concepts of explosibility and ignitability, the safety targets of dilution and purge can be better defined and utilized for guiding safe operations in process safety. This book provides various engineering approaches to mixture flammability, benefiting not only the safety students, but also field operators, as a useful resource for the safe handling of flammable gases and liquids. It will be useful to anyone who worries about the ignition potential of a flammable mixture.
This book is a short, but complete, introduction to the Loewner equation and the SLEs, which are a family of random fractal curves, as well as the relevant background in probability and complex analysis. The connection to statistical physics is also developed in the text in an example case. The book is based on a course (with the same title) lectured by the author. First three chapters are devoted to the background material, but at the same time, give the reader a good understanding on the overview on the subject and on some aspects of conformal invariance. The chapter on the Loewner equation develops in detail the connection of growing hulls and the differential equation satisfied by families of conformal maps. The Schramm-Loewner evolutions are defined and their basic properties are studied in the following chapter, and the regularity properties of random curves as well as scaling limits of discrete random curves are investigated in the final chapter. The book is aimed at graduate students or researchers who want to learn the subject fairly quickly.
This book presents an introduction to Evolutionary Game Theory (EGT) which is an emerging field in the area of complex systems attracting the attention of researchers from disparate scientific communities. EGT allows one to represent and study several complex phenomena, such as the emergence of cooperation in social systems, the role of conformity in shaping the equilibrium of a population, and the dynamics in biological and ecological systems.Since EGT models belong to the area of complex systems, statistical physics constitutes a fundamental ingredient for investigating their behavior. At the same time, the complexity of some EGT models, such as those realized by means of agent-based methods, often require the implementation of numerical simulations. Therefore, beyond providing an introduction to EGT, this book gives a brief overview of the main statistical physics tools (such as phase transitions and the Ising model) and computational strategies for simulating evolutionary games (such as Monte Carlo algorithms on lattices). This book will appeal to students and researchers in this burgeoning field of complex systems.
This book explores the working principles of all kinds of turbomachines. The same theoretical framework is used to analyse the different machine types. Fundamentals are first presented and theoretical concepts are then elaborated for particular machine types, starting with the simplest ones.For each machine type, the author strikes a balance between building basic understanding and exploring knowledge of practical aspects. Readers are invited through challenging exercises to consider how the theory applies to particular cases and how it can be generalised. The book is primarily meant as a course book. It teaches fundamentals and explores applications. It will appeal to senior undergraduate and graduate students in mechanical engineering and to professional engineers seeking to understand the operation of turbomachines. Readers will gain a fundamental understanding of turbomachines. They will also be able to make a reasoned choice of turbomachine for a particular application and to understand its operation. Basic design of the simplest turbomachines as a centrifugal fan, an axial steam turbine or a centrifugal pump, is also possible using the topics covered in the book.
This work addresses the gap in the current collective action literature exposed by the new Information and Communication Technologies (ICTs) landscape by bringing together qualitative and quantitative studies from computational and social sciences. The book offers a rigorous and systematic investigation of both methodological and theoretical underpinnings and, thus, collectively promotes a symbiotic and synergistic advancement of the multiple interconnected disciplines in studying online collective actions. More specifically, the book is intended to illuminate several fundamental and powerful yet theoretically undeveloped and largely unexplored aspects of collective action in the participatory media (e.g., social media). Through in-depth exploration of relevant concepts, theories, methodologies, applications, and case studies, the reader will gain an advanced understanding of collective action with the advent of the new generation of ICTs enabled by social media and the Internet. The developed theories will be valuable and comprehensive references for those interested in examining the role of ICTs not only in collective action but also in decision and policy making, understanding the dynamics of interaction, collaboration, cooperation, communication, as well as information flow and propagation, and social network research for years to come. Further, the book also serves as an extensive repository of data sets and tools that can be used by researchers leading to a deeper and more fundamental understanding of the dynamics of the crowd in online collective actions.
Fifty years ago, enthused by successes in creating digital computers and the DNA model of heredity, scientists were con?dent that solutions to the problems of und- standing biological intelligence and creating machine intelligence were within their grasp. Progress at ?rst seemed rapid. Giant 'brains' that ?lled air-conditioned rooms were shrunk into briefcases. The speed of computation doubled every two years. What these advances revealed is not the solutions but the dif?culties of the pr- lems. We are like the geographers who 'discovered' America, not as a collection of islands but as continents seen only at shores and demanding exploration. We are astounded less by the magnitude of our discoveries about how brains cogitate than by the enormity of the tasks we have undertaken, to explain and replicate the higher functions of brains. Five decades of brain research have led to the emergence of a new ?eld, which spans the entire range of brain cognition from quantum ?elds to social interactions, and which is combined by the conceptions of nonlinear neurodynamics operating simultaneously at and across all levels. A new breed of scientists has emerged, schooled in multiple academic disciplines, comfortable in working with data from different levels, and conversant with the mathematical tools that are essential to cross boundaries.
The model investigated in this work, a particular cellular automaton with stochastic evolution, was introduced as the simplest case of self-organized-criticality, that is, a dynamical system which shows algebraic long-range correlations without any tuning of parameters. The author derives exact results which are potentially also interesting outside the area of critical phenomena. Exact means also site-by-site and not only ensemble average or coarse graining. Very complex and amazingly beautiful periodic patterns are often generated by the dynamics involved, especially in deterministic protocols in which the sand is added at chosen sites. For example, the author studies the appearance of allometric structures, that is, patterns which grow in the same way in their whole body, and not only near their boundaries, as commonly occurs. The local conservation laws which govern the evolution of these patterns are also presented. This work has already attracted interest, not only in non-equilibrium statistical mechanics, but also in mathematics, both in probability and in combinatorics. There are also interesting connections with number theory. Lastly, it also poses new questions about an old subject. As such, it will be of interest to computer practitioners, demonstrating the simplicity with which charming patterns can be obtained, as well as to researchers working in many other areas.
In this book basic and some more advanced thermodynamics and phase as well as stability diagrams relevant for diffusion studies are introduced. Following, Fick's laws of diffusion, atomic mechanisms, interdiffusion, intrinsic diffusion, tracer diffusion and the Kirkendall effect are discussed. Short circuit diffusion is explained in detail with an emphasis on grain boundary diffusion. Recent advances in the area of interdiffusion will be introduced. Interdiffusion in multi-component systems is also explained. Many practical examples will be given, such that researches working in this area can learn the practical evaluation of various diffusion parameters from experimental results. Large number of illustrations and experimental results are used to explain the subject. This book will be appealing for students, academicians, engineers and researchers in academic institutions, industry research and development laboratories.
This book presents the theory of gas discharge plasmas in a didactical way. It explains the processes in gas discharge plasmas. A gas discharge plasma is an ionized gas which is supported by an external electric field. Therefore its parameters are determined by processes in it. The properties of a gas discharge plasma depend on its gas component, types of external fields, their geometry and regimes of gas discharge. Fundamentals of a gas discharge plasma include elementary, radiative and transport processes which are included in its kinetics influence. They are represented in this book together with the analysis of simple gas discharges. These general principles are applied to stationary gas discharge plasmas of helium and argon. The analysis of such plasmas under certain conditions is theoretically determined by numerical plasma parameters for given regimes and conditions.
This book extends the development of the thermodynamic theory of specific intermolecular interactions to element-organic and specific organometallic compounds. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated, based on a concept of pentacoordinate carbon atoms. Prof. Baev has introduced the theory already in his successful books "Specific Intermolecular Interactions of Organic Compounds" and "Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds". In this book he also demonstrates it for element organic and specific organometallic compounds, a class of substances which is of great importance in synthetic chemistry and catalysis. Furthermore, organic compound classes, that have not been treated in the previous books, are included. New types of hydrogen bonds and specific interactions are substantiated and their energies are determined on the basis of the developed methodology. In this way, the influence of the molecular structure on the energy and on intermolecular interactions can be discussed for these particular compound classes.
This textbook offers an advanced undergraduate or initial graduate level introduction to topics such as kinetic theory, equilibrium statistical mechanics and the theory of fluctuations from a modern perspective. The aim is to provide the reader with the necessary tools of probability theory and thermodynamics (especially the thermodynamic potentials) to enable subsequent study at advanced graduate level. At the same time, the book offers a bird's eye view on arguments that are often disregarded in the main curriculum courses. Further features include a focus on the interdisciplinary nature of the subject and in-depth discussion of alternative interpretations of the concept of entropy. While some familiarity with basic concepts of thermodynamics and probability theory is assumed, this does not extend beyond what is commonly obtained in basic undergraduate curriculum courses.
Physics on Your Feet (2nd Edition) is a significantly expanded collection of physics problems covering the broad range of topics in classical and modern physics that were, or could have been, asked at oral PhD exams at University of California at Berkeley. The questions are easy to formulate, but some of them can only be answered using an outside-of-the box approach. Detailed solutions are provided, from which the reader is guaranteed to learn a lot about the physicists' way of thinking. The book is also packed full of cartoons and dry humor to help take the edge off the stress and anxiety surrounding exams. This is a helpful guide for students preparing for their exams, as well as a resource for university lecturers looking for good instructive problems. No exams are necessary to enjoy the book!
The study of nonlinear localized excitations is a long-standing challenge for research in basic and applied science, as well as engineering, due to their importance in understanding and predicting phenomena arising in nonlinear and complex systems, but also due to their potential for the development and design of novel applications. This volume is a compilation of chapters representing the current state-of-the-art on the field of localized excitations and their role in the dynamics of complex physical systems.
This dissertation focuses on the calculation of transport coefficients in the matter created in a relativistic heavy-ion collision after chemical freeze-out. This matter can be well approximated using a pion gas out of equilibrium. We describe the theoretical framework needed to obtain the shear and bulk viscosities, the thermal and electrical conductivities and the flavor diffusion coefficients of a meson gas at low temperatures. To describe the interactions of the degrees of freedom, we use effective field theories with chiral and heavy quark symmetries. We subsequently introduce the unitarization methods in order to obtain a scattering amplitude that satisfies the unitarity condition exactly, then go on to calculate the transport properties of the low-temperature phase of quantum chromodynamics - the hadronic medium - which can be used in hydrodynamic simulations of a relativistic heavy-ion collision and its subsequent evolution. We show that the shear viscosity over entropy density exhibits a minimum in a phase transition by studying this coefficient in atomic Argon (around the liquid-gas phase transition) and in the linear sigma model in the limit of a large number of scalar fields (which presents a chiral phase transition). Finally, we provide an experimental method for estimating the bulk viscosity in relativistic heavy-ion collisions by performing correlations of the fluctuating components of the stress-energy tensor.
Making Flory-Huggins Practical: Thermodynamics of
Polymer-Containing Mixtures, by B. A. Wolf
This book focuses on the assembly, organization and resultant collective dynamics of soft matter systems maintained away from equilibrium by an energy flux. Living matter is the ultimate example of such systems, which are comprised of different constituents on very different scales (ions, nucleic acids, proteins, cells). The result of their diverse interactions, maintained using the energy from physiological processes, is a fantastically well-organized and dynamic whole. This work describes results from minimal, biomimetic systems and primarily investigates membranes and active emulsions, as well as key aspects of both soft matter and non-equilibrium phenomena. It is shown that these minimal reconstitutions are already capable of a range of complex behaviour such as nonlinear electric responses, chemical communication and locomotion. These studies will bring us closer to a fundamental understanding of complex systems by reconstituting key aspects of their form and function in simple model systems. Further, they may also serve as the first technological steps towards artificial soft functional matter.
In this volume a theory for models of transport in the presence of a free boundary is developed.Macroscopic laws of transport are described by PDE's. When the system is open, there are several mechanisms to couple the system with the external forces. Here a class of systems where the interaction with the exterior takes place in correspondence of a free boundary is considered. Both continuous and discrete models sharing the same structure are analysed. In Part I a free boundary problem related to the Stefan Problem is worked out in all details. For this model a new notion of relaxed solution is proposed for which global existence and uniqueness is proven. It is also shown that this is the hydrodynamic limit of the empirical mass density of the associated particle system. In Part II several other models are discussed. The expectation is that the results proved for the basic model extend to these other cases.All the models discussed in this volume have an interest in problems arising in several research fields such as heat conduction, queuing theory, propagation of fire, interface dynamics, population dynamics, evolution of biological systems with selection mechanisms.In general researchers interested in the relations between PDE's and stochastic processes can find in this volume an extension of this correspondence to modern mathematical physics.
In this monograph Prof. Pramanick explicates the law of motive force, a fundamental law of nature that can be observed and appreciated as an addition to the existing laws of thermodynamics. This unmistakable and remarkable tendency of nature is equally applicable to all other branches of studies. He first conceptualized the law of motive force in 1989, when he was an undergraduate student. Here he reports various applications of the law in the area of thermodynamics, heat transfer, fluid mechanics and solid mechanics, and shows how it is possible to solve analytically century-old unsolved problems through its application. This book offers a comprehensive account of the law and its relation to other laws and principles, such as the generalized conservation principle, variational formulation, Fermat's principle, Bejan's constructal law, entropy generation minimization, Bejan's method of intersecting asymptotes and equipartition principle. Furthermore, the author addresses some interrelated fundamental problems of contemporary interest, especially to thermodynamicists, by combining analytical methods, physical reasoning and the proposed law of motive force. This foundational work is a valuable reading for both students and researchers in exact as well as non-exact sciences and, at the same time, a pleasant learning experience for the novice.
While we all live our lives in designed landscapes of various types, only on occasion do we consider what these landscapes mean to us and how they have acquired that significance. Can a landscape architect or garden designer really imbue new settings with meaning, or does meaning evolve over time, created by those who perceive and use these landscapes? What role does the selection and arrangement of plants and hard materials play in this process and just where does the passage of time enter into the equation? These questions collectively provide the core material for Meaning in Landscape Architecture and Gardens, a compendium of four landmark essays written over a period of twenty years by leading scholars in the field of landscape architecture. New commentaries by the authors accompany each of the essays and reflect on the thinking behind them as well as the evolution of the author s thoughts since their original publication. Although the central theme of these writings is landscape architecture broadly taken, the principal subject of several essays and commentaries is the garden, a subject historically plentiful in allusions and metaphors. As a whole Meaning in Landscape Architecture and Gardens offers the general reader as well as the professional a rich source of ideas about the designed landscape and the ways by which we perceive, consider, react, and dwell within them and what they mean to us. The essays have been perennial favorites in landscape courses since their original publication in Landscape Journal. Bringing them together bolstered by the new commentaries creates a book valuable to all those creating gardens and landscapes, as well as those teaching and studying these subjects.
This brief discusses the mechanism of functional expression of a protein or protein complex utilizing the ATP hydrolysis cycle or proton-motive force from a unique point of view focused on the roles of water. A variety of processes are considered such as the unidirectional movement of a linear-motor protein along a filament, insertion of an unfolded protein into a chaperonin and release of the folded protein from it, transport of diverse substrates across the membrane by a transporter, and directed rotation of the central subunit within a rotatory motor protein complex. These topics are discussed in a unified manner within the same theoretical framework. The author argues that water plays imperative roles in the functional expression of these molecular machines. A pivotal factor is the entropic force or potential originating from the translational displacement of water molecules coexisting with the molecular machines in the entire system.
The study of thermodynamics is often limited to classical thermodynamics where minimal laws and concepts lead to a wealth of equations and applications. The resultant equations best describe systems at equilibrium with no temporal or s- tial parameters. The equations do, however, often provide accurate descriptions for systems close to equilibrium. . Statistical thermodynamics produces the same equilibrium information starting with the microscopic properties of the atoms or molecules in the system that correlates with the results from macroscopic classical thermodynamics. Because both these disciplines develop a wealth of information from a few starting postulates, e. g. , the laws of thermodyamics, they are often introduced as independent disciplines. However, the concepts and techniques dev- oped for these disciplines are extremely useful in many other disciplines. This book is intended to provide an introduction to these disciplines while revealing the connections between them. Chemical kinetics uses the statistics and probabilities developed for statistical thermodynamics to explain the evolution of a system to equilibrium. Irreversible thermodynamics, which is developed from the equations of classical thermodyn- ics, centers on distance-dependent forces, and time-dependent ?uxes. The force ?ux equations of irreversible thermodynamics lead are generated from the intensive and extensive variables of classical thermodynamics. These force ?ux equations lead, in turn, to transport equations such as Fick's ?rst law of diffusion and the Nernst Planck equation for electrochemical transport. The book illustrates the concepts using some simple examples.
Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for students in chemical engineering and the chemical sciences. |
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