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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
This textbook is for undergraduate students on a basic course in Statistical Mechanics. The prerequisite is thermodynamics. It begins with a study of three situations -- the closed system and the systems in thermal contact with a reservoir -- in order to formulate the important fundamentals: entropy from Boltzmann formula, partition function and grand partition function. Through the presentation of quantum statistics, Bose statistics and Fermi-Dirac statistics are established, including as a special case the classical situation of Maxell-Boltzmann statistics. A series of examples ensue it: the harmonic oscillator, the polymer chain, the two level system, bosons (photons, phonons, and the Bose-Einstein condensation) and fermions (electrons in metals and in semiconductors). A compact historical note on influential scientists forms the concluding chapter. The unique presentation starts off with the principles, elucidating the well-developed theory, and only thereafter the application of theory. Calculations on the main steps are detailed, leaving behind minimal gap. The author emphasizes with theory the link between the macroscopic world (thermodynamics) and the microscopic world.
This book describes, by using elementary techniques, how some geometrical structures widely used today in many areas of physics, like symplectic, Poisson, Lagrangian, Hermitian, etc., emerge from dynamics. It is assumed that what can be accessed in actual experiences when studying a given system is just its dynamical behavior that is described by using a family of variables ("observables" of the system). The book departs from the principle that ''dynamics is first'' and then tries to answer in what sense the sole dynamics determines the geometrical structures that have proved so useful to describe the dynamics in so many important instances. In this vein it is shown that most of the geometrical structures that are used in the standard presentations of classical dynamics (Jacobi, Poisson, symplectic, Hamiltonian, Lagrangian) are determined, though in general not uniquely, by the dynamics alone. The same program is accomplished for the geometrical structures relevant to describe quantum dynamics. Finally, it is shown that further properties that allow the explicit description of the dynamics of certain dynamical systems, like integrability and super integrability, are deeply related to the previous development and will be covered in the last part of the book. The mathematical framework used to present the previous program is kept to an elementary level throughout the text, indicating where more advanced notions will be needed to proceed further. A family of relevant examples is discussed at length and the necessary ideas from geometry are elaborated along the text. However no effort is made to present an ''all-inclusive'' introduction to differential geometry as many other books already exist on the market doing exactly that. However, the development of the previous program, considered as the posing and solution of a generalized inverse problem for geometry, leads to new ways of thinking and relating some of the most conspicuous geometrical structures appearing in Mathematical and Theoretical Physics.
This is a masters/graduate level textbook on statistical physics. The basics of the discipline and its application in the current topics of interest like BoseEinstein condensate, statistical astrophysics and phase transitions have been discussed with thoroughness. This is a systematic introduction and development of a course material tried successful over a number of years. Feedback from the students tells that it has immensely helped them in their later research.
This is the first comprehensive monograph on a new thermodynamic theory that goes beyond the classical theory of irreversible processes. In contrast to the classical approach, the local equilibrium hypothesis is abandoned, and the basic variables are complemented by non-equilibrium quantities. The claims made for extended thermodynamics are confirmed by the kinetic theory of gases and statistical mechanics. The book covers a wide spectrum of applications, and also contains a wide discussion of the foundations and the scope of the most current theories of non-equilibrium thermodynamics. The present edition reflects new developments in the theory of applications, adds new problems and provides a more detailed comparison with other fields of active research. It contains 130 proposed problems, whose detailed solutions, as well as wide bibliography on extended irreversible thermodynamics and related topices, may be unloaded from the www.uab.es/dep-fisica/eit website.
This practical introduction to the analysis of data collected from reliability studies offers clear, detailed explanations of the best and most up-to-date techniques available. Topics include survival analysis with covariates, the assessment of systems performance, reliability growth models, dependency (which encompasses both engineering and statistical approaches), and practical aspects of analysis. A wealth of interesting case studies appear throughout the text, lending "real-world" examples to the more theoretical discussions. Throughout, the authors stress the need for investigators to understand the background and nature of their data if they are to select the most appropriate analysis method. They also provide in-depth treatments of the mathematical and statistical bases underlying each technique. Accessible and comprehensive, the book will be welcomed by students, professionals, and statisticians who are interested in the practical aspects of reliability data analysis.
How can one construct dynamical systems obeying the first and second laws of thermodynamics: mean energy is conserved and entropy increases with time? This book answers the question for classical probability (Part I) and quantum probability (Part II). A novel feature is the introduction of heat particles which supply thermal noise and represent the kinetic energy of the molecules. When applied to chemical reactions, the theory leads to the usual nonlinear reaction-diffusion equations as well as modifications of them. These can exhibit oscillations, or can converge to equilibrium. In this second edition, the text is simplified in parts and the bibliography has been expanded. The main difference is the addition of two new chapters; in the first, classical fluid dynamics is introduced. A lattice model is developed, which in the continuum limit gives us the Euler equations. The five Navier???Stokes equations are also presented, modified by a diffusion term in the continuity equation. The second addition is in the last chapter, which now includes estimation theory, both classical and quantum, using information geometry.
How can one construct dynamical systems obeying the first and second laws of thermodynamics: mean energy is conserved and entropy increases with time? This book answers the question for classical probability (Part I) and quantum probability (Part II). A novel feature is the introduction of heat particles which supply thermal noise and represent the kinetic energy of the molecules. When applied to chemical reactions, the theory leads to the usual nonlinear reaction-diffusion equations as well as modifications of them. These can exhibit oscillations, or can converge to equilibrium. In this second edition, the text is simplified in parts and the bibliography has been expanded. The main difference is the addition of two new chapters; in the first, classical fluid dynamics is introduced. A lattice model is developed, which in the continuum limit gives us the Euler equations. The five Navier???Stokes equations are also presented, modified by a diffusion term in the continuity equation. The second addition is in the last chapter, which now includes estimation theory, both classical and quantum, using information geometry.
Instantons, or pseudoparticles, are solutions to the equations of motion in classical field theories on a Euclidean spacetime. Instantons are found everywhere in quantum theories as they have many applications in quantum tunnelling. Diverse physical phenomena may be described through quantum tunnelling, for example: the Josephson effect, the decay of meta-stable nuclear states, band formation in tight binding models of crystalline solids, the structure of the gauge theory vacuum, confinement in 2+1 dimensions, and the decay of superheated or supercooled phases. Drawing inspiration from Sidney Coleman's Erice lectures, this volume provides an accessible, detailed introduction to instanton methods, with many applications, making it a valuable resource for graduate students in many areas of physics, from condensed matter, particle and nuclear physics, to string theory. This title, first published in 2017, has been reissued as an Open Access publication on Cambridge Core.
Thermal and statistical physics has established the principles and procedures needed to understand and explain the properties of systems consisting of macroscopically large numbers of particles. By developing microscopic statistical physics and macroscopic classical thermodynamic descriptions in tandem, Statistical and Thermal Physics: An Introduction provides insight into basic concepts and relationships at an advanced undergraduate level. This second edition is updated throughout, providing a highly detailed, profoundly thorough, and comprehensive introduction to the subject and features exercises within the text as well as end-of-chapter problems. Part I of this book consists of nine chapters, the first three of which deal with the basics of equilibrium thermodynamics, including the fundamental relation. The following three chapters introduce microstates and lead to the Boltzmann definition of the entropy using the microcanonical ensemble approach. In developing the subject, the ideal gas and the ideal spin system are introduced as models for discussion. The laws of thermodynamics are compactly stated. The final three chapters in Part I introduce the thermodynamic potentials and the Maxwell relations. Applications of thermodynamics to gases, condensed matter, and phase transitions and critical phenomena are dealt with in detail. Initial chapters in Part II present the elements of probability theory and establish the thermodynamic equivalence of the three statistical ensembles that are used in determining probabilities. The canonical and the grand canonical distributions are obtained and discussed. Chapters 12-15 are concerned with quantum distributions. By making use of the grand canonical distribution, the Fermi-Dirac and Bose-Einstein quantum distribution functions are derived and then used to explain the properties of ideal Fermi and Bose gases. The Planck distribution is introduced and applied to photons in radiation and to phonons on solids. The last five chapters cover a variety of topics: the ideal gas revisited, nonideal systems, the density matrix, reactions, and irreversible thermodynamics. A flowchart is provided to assist instructors on planning a course. Key Features: Fully updated throughout, with new content on exciting topics, including black hole thermodynamics, Heisenberg antiferromagnetic chains, entropy and information theory, renewable and nonrenewable energy sources, and the mean field theory of antiferromagnetic systems Additional problem exercises with solutions provide further learning opportunities Suitable for advanced undergraduate students in physics or applied physics. Michael J.R. Hoch spent many years as a visiting scientist at the National High Magnetic Field Laboratory at Florida State University, USA. Prior to this, he was a professor of physics and the director of the Condensed Matter Physics Research Unit at the University of the Witwatersrand, Johannesburg, where he is currently professor emeritus in the School of Physics.
In this unique book, the reader is invited to experience the joy of appreciating something which has eluded understanding for many years - entropy and the Second Law of Thermodynamics. The book has a two-pronged message: first, that the second law is not infinitely incomprehensible as commonly stated in most textbooks on thermodynamics, but can, in fact, be comprehended through sheer common sense; and second, that entropy is not a mysterious quantity that has resisted understanding but a simple, familiar and easily comprehensible concept.Written in an accessible style, the book guides the reader through an abundance of dice games and examples from everyday life. The author paves the way for readers to discover for themselves what entropy is, how it changes, and, most importantly, why it always changes in one direction in a spontaneous process.In this new edition, seven simulated games are included so that the reader can actually experiment with the games described in the book. These simulated games are meant to enhance the readers' understanding and sense of joy upon discovering the Second Law of Thermodynamics.
This book explores applications of computational intelligence in key and emerging fields of engineering, especially with regard to condition monitoring and fault diagnosis, inverse problems, decision support systems and optimization. These applications can be beneficial in a broad range of contexts, including: water distribution networks, manufacturing systems, production and storage of electrical energy, heat transfer, acoustic levitation, uncertainty and robustness of infinite-dimensional objects, fatigue failure prediction, autonomous navigation, nanotechnology, and the analysis of technological development indexes. All applications, mathematical and computational tools, and original results are presented using rigorous mathematical procedures. Further, the book gathers contributions by respected experts from 22 different research centers and eight countries: Brazil, Cuba, France, Hungary, India, Japan, Romania and Spain. The book is intended for use in graduate courses on applied computation, applied mathematics, and engineering, where tools like computational intelligence and numerical methods are applied to the solution of real-world problems in emerging areas of engineering.
Statistical Mechanics: Fundamentals and Model Solutions, Second Edition Fully updated throughout and with new chapters on the Mayer expansion for classical gases and on cluster expansion for lattice models, this new edition of Statistical Mechanics: Fundamentals and Model Solutions provides a comprehensive introduction to equilibrium statistical mechanics for advanced undergraduate and graduate students of mathematics and physics. The author presents a fresh approach to the subject, setting out the basic assumptions clearly and emphasizing the importance of the thermodynamic limit and the role of convexity. With problems and solutions, the book clearly explains the role of models for physical systems, and discusses and solves various models. An understanding of these models is of increasing importance as they have proved to have applications in many areas of mathematics and physics. Features Updated throughout with new content from the field An established and well-loved textbook Contains new problems and solutions for further learning opportunity Author Professor Teunis C. Dorlas is at the Dublin Institute for Advanced Studies, Ireland.
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term "entropy" with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the "driving force" of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term "entropy"; almost 50 years since Shannon developed the mathematical theory of "information" - subsequently renamed "entropy". In this book, the author advocates replacing "entropy" by "information", a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term "entropy".The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the "driving force" for which is analyzed in terms of information.
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term "entropy" with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the "driving force" of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term "entropy"; almost 50 years since Shannon developed the mathematical theory of "information" - subsequently renamed "entropy". In this book, the author advocates replacing "entropy" by "information", a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term "entropy".The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the "driving force" for which is analyzed in terms of information.
In this unique book, Arieh Ben-Naim invites the reader to experience the joy of appreciating something which has eluded understanding for many years -- entropy and the Second Law of Thermodynamics. The book has a two-pronged message: first, that the Second Law is not "infinitely incomprehensible" as commonly stated in textbooks of thermodynamics but can, in fact, be comprehended through sheer common sense; and second, that entropy is not a mysterious quantity that has "resisted understanding" but a simple, familiar and easily comprehensible concept. Written in an accessible style, the book guides the reader through an abundance of dice games and examples from everyday life. The author paves the way for readers to discover for themselves what entropy is, how it changes, and most importantly, why it always changes in one direction in a spontaneous process.
This book provides a solid foundation in the principles of heat and mass transfer and shows how to solve problems by applying modern methods. The basic theory is developed systematically, exploring in detail the solution methods to all important problems. The revised second edition incorporates state-of-the-art findings on heat and mass transfer correlations. The book will be useful not only to upper- and graduate-level students, but also to practicing scientists and engineers. Many worked-out examples and numerous exercises with their solutions will facilitate learning and understanding, and an appendix includes data on key properties of important substances.
This book offers an easy to read, all-embracing history of thermodynamics. It describes the long development of thermodynamics, from the misunderstood and misinterpreted to the conceptually simple and extremely useful theory that we know today. Coverage identifies not only the famous physicists who developed the field, but also engineers and scientists from other disciplines who helped in the development and spread of thermodynamics as well.
This book is an introductory text on fundamental aspects of combustion including thermodynamics, heat and mass transfer and chemical kinetics which are used to systematically derive the basic concepts of combustion. Apart from the fundamental aspects, many of the emerging topics in the field like microscale combustion, combustion dynamics, oxy-fuel combustion and combustion diagnostics are also covered in the book. This would help the beginners in the subject to get initiated to the state of the art topics. Key Features: Coverage of the essential aspects of combustion engineering suitable for both beginners and practicing professionals Topics like entropy generation, microscale combustion, combustion diagnostics, second law-based analysis exclusive to the title Balanced treatment of thermodynamics, transport phenomena and chemical kinetics Discussion on state of the art techniques in combustion diagnostics Illustrates combustion of gaseous, liquid and solid fuels along with emission of pollutants and greenhouse gases
This third edition of one of the most important and best selling textbooks in statistical physics, is a graduate level text suitable for students in physics, chemistry, and materials science.The discussion of strongly interacting condensed matter systems has been expanded. A chapter on stochastic processes has also been added with emphasis on applications of the Fokker-Planck equation.The modern theory of phase transitions occupies a central place. The chapter devoted to the renormalization group approach is largely rewritten and includes a detailed discussion of the basic concepts and examples of both exact and approximate calculations. The development of the basic tools includes a chapter on computer simulations in which both Monte Carlo method and molecular dynamics are introduced, and a section on Brownian dynamics added.The theories are applied to a number of important systems such as liquids, liquid crystals, polymers, membranes, Bose condensation, superfluidity and superconductivity. There is also an extensive treatment of interacting Fermi and Bose systems, percolation theory and disordered systems in general.
This third edition of one of the most important and best selling textbooks in statistical physics, is a graduate level text suitable for students in physics, chemistry, and materials science.The discussion of strongly interacting condensed matter systems has been expanded. A chapter on stochastic processes has also been added with emphasis on applications of the Fokker-Planck equation.The modern theory of phase transitions occupies a central place. The chapter devoted to the renormalization group approach is largely rewritten and includes a detailed discussion of the basic concepts and examples of both exact and approximate calculations. The development of the basic tools includes a chapter on computer simulations in which both Monte Carlo method and molecular dynamics are introduced, and a section on Brownian dynamics added.The theories are applied to a number of important systems such as liquids, liquid crystals, polymers, membranes, Bose condensation, superfluidity and superconductivity. There is also an extensive treatment of interacting Fermi and Bose systems, percolation theory and disordered systems in general.
Chemical Thermodynamics for Industry presents the latest developments in applied thermodynamics and highlights the role of thermodynamics in the chemical industry. Written by leading experts in the field, Chemical Thermodynamics for Industry covers the latest developments in traditional areas such as calorimetry, microcalorimetry, transport properties, crystallization, adsorption, electrolyte systems and transport fuels, It highlights newly established areas such as multiphase modeling, reactive distillation, non-equilibrium thermodynamics and spectro-calorimetry. It also explores new ways of treating old technologies as well as new and potentially important areas such as ionic liquids, new materials, ab-initia quantum chemistry, nano-particles, polymer recycling, clathrates and the economic value of applied thermodynamics. This book is aimed not only at those working in a specific area of chemical thermodynamics but also at the general chemist, the prospective researcher and those involved in funding chemical research.
This textbook concerns thermal properties of bulk matter and is aimed at advanced undergraduate or first-year graduate students in a range of programs in science or engineering. It provides an intermediate level presentation of statistical thermodynamics for students in the physical sciences (chemistry, nanosciences, physics) or related areas of applied science/engineering (chemical engineering, materials science, nanotechnology engineering), as they are areas in which statistical mechanical concepts play important roles. The book enables students to utilize microscopic concepts to achieve a better understanding of macroscopic phenomena and to be able to apply these concepts to the types of sub-macroscopic systems encountered in areas of nanoscience and nanotechnology.
This thesis explores several interdisciplinary topics at the border of theoretical physics and biology, presenting results that demonstrate the power of methods from statistical physics when applied to neighbouring disciplines. From birth-death processes in switching environments to discussions on the meaning of quasi-potential landscapes in high-dimensional spaces, this thesis is a shining example of the efficacy of interdisciplinary research. The fields advanced in this work include game theory, the dynamics of cancer, and invasion of mutants in resident populations, as well as general contributions to the theory of stochastic processes. The background material provides an intuitive introduction to the theory and applications of stochastic population dynamics, and the use of techniques from statistical physics in their analysis. The thesis then builds on these foundations to address problems motivated by biological phenomena.
The utilization of refrigeration and cryogenics contributes to high-quality preservation and processing of foods, in environmental protection, and in case of emergencies. Refrigerating and cryogenic engineering enhance progress in machine-building and automation of manufacturing processes, while refrigeration and cryogenics are increasingly used in construction. Refrigerating engineering is the backbone of the air-conditioning industry.
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