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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
Thermal and statistical physics has established the principles and procedures needed to understand and explain the properties of systems consisting of macroscopically large numbers of particles. By developing microscopic statistical physics and macroscopic classical thermodynamic descriptions in tandem, Statistical and Thermal Physics: An Introduction provides insight into basic concepts and relationships at an advanced undergraduate level. This second edition is updated throughout, providing a highly detailed, profoundly thorough, and comprehensive introduction to the subject and features exercises within the text as well as end-of-chapter problems. Part I of this book consists of nine chapters, the first three of which deal with the basics of equilibrium thermodynamics, including the fundamental relation. The following three chapters introduce microstates and lead to the Boltzmann definition of the entropy using the microcanonical ensemble approach. In developing the subject, the ideal gas and the ideal spin system are introduced as models for discussion. The laws of thermodynamics are compactly stated. The final three chapters in Part I introduce the thermodynamic potentials and the Maxwell relations. Applications of thermodynamics to gases, condensed matter, and phase transitions and critical phenomena are dealt with in detail. Initial chapters in Part II present the elements of probability theory and establish the thermodynamic equivalence of the three statistical ensembles that are used in determining probabilities. The canonical and the grand canonical distributions are obtained and discussed. Chapters 12-15 are concerned with quantum distributions. By making use of the grand canonical distribution, the Fermi-Dirac and Bose-Einstein quantum distribution functions are derived and then used to explain the properties of ideal Fermi and Bose gases. The Planck distribution is introduced and applied to photons in radiation and to phonons on solids. The last five chapters cover a variety of topics: the ideal gas revisited, nonideal systems, the density matrix, reactions, and irreversible thermodynamics. A flowchart is provided to assist instructors on planning a course. Key Features: Fully updated throughout, with new content on exciting topics, including black hole thermodynamics, Heisenberg antiferromagnetic chains, entropy and information theory, renewable and nonrenewable energy sources, and the mean field theory of antiferromagnetic systems Additional problem exercises with solutions provide further learning opportunities Suitable for advanced undergraduate students in physics or applied physics. Michael J.R. Hoch spent many years as a visiting scientist at the National High Magnetic Field Laboratory at Florida State University, USA. Prior to this, he was a professor of physics and the director of the Condensed Matter Physics Research Unit at the University of the Witwatersrand, Johannesburg, where he is currently professor emeritus in the School of Physics.
In this unique book, the reader is invited to experience the joy of appreciating something which has eluded understanding for many years - entropy and the Second Law of Thermodynamics. The book has a two-pronged message: first, that the second law is not infinitely incomprehensible as commonly stated in most textbooks on thermodynamics, but can, in fact, be comprehended through sheer common sense; and second, that entropy is not a mysterious quantity that has resisted understanding but a simple, familiar and easily comprehensible concept.Written in an accessible style, the book guides the reader through an abundance of dice games and examples from everyday life. The author paves the way for readers to discover for themselves what entropy is, how it changes, and, most importantly, why it always changes in one direction in a spontaneous process.In this new edition, seven simulated games are included so that the reader can actually experiment with the games described in the book. These simulated games are meant to enhance the readers' understanding and sense of joy upon discovering the Second Law of Thermodynamics.
This book explores applications of computational intelligence in key and emerging fields of engineering, especially with regard to condition monitoring and fault diagnosis, inverse problems, decision support systems and optimization. These applications can be beneficial in a broad range of contexts, including: water distribution networks, manufacturing systems, production and storage of electrical energy, heat transfer, acoustic levitation, uncertainty and robustness of infinite-dimensional objects, fatigue failure prediction, autonomous navigation, nanotechnology, and the analysis of technological development indexes. All applications, mathematical and computational tools, and original results are presented using rigorous mathematical procedures. Further, the book gathers contributions by respected experts from 22 different research centers and eight countries: Brazil, Cuba, France, Hungary, India, Japan, Romania and Spain. The book is intended for use in graduate courses on applied computation, applied mathematics, and engineering, where tools like computational intelligence and numerical methods are applied to the solution of real-world problems in emerging areas of engineering.
Statistical Mechanics: Fundamentals and Model Solutions, Second Edition Fully updated throughout and with new chapters on the Mayer expansion for classical gases and on cluster expansion for lattice models, this new edition of Statistical Mechanics: Fundamentals and Model Solutions provides a comprehensive introduction to equilibrium statistical mechanics for advanced undergraduate and graduate students of mathematics and physics. The author presents a fresh approach to the subject, setting out the basic assumptions clearly and emphasizing the importance of the thermodynamic limit and the role of convexity. With problems and solutions, the book clearly explains the role of models for physical systems, and discusses and solves various models. An understanding of these models is of increasing importance as they have proved to have applications in many areas of mathematics and physics. Features Updated throughout with new content from the field An established and well-loved textbook Contains new problems and solutions for further learning opportunity Author Professor Teunis C. Dorlas is at the Dublin Institute for Advanced Studies, Ireland.
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term "entropy" with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the "driving force" of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term "entropy"; almost 50 years since Shannon developed the mathematical theory of "information" - subsequently renamed "entropy". In this book, the author advocates replacing "entropy" by "information", a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term "entropy".The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the "driving force" for which is analyzed in terms of information.
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term "entropy" with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the "driving force" of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term "entropy"; almost 50 years since Shannon developed the mathematical theory of "information" - subsequently renamed "entropy". In this book, the author advocates replacing "entropy" by "information", a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term "entropy".The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the "driving force" for which is analyzed in terms of information.
Over the last decade new experimental tools and theoretical concepts are providing new insights into collective nonequilibrium behavior of quantum systems. The exquisite control provided by laser trapping and cooling techniques allows us to observe the behavior of condensed bose and degenerate Fermi gases under nonequilibrium drive or after `quenches' in which a Hamiltonian parameter is suddenly or slowly changed. On the solid state front, high intensity short-time pulses and fast (femtosecond) probes allow solids to be put into highly excited states and probed before relaxation and dissipation occur. Experimental developments are matched by progress in theoretical techniques ranging from exact solutions of strongly interacting nonequilibrium models to new approaches to nonequilibrium numerics. The summer school `Strongly interacting quantum systems out of equilibrium' held at the Les Houches School of Physics as its XCIX session was designed to summarize this progress, lay out the open questions and define directions for future work. This books collects the lecture notes of the main courses given in this summer school.
In this unique book, Arieh Ben-Naim invites the reader to experience the joy of appreciating something which has eluded understanding for many years -- entropy and the Second Law of Thermodynamics. The book has a two-pronged message: first, that the Second Law is not "infinitely incomprehensible" as commonly stated in textbooks of thermodynamics but can, in fact, be comprehended through sheer common sense; and second, that entropy is not a mysterious quantity that has "resisted understanding" but a simple, familiar and easily comprehensible concept. Written in an accessible style, the book guides the reader through an abundance of dice games and examples from everyday life. The author paves the way for readers to discover for themselves what entropy is, how it changes, and most importantly, why it always changes in one direction in a spontaneous process.
This book provides a solid foundation in the principles of heat and mass transfer and shows how to solve problems by applying modern methods. The basic theory is developed systematically, exploring in detail the solution methods to all important problems. The revised second edition incorporates state-of-the-art findings on heat and mass transfer correlations. The book will be useful not only to upper- and graduate-level students, but also to practicing scientists and engineers. Many worked-out examples and numerous exercises with their solutions will facilitate learning and understanding, and an appendix includes data on key properties of important substances.
This book offers an easy to read, all-embracing history of thermodynamics. It describes the long development of thermodynamics, from the misunderstood and misinterpreted to the conceptually simple and extremely useful theory that we know today. Coverage identifies not only the famous physicists who developed the field, but also engineers and scientists from other disciplines who helped in the development and spread of thermodynamics as well.
This book is an introductory text on fundamental aspects of combustion including thermodynamics, heat and mass transfer and chemical kinetics which are used to systematically derive the basic concepts of combustion. Apart from the fundamental aspects, many of the emerging topics in the field like microscale combustion, combustion dynamics, oxy-fuel combustion and combustion diagnostics are also covered in the book. This would help the beginners in the subject to get initiated to the state of the art topics. Key Features: Coverage of the essential aspects of combustion engineering suitable for both beginners and practicing professionals Topics like entropy generation, microscale combustion, combustion diagnostics, second law-based analysis exclusive to the title Balanced treatment of thermodynamics, transport phenomena and chemical kinetics Discussion on state of the art techniques in combustion diagnostics Illustrates combustion of gaseous, liquid and solid fuels along with emission of pollutants and greenhouse gases
This third edition of one of the most important and best selling textbooks in statistical physics, is a graduate level text suitable for students in physics, chemistry, and materials science.The discussion of strongly interacting condensed matter systems has been expanded. A chapter on stochastic processes has also been added with emphasis on applications of the Fokker-Planck equation.The modern theory of phase transitions occupies a central place. The chapter devoted to the renormalization group approach is largely rewritten and includes a detailed discussion of the basic concepts and examples of both exact and approximate calculations. The development of the basic tools includes a chapter on computer simulations in which both Monte Carlo method and molecular dynamics are introduced, and a section on Brownian dynamics added.The theories are applied to a number of important systems such as liquids, liquid crystals, polymers, membranes, Bose condensation, superfluidity and superconductivity. There is also an extensive treatment of interacting Fermi and Bose systems, percolation theory and disordered systems in general.
This third edition of one of the most important and best selling textbooks in statistical physics, is a graduate level text suitable for students in physics, chemistry, and materials science.The discussion of strongly interacting condensed matter systems has been expanded. A chapter on stochastic processes has also been added with emphasis on applications of the Fokker-Planck equation.The modern theory of phase transitions occupies a central place. The chapter devoted to the renormalization group approach is largely rewritten and includes a detailed discussion of the basic concepts and examples of both exact and approximate calculations. The development of the basic tools includes a chapter on computer simulations in which both Monte Carlo method and molecular dynamics are introduced, and a section on Brownian dynamics added.The theories are applied to a number of important systems such as liquids, liquid crystals, polymers, membranes, Bose condensation, superfluidity and superconductivity. There is also an extensive treatment of interacting Fermi and Bose systems, percolation theory and disordered systems in general.
Chemical Thermodynamics for Industry presents the latest developments in applied thermodynamics and highlights the role of thermodynamics in the chemical industry. Written by leading experts in the field, Chemical Thermodynamics for Industry covers the latest developments in traditional areas such as calorimetry, microcalorimetry, transport properties, crystallization, adsorption, electrolyte systems and transport fuels, It highlights newly established areas such as multiphase modeling, reactive distillation, non-equilibrium thermodynamics and spectro-calorimetry. It also explores new ways of treating old technologies as well as new and potentially important areas such as ionic liquids, new materials, ab-initia quantum chemistry, nano-particles, polymer recycling, clathrates and the economic value of applied thermodynamics. This book is aimed not only at those working in a specific area of chemical thermodynamics but also at the general chemist, the prospective researcher and those involved in funding chemical research.
This textbook concerns thermal properties of bulk matter and is aimed at advanced undergraduate or first-year graduate students in a range of programs in science or engineering. It provides an intermediate level presentation of statistical thermodynamics for students in the physical sciences (chemistry, nanosciences, physics) or related areas of applied science/engineering (chemical engineering, materials science, nanotechnology engineering), as they are areas in which statistical mechanical concepts play important roles. The book enables students to utilize microscopic concepts to achieve a better understanding of macroscopic phenomena and to be able to apply these concepts to the types of sub-macroscopic systems encountered in areas of nanoscience and nanotechnology.
This thesis explores several interdisciplinary topics at the border of theoretical physics and biology, presenting results that demonstrate the power of methods from statistical physics when applied to neighbouring disciplines. From birth-death processes in switching environments to discussions on the meaning of quasi-potential landscapes in high-dimensional spaces, this thesis is a shining example of the efficacy of interdisciplinary research. The fields advanced in this work include game theory, the dynamics of cancer, and invasion of mutants in resident populations, as well as general contributions to the theory of stochastic processes. The background material provides an intuitive introduction to the theory and applications of stochastic population dynamics, and the use of techniques from statistical physics in their analysis. The thesis then builds on these foundations to address problems motivated by biological phenomena.
The utilization of refrigeration and cryogenics contributes to high-quality preservation and processing of foods, in environmental protection, and in case of emergencies. Refrigerating and cryogenic engineering enhance progress in machine-building and automation of manufacturing processes, while refrigeration and cryogenics are increasingly used in construction. Refrigerating engineering is the backbone of the air-conditioning industry.
Despite more than half a century of theoretical work, the Casimir effect is still not as fully understood as some suppose. In this treatise, the author uncovers new puzzles and paradoxes concerning this mysterious phenomenon. In particular, he clearly demonstrates that the most sophisticated theories fail when confronted with dielectrics in which the refractive index is not uniform but gradually changes.
For almost 20 years the author has conducted research on both macroscopic and molecular theories. The results of his investigation, which can be found in this work, are that irreversible thermodynamics and kinetic theory of matter are not separable especially for nonlinear irreversible processes occurring in systems removed far from equilibrium and thus must be examined together in a mutually consistent manner. Includes coverage of such topics as mass and momentum conservation law, bilinear and quadratic forms for entropy production, viscous phenomena, boundary conditions for velocities and much more.
This book, based on a selection of invited presentations from a topical workshop, focusses on time-variable oscillations and their interactions. The problem is challenging, because the origin of the time variability is usually unknown. In mathematical terms, the oscillations are non-autonomous, reflecting the physics of open systems where the function of each oscillator is affected by its environment. Time-frequency analysis being essential, recent advances in this area, including wavelet phase coherence analysis and nonlinear mode decomposition, are discussed. Some applications to biology and physiology are described. Although the most important manifestation of time-variable oscillations is arguably in biology, they also crop up in, e.g. astrophysics, or for electrons on superfluid helium. The book brings together the research of the best international experts in seemingly very different disciplinary areas.
Thermal Conductivity: Thermal Conductivity of LooseFill Materials by a RadialHeatFlow Method (D.R. Flynn). The Probe Method for Measurement of Thermal Conductivity (A.E. Wechsler). Electrical Resistivity: Methods for Electrical Resistivity Measurement Applicable to Medium and Good Electrical Conductors (B. Cales, P. Abelard). Thermal Diffusivity: Modulated Electron Beam Thermal Diffusivity Equipment (R. De Conink). The Apparatus for Measurement of Thermophysical Properties of Liquids by AC HotWire Technique (L.P. Phylippov et al.). Specific Heat: Practical Modulation Calorimetry (Y.A. Kraftmakher). The Application of Differential Scanning Calorimetry to the Measurement of Specific Heat (M.J. Richardson). Thermal Expansion: Methods of Measuring Thermal Expansion (R.K. Kirby). The Review of Certified Thermophysical Property SRMs. Fourteen additonal articles. Index.
Geostationary or equatorial synchronous satellites are a daily reminder of our space efforts during the past two decades. The nightly television satellite weather picture, the intercontinental telecommunications of television transmissions and telephone conversations, and the establishrnent of educational programs in remote regions on Earth are constant reminders of the presence of these satellites. As used here, the term 'geo stationary' must be taken loosely because, in the long run, the satellites will not remain 'stationary' with respect to an Earth-fixed reference frame. This results from the fact that these satellites, as is true for all satellites, are incessantly subject to perturbations other than the central-body attraction of the Earth. Among the more predominant pertur bations are: the ellipticity of the Earth's equator, the Sun and Moon, and solar radiation pressure. Higher harmonics of the Earth's potential and tidal effects also influence satellite motion, but they are of second order when compared to the predominant perturbations. This volume deals with the theory of geostationary satellites. It consists of seven chapters. Chapter 1 provides a general discussion including a brief history of geostationary satellites and their practical applications. Chapter 2 describes the Earth's gravitational potential field and the methodology of solving the geostationary satellite problem. Chapter 3 treats the effect of Earth's equatorial ellipticity (triaxiality) on a geostationary satellite. Chapter 4 deals with the effects of the Sun and Moon on the satellite's motion while Chapter 5 presents the combined influences of the Sun, Moon and solar radiation pressure. Chapter 6 describes various station-keeping techniques which may be used to make geostationary satellites practically stationary. Finally, Chapter 7 describes the verification of the theory developed in Chapters 3, 4 and 5 by utilizing the Early Bird synchronous satellite observed data as well as its numerically integrated results.
Thermodynamics and Statistical Mechanics provides undergraduate chemistry students with a grounding in both classical and statistical thermodynamics. Thermodynamic quantities and relationships are introduced and developed in a coherent way, enabling students to apply thermodynamic analysis to chemical problems with confidence. Each stage in the development is well illustrated with examples. The text aims to help students understand energy, its different forms and transformations, and the key role of entropy, as applied to chemical systems, addressing questions such as: (i) How much work is performed, and how much heat transfer occurs, during chemical processes and reactions, and how do they depend on temperature? (ii) How is it possible for endothermic processes to occur spontaneously, and will a given reaction occur spontaneously? (iii) What determines the equilibrium between phases? (iv) How do temperature and pressure affect equilibrium? (v) What is the meaning of entropy? (vi) How are macroscopic thermodynamic properties related to microscopic energy levels? Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.
This volume discusses the advances in numerical heat transfer modeling by applying high-performance computing resources, striking a balance between generic fundamentals, specific fundamentals, generic applications, and specific applications. |
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