This book provides a general formalism for the calculation of the spectral correlation function for the fluctuating electromagnetic field. The procedure is applied to the radiative heat transfer and the van der Waals friction using both the semi-classical theory of the fluctuating electromagnetic field and quantum field theory. Applications of the radiative heat transfer and non-contact friction to scanning probe spectroscopy are presented. The theory gives a tentative explanation for the experimental non-contact friction data. The book explains that radiative heat transfer and the van der Waals friction are largely enhanced at short separations between the bodies due to the evanescent electromagnetic waves. Particular strong enhancement occurs if the surfaces of the bodies can support localized surface modes like surface plasmons, surface polaritons or adsorbate vibrational modes. An electromagnetic field outside a moving body can also be created by static charges which are always present on the surface of the body due to inhomogeneities, or due to a bias voltage. This electromagnetic field produces electrostatic friction which can be significantly enhanced if on the surface of the body there is a 2D electron or hole system or an incommensurate adsorbed layer of ions exhibiting acoustic vibrations.

This book gives a rigorous treatment of entanglement measures in the general context of quantum field theory. It covers a broad range of models and the use of fields allows us to properly take the localization of systems into account. The required mathematical techniques are introduced in a self-contained way.

This book introduces and discusses the analysis of interacting many-body complex systems exhibiting spontaneous synchronization from the perspective of nonequilibrium statistical physics. While such systems have been mostly studied using dynamical system theory, the book underlines the usefulness of the statistical physics approach to obtain insightful results in a number of representative dynamical settings. Although it is intractable to follow the dynamics of a particular initial condition, statistical physics allows to derive exact analytical results in the limit of an infinite number of interacting units. Chapter one discusses dynamical characterization of individual units of synchronizing systems as well as of their interaction and summarizes the relevant tools of statistical physics. The latter are then used in chapters two and three to discuss respectively synchronizing systems with either a first- or a second-order evolution in time. This book provides a timely introduction to the subject and is meant for the uninitiated as well as for experienced researchers working in areas of nonlinear dynamics and chaos, statistical physics, and complex systems.

The 3rd edition of this important dictionary offers more than 12,000 entries with expanded encyclopaedic-style definitions making this major reference work invaluable to practitioners, researchers and students working in the area of polymer science and technology. This new edition now includes entries on computer simulation and modeling, surface and interfacial properties and their characterization, functional and smart polymers. New and controlled architectures of polymers, especially dendrimers and controlled radical polymerization are also covered.

This book introduces readers to essential tools for the measurement and analysis of information loss in signal processing systems. Employing a new information-theoretic systems theory, the book analyzes various systems in the signal processing engineer's toolbox: polynomials, quantizers, rectifiers, linear filters with and without quantization effects, principal components analysis, multirate systems, etc. The user benefit of signal processing is further highlighted with the concept of relevant information loss. Signal or data processing operates on the physical representation of information so that users can easily access and extract that information. However, a fundamental theorem in information theory-data processing inequality-states that deterministic processing always involves information loss. These measures form the basis of a new information-theoretic systems theory, which complements the currently prevailing approaches based on second-order statistics, such as the mean-squared error or error energy. This theory not only provides a deeper understanding but also extends the design space for the applied engineer with a wide range of methods rooted in information theory, adding to existing methods based on energy or quadratic representations.

This book shows how Bohmian mechanics overcomes the need for a measurement postulate involving wave function collapse. The measuring process plays a very important role in quantum mechanics. It has been widely analyzed within the Copenhagen approach through the Born and von Neumann postulates, with later extension due to Luders. In contrast, much less effort has been invested in the measurement theory within the Bohmian mechanics framework. The continuous measurement (sharp and fuzzy, or strong and weak) problem is considered here in this framework. The authors begin by generalizing the so-called Mensky approach, which is based on restricted path integral through quantum corridors. The measuring system is then considered to be an open quantum system following a stochastic Schroedinger equation. Quantum stochastic trajectories (in the Bohmian sense) and their role in basic quantum processes are discussed in detail. The decoherence process is thereby described in terms of classical trajectories issuing from the violation of the noncrossing rule of quantum trajectories.

This book studies the collision, coalescence and deposition of nanoparticles in stagnation flames. With the help of synthesis experiments, in-situ laser diagnostics and molecular dynamics simulations, it investigates the growth of nanoparticles in flames and their deposition in boundary layers at a macroscopic flow field scale, as well as particle and molecular scale issues such as the interaction force between particles, how the collision rate is enhanced by attractive forces, and how the nano-scale coalescence process is influenced by the high surface curvature - all of which are crucial to understanding nanoparticle transport phenomena at high temperatures. The book also reports on a novel in-situ laser diagnostics phenomenon called phase-selective laser-induced breakdown spectroscopy and related applications for tracing gas-to-particle transitions and measuring local particle volume fractions in nano-aerosols.

This textbook is the result of the enhancement of several courses on non-equilibrium statistics, stochastic processes, stochastic differential equations, anomalous diffusion and disorder. The target audience includes students of physics, mathematics, biology, chemistry, and engineering at undergraduate and graduate level with a grasp of the basic elements of mathematics and physics of the fourth year of a typical undergraduate course. The little-known physical and mathematical concepts are described in sections and specific exercises throughout the text, as well as in appendices. Physical-mathematical motivation is the main driving force for the development of this text. It presents the academic topics of probability theory and stochastic processes as well as new educational aspects in the presentation of non-equilibrium statistical theory and stochastic differential equations.. In particular it discusses the problem of irreversibility in that context and the dynamics of Fokker-Planck. An introduction on fluctuations around metastable and unstable points are given. It also describes relaxation theory of non-stationary Markov periodic in time systems. The theory of finite and infinite transport in disordered networks, with a discussion of the issue of anomalous diffusion is introduced. Further, it provides the basis for establishing the relationship between quantum aspects of the theory of linear response and the calculation of diffusion coefficients in amorphous systems.

This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions. These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Neel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This new edition presents expanded sections on phase transitions, liquid crystals and magnetic systems, for all problems detailed solutions are provided. It is intended for students in physics and chemistry and provides a unique combination of thorough theoretical explanation and presentation of applications in both areas. Chapter summaries, highlighted essentials and problems with solutions enable a self sustained approach and deepen the knowledge. It is intended for students in physics and chemistry and provides a unique combination of thorough theoretical explanation and presentation of applications in both areas. Chapter summaries, highlighted essentials and problems with solutions enable a self sustained approach and deepen the knowledge.

This textbook takes the reader on a tour of the most important landmarks of theoretical physics: classical, quantum, and statistical mechanics, relativity, electrodynamics, as well as the most modern and exciting of all: elementary particles and the physics of fractals. The second edition has been supplemented with a new chapter devoted to concise though complete presentation of dynamical systems, bifurcations and chaos theory. The treatment is confined to the essentials of each area, presenting all the central concepts and equations at an accessible level. Chapters 1 to 4 contain the standard material of courses in theoretical physics and are supposed to accompany lectures at the university; thus they are rather condensed. They are supposed to fill one year of teaching. Chapters 5 and 6, in contrast, are written less condensed since this material may not be part of standard lectures and thus could be studied without the help of a university teacher. An appendix on elementary particles lies somewhere in between: It could be a summary of a much more detailed course, or studied without such a course. Illustrations and numerous problems round off this unusual textbook. It will ideally accompany the students all along their course in theoretical physics and prove indispensable in preparing and revising the exams. It is also suited as a reference for teachers or scientists from other disciplines who are interested in the topic.

Partition functions arise in combinatorics and related problems of statistical physics as they encode in a succinct way the combinatorial structure of complicated systems. The main focus of the book is on efficient ways to compute (approximate) various partition functions, such as permanents, hafnians and their higher-dimensional versions, graph and hypergraph matching polynomials, the independence polynomial of a graph and partition functions enumerating 0-1 and integer points in polyhedra, which allows one to make algorithmic advances in otherwise intractable problems. The book unifies various, often quite recent, results scattered in the literature, concentrating on the three main approaches: scaling, interpolation and correlation decay. The prerequisites include moderate amounts of real and complex analysis and linear algebra, making the book accessible to advanced math and physics undergraduates.

Topological surgery is a mathematical technique used for creating new manifolds out of known ones. In this book the authors observe that it also occurs in natural phenomena of all scales: 1-dimensional surgery happens during DNA recombination and when cosmic magnetic lines reconnect; 2-dimensional surgery happens during tornado formation and cell mitosis; and they conjecture that 3-dimensional surgery happens during the formation of black holes from cosmic strings, offering an explanation for the existence of a black hole's singularity. Inspired by such phenomena, the authors present a new topological model that extends the formal definition to a continuous process caused by local forces. Lastly, they describe an intrinsic connection between topological surgery and a chaotic dynamical system exhibiting a "hole drilling" behavior. The authors' model indicates where to look for the forces causing surgery and what deformations should be observed in the local submanifolds involved. These predictions are significant for the study of phenomena exhibiting surgery and they also open new research directions. This novel study enables readers to gain a better understanding of the topology and dynamics of various natural phenomena, as well as topological surgery itself and serves as a basis for many more insightful observations and new physical implications.

Thermodynamics Problem Solving in Physical Chemistry: Study Guide and Map is an innovative and unique workbook that guides physical chemistry students through the decision-making process to assess a problem situation, create appropriate solutions, and gain confidence through practice solving physical chemistry problems. The workbook includes six major sections with 20 - 30 solved problems in each section that span from easy, single objective questions to difficult, multistep analysis problems. Each section of the workbook contains key points that highlight major features of the topic to remind students of what they need to apply to solve problems in the topic area. Key Features: Provides instructor access to a visual map depicting how all equations used in thermodynamics are connected and how they are derived from the three major energy laws. Acts as a guide in deriving the correct solution to a problem. Illustrates the questions students should ask themselves about the critical features of the concepts to solve problems in physical chemistry Can be used as a stand-alone product for review of Thermodynamics questions for major tests.

This book contains the proceedings as well as invited papers for the first annual conference of the UNESCO Unitwin Complex System Digital Campus (CSDC), which is an international initiative gathering 120 Universities on four continents, and structured in ten E-Departments. First Complex Systems Digital Campus World E-Conference 2015 features chapters from the latest research results on theoretical questions of complex systems and their experimental domains. The content contained bridges the gap between the individual and the collective within complex systems science and new integrative sciences on topics such as: genes to organisms to ecosystems, atoms to materials to products, and digital media to the Internet. The conference breaks new ground through a dedicated video-conferencing system - a concept at the heart of the international UNESCO UniTwin, embracing scientists from low-income and distant countries. This book promotes an integrated system of research, education, and training. It also aims at contributing to global development by taking into account its social, economic, and cultural dimensions. First Complex Systems Digital Campus World E-Conference 2015 will appeal to students and researchers working in the fields of complex systems, statistical physics, computational intelligence, and biological physics.

This is the physical chemistry textbook for students with an affinity for computers! It offers basic and advanced knowledge for students in the second year of chemistry masters studies and beyond. In seven chapters, the book presents thermodynamics, chemical kinetics, quantum mechanics and molecular structure (including an introduction to quantum chemical calculations), molecular symmetry and crystals. The application of physical-chemical knowledge and problem solving is demonstrated in a chapter on water, treating both the water molecule as well as water in condensed phases. Instead of a traditional textbook top-down approach, this book presents the subjects on the basis of examples, exploring and running computer programs (Mathematica (R)), discussing the results of molecular orbital calculations (performed using Gaussian) on small molecules and turning to suitable reference works to obtain thermodynamic data. Selected Mathematica (R) codes are explained at the end of each chapter and cross-referenced with the text, enabling students to plot functions, solve equations, fit data, normalize probability functions, manipulate matrices and test physical models. In addition, the book presents clear and step-by-step explanations and provides detailed and complete answers to all exercises. In this way, it creates an active learning environment that can prepare students for pursuing their own research projects further down the road. Students who are not yet familiar with Mathematica (R) or Gaussian will find a valuable introduction to computer-based problem solving in the molecular sciences. Other computer applications can alternatively be used. For every chapter learning goals are clearly listed in the beginning, so that readers can easily spot the highlights, and a glossary in the end of the chapter offers a quick look-up of important terms.

Starting from a broad overview of heat transport based on the Boltzmann Transport Equation, this book presents a comprehensive analysis of heat transport in bulk and nanomaterials based on a kinetic-collective model (KCM). This has become key to understanding the field of thermal transport in semiconductors, and represents an important stride. The book describes how heat transport becomes hydrodynamic at the nanoscale, propagating very much like a viscous fluid and manifesting vorticity and friction-like behavior. It introduces a generalization of Fourier's law including a hydrodynamic term based on collective behavior in the phonon ensemble. This approach makes it possible to describe in a unifying way recent experiments that had to resort to unphysical assumptions in order to uphold the validity of Fourier's law, demonstrating that hydrodynamic heat transport is a pervasive type of behavior in semiconductors at reduced scales.

This book provides a detailed yet comprehensive presentation of the theory of periodic conjugate heat transfer. It contains an analytical approach to the effects of thermophysical and geometrical properties of a solid body on the experimentally determined heat transfer coefficient. The main objective of the book is a simplified description of the interaction between a solid body and a fluid as a boundary value problem of the heat conduction equation.This third and extended edition covers Wall's thermal effect on Landau stability, gas bubbles pulsations in fluids, and also the interplay between periodic conjugate heat transfer and non-Fourier heat conduction. The target audience primarily comprises research experts in the field of thermodynamics and fluid dynamics, but the book may also be beneficial for graduate students in engineering.

This authoritative book presents a comprehensive account of the essential roles of nonlinear dynamic and chaos theories in understanding, modeling, and forecasting hydrologic systems. This is done through a systematic presentation of: (1) information on the salient characteristics of hydrologic systems and on the existing theories for their modeling; (2) the fundamentals of nonlinear dynamic and chaos theories, methods for chaos identification and prediction, and associated issues; (3) a review of the applications of chaos theory in hydrology; and (4) the scope and potential directions for the future. This book bridges the divide between the deterministic and the stochastic schools in hydrology, and is well suited as a textbook for hydrology courses.

This thesis discusses the random Euclidean bipartite matching problem, i.e., the matching problem between two different sets of points randomly generated on the Euclidean domain. The presence of both randomness and Euclidean constraints makes the study of the average properties of the solution highly relevant. The thesis reviews a number of known results about both matching problems and Euclidean matching problems. It then goes on to provide a complete and general solution for the one dimensional problem in the case of convex cost functionals and, moreover, discusses a potential approach to the average optimal matching cost and its finite size corrections in the quadratic case. The correlation functions of the optimal matching map in the thermodynamical limit are also analyzed. Lastly, using a functional approach, the thesis puts forward a general recipe for the computation of the correlation function of the optimal matching in any dimension and in a generic domain.

These proceedings of the 18th International Conference on Difference Equations and Applications cover a number of different aspects of difference equations and discrete dynamical systems, as well as the interplay between difference equations and dynamical systems. The conference was organized by the Department of Mathematics at the Universitat Autonoma de Barcelona (UAB) under the auspices of the International Society of Difference Equations (ISDE) and held in Barcelona (Catalonia, Spain) in July 2012. Its purpose was to bring together experts and novices in these fields to discuss the latest developments. The book gathers contributions in the field of combinatorial and topological dynamics, complex dynamics, applications of difference equations to biology, chaotic linear dynamics, economic dynamics and control and asymptotic behavior, and periodicity of difference equations. As such it is of interest to researchers and scientists engaged in the theory and applications of difference equations and discrete dynamical systems.

This book elaborates on the asymptotic behaviour, when N is large, of certain N-dimensional integrals which typically occur in random matrices, or in 1+1 dimensional quantum integrable models solvable by the quantum separation of variables. The introduction presents the underpinning motivations for this problem, a historical overview, and a summary of the strategy, which is applicable in greater generality. The core aims at proving an expansion up to o(1) for the logarithm of the partition function of the sinh-model. This is achieved by a combination of potential theory and large deviation theory so as to grasp the leading asymptotics described by an equilibrium measure, the Riemann-Hilbert approach to truncated Wiener-Hopf in order to analyse the equilibrium measure, the Schwinger-Dyson equations and the boostrap method to finally obtain an expansion of correlation functions and the one of the partition function. This book is addressed to researchers working in random matrices, statistical physics or integrable systems, or interested in recent developments of asymptotic analysis in those fields.

This book covers the parameterization of entry capsules, including Apollo capsules and planetary probes, and winged entry vehicles such as the Space Shuttle and lifting bodies. The aerodynamic modelling is based on a variety of panel methods that take shadowing into account, and it has been validated with flight and wind tunnel data of Apollo and the Space Shuttle. The shape optimization is combined with constrained trajectory analysis, and the multi-objective approach provides the engineer with a Pareto front of optimal shapes. The method detailed in Conceptual Shape Optimization of Entry Vehicles is straightforward, and the output gives the engineer insight in the effect of shape variations on trajectory performance. All applied models and algorithms used are explained in detail, allowing for reconstructing the design tool to the researcher's requirements. Conceptual Shape Optimization of Entry Vehicles will be of interest to both researchers and graduate students in the field of aerospace engineering, and to practitioners within the aerospace industry.

This book has developed over the past fifteen years from a modern course on stochastic chemical kinetics for graduate students in physics, chemistry and biology. The first part presents a systematic collection of the mathematical background material needed to understand probability, statistics, and stochastic processes as a prerequisite for the increasingly challenging practical applications in chemistry and the life sciences examined in the second part. Recent advances in the development of new techniques and in the resolution of conventional experiments at nano-scales have been tremendous: today molecular spectroscopy can provide insights into processes down to scales at which current theories at the interface of physics, chemistry and the life sciences cannot be successful without a firm grasp of randomness and its sources. Routinely measured data is now sufficiently accurate to allow the direct recording of fluctuations. As a result, the sampling of data and the modeling of relevant processes are doomed to produce artifacts in interpretation unless the observer has a solid background in the mathematics of limited reproducibility. The material covered is presented in a modular approach, allowing more advanced sections to be skipped if the reader is primarily interested in applications. At the same time, most derivations of analytical solutions for the selected examples are provided in full length to guide more advanced readers in their attempts to derive solutions on their own. The book employs uniform notation throughout, and a glossary has been added to define the most important notions discussed.

This book offers a short and concise introduction to the many facets of chaos theory. While the study of chaotic behavior in nonlinear, dynamical systems is a well-established research field with ramifications in all areas of science, there is a lot to be learnt about how chaos can be controlled and, under appropriate conditions, can actually be constructive in the sense of becoming a control parameter for the system under investigation, stochastic resonance being a prime example. The present work stresses the latter aspects and, after recalling the paradigm changes introduced by the concept of chaos, leads the reader skillfully through the basics of chaos control by detailing the relevant algorithms for both Hamiltonian and dissipative systems, among others. The main part of the book is then devoted to the issue of synchronization in chaotic systems, an introduction to stochastic resonance, and a survey of ratchet models. In this second, revised and enlarged edition, two more chapters explore the many interfaces of quantum physics and dynamical systems, examining in turn statistical properties of energy spectra, quantum ratchets, and dynamical tunneling, among others. This text is particularly suitable for non-specialist scientists, engineers, and applied mathematical scientists from related areas, wishing to enter the field quickly and efficiently. From the reviews of the first edition: This book is an excellent introduction to the key concepts and control of chaos in (random) dynamical systems [...] The authors find an outstanding balance between main physical ideas and mathematical terminology to reach their audience in an impressive and lucid manner. This book is ideal for anybody who would like to grasp quickly the main issues related to chaos in discrete and continuous time. Henri Schurz, Zentralblatt MATH, Vol. 1178, 2010.