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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
Statistical Thermodynamics and Properties of Matter is written with the advanced undergraduate and graduate student in mind. Its aim is to familiarize the student with the approach that a physicist would take, for example, when tackling problems related to quantum mechanics or thermodynamics.
This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been given to the rigor of mathematical developments. This second volume in the set is devoted to the study of liquid phases.
Thermodynamics is used increasingly in ecology to understand the system properties of ecosystems because it is a basic science that describes energy transformation from a holistic view. In the last decade, many contributions to ecosystem theory based on thermodynamics have been published, therefore an important step toward integrating these theories and encouraging a more wide spread use of them is to present them in one volume.
Thermodynamics and information touch theory every facet of chemistry. However, the physical chemistry curriculum digested by students worldwide is still heavily skewed toward heat/work principles established more than a century ago. Rectifying this situation, Chemical Thermodynamics and Information Theory with Applications explores applications drawn from the intersection of thermodynamics and information theory-two mature and far-reaching fields. In an approach that intertwines information science and chemistry, this book covers: The informational aspects of thermodynamic state equations The algorithmic aspects of transformations-compression, expansion, cyclic, and more The principles of best-practice programming How molecules transmit and modify information via collisions and chemical reactions Using examples from physical and organic chemistry, this book demonstrates how the disciplines of thermodynamics and information theory are intertwined. Accessible to curiosity-driven chemists with knowledge of basic calculus, probability, and statistics, the book provides a fresh perspective on time-honored subjects such as state transformations, heat and work exchanges, and chemical reactions.
Der Grundkurs Theoretische Physik deckt in 7 Banden alle fur das Diplom und fur Bachelor/Master-Studiengange massgeblichen Gebiete ab. Jeder Band vermittelt das im jeweiligen Semester notwendige theoretisch-physikalische Rustzeug. UEbungsaufgaben mit ausfuhrlichen Loesungen dienen der Vertiefung des Stoffs. Der 4. Band behandelt die Gebiete Thermodynamik und Relativitatstheorie. Fur die Neuauflage wurde er grundlegend uberarbeitet und um 24 Aufgaben erganzt. Durch die zweifarbige Gestaltung ist der Stoff jetzt noch ubersichtlicher gegliedert.
In this invaluable book, macroscopic irreversible thermodynamics is presented in its realm and its splendor by appealing to the notion of internal variables of state. This applies to both fluids and solids with or without microstructures of mechanical or electromagnetic origin. This unmatched richness of essentially nonlinear behaviors is the result of the use of modern mathematical techniques such as convex analysis in a clear-cut framework which allows one to put under the umbrella of "irreversible thermodynamics" behaviors which until now have been commonly considered either not easily covered, or even impossible to incorporate into such a framework.The book is intended for all students and researchers whose main concern is the rational modeling of complex and/or new materials with physical and engineering applications, such as those accounting for coupled-field, hysteresis, fracture, nonlinear-diffusion, and phase-transformation phenomena.
Emergence and complexity refer to the appearance of higher-level properties and behaviours of a system that obviously comes from the collective dynamics of that system's components. These properties are not directly deducible from the lower-level motion of that system. Emergent properties are properties of the "whole'' that are not possessed by any of the individual parts making up that whole. Such phenomena exist in various domains and can be described, using complexity concepts and thematic knowledges. This book highlights complexity modelling through dynamical or behavioral systems. The pluridisciplinary purposes, developed along the chapters, are able to design links between a wide-range of fundamental and applicative Sciences. Developing such links - instead of focusing on specific and narrow researches - is characteristic of the Science of Complexity that we try to promote by this contribution.
Over 130 years ago, James Clerk Maxwell introduced his hypothetical "demon" as a challenge to the scope of the second law of thermodynamics. Fascination with the demon persisted throughout the development of statistical and quantum physics, information theory, and computer science, and links have been established between Maxwell's demon and each of these disciplines. The demon's seductive quality makes it appealing to physical scientists, engineers, computer scientists, biologists, psychologists, and historians and philosophers of science. Since the publication of Maxwell's Demon: Entropy, Information, Computing in 1990, Maxwell's demon has been the subject of renewed and increased interest by numerous researchers in the fields mentioned above. Updated and expanded, Maxwell's Demon 2: Entropy, Classical and Quantum Information, Computing retains many of the seminal papers that appeared in the first edition, including the original thoughts of James Clerk Maxwell and William Thomson; a historical review by Martin Klein; and key articles by Leo Szilard, Leon Brillouin, Rolf Landauer, and Charles Bennett that led to new branches of research on the demon. This second edition contains newer articles by Landauer, Bennett, and others, related to Landauer's principle; connections with quantum mechanics; algorithmic information; and the thermodynamics and limits of computation. The book also includes two separate bibliographies: an alphabetical listing by author and a chronological bibliography that is annotated by the editors and contains selected quotes from the books and articles listed. The bibliography has more than doubled in size since publication of the first edition and now contains over 570 entries.
This classic book marks the beginning of an era of vigorous mathematical progress in equilibrium statistical mechanics. Its treatment of the infinite system limit has not been superseded, and the discussion of thermodynamic functions and states remains basic for more recent work. The conceptual foundation provided by the Rigorous Results remains invaluable for the study of the spectacular developments of statistical mechanics in the second half of the 20th century.
A thorough understanding of statistical mechanics depends strongly on the insights and manipulative skills that are acquired through the solving of problems. Problems on Statistical Mechanics provides over 120 problems with model solutions, illustrating both basic principles and applications that range from solid-state physics to cosmology. An introductory chapter provides a summary of the basic concepts and results that are needed to tackle the problems, and also serves to establish the notation that is used throughout the book. The problems themselves occupy five chapters, progressing from the simpler aspects of thermodynamics and equilibrium statistical ensembles to the more challenging ideas associated with strongly interacting systems and nonequilibrium processes. Comprehensive solutions to all of the problems are designed to illustrate efficient and elegant problem-solving techniques. Where appropriate, the authors incorporate extended discussions of the points of principle that arise in the course of the solutions. The appendix provides useful mathematical formulae.
This monograph introduces an exact model for a critical spin chain with arbitrary spin S, which includes the Haldane--Shastry model as the special case S=1/2. While spinons in the Haldane-Shastry model obey abelian half-fermi statistics, the spinons in the general model introduced here obey non-abelian statistics. This manifests itself through topological choices for the fractional momentum spacings. The general model is derived by mapping exact models of quantized Hall states onto spin chains. The book begins with pedagogical review of all the relevant models including the non-abelian statistics in the Pfaffian Hall state, and is understandable to every student with a graduate course in quantum mechanics.
This text provides a uniform and consistent approach to diversified
problems encountered in the study of dynamical processes in
condensed phase molecular systems. Given the broad
interdisciplinary aspect of this subject, the book focuses on three
themes: coverage of needed background material, in-depth
introduction of methodologies, and analysis of several key
applications. The uniform approach and common language used in all
discussions help to develop general understanding and insight on
condensed phases chemical dynamics. The applications discussed are
among the most fundamental processes that underlie physical,
chemical and biological phenomena in complex systems.
Computer science and physics have been closely linked since the
birth of modern computing. In recent years, an interdisciplinary
area has blossomed at the junction of these fields, connecting
insights from statistical physics with basic computational
challenges. Researchers have successfully applied techniques from
the study of phase transitions to analyze NP-complete problems such
as satisfiability and graph coloring. This is leading to a new
understanding of the structure of these problems, and of how
algorithms perform on them.
Kinetic Theory of granular Gases provides an introduction to the rapidly developing theory of dissipative gas dynamics as it has been developed mainly during the past decade. The book is aimed at readers from the advanced undergraduate level onwards and leads up to the present state of research. The text is self-contained, in the sense that no mathematical or physical knowledge is required that goes beyond standard undergraduate physics courses. The material is adequate for a one-semester course and contains chapter summaries as well as exercises with detailed solutions. Special emphasis is put on a microscopically consistent description of pairwise particle collisions which leads to an impact-velocity dependent coefficient of restitution. The description of the many-particle system, based on the Boltzmann equation, starts with the derivation of the velocity distribution function, followed by the investigation of self-diffusion and Brownian motion. Using hydrodynamical methods, transport processes and self-organized structure formulation are studies. An appendix gives a brief introduction to event-driven molecular dynamics. A second appendix describes a novel mathematical technique for the derivation of the kinetic properties which allows for the application of computer algebra. The book is accompanied by a web page where the molecular dynamics program as well as the computer-algebra programs are provided.
The book details sources of thermal energy, methods of capture, and applications. It describes the basics of thermal energy, including measuring thermal energy, laws of thermodynamics that govern its use and transformation, modes of thermal energy, conventional processes, devices and materials, and the methods by which it is transferred. It covers 8 sources of thermal energy: combustion, fusion (solar) fission (nuclear), geothermal, microwave, plasma, waste heat, and thermal energy storage. In each case, the methods of production and capture and its uses are described in detail. It also discusses novel processes and devices used to improve transfer and transformation processes.
This book discusses all three formalisms used in the study of finite temperature field theory, namely the imaginary time formalism, the closed time formalism and thermofield dynamics. Applications of the formalisms are worked out in detail. Gauge field theories and symmetry restoration at finite temperature are among the practical examples discussed in depth. The question of gauge dependence of the effective potential and the Nielsen identities are explained. The nonrestoration of some symmetries at high temperature (such as supersymmetry) and theories on nonsimply connected space-times are also described thoroughly. Other topics include (1+1)- and (2+1)-dimensional field theories at finite temperature and phase transitions, derivative expansion, linear response theory and the question of infrared divergences at finite temperature. In addition, examples of nonequilibrium phenomena are discussed with the disoriented chiral condensates as an illustration.This book is a very useful tool for graduate students, teachers and researchers in theoretical physics.
Making Flory-Huggins Practical: Thermodynamics of
Polymer-Containing Mixtures, by B. A. Wolf
This book presents a consistent mathematical theory of the non-electronic physical properties of disordered and amorphous solids, starting from the atomic-level dynamics and leading to experimentally verifiable descriptions of macroscopic properties such as elastic and viscoelastic moduli, plasticity, phonons and vibrational spectra, and thermal properties. This theory begins with the assumption of the undeniable existence of an “amorphous lattice”, which allows one to relegate the theoretical uncertainties about the ultimate nature of the glass transition to a subsidiary role and thus take a more pragmatic approach towards the modelling of physical properties. The book introduces the reader not only to the subtle physical concepts underlying the dynamics, mechanics, and statistical physics of glasses and amorphous solids, but also to the essential mathematical and numerical methods that cannot be readily gleaned from specialized literature since they are spread out among many often technically demanding papers. These methods are presented in this book in such a way as to be sufficiently general, allowing for the mathematical or numerical description of novel physical phenomena observed in many different types of amorphous solids (including soft and granular systems), regardless of the atomistic details and particular chemistry of the material. This monograph is aimed at researchers and graduate-level students in physics, materials science, physical chemistry and engineering working in the areas of amorphous materials, soft matter and granular systems, statistical physics, continuum mechanics, plasticity, and solid mechanics. It is also particularly well suited to those working on molecular dynamics simulations, molecular coarse-grained simulations, as well as ab initio atomistic and DFT methods for solid-state and materials science.
The CRC Handbook of Thermophysical and Thermochemical Data is an interactive software and handbook package that provides an invaluable source of reliable data embracing a wide range of properties of chemical substances, mixtures, and reacting systems. Use the handbook and software together to quickly, and easily generate property values at any desired temperature, pressure, or mixture composition.
This book introduces combustion related topics, including chemical thermodynamics, chemical kinetics, deflagrations, detonations in premixed media, diffusion flames, ignition, and flame stabilization, to undergraduate students in mechanical, aerospace, chemical, and civil engineering.
Recent groundbreaking discoveries in physics, including the discovery of the Higgs Boson and gravitational waves, have relied on chi-squared analysis and model testing, a data analysis method. This is the first book to make chi-squared model testing accessible to students in introductory physics lab courses and others who need to learn this method, such as beginning researchers in astrophysics and particle physics, beginners in data science, and lab students in other experimental sciences. For over a decade, Harvard University's introductory physics lab sequence has made chi-squared model testing its central theme. Written by two faculty members, the book is based on years of experience teaching students learn how to think like scientists by testing their models using chi-squared analysis. By including uncertainties in the curve fitting technique, chi-squared data analysis improves on the centuries old ordinary least squares and linear regression methods and combines best fit parameter estimation and model testing in one method. A toolkit of essential statistical and experimental concepts is developed from the ground up with novel features to interest even those familiar with the material. The presentation of one and two parameter chi-squared model testing, requiring only elementary probability and algebra, is followed by case studies that apply the methods to simple introductory physics lab experiments. More challenging topics requiring calculus are addressed in an advanced topic chapter. This self-contained and student-friendly introduction includes a glossary, end of chapter problems with complete solutions, and software scripts available in several popular programming languages that the reader can use for chi-squared model testing.
Many real-life systems are dynamic, evolving, and intertwined. Examples of such systems displaying 'complexity', can be found in a wide variety of contexts ranging from economics to biology, to the environmental and physical sciences. The study of complex systems involves analysis and interpretation of vast quantities of data, which necessitates the application of many classical and modern tools and techniques from statistics, network science, machine learning, and agent-based modelling. Drawing from the latest research, this self-contained and pedagogical text describes some of the most important and widely used methods, emphasising both empirical and theoretical approaches. More broadly, this book provides an accessible guide to a data-driven toolkit for scientists, engineers, and social scientists who require effective analysis of large quantities of data, whether that be related to social networks, financial markets, economies or other types of complex systems.
This thesis make significant contributions to both the numerical and analytical aspects of particle physics, reducing the noise associated with matrix calculations in quantum chromodynamics (QCD) and modeling multi-quark mesonic matters that could be used to investigate particles previously unseen in nature. Several methods are developed that can reduce the statistical uncertainty in the extraction of hard-to-detect lattice QCD signals from disconnected diagrams. The most promising technique beats competing methods by 1700 percent, leading to a potential decrease in the computation time of quark loop quantities by an order of magnitude. This not only increases efficiency but also works for QCD matrices with almost-zero eigenvalues, a region where most QCD algorithms break down. This thesis also develops analytical solutions used to investigate exotic particles, specifically the Thomas-Fermi quark model, giving insight into possible new states formed from mesonic matter. The main benefit of this model is that it can work for a large number of quarks which is currently almost impossible with lattice QCD. Patterns of single-quark energies are observed which give the first a priori indication that stable octa-quark and hexadeca-quark versions of the charmed and bottom Z-meson exist. |
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