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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
This book provides a systematic and comprehensive description of high-entropy alloys (HEAs). The authors summarize key properties of HEAs from the perspective of both fundamental understanding and applications, which are supported by in-depth analyses. The book also contains computational modeling in tackling HEAs, which help elucidate the formation mechanisms and properties of HEAs from various length and time scales.
This thesis represents the first systematic description of the two-phase flow problem. Two-phase flows of volatile fluids in confined geometries driven by an applied temperature gradient play an important role in a range of applications, including thermal management, such as heat pipes, thermosyphons, capillary pumped loops and other evaporative cooling devices. Previously, this problem has been addressed using a piecemeal approach that relied heavily on correlations and unproven assumptions, and the science and technology behind heat pipes have barely evolved in recent decades. The model introduced in this thesis, however, presents a comprehensive physically based description of both the liquid and the gas phase. The model has been implemented numerically and successfully validated against the available experimental data, and the numerical results are used to determine the key physical processes that control the heat and mass flow and describe the flow stability. One of the key contributions of this thesis work is the description of the role of noncondensables, such as air, on transport. In particular, it is shown that many of the assumptions used by current engineering models of evaporative cooling devices are based on experiments conducted at atmospheric pressures, and these assumptions break down partially or completely when most of the noncondensables are removed, requiring a new modeling approach presented in the thesis. Moreover, Numerical solutions are used to motivate and justify a simplified analytical description of transport in both the liquid and the gas layer, which can be used to describe flow stability and determine the critical Marangoni number and wavelength describing the onset of the convective pattern. As a result, the results presented in the thesis should be of interest both to engineers working in heat transfer and researchers interested in fluid dynamics and pattern formation.
In the present volume numerous descriptions of Ram accelerators are presented. These descriptions provide good overview on the progress made and the present state of the Ram accelerator technology worldwide. In addition, articles describing light gas gun, ballistic range including a chapter dealing with shock waves in solids are given. Along with the technical description of considered facilities, samples of obtained results are also included. Each chapter is written by an expert in the described topic providing a comprehensive description of the discussed phenomena.
Thermodynamics is fundamental to university and college curricula in chemistry, physics, engineering and many life sciences around the world. It is also notoriously difficult for students to understand, learn and apply. What makes this book different, and special, is the clarity of the text. The writing style is fluid, natural and lucid, and everything is explained in a logical and transparent manner. Thermodynamics is a deep, and important, branch of science, and this book does not make it "easy". But it does make it intelligible. This book introduces a new, 'Fourth Law' of Thermodynamics' based on the notion of Gibbs free energy, which underpins almost every application of thermodynamics and which the authors claim is worthy of recognition as a 'law'. The last four chapters bring thermodynamics into the twenty-first century, dealing with bioenergetics (how living systems capture and use free energy), macromolecule assembly (how proteins fold), and macromolecular aggregation (how, for example, virus capsids assemble). This is of great current relevance to students of biochemistry, biochemical engineering and pharmacy, and is covered in very few other texts on thermodynamics. The book also contains many novel and effective examples, such as the explanation of why friction is irreversible, the proof of the depression of the freezing point, and the explanation of the biochemical standard state.
This book is an introduction to quantum Markov chains and explains how this concept is connected to the question of how well a lost quantum mechanical system can be recovered from a correlated subsystem. To achieve this goal, we strengthen the data-processing inequality such that it reveals a statement about the reconstruction of lost information. The main difficulty in order to understand the behavior of quantum Markov chains arises from the fact that quantum mechanical operators do not commute in general. As a result we start by explaining two techniques of how to deal with non-commuting matrices: the spectral pinching method and complex interpolation theory. Once the reader is familiar with these techniques a novel inequality is presented that extends the celebrated Golden-Thompson inequality to arbitrarily many matrices. This inequality is the key ingredient in understanding approximate quantum Markov chains and it answers a question from matrix analysis that was open since 1973, i.e., if Lieb's triple matrix inequality can be extended to more than three matrices. Finally, we carefully discuss the properties of approximate quantum Markov chains and their implications. The book is aimed to graduate students who want to learn about approximate quantum Markov chains as well as more experienced scientists who want to enter this field. Mathematical majority is necessary, but no prior knowledge of quantum mechanics is required.
This book presents research advances in automotive AC systems using an interdisciplinary approach combining both thermal science, and automotive engineering. It covers a variety of topics, such as: control strategies, optimization algorithms, and diagnosis schemes developed for when automotive air condition systems interact with powertrain dynamics. In contrast to the rapid advances in the fields of building HVAC and automotive separately, an interdisciplinary examination of both areas has long been neglected. The content presented in this book not only reveals opportunities when interaction between on-board HVAC and powertrain is considered, but also provides new findings to achieve performance improvement using model-based methodologies.
This book presents a collection of recent research on building diagnosis techniques related to construction pathology, hygrothermal behavior and durability, and diagnostic techniques. It highlights recent advances and new developments in the field of building physics, building anomalies in materials and components, new techniques for improved energy efficiency analysis, and diagnosis techniques such as infrared thermography. This book will be of interest to a wide readership of professionals, scientists, students, practitioners, and lecturers.
This book is a short, but complete, introduction to the Loewner equation and the SLEs, which are a family of random fractal curves, as well as the relevant background in probability and complex analysis. The connection to statistical physics is also developed in the text in an example case. The book is based on a course (with the same title) lectured by the author. First three chapters are devoted to the background material, but at the same time, give the reader a good understanding on the overview on the subject and on some aspects of conformal invariance. The chapter on the Loewner equation develops in detail the connection of growing hulls and the differential equation satisfied by families of conformal maps. The Schramm-Loewner evolutions are defined and their basic properties are studied in the following chapter, and the regularity properties of random curves as well as scaling limits of discrete random curves are investigated in the final chapter. The book is aimed at graduate students or researchers who want to learn the subject fairly quickly.
This book systematically interprets and documents new, unifying principles and basic laws describing the most relevant aspects of hierarchy. To do so, it discusses recent experiments and models that are simple and realistic enough to reproduce the observations, and develops concepts for a better understanding of the complexity of systems consisting of many organisms. The book covers systems ranging from flocks of birds to groups of people. Although it focuses on hierarchical collective behavior in general, two aspects pop up in the majority of cases: collective motion and dynamically changing, partially directed networks (and the natural relation between the two). In addition, it offers a brief description of the most relevant definitions and concepts involved in the context of hierarchies, presenting both a review of the current literature and a number of new experimental and computational results in more detail. It is a valuable resource for students and scholars pursuing research on the structure of interactions within the collectives of animals and humans.
This book presents an introduction to Evolutionary Game Theory (EGT) which is an emerging field in the area of complex systems attracting the attention of researchers from disparate scientific communities. EGT allows one to represent and study several complex phenomena, such as the emergence of cooperation in social systems, the role of conformity in shaping the equilibrium of a population, and the dynamics in biological and ecological systems.Since EGT models belong to the area of complex systems, statistical physics constitutes a fundamental ingredient for investigating their behavior. At the same time, the complexity of some EGT models, such as those realized by means of agent-based methods, often require the implementation of numerical simulations. Therefore, beyond providing an introduction to EGT, this book gives a brief overview of the main statistical physics tools (such as phase transitions and the Ising model) and computational strategies for simulating evolutionary games (such as Monte Carlo algorithms on lattices). This book will appeal to students and researchers in this burgeoning field of complex systems.
This book is an introduction to maximum-entropy models of random graphs with given topological properties and their applications. Its original contribution is the reformulation of many seemingly different problems in the study of both real networks and graph theory within the unified framework of maximum entropy. Particular emphasis is put on the detection of structural patterns in real networks, on the reconstruction of the properties of networks from partial information, and on the enumeration and sampling of graphs with given properties. After a first introductory chapter explaining the motivation, focus, aim and message of the book, chapter 2 introduces the formal construction of maximum-entropy ensembles of graphs with local topological constraints. Chapter 3 focuses on the problem of pattern detection in real networks and provides a powerful way to disentangle nontrivial higher-order structural features from those that can be traced back to simpler local constraints. Chapter 4 focuses on the problem of network reconstruction and introduces various advanced techniques to reliably infer the topology of a network from partial local information. Chapter 5 is devoted to the reformulation of certain "hard" combinatorial operations, such as the enumeration and unbiased sampling of graphs with given constraints, within a "softened" maximum-entropy framework. A final chapter offers various overarching remarks and take-home messages.By requiring no prior knowledge of network theory, the book targets a broad audience ranging from PhD students approaching these topics for the first time to senior researchers interested in the application of advanced network techniques to their field.
This book presents an innovative control system design process motivated by renewable energy electric grid integration problems. The concepts developed result from the convergence of research and development goals which have important concepts in common: exergy flow, limit cycles, and balance between competing power flows. A unique set of criteria is proposed to design controllers for a class of nonlinear systems. A combination of thermodynamics with Hamiltonian systems provides the theoretical foundation which is then realized in a series of connected case studies. It allows the process of control design to be viewed as a power flow control problem, balancing the power flowing into a system against that being dissipated within it and dependent on the power being stored in it - an interplay between kinetic and potential energies. Human factors and the sustainability of self-organizing systems are dealt with as advanced topics.
Analyzing the phase transition from diffusive to localized behavior in a model of directed polymers in a random environment, this volume places particular emphasis on the localization phenomenon. The main questionis: What does the path of a random walk look like if rewards and penalties are spatially randomly distributed?This model, which provides a simplified version of stretched elastic chains pinned by random impurities, has attracted much research activity, but it (and its relatives) still holds many secrets, especially in high dimensions. It has non-gaussian scaling limits and it belongs to the so-called KPZ universality class when the space is one-dimensional. Adopting a Gibbsian approach, using general and powerful tools from probability theory, the discrete model is studied in full generality. Presenting the state-of-the art from different perspectives, and written in the form of a first course on the subject, this monograph is aimed at researchers in probability or statistical physics, but is also accessible to masters and Ph.D. students.
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term "entropy" with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the "driving force" of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term "entropy"; almost 50 years since Shannon developed the mathematical theory of "information" - subsequently renamed "entropy". In this book, the author advocates replacing "entropy" by "information", a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term "entropy".The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the "driving force" for which is analyzed in terms of information.
This is the first in a series of three proceedings of the 20th Pacific Basin Nuclear Conference (PBNC). This volume covers the topics of Safety and Security, Public Acceptance and Nuclear Education, as well as Economics and Reducing Cost. As one in the most important and influential conference series of nuclear science and technology, the 20th PBNC was held in Beijing and the theme of this meeting was "Nuclear: Powering the Development of the Pacific Basin and the World". It brought together outstanding nuclear scientist and technical experts, senior industry executives, senior government officials and international energy organization leaders from all across the world. The book is not only a good summary of the new developments in the field, but also a useful guideline for the researchers, engineers and graduate students.
This book treats ensembles of Young diagrams originating from group-theoretical contexts and investigates what statistical properties are observed there in a large-scale limit. The focus is mainly on analyzing the interesting phenomenon that specific curves appear in the appropriate scaling limit for the profiles of Young diagrams. This problem is regarded as an important origin of recent vital studies on harmonic analysis of huge symmetry structures. As mathematics, an asymptotic theory of representations is developed of the symmetric groups of degree n as n goes to infinity. The framework of rigorous limit theorems (especially the law of large numbers) in probability theory is employed as well as combinatorial analysis of group characters of symmetric groups and applications of Voiculescu's free probability. The central destination here is a clear description of the asymptotic behavior of rescaled profiles of Young diagrams in the Plancherel ensemble from both static and dynamic points of view.
This easy-to read book looks at the many ways in which diffusion bears on processes that involve dispersion, starting from the Brownian motion of molecules, covering the invasion of exotic plants, migration of populations, epidemics, and extending to the spreading of languages and ideas. Recently, there has been a growing interest in understanding migrations, diffusion and spreading outside the "hard" natural sciences of physics and chemistry, for example the spreading of plants introduced as a result of globalization. Another fascinating story is that of human migration in the distant past, i.e. the immigration of our ancestors who brought agriculture from the Near East, or the fast spread of the Palaeo-Indians into the Americas after the end of the Ice Age. Likewise, the spread of languages in the past, and even more so the current spread and retreat of languages will be described here in terms of diffusion. By understanding these principles, there is hope that some of the less common languages that are threatened by globalization can be saved. Another important implication discussed by the author concerns the outbreak of epidemics; these may be mitigated if we understand their spreading mechanism. Last but not least the spreading of ideas and innovations, a process which changes the world sometimes faster than we wish, can also be usefully described in this picture.
Thermodynamically constrained averaging theory provides a consistent method for upscaling conservation and thermodynamic equations for application in the study of porous medium systems. The method provides dynamic equations for phases, interfaces, and common curves that are closely based on insights from the entropy inequality. All larger scale variables in the equations are explicitly defined in terms of their microscale precursors, facilitating the determination of important parameters and macroscale state equations based on microscale experimental and computational analysis. The method requires that all assumptions that lead to a particular equation form be explicitly indicated, a restriction which is useful in ascertaining the range of applicability of a model as well as potential sources of error and opportunities to improve the analysis.
This book is dedicated to the recent developments in RET with the aim to explore polyatomic gas, dense gas and mixture of gases in non-equilibrium. In particular we present the theory of dense gases with 14 fields, which reduces to the Navier-Stokes Fourier classical theory in the parabolic limit. Molecular RET with an arbitrary number of field-variables for polyatomic gases is also discussed and the theory is proved to be perfectly compatible with the kinetic theory in which the distribution function depends on an extra variable that takes into account a molecule's internal degrees of freedom. Recent results on mixtures of gases with multi-temperature are presented together with a natural definition of the average temperature. The qualitative analysis and in particular, the existence of the global smooth solution and the convergence to equilibrium are also studied by taking into account the fact that the differential systems are symmetric hyperbolic. Applications to shock and sound waves are analyzed together with light scattering and heat conduction and the results are compared with experimental data. Rational extended thermodynamics (RET) is a thermodynamic theory that is applicable to non-equilibrium phenomena. It is described by differential hyperbolic systems of balance laws with local constitutive equations. As RET has been strictly related to the kinetic theory through the closure method of moment hierarchy associated to the Boltzmann equation, the applicability range of the theory has been restricted within rarefied monatomic gases. The book represents a valuable resource for applied mathematicians, physicists and engineers, offering powerful models for potential applications like satellites reentering the atmosphere, semiconductors and nano-scale phenomena.
The book systematically presents the theories of pseudo-differential operators with symbols singular in dual variables, fractional order derivatives, distributed and variable order fractional derivatives, random walk approximants, and applications of these theories to various initial and multi-point boundary value problems for pseudo-differential equations. Fractional Fokker-Planck-Kolmogorov equations associated with a large class of stochastic processes are presented. A complex version of the theory of pseudo-differential operators with meromorphic symbols based on the recently introduced complex Fourier transform is developed and applied for initial and boundary value problems for systems of complex differential and pseudo-differential equations.
This work presents a series of experiments with ultracold one-dimensional Bose gases, which establish said gases as an ideal model system for exploring a wide range of non-equilibrium phenomena. With the help of newly developed tools, like full distributions functions and phase correlation functions, the book reveals the emergence of thermal-like transient states, the light-cone-like emergence of thermal correlations and the observation of generalized thermodynamic ensembles. This points to a natural emergence of classical statistical properties from the microscopic unitary quantum evolution, and lays the groundwork for a universal framework of non-equilibrium physics. The thesis investigates a central question that is highly contested in quantum physics: how and to which extent does an isolated quantum many-body system relax? This question arises in many diverse areas of physics, and many of the open problems appear at vastly different energy, time and length scales, ranging from high-energy physics and cosmology to condensed matter and quantum information. A key challenge in attempting to answer this question is the scarcity of quantum many-body systems that are both well isolated from the environment and accessible for experimental study.
Nonlinear Time Series Analysis with R provides a practical guide to emerging empirical techniques allowing practitioners to diagnose whether highly fluctuating and random appearing data are most likely driven by random or deterministic dynamic forces. It joins the chorus of voices recommending 'getting to know your data' as an essential preliminary evidentiary step in modelling. Time series are often highly fluctuating with a random appearance. Observed volatility is commonly attributed to exogenous random shocks to stable real-world systems. However, breakthroughs in nonlinear dynamics raise another possibility: highly complex dynamics can emerge endogenously from astoundingly parsimonious deterministic nonlinear models. Nonlinear Time Series Analysis (NLTS) is a collection of empirical tools designed to aid practitioners detect whether stochastic or deterministic dynamics most likely drive observed complexity. Practitioners become 'data detectives' accumulating hard empirical evidence supporting their modelling approach. This book is targeted to professionals and graduate students in engineering and the biophysical and social sciences. Its major objectives are to help non-mathematicians - with limited knowledge of nonlinear dynamics - to become operational in NLTS; and in this way to pave the way for NLTS to be adopted in the conventional empirical toolbox and core coursework of the targeted disciplines. Consistent with modern trends in university instruction, the book makes readers active learners with hands-on computer experiments in R code directing them through NLTS methods and helping them understand the underlying logic (please see www.marco.bittelli.com). The computer code is explained in detail so that readers can adjust it for use in their own work. The book also provides readers with an explicit framework - condensed from sound empirical practices recommended in the literature - that details a step-by-step procedure for applying NLTS in real-world data diagnostics.
This book addresses the application of methods used in statistical physics to complex systems-from simple phenomenological analogies to more complex aspects, such as correlations, fluctuation-dissipation theorem, the concept of free energy, renormalization group approach and scaling. Statistical physics contains a well-developed formalism that describes phase transitions. It is useful to apply this formalism for damage phenomena as well. Fractals, the Ising model, percolation, damage mechanics, fluctuations, free energy formalism, renormalization group, and scaling, are some of the topics covered in Statistical Physics of Phase Transitions.
Most interesting and difficult problems in equilibrium statistical mechanics concern models which exhibit phase transitions. For graduate students and more experienced researchers this book provides an invaluable reference source of approximate and exact solutions for a comprehensive range of such models. Part I contains background material on classical thermodynamics and statistical mechanics, together with a classification and survey of lattice models. The geometry of phase transitions is described and scaling theory is used to introduce critical exponents and scaling laws. An introduction is given to finite-size scaling, conformal invariance and Schramm-Loewner evolution. Part II contains accounts of classical mean-field methods. The parallels between Landau expansions and catastrophe theory are discussed and Ginzburg--Landau theory is introduced. The extension of mean-field theory to higher-orders is explored using the Kikuchi--Hijmans--De Boer hierarchy of approximations. In Part III the use of algebraic, transformation and decoration methods to obtain exact system information is considered. This is followed by an account of the use of transfer matrices for the location of incipient phase transitions in one-dimensionally infinite models and for exact solutions for two-dimensionally infinite systems. The latter is applied to a general analysis of eight-vertex models yielding as special cases the two-dimensional Ising model and the six-vertex model. The treatment of exact results ends with a discussion of dimer models. In Part IV series methods and real-space renormalization group transformations are discussed. The use of the De Neef-Enting finite-lattice method is described in detail and applied to the derivation of series for a number of model systems, in particular for the Potts model. The use of Pad\'e, differential and algebraic approximants to locate and analyze second- and first-order transitions is described. The realization of the ideas of scaling theory by the renormalization group is presented together with treatments of various approximation schemes including phenomenological renormalization. Part V of the book contains a collection of mathematical appendices intended to minimise the need to refer to other mathematical sources.
Statistical mechanics is concerned with defining the thermodynamic properties of a macroscopic sample in terms of the properties of the microscopic systems of which it is composed. The previous book Introduction to Statistical Mechanics provided a clear, logical, and self-contained treatment of equilibrium statistical mechanics starting from Boltzmann's two statistical assumptions, and presented a wide variety of applications to diverse physical assemblies. An appendix provided an introduction to non-equilibrium statistical mechanics through the Boltzmann equation and its extensions. The coverage in that book was enhanced and extended through the inclusion of many accessible problems. The current book provides solutions to those problems. These texts assume only introductory courses in classical and quantum mechanics, as well as familiarity with multi-variable calculus and the essentials of complex analysis. Some knowledge of thermodynamics is also assumed, although the analysis starts with an appropriate review of that topic. The targeted audience is first-year graduate students and advanced undergraduates, in physics, chemistry, and the related physical sciences. The goal of these texts is to help the reader obtain a clear working knowledge of the very useful and powerful methods of equilibrium statistical mechanics and to enhance the understanding and appreciation of the more advanced texts. |
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