The study of thermodynamics is often limited to classical thermodynamics where minimal laws and concepts lead to a wealth of equations and applications. The resultant equations best describe systems at equilibrium with no temporal or s- tial parameters. The equations do, however, often provide accurate descriptions for systems close to equilibrium. . Statistical thermodynamics produces the same equilibrium information starting with the microscopic properties of the atoms or molecules in the system that correlates with the results from macroscopic classical thermodynamics. Because both these disciplines develop a wealth of information from a few starting postulates, e. g. , the laws of thermodyamics, they are often introduced as independent disciplines. However, the concepts and techniques dev- oped for these disciplines are extremely useful in many other disciplines. This book is intended to provide an introduction to these disciplines while revealing the connections between them. Chemical kinetics uses the statistics and probabilities developed for statistical thermodynamics to explain the evolution of a system to equilibrium. Irreversible thermodynamics, which is developed from the equations of classical thermodyn- ics, centers on distance-dependent forces, and time-dependent ?uxes. The force ?ux equations of irreversible thermodynamics lead are generated from the intensive and extensive variables of classical thermodynamics. These force ?ux equations lead, in turn, to transport equations such as Fick's ?rst law of diffusion and the Nernst Planck equation for electrochemical transport. The book illustrates the concepts using some simple examples.

As an introductory account of the theory of phase transitions and critical phenomena, this book reflects lectures given by the authors to graduate students at their departments and is thus classroom-tested to help beginners enter the field. Most parts are written as self-contained units and every new concept or calculation is explained in detail without assuming prior knowledge of the subject. The book significantly enhances and revises a Japanese version which is a bestseller in the Japenese market and is considered a standard textbook in the field. It contains new pedagogical presentations of field theory methods, including a chapter on conformal field theory, and various modern developments hard to find in a single textbook on phase transitions. Exercises are presented as the topics develop, with solutions found at the end of the book, making the usefil for self-teaching, as well as for classroom learning.

Hydrogen in Intermetallics I is the first of two volumes aiming to provide atutorial introduction to the general topic of hydrogen in intermetallic compounds and alloys. In the present volume, a series of chapters, each written by two experts in the field, gives a comprehensive review of thefollowing areas: -preparation of intermetallics and their hydrides on a laboratory and industrial scale; - thermodynamic properties; -crystal and magnetic structure; - electronic properties; - heat of formation models; - magnetism and superconductivity.

In this comprehensive text a systematic numerical and analytical treatment of the procedures for reducing complicated systems to a simplified reaction mechanism is presented. The results of applying the reduced reaction mechanism to a one-dimensional laminar flame are discussed. A set of premixed and non-premixed methane-air flames with simplified transport and skeletal chemistry are employed as test problems that are used later on to evaluate the results and assumptions in reduced reaction networks. The first four chapters form a short tutorial on the procedures used in formulating the test problems and in reducing reaction mechanisms by applying steady-state and partial-equilibrium approximations. The final six chapters discuss various aspects of the reduced chemistry problem for premixed and nonpremixed combustion.

In this volume the author gives a detailed presentation of his theory of multiphase mixtures with structure. The book also addresses students, and in addition encourages further research. Based on the concept of averaging the field equations, conservation and balance equations are developed. A material deformation postulate leads to structured mixtures. The resulting model is compared with those in use elsewhere. The final chapters are devoted to constitutive theory and constitutive equations. In particular, two-phase mixtures are treated in some detail.

This thesis presents a novel coarse-grained model of DNA, in which bases are represented as rigid nucleotides. The model is shown to quantitatively reproduce many phenomena, including elastic properties of the double-stranded state, hairpin formation in single strands and hybridization of pairs of strands to form duplexes, the first time such a wide range of properties has been captured by a coarse-grained model. The scope and potential of the model is demonstrated by simulating DNA tweezers, an iconic nanodevice, and a two-footed DNA walker - the first time that coarse-grained modelling has been applied to dynamic DNA nanotechnology.

The book is about the key elements required for designing, building and controlling effective artificial swarms comprised of multiple moving physical agents. Therefore this book presents the fundamentals of each of those key elements in the particular frame of dynamic swarming, specifically exposing the profound connections between these elements and establish some general design principles for swarming behaviors. This scientific endeavor requires an inter-disciplinary approach: biomimetic inspiration from ethology and ecology, study of social information flow, analysis of temporal and adaptive signaling network of interaction, considerations of control of networked real-time systems, and lastly, elements of complex adaptive dynamical systems. This book offers a completely new perspective on the scientific understanding of dynamic collective behaviors thanks to its multi-disciplinary approach and its focus on artificial swarm of physical agents. Two of the key problems in understanding the emergence of swarm intelligent behaviors are identifying the social interaction rules a.k.a. the behavioral algorithm and uncovering how information flows between swarming agents. While most books about swarm dynamics have been focusing on the former, this book emphasizes the much-less discussed topic of distributed information flow, always with the aim of establishing general design principles.

There are many examples of cooperation in Nature: cells cooperate to form tissues, organs cooperate to form living organisms, and individuals cooperate to raise their offspring or to hunt. However, why cooperation emerges and survives in hostile environments, when defecting would be a much more profitable short-term strategy, is a question that still remains open. During the past few years, several explanations have been proposed, including kin and group selection, punishment and reputation mechanisms, or network reciprocity. This last one will be the center of the present study. The thesis explores the interface between the underlying structure of a given population and the outcome of the cooperative dynamics taking place on top of it, (namely, the Prisoner's Dilemma Game). The first part of this work analyzes the case of a static system, where the pattern of connections is fixed, so it does not evolve over time. The second part develops two models for growing topologies, where the growth and the dynamics are entangled.

What are the principles that keep our society together? This question is even more difficult to answer than the long-standing question, what are the forces that keep our world together. However, the social challenges of humanity in the 21st century ranging from the financial crises to the impacts of globalization, require us to make fast progress in our understanding of how society works, and how our future can be managed in a resilient and sustainable way. This book can present only a few very first steps towards this ambitious goal. However, based on simple models of social interactions, one can already gain some surprising insights into the social, ``macro-level'' outcomes and dynamics that is implied by individual, ``micro-level'' interactions. Depending on the nature of these interactions, they may imply the spontaneous formation of social conventions or the birth of social cooperation, but also their sudden breakdown. This can end in deadly crowd disasters or tragedies of the commons (such as financial crises or environmental destruction). Furthermore, we demonstrate that classical modeling approaches (such as representative agent models) do not provide a sufficient understanding of the self-organization in social systems resulting from individual interactions. The consideration of randomness, spatial or network interdependencies, and nonlinear feedback effects turns out to be crucial to get fundamental insights into how social patterns and dynamics emerge. Given the explanation of sometimes counter-intuitive phenomena resulting from these features and their combination, our evolutionary modeling approach appears to be powerful and insightful. The chapters of this book range from a discussion of the modeling strategy for socio-economic systems over experimental issues up the right way of doing agent-based modeling. We furthermore discuss applications ranging from pedestrian and crowd dynamics over opinion formation, coordination, and cooperation up to conflict, and also address the response to information, issues of systemic risks in society and economics, and new approaches to manage complexity in socio-economic systems. Selected parts of this book had been previously published in peer reviewed journals.

An understanding of statistical thermodynamic molecular theory is fundamental to the appreciation of molecular solutions. This complex subject has been simplified by the authors with down-to-earth presentations of molecular theory. Using the potential distribution theorem (PDT) as the basis, the text provides a discussion of practical theories in conjunction with simulation results. The authors discuss the field in a concise and simple manner, illustrating the text with useful models of solution thermodynamics and numerous exercises. Modern quasi-chemical theories that permit statistical thermodynamic properties to be studied on the basis of electronic structure calculations are given extended development, as is the testing of those theoretical results with ab initio molecular dynamics simulations. The book is intended for students taking up research problems of molecular science in chemistry, chemical engineering, biochemistry, pharmaceutical chemistry, nanotechnology and biotechnology.

This unique book provides a fundamental introduction to all aspects of modern plasma chemistry. The book describes mechanisms and kinetics of chemical processes in plasma, plasma statistics, thermodynamics, fluid mechanics, and electrodynamics, as well as all major electric discharges applied in plasma chemistry. The book considers most of the major applications of plasma chemistry from electronics to thermal coatings, from treatment of polymers to fuel conversion and hydrogen production, and from plasma metallurgy to plasma medicine. The book can be helpful to engineers, scientists, and students interested in plasma physics, plasma chemistry, plasma engineering, and combustion, as well as in chemical physics, lasers, energy systems, and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics as well as a lot of convenient numerical formulas for practical calculations related to specific plasma-chemical processes and applications. The book contains a large number of problems and concept questions that are helpful in university courses related to plasma, lasers, combustion, chemical kinetics, statistics and thermodynamics, and high-temperature and high-energy fluid mechanics.

This book provides a largely self-contained and broadly accessible exposition on two cosmological applications of algebraic quantum field theory (QFT) in curved spacetime: a fundamental analysis of the cosmological evolution according to the Standard Model of Cosmology; and a fundamental study of the perturbations in inflation. The two central sections of the book dealing with these applications are preceded by sections providing a pedagogical introduction to the subject. Introductory material on the construction of linear QFTs on general curved spacetimes with and without gauge symmetry in the algebraic approach, physically meaningful quantum states on general curved spacetimes, and the backreaction of quantum fields in curved spacetimes via the semiclassical Einstein equation is also given. The reader should have a basic understanding of General Relativity and QFT on Minkowski spacetime, but no background in QFT on curved spacetimes or the algebraic approach to QFT is required.>

Time asymmetric phenomena are successfully predicted by statistical mechanics. Yet the foundations of this theory are surprisingly shaky. Its explanation for the ease of mixing milk with coffee is incomplete, and even implies that un-mixing them should be just as easy. In this book the authors develop a new conceptual foundation for statistical mechanics that addresses this difficulty. Explaining the notions of macrostates, probability, measurement, memory, and the arrow of time in statistical mechanics, they reach the startling conclusion that Maxwell's Demon, the famous perpetuum mobile, is consistent with the fundamental physical laws. Mathematical treatments are avoided where possible, and instead the authors use novel diagrams to illustrate the text. This is a fascinating book for graduate students and researchers interested in the foundations and philosophy of physics.

Computational Fluid Dynamics has now grown into a multidisciplinary activity with considerable industrial applications. The papers in this volume bring out the current status and future trends in CFD very effectively. They cover numerical techniques for solving Euler and Navier-Stokes equations and other models of fluid flow, along with a number of papers on applications. Besides the 88 contributed papers by research workers from all over the world, the book also includes 6 invited lectures from distinguished scientists and engineers.

This monograph presents an integrated perspective of the wide range of phenomena and processes applicable to the study of transport of species in porous materials. In order to formulate the entire range of porous media and their uses, this book gives the basics of continuum mechanics, thermodynamics, seepage and consolidation and diffusion, including multiscale homogenization methods. The particular structure of the book has been chosen because it is essential to be aware of the true properties of porous materials particularly in terms of nano, micro and macro mechanisms. This book is of pedagogical and practical importance to the fields covered by civil, environmental, nuclear and petroleum engineering and also in chemical physics and geophysics as it relates to radioactive waste disposal, geotechnical engineering, mining and petroleum engineering and chemical engineering.

The thesis deals with averaging dynamics in a multiagent networked system, which is a main mechanism for diffusing the information over such networks. It arises in a wide range of applications in engineered physical networks (such as mobile communication and sensor networks), as well as social and economic networks. The thesis provides in depth study of stability and other phenomena characterizing the limiting behavior of both deterministic and random averaging dynamics. By developing new concepts, and using the tools from dynamic system theory and non-negative matrix theory, several novel fundamental results are rigorously developed. These contribute significantly to our understanding of averaging dynamics as well as to non-negative random matrix theory. The exposition, although highly rigorous and technical, is elegant and insightful, and accompanied with numerous illustrative examples, which makes this thesis work easily accessible to those just entering this field and will also be much appreciated by experts in the field.

Local and global spatial coupling mechanisms form the basis of transport processes that are of fundamental importance for the occurrence and the dynamic evolution of patterns on a mesoscopic and macroscopic scale. The present volume deals with these concepts and investigates applications in the fields of biophysics and chemistry.

Neural-network models for event analysis are widely used in experimental high-energy physics, star/galaxy discrimination, control of adaptive optical systems, prediction of nuclear properties, fast interpolation of potential energy surfaces in chemistry, classification of mass spectra of organic compounds, protein-structure prediction, analysis of DNA sequences, and design of pharmaceuticals. This book, devoted to this highly interdisciplinary research area, addresses scientists and graduate students. The pedagogically written review articles range over a variety of fields including astronomy, nuclear physics, experimental particle physics, bioinformatics, linguistics, and information processing.

One of the driving forces behind much of modern science and technology is the desire to foresee and thereby control the future. In recent years, however, it has become clear that, even in a deterministic world, there is alimit to the accuracy with which we can predict the future. This book details, in a largely nontechnical style, the extent to which we can predict the future development of various physical, biological and socio-economic processes.

This companion provides a collection of frequently needed numerical data as a convenient desk-top or pocket reference for atmospheric scientists as well as a concise source of information for others interested in this matter. The material contained in this book was extracted from the recent and the past scientific literature; it covers essentially all aspects of atmospheric chemistry. The data are presented primarily in the form of annotated tables while any explanatory text is kept to a minimum. In this condensed form of presentation, the volume may serve also as a supplement to many textbooks used in teaching the subject at various universities.

Peter Warneck, a physical chemist specializing in atmospheric chemistry, received the diploma in 1954 and the doctorate in 1956 at the university in Bonn, Germany. In 1959, following several postdoctoral assignments, he joined the GCA Corporation in Bedford, Massachusetts, where he explored elementary processes in the atmospheres of the earth and other planets. He returned to Germany in 1970 to head the chemical kinetics group in the Air Chemistry Division of the Max-Planck-Institute for Chemistry in Mainz. In 1974 he also became professor of physical chemistry at the university in Mainz. In 1991, following German reunification, Warneck was appointed the founding director of the new Institute for Tropospheric Research in Leipzig. He served in this position parallel to his activities in Mainz until official retirement. Warneck s research included laboratory studies of chemical mechanisms and photochemistry as well as the development of analytical techniques for field measurements. Since 1990, his interests are focused on chemical reactions in clouds.

Jonathan Williams is an atmospheric chemist. He received his BSc in Chemistry and French and his Ph.D. in Environmental Science from the University of East Anglia, England. Between 1995-1997 he worked as a postdoctoral researcher at the NOAA Aeronomy laboratory in Boulder, USA, and from 1998 to present as a member of staff at the Max Planck Institute for Chemistry, Mainz, Germany. He has participated in many international field measurement campaigns on aircraft, ships and at ground stations. Dr Williams is currently an editor on three atmospheric chemistry journals. His present research involves investigating the chemistry of reactive organic species in the atmosphere, in particular over forested ecosystems and in the marine boundary layer. Dr Williams leads a research group focussed specifically on Volatile Organic Compounds (VOC) at the Max Planck Institute and in 2008 he was made an honorary Reader at the University of East Anglia, UK."

This book treats the classical problem of gravitational physics within Einstein's theory of general relativity. It presents basic principles and equations needed to describe rotating fluid bodies, as well as black holes in equilibrium. It then goes on to deal with a number of analytically tractable limiting cases, placing particular emphasis on the rigidly rotating disc of dust. The book concludes by considering the general case using powerful numerical methods that are applied to various models, including the classical example of equilibrium figures of constant density. Researchers in general relativity, mathematical physics, and astrophysics will find this a valuable reference book on the topic. A related website containing codes for calculating various figures of equilibrium is available at www.cambridge.org/9781107407350.

For the present edition four chapters have been added which form the fourth 1 part at the end of the book . Entitled The triumph of neoliberalism , the new partexplains how theimplementation worldwide oftheneoliberal agenda paved the way for the present crisis. As a matter of fact, the evidence provided in chapter 9 suggests that the present crisis already began to build up in the mid-1970s. It is around 1975 that (real) US wages reached a peak-level they would never regain in f- lowing decades. It was also around 1975 that the number of strikes began to fall sharply. The mid-1970s also marked the beginning of a huge in ow of immigrants (in large part of Hispanic origin) into the United States. The in ated supply of labor depressed wages and this had the consequence that consumption could be increased only by an unprecedented development of credit. Perhaps the reader may think that to blame the prevailing economic system for the unfolding depression is a fairly common and all too easy temptation.

We started our work on theoretical methods in the phys ics of high pressures (in connec tion with geophysical applications) in 1956, and we immediately encountered many problems. Naturally, we searched the published Iiterature for solutions to these problems but whenever we failed to find a solution or when the solution did not satisfy us, we attempted to solve the problern ourselves. We realized that other investigators working in the physics of high pres sures would probably encounter the same problems and doubts. Therefore, we decided to write this book in order to save our colleagues time and effort. Apart from the descriptions of ex perimental methods, the book deals only with those problems which we encountered in our own work. Allproblems in high-pressure physics have, at present, only approximate solutions, which are very rough. Therefore, it is not surprising that different investigators approach the same problems in different ways. Our approach does not prejudge the issue and we are fully aware that there are other points of view. Our aim was always to solve a glven problern on a physical basis. For example, the concept of the Gruneisenparameter needs further develop ment but it is based on reliable physical ideas. On the other hand, Simon's equation for the melting curve has, in our opinion, no clear physical basis and is purely empirical. Equations of this type are useful in systematic presentation of the experimental material but they are un suitable for any major extrapolation.

Mechanics, Motion Control, Sensing and Programming, Synthesis and Design, Legged Locomotion and Biomechanical Aspects of Robots and Manipulators - world view of the state of the art. Characterization: This volume presents the latest contribution to the theory and practice of modern robotics given by the world recognized scientists from Australia, Canada, Europe, Japan, Mexico, Singapore and USA.

The investigation of nonlinear wave phenomena has been one of the main direc tions of research in optics for the last few decades. Soliton concepts applied to the description of intense electromagnetic beams and ultrashort pulse propagation in various media have contributed much to this field. The notion of solitons has proved to be very useful in describing wave processes in hydrodynamics, plasma physics and condensed matter physics. Moreover, it is also of great importance in optics for ultrafast information transmission and storage, radiation propagation in resonant media, etc. In 1973, Hasegawa and Tappert made a significant contribution to optical soliton physics when they predicted the existence of an envelope soliton in the regime of short pulses in optical fibres. In 1980, Mollenauer et al. conducted ex periments to elucidate this phenomenon. Since then the theory of optical solitons as well as their experimental investigation has progressed rapidly. The effects of inhomogeneities of the medium and energy pumping on optical solitons, the interaction between optical solitons and their generation in fibres, etc. have all been investigated and reported. Logical devices using optical solitons have been developed; new types of optical solitons in media with Kerr-type nonlinearity and in resonant media have been described."