Much data has been collected from experiments on the kinetios of
radical reactions in different solids, but to date, this has not
been presented in book format in a thorough and comprehensive way.
This book makes the experimental data accessible for all chemists
involved in these reactions. Various models of the tunnel atom
transfer are analyzed in order to explain the kinetic isotope
effect in solid phase reactions and photoinitiated radical
reactions are inspected for the kinetic non-equivalence of
particles and factors affecting their reactivity. Topics covered
include:
* kinetic description of reactions with dispersion particles in
reactivity
* the influence of space-orientation factors on reactivity in cage
reactions
* the influence of molecular dynamics on the kinetics of elementary
reactions
* the effect of structural-physical modification on kinetics of
cage radical reactions
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