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Symmetry in Inorganic and Coordination Compounds - A Student's Guide to Understanding Electronic Structure (Hardcover, 1st ed. 2021)
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Symmetry in Inorganic and Coordination Compounds - A Student's Guide to Understanding Electronic Structure (Hardcover, 1st ed. 2021)
Series: Lecture Notes in Chemistry, 106
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This book addresses the nature of the chemical bond in inorganic
and coordination compounds. In particular, it explains how general
symmetry rules can describe chemical bond of simple inorganic
molecules. Since the complexity of studying even simple molecules
requires approximate methods, this book introduces a quantum
mechanical treatment taking into account the geometric
peculiarities of the chemical compound. In the case of inorganic
molecules, a convenient approximation comes from symmetry, which
constrains both the electronic energies and the chemical bonds. The
book also gives special emphasis on symmetry rules and compares the
use of symmetry operators with that of Hamiltonian operators. Where
possible, the reactivity of molecules is also rationalized in terms
of these symmetry properties. As practical examples, electronic
spectroscopy and magnetism give experimental confirmation of the
predicted electronic energy levels. Adapted from university lecture
course notes, this book is the ideal companion for any inorganic
chemistry course dealing with group theory.
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