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Books > Professional & Technical > Industrial chemistry & manufacturing technologies > Industrial chemistry > Chemical engineering
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Advances in Friedel-Crafts Acylation Reactions - Catalytic and Green Processes (Paperback)
Loot Price: R2,404
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Advances in Friedel-Crafts Acylation Reactions - Catalytic and Green Processes (Paperback)
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Used in the production of a wide number of fine chemicals and
pharmaceuticals, the Friedel-Crafts acylation reaction represents a
synthetic process of great interest to organic chemists of academia
and industry. Nearly 40 years since the last major treatise on the
topic and reflecting the growing emphasis on green technology,
Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green
Processes focuses on how to make this reaction more economically
and environmentally friendly by using green acylating conditions,
thus minimizing the formation of waste and decreasing production
costs. Divided into four parts, the book explores stoichiometric
acylations, catalytic homogeneous acylations, catalytic
heterogeneous acylations, and phenol acylations. It is structured
according to the role played by the catalyst in the activation of
reagents as well as in the different modes of regioselectivity
encountered in the acylation of arenes, aromatic ethers, and
phenols. Incorporating examples of all acid-catalyzed
Friedel-Crafts acylation reactions, the text considers classic
Lewis and Broensted acid types along with more innovative and
advanced multicomponent superacid catalysts. These range from rare
earth triflates or triflimides and their combination with ionic
liquids to metal-promoted zeolites and zeotypes, clays, polymetal
oxides, sulfated zirconia, heteropoly acids, and Nafion. The book
emphasizes the major industrial applications, providing a critical
assessment of the differences, advantages, and disadvantages of
homogeneous and heterogeneous catalysis. Helping readers to better
understand the mechanism of the Friedel-Crafts acylation, the
examples in the book substantiate the development of more effective
catalysts and more selective processes achieved during the last few
decades, enabling industry to embark on a safer and more efficient
synthesis of aromatic ketones for the manufacture of a wide array
of products.
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