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Dual-Phase Depolarization Analysis - Interactive Coupling in the Amorphous State of Polymers (Hardcover)
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Dual-Phase Depolarization Analysis - Interactive Coupling in the Amorphous State of Polymers (Hardcover)
Series: De Gruyter Reference
Expected to ship within 12 - 17 working days
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This book focuses on the characterization of the amorphous phase of
polymers, whether they are pure amorphous or semi-crystalline ones,
above Tg or below Tg, by studying the relaxation of dipoles and
space charges naturally found in their structure after they have
been activated by the application of a voltage field. The
experimental deconvolution of the relaxation modes responsible for
internal motion in the amorphous phase is coupled with a
mathematical procedure (Thermal-Windowing Deconvolution-TWD) that
leads to the understanding of their coupling characteristics which,
it is shown, relate to the state of the material itself, for
instance its non-equilibrium state or its internal stress for
matter belonging to interfaces between aggregated or dispersed
phases. Describes quantitatively the Thermal Stimulated
Depolarization techniques of polymer characterization (TSD, TWD),
i.e. how to decouple the relaxation modes collectively interacting
(interactive coupling) and relate it to the thermodynamic
properties of the amorphous phase. Understands the results of
depolarization in terms of the new physics of polymer interactions:
the Dual-Phase model, here applied to the dipoles-space charge
dynamics. Provides a roaster of CASE STUDIES: practical
applications of the TSD and TWD characterization techniques to
describe coupled molecular motions in resins, medical tissues,
wood, blends and block copolymers interfaces, rubbers, can
coatings, internal stress in molded parts, etc
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