This thesis gives a thorough account of the development of
iron-catalysed hydrosilylation, hydroboration and hydromagnesiation
reactions. With extraordinary referencing and scientific argument,
Mark Greenhalgh describes the development of methodologies which
require only commercially available materials and non-specialised
techniques. The intention of this approach is to ensure the science
can be adopted widely by the chemical community. In addition to an
insight into the processes involved in methodology development,
Greenhalgh discusses and determines the relevant reaction
mechanisms. This thesis provides not only the most thorough review
of the area, but offers a level of insight well beyond that
expected from a Ph.D. student. The work in this thesis has been
published at the highest level, and the results and ideas have led
to 3 industry-funded Ph.D. studentships and grant income in excess
of GBP1 million.
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