Molecular Conformation and Organic Photochemistry - Time-resolved Photoionization Studies (Paperback, 2012 ed.)

Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecule relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation. Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics.

General

Imprint:	Springer-Verlag
Country of origin:	Germany
Series:	Springer Theses
Release date:	June 2014
First published:	2012
Authors:	Rasmus Y. Brogaard
Dimensions:	235 x 155 x 8mm (L x W x T)
Format:	Paperback
Pages:	124
Edition:	2012 ed.
ISBN-13:	978-3-642-42674-2
Categories:	Books > Science & Mathematics > Physics > Nuclear structure physics Books > Science & Mathematics > Chemistry > Physical chemistry > General Books > Science & Mathematics > Chemistry > Analytical chemistry > Qualitative analytical chemistry > Chemical spectroscopy, spectrochemistry > General
LSN:	3-642-42674-3
Barcode:	9783642426742

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