The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

This book discusses innovations in the field of hybrid energy storage systems (HESS) and covers the durability, practicality, cost-effectiveness, and utility of a HESS. It demonstrates how the coupling of two or more energy storage technologies can interact with and support renewable energy power systems. Different structures of stand-alone renewable energy power systems with hybrid energy storage systems such as passive, semi-active, and active hybrid energy storage systems are examined. A detailed review of the state-of-the-art control strategies, such as classical control strategies and intelligent control strategies for renewable energy power systems with hybrid energy storage systems are highlighted. The future trends for combination and control of the two systems are also discussed.

CMOS DC-DC Converters aims to provide a comprehensive dissertation on the matter of monolithic inductive Direct-Current to Direct-Current (DC-DC) converters. For this purpose seven chapters are defined which will allow the designer to gain specific knowledge on the design and implementation of monolithic inductive DC-DC converters, starting from the very basics.

Due to their environmental and efficiency characteristics fuel cells are promising technological solutions for many energy related applications (stationary power generation, vehicle propulsion, portable equipment). This book describes the economic dynamics of fuel cells by analyzing their diffusion perspectives as well as the strategic and organisational arrangements designed to promote their development. The costs, risks and economic stakes of fuel cell technologies require both a sustained involvement from public entities and the setting up of innovation networks with a large variety of heterogeneous actors. This context corresponds to a new space for technological competition located at the intersection between firms, networks and national/regional systems of innovation. The book presents a comprehensive analysis of this cooperation/competition phenomenon through different theoretical and empirical investigations. 

The field of solid state ionics is multidisciplinary in nature. Chemists, physicists, electrochimists, and engineers all are involved in the research and development of materials, techniques, and theoretical approaches. This science is one of the great triumphs of the second part of the 20th century. For nearly a century, development of materials for solid-state ionic technology has been restricted. During the last two decades there have been remarkable advances: more materials were discovered, modem technologies were used for characterization and optimization of ionic conduction in solids, trial and error approaches were deserted for defined predictions. During the same period fundamental theories for ion conduction in solids appeared. The large explosion of solid-state ionic material science may be considered to be due to two other influences. The first aspect is related to economy and connected with energy production, storage, and utilization. There are basic problems in industrialized countries from the economical, environmental, political, and technological points of view. The possibility of storing a large amount of utilizable energy in a comparatively small volume would make a number of non-conventional intermittent energy sources of practical convenience and cost. The second aspect is related to huge increase in international relationships between researchers and exchanges of results make considerable progress between scientists; one find many institutes joined in common search programs such as the material science networks organized by EEC in the European countries.

Graphite intercalation compounds are a new class of electronic materials that are classified as graphite-based host guest systems. They have specific structural features based on the alternating stacking of graphite and guest intercalate sheets. The electronic structures show two-dimensional metallic properties with a large variety of features including superconductivity. They are also interesting from the point of two-dimensional magnetic systems. This book presents the synthesis, crystal structures, phase transitions, lattice dynamics, electronic structures, electron transport properties, magnetic properties, surface phenomena, and applications of graphite intercalation compounds. The applications covered include batteries, highly conductive graphite fibers, exfoliated graphite and intercalated fullerenes and nanotubes.

A lithium-ion battery comprises essentially three components: two intercalation compounds as positive and negative electrodes, separated by an ionic-electronic electrolyte. Each component is discussed in sufficient detail to give the practising engineer an understanding of the subject, providing guidance on the selection of suitable materials in actual applications. Each topic covered is written by an expert, reflecting many years of experience in research and applications. Each topic is provided with an extensive list of references, allowing easy access to further information. Readership: Research students and engineers seeking an expert review. Graduate courses in electrical drives can also be designed around the book by selecting sections for discussion. The coverage and treatment make the book indispensable for the lithium battery community.

This book presents contributions to the topics of materials for energy infrastructure with a focus on data and informatics for materials. This spectrum of topics has been chosen because challenges in terms of materials are identified to lie in transport and storage of energy, adequate supply of food and water, well-working infrastructure, materials for medical application and health, efficient use of scarce resources or elements and alternate materials solutions as well as recycling. The contributions were invited at the 4th WMRIF Young Materials Scientist Workshop held at the National Institute for Standards and Technology (NIST) in Boulder, Colorado, USA during September 8-10, 2014.

Proton exchange membrane (PEM) fuel cells, including H2/O2 (air) and methanol/O2 (air) fuel cells, are promising clean energy converting devices with high efficiency and low to zero emissions. Such power sources can be used in transportation, stationary, portable and micro power applications. The key components of these fuel cells are catalysts and catalyst layers.

PEM Fuel Cell Electrocatalysts and Catalyst Layers covers all of the fundamental aspects and applications of this field. The opening chapters introduce the essential topics on electrochemical theory and fuel cell catalysis, including: electrode thermodynamics, kinetics, and mass transfer; electrode/electrolyte interface electrocatalysis; electrocatalytic reactions, including O2 reduction and H2/CH3OH oxidations; quantum chemistry simulations of catalyst activity; catalyst contamination; spectroscopic methods for catalysis research; porous gas electrode theory; and catalyst layers and modeling. Later chapters investigate the synthesis, characterization, and activity validation of PEM fuel cell catalysts. All fuel cell related catalysts are reviewed, including noble and non-noble catalysts and their preparation/performance. Further chapters describe in detail the integration of the electrocatalyst/catalyst layers into the fuel cell, and their performance validation, including; catalyst layer structure function and optimization, catalyst degradation and diagnosis, and strategies to mitigate the failure modes.

PEM Fuel Cell Electrocatalysts and Catalyst Layers provides a comprehensive, in-depth survey of PEM fuel cell electrocatalysts and catalyst layers, presented by internationally renowned fuel cell scientists. Researchers and engineers in the fuel cell industry will find this book a valuable resource, as will students of electrochemical engineering and catalyst synthesis.

PEM Fuel Cell Failure Mode Analysis presents a systematic analysis of PEM fuel cell durability and failure modes. It provides readers with a fundamental understanding of insufficient fuel cell durability, identification of failure modes and failure mechanisms of PEM fuel cells, fuel cell component degradation testing, and mitigation strategies against degradation.

The first several chapters of the book examine the degradation of various fuel cell components, including degradation mechanisms, the effects of operating conditions, mitigation strategies, and testing protocols. The book then discusses the effects of different contamination sources on the degradation of fuel cell components and explores the relationship between external environment and the degradation of fuel cell components and systems. It also reviews the correlation between operational mode, such as start-up and shut-down, and the degradation of fuel cell components and systems. The last chapter explains how the design of fuel cell hardware relates to failure modes.

Written by international scientists active in PEM fuel cell research, this volume is enriched with practical information on various failure modes analysis for diagnosing cell performance and identifying failure modes of degradation. This in turn helps in the development of mitigation strategies and the increasing commercialization of PEM fuel cells.

Publisher's Note: Products purchased from Third Party sellers are not guaranteed by the publisher for quality, authenticity, or access to any online entitlements included with the product. Thoroughly revised, comprehensive coverage of battery technology, characteristics, and applications This fully updated guide offers complete coverage of batteries and battery usage from classic designs to emerging technologies. Compiled by a pioneer in secondary lithium batteries, the book contains all the information needed to solve engineering problems and make proper battery selections. You will get in-depth descriptions of the principles, properties, and performance specifications of every major battery type. Linden's Handbook of Batteries, Fifth Edition, contains cutting-edge data and equations, design specifications, and troubleshooting techniques from international experts. New chapters discuss renewable energy systems, battery failure analysis, lithium-ion battery technology, materials, and component design. Recent advances in smartphones and hybrid car batteries are clearly explained, including maximizing re-chargeability, reducing cost, improving safety, and lessening environmental impact. Coverage includes: *Electricity, electrochemistry, and batteries*Raw materials*Battery components*Principles of electrochemical cell operations*Battery product overview*Electrochemical cell designs (platform technologies)*Primary batteries*Secondary batteries*Miscellaneous and specialty batteries*Battery applications*Battery industry infrastructure

This book focuses on nanocarbons (carbon nanotubes, graphene, nanoporous carbon, and carbon black) and related materials for energy conversion, including fuel cells (predominately proton exchange membrane fuel cells [PEMFC]), Li-ion batteries, and supercapacitors. Written by a group of internationally recognized researchers, it offers an in-depth review of the structure, properties, and functions of nanocarbons, and summarizes recent advances in the design, fabrication and characterization of nanocarbon-based catalysts for energy applications. As such, it is an invaluable resource for graduate students, academics and industrial scientists interested in the areas of nanocarbons, energy materials for fuel cells, batteries and supercapacitors as well as materials design, and supramolecular science.

This book contains an in-depth analysis of thermoelectric theory, an overview of present day thermoelectric materials and devices, and as an updated source of information on the most studied recent thermoelectric materials developments. The main emphasis is on a basic understanding of the concepts and experimental techniques needed to propel researchers towards new and novel classes of thermoelectric materials with enhanced properties. The aim is to assist researchers in the field. The text is an expanded edition of a previous text "Electronic Refrigeration" by one of the authors, Julian Goldsmid. Half of the text is devoted to research that has taken place since the publication of that text. In addition, emphasis is placed on new materials research and developments.

This book highlights the development of novel metal-supported solid oxide fuel cells (MS-SOFCs). It describes the metal-supported solid oxide fuel cells (MS-SOFCs) that consist of a microporous stainless steel support, nanoporous electrode composites and a thin ceramic electrolyte using the "tape casting-sintering-infiltrating" method. Further, it investigates the reaction kinetics of the fuel cells' electrodes, structure-performance relationship and degradation mechanism. By optimizing the electrode materials, preparation process for the fuel cells, and nano-micro structure of the electrode, the resulting MS-SOFCs demonstrated (1) great output power densities at low temperatures, e.g., 1.02 W cm-2 at 600 DegreesC, when operating in humidified hydrogen fuels and air oxidants; (2) excellent long-term stability, e.g., a degradation rate of 1.3% kh-1 when measured at 650 DegreesC and 0.9 A cm-2 for 1500 h. The design presented offers a promising pathway for the development of low-cost, high power-density and long-term-stable SOFCs for energy conversion.

The storage of electroenergy is an essential feature of modem energy technologies. Unfortunately, no economical and technically feasible method for the solution of this severe problem is presently available. But electrochemistry is a favourite candidate from an engineering point of view. It promises the highest energy densities of all possible alternatives. If this is true, there will be a proportionality between the amount of electricity to be stored and the possible voltage, together with the mass of materials which make this storage possible. Insofar it is a matter of material science to develop adequate systems. Electricity is by far the most important secondary energy source. The present production rate, mainly in the thermal electric power stations, is in the order of 1.3 TW. Rechargeable batteries (RB) are of widespread use in practice for electroenergy storage and supply. The total capacity of primary and rechargeable batteries being exploited is the same as that of the world electric power stations. However, the important goal in the light of modem energy technology, namely the economical storage of large amounts of electricity for electric vehicles, electric route transport, load levelling, solar energy utilization, civil video & audio devices, earth and spatial communications, etc. will not be met by the presently available systems. Unless some of the new emerging electrochemical systems are established up to date, RB's based on aqueous acidic or alkali accumulators are mainly produced today.

The book presents the modeling and control of hydrogen-air PEM fuel cells, including simultaneous estimation of the parameters and states, fuzzy cluster modeling, SPM-based predictive control and advanced fuzzy control. MATLAB/Simulink-based modeling and control programs are discussed in detail. With simulations and experiments, it is an essential reference for both scientists and industrial engineers.

Over the past decade the topic of energy and environment has been ackno- edged among many people as a critical issue to be solved in 21st century since the Kyoto Protocol came into e?ect in 1997. Its political recognition was put forward especially at Heiligendamm in 2007, when the e?ect of carbon dioxide emission and its hazard in global climate were discussed and shared univ- sallyascommonknowledge.Controllingtheglobalwarmingintheeconomical framework of massive development worldwide through this new century is a very challenging problem not only among political, economical, or social c- cles but also among technological or scienti?c communities. As long as the humans depend on the combustion of fossil for energy resources, the waste heat exhaustion and CO emission are inevitable. 2 In order to establish a new era of energy saving and environment benign society, which is supported by technologies and with social consensus, it is important to seek for a framework where new clean energy system is inc- porated as infrastructure for industry and human activities. Such a society strongly needs innovative technologies of least CO emission and e?cient en- 2 ergy conversion and utilization from remaining fossil energies on the Earth. Energy recycling system utilizing natural renewable energies and their c- version to hydrogen may be the most desirable option of future clean energy society. Thus the society should strive to change its energy basis, from foss- consuming energy to clean and recycling energy.

As a flexible, cost-effective energy alternative to large scale nuclear power reactors, this book examines the potential future use of small modular reactors for the generation of electricity in different regions. Exploring advanced nuclear technologies, chapters describe the current situation and perspective of the small modular reactors market (SMRs) in different regions around the word, including North and South America, Europe, Asia, Middle East and Africa. Particular attention is paid to the benefits of using these types of reactors for the generation of electricity, discussing their efficiency and reduced construction time, as well as exploring the main difficulties encountered in the development stage. Looking at the potential dangers that SMRs pose to the environment and population, the text presents the new safety measures that have been adopted in SMRs design to reduce future risk.

This book describes in detail the use of natural cellulose fibers for the production of innovative, low-cost, and easily recyclable lithium-ion (Li-ion) cells by means of fast and reliable papermaking procedures that employ water as a solvent. In addition, it proposes specific methods to optimize the safety features of these paper-based cells and to improve the electronic conductivity of the electrodes by means of a carbonization process- an interesting novel technology that enables higher current rate capabilities to be achieved. The in-depth descriptions of materials, methods, and techniques are complemented by the inclusion of a general overview of electrochemical devices and, in particular, of different Li-ion battery configurations. Presenting the outcomes of this important research, the work is of wide interest to electrochemical engineers in both research institutions and industry.

This book explores the use of nanomaterials as diesel fuel additives. It extensively reviews the diesel engine characteristics and the most frequently used nanomaterials and nanofuels and discusses the practical issues regarding the viability of nanomaterials as fuel additives from technical, environmental, and human health viewpoints. Special attention is focused on questions related to the short-term use of nanomaterials in diesel engines, such as: * What are the most important nanomaterial activities in diesel engines? * What happens to nanomaterials at various stages, from the fuel tank to exhaust? * What are the effects of nanofuel usage on diesel engine characteristics? and * What are the effects of nanomaterials on diesel engine parts and systems? Given its scope, this book is a valuable resource for researchers and engineers in environmental science, mechanical engineering, and chemical engineering fields, as well as for advanced undergraduate and postgraduate students.

This book delivers a comprehensive overview of the characteristics of several types of materials that are widely used in the current era of supercapacitors; namely, architectured carbon materials, transition metal oxides and conducting polymers. It provides readers with a complete introduction to the fundamentals of supercapacitors, including the development of new electrolytes and electrodes, while highlighting the advantages, challenges, applications and future of these materials. This book is part of the Handbook of Nanocomposite Supercapacitor Materials. Supercapacitors have emerged as promising devices for electrochemical energy storage, playing an important role in energy harvesting for meeting the current demands of increasing global energy consumption. The handbook covers the materials science and engineering of nanocomposite supercapacitors, ranging from their general characteristics and performance to materials selection, design and construction. Covering both fundamentals and recent developments, this handbook serves a readership encompassing students, professionals and researchers throughout academia and industry, particularly in the fields of materials chemistry, electrochemistry, and energy storage and conversion. It is ideal as a reference work and primary resource for any introductory senior-level undergraduate or beginning graduate course covering supercapacitors.

This book includes a collection of research articles presented at the "6th International Workshop on Hydro Scheduling in Competitive Electricity Markets". The workshop was a unique and intimate forum for researchers and practitioners to present state-of-the-art research and development concerning novel methodological findings, best practices and real-life applications of hydro scheduling. It also provided a platform for discussing the developments that are taking place in the industry, sharing different experiences and discussing future trends related to this area. This proceedings book is a collection of the most relevant, high-quality articles from the workshop. Discussing the state-of-the-art in the field of hydro scheduling, it is a valuable resource for a wide audience of researchers and practitioners in the field now and in the interesting and challenging times ahead.

This practical reference remains the most comprehensive guide to the fundamental theories, techniques, and strategies used for battery operation and design. It includes new and revised chapters focusing on the safety, performance, quality, and enhancement of various batteries and battery systems. From automotive, electrochemical, and high-energy applications to system implementation, selection, and standardization, the Second Edition presents expert discussions on electrochemical energy storage, the advantages of battery-powered traction, the disposal and recycling of used batteries, hazard prevention, and the chemistry and physics of lithium primary batteries.

This book addresses electrocatalysis based on chalcogenides, particularly in the nanoscale domain. Special attention is paid to the hydrogen evolution reaction (HER) and the oxygen reduction reaction (ORR). The book provides an introduction to materials synthesis; the basic principles of electrocatalysis; related precious metal versus non-precious metal catalytic center chalcogenides as well as supports; and the role of such supports in stabilizing the catalytic centers. In short: pursuing a bottom-up approach, it covers the properties of this class of electrocatalysts and examines their applications in low-temperature fuel systems such as microfluidic fuel cells for portable devices. Accordingly, it is ideally suited for all professionals and researchers interested in electrochemistry, renewable energy and electrocatalysis, and non-precious metal centers for chemical energy conversion.

Storage and conversion are critical components of important energy-related technologies. "Advanced Batteries: Materials Science Aspects" employs materials science concepts and tools to describe the critical features that control the behavior of advanced electrochemical storage systems. This volume focuses on the basic phenomena that determine the properties of the components, i.e. electrodes and electrolytes, of advanced systems, as well as experimental methods used to study their critical parameters. This unique materials science approach utilizes concepts and methodologies different from those typical in electrochemical texts, offering a fresh, fundamental and tutorial perspective of advanced battery systems. Graduate students, scientists and engineers interested in electrochemical energy storage and conversion will find "Advanced Batteries: Materials Science Aspects" a valuable reference.