With this volume, Ezequiel P. M. Leiva and co-authors fill a gap in the available literature, by providing a much-needed, comprehensive review of the relevant literature for electrochemists, materials scientists and energy researchers. For the first time, they present applications of underpotential deposition (UPD) on the nanoscale, such as nanoparticles and nanocavities, as well as for electrocatalysis. They also discuss real surface determinations and layer-by-layer growth of ultrathin films, as well as the very latest modeling approaches to UPD based on nanothermodynamics, statistical mechanics, molecular dynamics and Monte-Carlo simulations.

This book will guide Photovoltaics researchers in a new way of thinking about harvesting light energy from all wavelengths of the solar spectrum. It closes the gap between general solar cells books and photovoltaics journal articles, by focusing on the latest developments in our understanding of solid-state device physics. The material presented is experimental and based on II-VI thin-film materials, mainly CdTe-based solar cells. The authors describe the use of new device design, based on multilayer graded bandgap configuration, using CdTe-based solar cells. The authors also explain how the photo-generated currents can be enhanced using multi-step charge carrier production. The possibility of fabricating these devices using low-cost and scalable electroplating is demonstrated. The value of electroplating for large area electronic devices such as PV solar panels, display devices and nano-technology devices are also demonstrated. By enabling new understanding of the engineering of electroplated semiconductor materials and providing an overview of the semiconductor physics and technology, this practical book is ideal to guide researchers, engineers, and manufacturers on future solar cell device designs and fabrications. Discusses in detail the processes of growths, treatments, solar cell device fabrication and solid state physics, improving readers' understanding of fundamental solid state physics; Enables future improvements in CdTe-based device efficiency; Explains the significance of defects in deposited semiconductor materials and interfaces that affect the material properties and resulting device performance.

This book provides a consolidated description of the process of electro-spinning and detailed properties and applications of electro-spun electrodes and electrolytes in energy storage devices. It discusses the preparation, structure and electrochemical properties of nanofiber electrode and electrolyte materials. It focuses exclusively on Lithium Ion batteries, with the contents discussing different aspects of electrospinning in storage systems. This book aims to provide a comprehensive resource to help researchers choose the best electrodes and electrolyte materials based on the properties required for their desired commercial applications. It will be a useful guide to graduate students and researchers working in solid-state chemistry, physics, materials chemistry, and chemical engineering on aspects of energy storage.

This work revolves around the hydrogen economy and energy-storage electrochemical systems. More specifically, it investigates the possibility of using magnetron sputtering for deposition of efficient thin-film anode catalysts with low noble metal content for proton exchange membrane water electrolyzers (PEM-WEs) and unitized regenerative fuel cells (PEM-URFCs). The motivation for this research derives from the urgent need to minimize the price of such electrochemical devices should they enter the mass production. Numerous experiments were carried out, correlating the actual in-cell performance with the varying position of thin-film catalyst within the membrane electrode assembly, with the composition of high-surface support sublayer and with the chemical structure of the catalyst itself. The wide arsenal of analytical methods ranging from electrochemical impedance spectroscopy through electrochemical atomic force microscopy to photoelectron spectroscopy allowed the description of the complex phenomena behind different obtained efficiencies. Systematic optimizations led to the design of a novel PEM-WE anode thin-film iridium catalyst which performs similarly to the standard counterparts despite using just a fraction of their noble metal content. Moreover, the layer-by-layer approach resulted in the design of a Ir/TiC/Pt bi-functional anode for PEM-URFC which is able to operate in both the fuel cell and electrolyzer regime and thus helps to cut the cost of the whole conversion system even further.

The book describes methods of modeling, planning and implementing electric energy storage systems. Energy storage becomes an important issue when more and more electric power is generated by wind mills and photovoltaics systems, because green energy is more volatile. So energy storage is necessary to guarantee safe and secure electric energy supply.Market and power system oriented operations of electric energy storage require different planning methods and different algorithms for searching the optimal solution. These methods are described in detail for energy storage implementations in generation, transmission and distribution levels. Economic aspects are considered.For many years, the authors have been developing smart grid solutions as well as a methology of modeling and planning electric energy storage usage. The aim has been to increase the flexibility of the power system heading for an energy system which is completely generated by green energy.

Energy storage devices are a crucial area of research and development across many engineering disciplines and industries. While batteries provide the significant advantage of high energy density, their limited life cycles, disposal challenges and charge and discharge management constraints undercut their effectiveness in certain applications. Compared to electrochemical cells, supercapacitors are charge-storage devices with much longer life cycles, yet they have traditionally been hobbled by limited DC voltage capabilities and energy density. However, recent advances are improving these issues.

This book provides the opportunity to expand your knowledge of innovative supercapacitor applications, comparing them to other commonly used energy storage devices. It will strengthen your understanding of energy storage from a practical, applications-based point-of-view, without requiring detailed examination of underlying electrochemical equations. No matter what your field, you will find inspiration and guidance in the cutting-edge advances in energy storage devices in this book.
Provides explanations of the latest energy storage devices in a practical applications-based context Includes examples of circuit designs that optimize the use of supercapacitors, and pathways to improve existing designs by effectively managing energy storage devices crucial to both low and high power applications.Covers batteries, BMS (battery management systems) and cutting-edge advances in supercapacitors, providing a unique compare and contrast examination demonstrating applications where each technology can offer unique benefits

This book presents ongoing research activities of currently available renewable energy technologies and the approaches towards clean technology for enabling a socio-economic model for the present and future generations to live in a clean and healthy environment. The book provides chapter wise implementation of research works in the area of green energy technologies with proper methods used with solution strategies and energy efficiency approaches by combining theory and practical applications. Readers are introduced to practical problems of green computation and hybrid resources optimization with solution based approaches from the current research outcomes. The book will be of use to researchers, professionals, and policy-makers alike.

The advance of variable speed drives systems (VSDs) engineering highlights the need of specific technical guidance provision by electrical machines and drives manufacturers, so that such applications can be properly designed to present advantages in terms of both energy efficiency and expenditure. This book presents problems and solutions related to inverter-fed electrical motors. Practically orientated, the book describes the reasons, theory and analysis of those problems. Various solutions for individual problems are presented together with the complete design process, modelling and simulation examples with MATLAB/Simulink on the companion website. A key focus of Variable Speed AC Drives with Inverter Output Filters is to examine the state variables estimation and motor control structures which have to be modified according to the used solution (filter). In most control systems the structure and parameters are taken into account to make it possible for precise control of the motor. This methodology is able to include modifications and extensions depending on specific control and estimation structures. Highly accessible, this is an invaluable resource for practising R&D engineers in drive companies, power electronics & control engineers and manufacturers of electrical drives. Senior undergraduate and postgraduate students in electronics and control engineering will also find it of value.

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The aim of this book is to review innovative physical multiscale modeling methods which numerically simulate the structure and properties of electrochemical devices for energy storage and conversion. Written by world-class experts in the field, it revisits concepts, methodologies and approaches connecting ab initio with micro-, meso- and macro-scale modeling of components and cells. It also discusses the major scientific challenges of this field, such as that of lithium-ion batteries. This book demonstrates how fuel cells and batteries can be brought together to take advantage of well-established multi-scale physical modeling methodologies to advance research in this area. This book also highlights promising capabilities of such approaches for inexpensive virtual experimentation. In recent years, electrochemical systems such as polymer electrolyte membrane fuel cells, solid oxide fuel cells, water electrolyzers, lithium-ion batteries and supercapacitors have attracted much attention due to their potential for clean energy conversion and as storage devices. This has resulted in tremendous technological progress, such as the development of new electrolytes and new engineering designs of electrode structures. However, these technologies do not yet possess all the necessary characteristics, especially in terms of cost and durability, to compete within the most attractive markets. Physical multiscale modeling approaches bridge the gap between materials' atomistic and structural properties and the macroscopic behavior of a device. They play a crucial role in optimizing the materials and operation in real-life conditions, thereby enabling enhanced cell performance and durability at a reduced cost. This book provides a valuable resource for researchers, engineers and students interested in physical modelling, numerical simulation, electrochemistry and theoretical chemistry.

This proceedings volume gathers selected papers presented at the Chinese Materials Conference 2017 (CMC2017), held in Yinchuan City, Ningxia, China, on July 06-12, 2017. This book covers a wide range of energy conversion and storage materials, thermoelectric materials and devices, nuclear materials, solar energy materials and solar cells, minerals and oil and gas materials, photocatalytic materials for energy production, eco-materials, and environmental engineering materials. The Chinese Materials Conference (CMC) is the most important serial conference of the Chinese Materials Research Society (C-MRS) and has been held each year since the early 1990s. The 2017 installment included 37 Symposia covering four fields: Advances in energy and environmental materials; High performance structural materials; Fundamental research on materials; and Advanced functional materials. More than 5500 participants attended the congress, and the organizers received more than 700 technical papers. Based on the recommendations of symposium organizers and after peer reviewing, 490 papers have been included in the present proceedings, which showcase the latest original research results in the field of materials, achieved by more than 300 research groups at various universities and research institutes.

Demand for fuel cell technology is growing rapidly. Fuel cells are being commercialized to provide power to buildings like hospitals and schools, to replace batteries in portable electronic devices, and as replacements for internal combustion engines in vehicles. PEM (Proton Exchange Membrane) fuel cells are lighter, smaller, and more efficient than other types of fuel cell. As a result, over 80% of fuel cells being produced today are PEM cells.

This new edition of Dr. Barbir s groundbreaking book still lays the groundwork for engineers, technicians and students better than any other resource, covering fundamentals of design, electrochemistry, heat and mass transport, as well as providing the context of system design and applications. Yet it now also provides invaluable information on the latest advances in modeling, diagnostics, materials, and components, along with an updated chapter on the evolving applications areas wherein PEM cells are being deployed.
Comprehensive guide covers all aspects of PEM fuel cells, from theory and fundamentals to practical applicationsProvides solutions to heat and water management problems engineers must face when designing and implementing PEM fuel cells in systemsHundreds of original illustrations, real-life engineering examples, and end-of-chapter problems help clarify, contextualize, and aid understanding"

This book covers system-level design optimization and implementation of hybrid energy storage systems. The author introduces various techniques to improve the performance of hybrid energy storage systems, in the context of design optimization and automation. Various energy storage techniques are discussed, each with its own advantages and drawbacks, offering viable, hybrid approaches to building a high performance, low cost energy storage system. Novel design optimization techniques and energy-efficient operation schemes are introduced. The author also describes the technical details of an actual prototype implementation of a 300 W scale hybrid energy storage system.

Batteries that can store electricity from solar and wind generation farms are a key component of a sustainable energy strategy. Featuring 15 peer-reviewed entries from the Encyclopedia of Sustainability Science and Technology, this book presents a wide range of battery types and components, from nanocarbons for supercapacitors to lead acid battery systems and technology. Worldwide experts provides a snapshot-in-time of the state-of-the art in battery-related R&D, with a particular focus on rechargeable batteries. Such batteries can store electrical energy generated by renewable energy sources such as solar, wind, and hydropower installations with high efficiency and release it on demand. They are efficient, non-polluting, self-contained devices, and their components can be recovered and used to recreate battery systems. Coverage also highlights the significant efforts currently underway to adapt battery technology to power cars, trucks and buses in order to eliminate pollution from petroleum combustion. Written for an audience of undergraduate and graduate students, researchers, and industry experts, Batteries for Sustainability is an invaluable one-stop reference to this essential area of energy technology.

This book provides a comprehensive overview of thin film structures in energy applications. Each chapter contains both fundamentals principles for each thin film structure as well as the relevant energy application technologies. The authors cover thin films for a variety of energy sectors including inorganic and organic solar cells, DSSCs, solid oxide fuel cells, thermoelectrics, phosphors and cutting tools.

This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.

This book discusses renewable energy systems and applications, and demonstrates how an accelerated transition to 100% renewable energy can be achieved. It examines the systems from a thermodynamic perspective, focusing on the irreversible aspects of the current energy system and highlighting the solutions developed to date. Presenting global research and developments, this book is intended for those working within the field of renewable energy research and policy who are interested in learning how they can contribute to the transition from fossil fuels to renewable resources.

The expected end of the "oil age" will lead to increasing focus and reliance on alternative energy conversion devices, among which fuel cells have the potential to play an important role. Not only can phosphoric acid and solid oxide fuel cells already efficiently convert today's fossil fuels, including methane, into electricity, but other types of fuel cells, such as polymer electrolyte membrane fuel cells, have the potential to become the cornerstones of a possible future hydrogen economy. Featuring 21 peer-reviewed entries from the Encyclopedia of Sustainability Science and Technology, Fuel Cells offers concise yet comprehensive coverage of the current state of research and identifies key areas for future investigation. Internationally renowned specialists provide authoritative introductions to a wide variety of fuel cell types, and discuss materials, components, and systems for these technologies. The entries also cover sustainability and marketing considerations, including comparisons of fuel cells with alternative technologies.

This book presents studies and discussions on anionic redox, which can be used to boost the capacities of cathode electrodes by providing extra electron transfer. This theoretically and practically significant book facilitates the implementation of anionic redox in electrodes for real-world use and accelerates the development of high-energy-density lithium-ion batteries. Lithium-ion batteries, as energy storage systems, are playing a more and more important role in powering modern society. However, their energy density is still limited by the low specific capacity of the cathode electrodes. Based on a profound understanding of band theory, the author has achieved considerable advances in tuning the redox process of lithium-rich electrodes to obtain enhanced electrochemical performance, identifying both the stability mechanism of anionic redox in lithium-rich cathode materials, and its activation mechanism in these electrode systems.

This book covers various aspects of thermal energy storage. It looks at storage methods for thermal energy and reviews the various materials that store thermal energy and goes on to propose advanced materials that store energy better than conventional materials. The book also presents various thermophysical properties of advanced materials and the role of thermal energy storage in different applications such as buildings, solar energy, seawater desalination and cooling devices. The advanced energy storage materials have massive impact on heat transfer as compared to conventional energy storage materials. A concise discussion regarding current status, leading groups, journals and the countries working on advanced energy storage materials has also been provided. This book is useful to researchers, professionals and policymakers alike.

This book discusses heat transfer in underground energy systems. It covers a wide range of important and practical topics including the modeling and optimization of underground power cable systems, modeling of thermal energy storage systems utilizing waste heat from PV panels cooling. Modeling of PV pannels with cooling. While the performance of energy systems which utilize heat transfer in the ground is not yet fully understood, this book attempts to make sense of them. It provides mathematical modeling fundaments, as well as experimental investigation for underground energy systems. The book shows detailed examples, with solution procedures. The solutions are based on the Finite Element Method and the Finite Volume Method. The book allows the reader to perform a detailed design of various underground energy systems, as well as enables them to study the economic aspects and energy efficiency of underground energy systems. Therefore, this text is of interest to researchers, students, and lecturers alike.

An apparently appropriate control scheme for PEM fuel cells may actually lead to an inoperable plant when it is connected to other unit operations in a process with recycle streams and energy integration. PEM Fuel Cells with Bio-Ethanol Processor Systems presents a control system design that provides basic regulation of the hydrogen production process with PEM fuel cells. It then goes on to construct a fault diagnosis system to improve plant safety above this control structure. PEM Fuel Cells with Bio-Ethanol Processor Systems is divided into two parts: the first covers fuel cells and the second discusses plants for hydrogen production from bio-ethanol to feed PEM fuel cells. Both parts give detailed analyses of modeling, simulation, advanced control, and fault diagnosis. They give an extensive, in-depth discussion of the problems that can occur in fuel cell systems and propose a way to control these systems through advanced control algorithms. A significant part of the book is also given over to computer-aided engineering software tools that can be used to evaluate the dynamic performance of the overall plant. PEM Fuel Cells with Bio-Ethanol Processor Systems is intended for use by researchers and advanced students on chemical, electrical-electronic and mechanical engineering courses in which dynamics and control are incorporated with the traditional steady-state coverage of flowsheet synthesis, engineering economics and optimization.

The development of a direct, inexpensive, and efficient method for converting solar energy into a portable, clean fuel would allow elimination of the growing problems associated with the ever increasing use of fossil fuels and the reality of their rapid depletion. As the title suggests, Light, Water, Hydrogen: The Solar Generation of Hydrogen by Water Photoelectrolysis, considers the combination of water and light with a suitable semiconductor to achieve a safe, renewable and therefore inexhaustable means for hydrogen generation via the splitting of the water molecule, or photoelectrolysis.

The authors consider the impact of recent advances in nanotechnology on the water photoelectrolysis field, providing specific examples as well as the theories and methods necessary for achieving useful water photoelectrolysis systems. Written for users in a wide range of disciplines, including materials scientists, chemists, electrical engineers, and physicists, Light, Water, Hydrogen: The Solar Generation of Hydrogen by Water Photoelectrolysis is an up-to-date, invaluable resource for graduate students and researchers.

This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential ( 3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

This book fills the need for a practical reference for all scientists and graduate students who are seeking to define a mathematical model for Solid Oxide Fuel Cell (SOFC) simulation. Structured in two parts, part one presents the basic theory, and the general equations describing SOFC operation phenomena. Part two deals with the application of the theory to practical examples, where different SOFC geometries, configurations, and different phenomena are analyzed in detail.