This book describes methods for adaptive control of distributed-collector solar fields: plants that collect solar energy and deliver it in thermal form. Controller design methods are presented that can overcome difficulties found in these type of plants: they are distributed-parameter systems, i.e., systems with dynamics that depend on space as well as time; their dynamics is nonlinear, with a bilinear structure; there is a significant level of uncertainty in plant knowledge. Adaptive methods form the focus of the text because of the degree of uncertainty in the knowledge of plant dynamics. Parts of the text are devoted to design methods that assume only a very limited knowledge about the plant. Other parts detail methods that rely on knowledge of the dominant plant structure. These methods are more plant specific, but allow the improvement of performance. Adaptive Control of Solar Energy Collector Systems demonstrates the dynamics of solar fields to be rich enough to present a challenge to the control designer while, at the same time, simple enough to allow analytic work to be done, providing case studies on dynamics and nonlinear control design in a simple and revealing, but nontrivial way. The control approaches treated in this monograph can be generalized to apply to other plants modelled by hyperbolic partial differential equations, especially process plants in which transport phenomena occur, plants like dryers, steam super-heaters and even highway traffic. An important example, used repeatedly throughout the text, is a distributed-collector solar field installed at Plataforma Solar de Almeria, located in southern Spain. The control algorithms laid out in the text are illustrated with experimental results generated from this plant. Although the primary focus of this monograph is solar energy collector, the range of other systems which can benefit from the methods described will make it of interest to control engineers working in many industries as well as to academic control researchers interested in adaptive control and its applications.

Li-Co-Mn-Ni oxides have been of extreme interest as potential positive electrode materials for next generation Li-ion batteries.  Though many promising materials have been discovered and studied extensively, much debate remains in the literature about the structures of these materials. There is no consensus as to whether the lithium-rich layered materials are single-phase or form a layered-layered composite on the few nanometer length-scales. Much of this debate came about because no phase diagrams existed to describe these systems under the synthesis conditions used to make electrode materials.  Detailed in this thesis are the complete Li-Co-Mn-O and Li-Mn-Ni-O phase diagrams generated by way of the combinatorial synthesis of mg-scale samples at over five hundred compositions characterized with X-ray diffraction. Selected bulk samples were used to confirm that the findings are relevant to synthesis conditions used commercially. The results help resolve a number of points of confusion and contradiction in the literature. Amongst other important findings, the compositions and synthesis conditions giving rise to layered-layered nano-composites are presented and electrochemical results are used to show how better electrode materials can be achieved by making samples in the single phase-layered regions.

This textbook offers original and new approaches to the teaching of electrochemical concepts, principles and applications. Throughout the text the authors provide a balanced coverage of the thermodynamic and kinetic processes at the heart of electrochemical systems. The first half of the book outlines fundamental concepts appropriate to undergraduate students and the second half gives an in-depth account of electrochemical systems suitable for experienced scientists and course lecturers. Concepts are clearly explained and mathematical treatments are kept to a minimum or reported in appendices. This book features: - Questions and answers for self-assessment - Basic and advanced level numerical descriptions - Illustrated electrochemistry applications This book is accessible to both novice and experienced electrochemists and supports a deep understanding of the fundamental principles and laws of electrochemistry.

This second edition of the highly successful dictionary offers more than 300 new or revised terms. A distinguished panel of electrochemists provides up-to-date, broad and authoritative coverage of 3000 terms most used in electrochemistry and energy research as well as related fields, including relevant areas of physics and engineering. Each entry supplies a clear and precise explanation of the term and provides references to the most useful reviews, books and original papers to enable readers to pursue a deeper understanding if so desired. Almost 600 figures and illustrations elaborate the textual definitions. The "Electrochemical Dictionary" also contains biographical entries of people who have substantially contributed to electrochemistry. From reviews of the first edition: 'the creators of the Electrochemical Dictionary have done a laudable job to ensure that each definition included here has been defined in precise terms in a clear and readily accessible style' (The Electric Review) 'It is a must for any scientific library, and a personal purchase can be strongly suggested to anybody interested in electrochemistry' (Journal of Solid State Electrochemistry) 'The text is readable, intelligible and very well written' (Reference Reviews)

The aim of this book is to review innovative physical multiscale modeling methods which numerically simulate the structure and properties of electrochemical devices for energy storage and conversion. Written by world-class experts in the field, it revisits concepts, methodologies and approaches connecting ab initio with micro-, meso- and macro-scale modeling of components and cells. It also discusses the major scientific challenges of this field, such as that of lithium-ion batteries. This book demonstrates how fuel cells and batteries can be brought together to take advantage of well-established multi-scale physical modeling methodologies to advance research in this area. This book also highlights promising capabilities of such approaches for inexpensive virtual experimentation. In recent years, electrochemical systems such as polymer electrolyte membrane fuel cells, solid oxide fuel cells, water electrolyzers, lithium-ion batteries and supercapacitors have attracted much attention due to their potential for clean energy conversion and as storage devices. This has resulted in tremendous technological progress, such as the development of new electrolytes and new engineering designs of electrode structures. However, these technologies do not yet possess all the necessary characteristics, especially in terms of cost and durability, to compete within the most attractive markets. Physical multiscale modeling approaches bridge the gap between materials' atomistic and structural properties and the macroscopic behavior of a device. They play a crucial role in optimizing the materials and operation in real-life conditions, thereby enabling enhanced cell performance and durability at a reduced cost. This book provides a valuable resource for researchers, engineers and students interested in physical modelling, numerical simulation, electrochemistry and theoretical chemistry.

This book presents an innovative methodology for identifying optimum investment strategies in the power industry. To do so, it examines results including, among others, the impact of oxy-fuel technology on CO2 emissions prices, and the specific cost of electricity production. The technical and economic analysis presented here extend the available knowledge in the field of investment optimization in energy engineering, while also enabling investors to make decisions involving its application. Individual chapters explore the potential impacts of different factors like environmental charges on costs connected with investments in the power sector, as well as discussing the available technologies for heat and power generation. The book offers a valuable resource for researchers, market analysts, decision makers, power engineers and students alike.

Have you ever wondered by how much CO2 emissions can be reduced by running cars electrically or with hydrogen as fuel? This Brief provides a quantitative answer to this question using the example of the combined road traffic in Spain. The authors calculate the resulting greenhouse gas (GHG) emissions for the production of hydrogen gas or the required electricity and installing and maintaining the necessary infrastructure. In this way, they can compare with the GHG emissions in the present situation of oil fueled cars. Using different scenarios, they obtain an assessment how much 'greener' the electric or hydrogen cars can get.The method described in this Brief is scalable and readily adaptable to other countries. It can thus be used for investigating sensible approaches and developing recommendations for a conversion. As expected, the results depend strongly on the production scenarios for hydrogen or electricity production. The wrong choice can even result in increased GHG emissions. A proper choice of the roadmap toward a more sustainable and greener future is of greatest importance - the results described in this Brief can serve as a valuable and useful guide on our way.

This book contains a novel combination of experimental and model-based investigations, elucidating the complex processes inside zinc air batteries. The work presented helps to answer which battery composition and which air-composition should be adjusted to maintain stable and efficient charge/discharge cycling. In detail, electrochemical investigations and X-ray transmission tomography are applied on button cell zinc air batteries and in-house set-ups. Moreover, model-based investigations of the battery anode and the impact of relative humidity, active operation, carbon dioxide and oxygen on zinc air battery operation are presented. The techniques used in this work complement each other well and yield an unprecedented understanding of zinc air batteries. The methods applied are adaptable and can potentially be applied to gain further understanding of other metal air batteries.

This book covers system-level design optimization and implementation of hybrid energy storage systems. The author introduces various techniques to improve the performance of hybrid energy storage systems, in the context of design optimization and automation. Various energy storage techniques are discussed, each with its own advantages and drawbacks, offering viable, hybrid approaches to building a high performance, low cost energy storage system. Novel design optimization techniques and energy-efficient operation schemes are introduced. The author also describes the technical details of an actual prototype implementation of a 300 W scale hybrid energy storage system.

The third volume of 'Frontiers of Electrochemistry' concentrates on materials science. It provides a review of recent progress in the study of the electrochemical properties of novel materials and describes advances in the development of electrode materials for photoelectrochemistry, polymeric materials and insertion compounds for Lithium batteries. The book provides a careful description of electrochemistry of carbon, thin polymer film coated electrodes, electrocatalytic metal-oxide electrodes, electrochemistry of nuclear fuels and electrochemistry of clays and zeolites. The selection of excellent review articles was written by the best experts in their field of research. The book will interest electrochemists, materials scientists, electrochemical engineers, and other scientists in academic and industrial settings. In the preface, the editors point out that each chapter provides sufficient background material so that it can be read and appreciate by specialists and non specialists alike

This book presents a detailed technical overview of short- and long-term materials and design challenges to zinc/bromine flow battery advancement, the need for energy storage in the electrical grid and how these may be met with the Zn/Br system. Practical interdisciplinary pathways forward are identified via cross-comparison and comprehensive review of significant findings from more than 300 published works, with clear in-depth explanations spanning initial RFB development to state-of-the-art research in related systems. Promising strategies described include the use of modern electrochemical techniques to study and optimize physical processes occurring within the system during operation, improving zinc electroplating quality during the charge phase through the strategic use of organic additives, as well as identifying suitable catalysts to optimize the bromine/bromide redox couple. The primary focus is on research and development of novel materials in the areas of electrolyte formulation and multifunctional "smart" electrode surfaces to achieve a higher degree of control over processes at the electrode-electrolyte interface. The strategies suggested in this book are also highly adaptable for use in other similar flow battery systems, while the unique cross-comparative approach makes it a useful reference and source of new ideas for both new and established researchers in the field of energy storage and battery technology.

This book presents contributions to the topics of materials for energy infrastructure with a focus on data and informatics for materials. This spectrum of topics has been chosen because challenges in terms of materials are identified to lie in transport and storage of energy, adequate supply of food and water, well-working infrastructure, materials for medical application and health, efficient use of scarce resources or elements and alternate materials solutions as well as recycling. The contributions were invited at the 4th WMRIF Young Materials Scientist Workshop held at the National Institute for Standards and Technology (NIST) in Boulder, Colorado, USA during September 8-10, 2014.

This book shows how severe plastic deformation techniques could be used to enhance the hydrogen storage properties of metal hybrides. The mechanochemical techniques of ball-milling (BM), Cold Rolling (CR), Equal Chanel Angular Pressing (ECAP) and High Pressure Torsion (HPT) are covered. Each technique is described and critically assessed with respect to its usefulness to process metal hybrides at an industrial scale.

Gaining public attention due, in part,  to their potential application as energy storage devices in cars, Lithium-ion batteries have encountered widespread demand, however, the understanding of lithium-ion technology has often lagged behind production. This book defines the most commonly encountered challenges from the perspective of a high-end lithium-ion manufacturer with two decades of experience with lithium-ion batteries and over six decades of experience with batteries of other chemistries. Authors with years of experience in the applied science and engineering of lithium-ion batteries gather to share their view on where lithium-ion technology stands now, what are the main challenges, and their possible solutions. The book contains real-life examples of how a subtle change in cell components can have a considerable effect on cell’s performance. Examples are supported with approachable basic science commentaries. Providing a unique combination of practical know-how with an in-depth perspective, this book will appeal to graduate students, young faculty members, or others interested in the current research and development trends in lithium-ion technology.

Liberating Energy from Carbon analyzes energy options in a carbon-constrained world. Major strategies and pathways to decarbonizing the carbon-intensive economy are laid out with a special emphasis on the prospects of achieving low-risk atmospheric CO2 levels. The opportunities and challenges in developing and bringing to market novel low and zero-carbon technologies are highlighted from technical, economic and environmental viewpoints. This book takes a unique approach by treating carbon in a holistic manner-tracking its complete transformation chain from fossil fuel sources to the unique properties of the CO2 molecule, to carbon capture and storage and finally, to CO2 industrial utilization and its conversion to value-added products and fuels. This concise but comprehensive sourcebook guides readers through recent scientific and technological developments as well as commercial projects that aim for the decarbonization of the fossil fuel-based economy and CO2 utilization that will play an increasingly important role in the near- and mid-term future. This book is intended for researchers, engineers, and students working and studying in practically all areas of energy technology and alternative energy sources and fuels.

This book describes recent breakthroughs that promise major cost reductions in solar energy production in a clear and highly accessible manner. The author addresses the three key areas that have commonly resulted in criticism of solar energy in the past: cost, availability, and variability. Coverage includes cutting-edge information on recently developed 40 efficient solar cells, which can produce double the power of currently available commercial cells. The discussion also highlights the potentially transformative emergence of opportunities for integration of solar energy storage and natural gas combined heat and power systems. Solar energy production in the evening hours is also given fresh consideration via the convergence of low cost access to space and the growing number of large terrestrial solar electric power fields around the world. Dr. Fraas has been active in the development of Solar Cells and Solar Electric Power Systems for space and terrestrial applications since 1975. His research team at Boeing demonstrated the first GaAs/GaSb tandem concentrator solar cell in 1989 with a world record energy conversion efficiency of 35 , garnering awards from Boeing and NASA. He has over 30 years of experience at Hughes Research Labs, Chevron Research Co, and the Boeing High Technology Center working with advanced semiconductor devices. In a pioneering paper, he proposed the InGaP/GaInAs/Ge triple junction solar cell predicting a cell terrestrial conversion efficiency of 40 at 300 suns concentration. Having become today's predominant cell for space satellites, that cell is now entering high volume production for terrestrial Concentrated Photovoltaic (CPV) systems. Since joining JX Crystals, Dr. Fraas has pioneered the development of various thermophotovoltaic (TPV) systems based on the new GaSb infrared sensitive PV cell. Dr. Fraas holds degrees from Caltech (B.Sc. Physics), Harvard (M. A. Applied Physics), and USC (Ph.D. EE).

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Fuel cells are one of the most promising clean energy conversion devices that can solve the environmental and energy problems in our society. However, the high platinum loading of fuel cells - and thus their high cost - prevents their commercialization. Non- or low- platinum electrocatalysts are needed to lower the fuel cell cost. Electrocatalysis in Fuel Cells: A Non and Low Platinum Approach is a comprehensive book summarizing recent advances of electrocatalysis in oxygen reduction and alcohol oxidation, with a particular focus on non- and low-Pt electrocatalysts. All twenty four chapters were written by worldwide experts in their fields. The fundamentals and applications of novel electrocatalysts are discussed thoroughly in the book. The book is geared toward researchers in the field, postgraduate students and lecturers, and scientists and engineers at fuel cell and automotive companies. It can even be a reference book for those who are interested in this area.

The book focuses on the solid-state physics, chemistry and electrochemistry that are needed to grasp the technology of and research on high-power Lithium batteries. After an exposition of fundamentals of lithium batteries, it includes experimental techniques used to characterize electrode materials, and a comprehensive analysis of the structural, physical, and chemical properties necessary to insure quality control in production. The different properties specific to each component of the batteries are discussed in order to offer manufacturers the capability to choose which kind of battery should be used: which compromise between power and energy density and which compromise between energy and safety should be made, and for which cycling life. Although attention is primarily on electrode materials since they are paramount in terms of battery performance and cost, different electrolytes are also reviewed in the context of safety concerns and in relation to the solid-electrolyte interface. Separators are also reviewed in light of safety issues. The book is intended not only for scientists and graduate students working on batteries but also for engineers and technologists who want to acquire a sound grounding in the fundamentals of battery science arising from the interaction of electrochemistry, solid state materials science, surfaces and interfaces.

Cisterns: Sustainable Development, Architecture and Energy was written on beliefs that based on historical evidence and actual findings, Iran is most probably the country where cisterns, or "Aub-anbars" in Farsi, were first developed and built. Therefore, it is quite natural for the author to name cisterns in the text Aub-anbars, as it has been called for centuries in this country, the translation of the same name having been used in other countries too. Although in some books, journals and papers published out of Iran by foreign and Iranian scholars, the names Cistern or Water Reservoir have been used. The word Aub-anbar is a compound noun in Farsi; Aub means water and Anbar means tank/reservoir. Putting them together gives the noun Aub-anbarand it should be used as one word.People of the region wanting reserved cool water whether in cities or in different locations across the harsh desert during their travel. Queen Zubeida, the wife of Khalifa Haroon Al-Rasheed in 750 AD built one of these cistern closer to the town of Hiyal in Saudi Arabia so that the Pilgrims? Caravans going to Mecca will have cool, fresh water. This book consists of 11-chapters with full analysis, illustrations and photographs. It makes interesting readings to those interested into vernacular architecture, traditional buildings and creative thinking.

AC voltage frequency changes is one of the most important functions of solid state power converters. The most desirable features in frequency converters are the ability to generate load voltages with arbitrary amplitude and frequency, sinusoidal currents and voltages waveforms; the possibility of providing unity power factor for any load; and, finally, a simple and compact power circuit. Over the past decades, a number of different frequency converter topologies have appeared in the literature, but only the converters with either a voltage or current DC link are commonly used in industrial applications. Improvements in power semiconductor switches over recent years have resulted in the development of many structures of AC-AC converters without DC electric energy storage. Such converters are an alternative solution for frequently recommended systems with DC energy storage and are characterized by a lower price, smaller size and longer lifetime. Most of the these topologies are based on the structure of the matrix converter. Three-Phase AC-AC Power Converters Based On Matrix Converter Topology: Matrix-reactance frequency converters concept presents a review of power frequency converters, with special attention paid to converters without DC energy storage. Particular attention is paid to nine new converters named matrix-reactance frequency converters which have been developed by the author and the team of researchers from Institute of Electrical Engineering at the University of Zielona Gora. The topologies of the presented matrix-reactance frequency converters are based on a three-phase unipolar buck-boost matrix-reactance chopper with source or load switches arranged as in a matrix converter. This kind of approach makes it possible to obtain an output voltage greater than the input one (similar to that in a matrix-reactance chopper) and a frequency conversion (similar to that in a matrix converter). Written for researchers and Ph.D. students working in the field of power electronics converters and drive systems, Three-Phase AC-AC Power Converters Based On Matrix Converter Topology: Matrix-reactance frequency converters concept will also be valuable to power electronics converter designers and users; R&D centers; and readers needing industry solutions in variable speed drive systems, such as automation and aviation.

Here, the authors provide a unified concept for understanding multi-electron processes in electrochemical systems such as molten salts, ionic liquids, or ionic solutions. A major advantage of this concept is its independence of assumptions like one-step many-electron transfers or 'discrete' discharge of complex species. Therefore this monograph is a unique resource for basic electrochemical research but also for many important applications such as electrodeposition, electrorefining, or electrowinning of polyvalent metals from molten salts and other ionic media.

The current volume provides examples of how environmental hazards such as landslides, earthquakes, mountain processes, cold climate processes and tidal flows and currents can affect the energy supply infrastructure. In times of uncertainty, the security of the European cross-border energy supply infrastructure, such as pipelines, has great importance. Whilst the potential effects of political disagreement, economic inequalities and social differences are relatively well understood, the impact of environmental change is often poorly appreciated by decision-makers. New approaches have been examined for monitoring of hazardous landslide processes, including early warning systems, and near-real-time 3D data processing and visualization. The scientific problems of environmental systems design have been discussed and approaches for their implementation have been suggested. New integrated remote sensing techniques consisting mainly of hyperspectral and radar imagery are presented together with the processing of monitoring data using GIS techniques and, in particular, dynamic visualization. Attention is also given to conceptual issues of environmental and energy security and the role of education, to help resolve environmental problems through cooperation in the development of the European energy supply infrastructure.

Power Conversion of Renewable Energy Systems presents an introduction to conventional energy conversion components and systems, as well as those related to renewable energy. This volume introduces systems first, and then in subsequent chapters describes the components of energy systems in detail. Readers will find examples of renewable and conventional energy and power systems, including energy conversion, variable-speed drives and power electronics, in addition to magnetic devices such as transformers and rotating machines. Applications of PSpice, MATLAB, and Mathematica are also included, along with solutions to over 100 application examples. Power Conversion of Renewable Energy Systems aims to instruct readers how to actively apply the theories discussed within. It would be an ideal volume for researchers, students and engineers working with energy systems and renewable energy.

This thesis focuses on porous monolithic materials that are not in the forms of particles, fibers, or films. In particular, the synthetic strategy of porous monolithic materials via the sol-gel method accompanied by phase separation, which is characterized as the non-templating method for tailoring well-defined macropores, is described from the basics to actual synthesis. Porous materials are attracting more and more attention in various fields such as electronics, energy storage, catalysis, sensing, adsorbents, biomedical science, and separation science. To date, many efforts have been made to synthesize porous materials in various chemical compositions-organics, inorganics including metals, glasses and ceramics, and organic-inorganic hybrids. Also demonstrated in this thesis are the potential applications of synthesized porous monolithic materials to separation media as well as to electrodes for electric double-layer capacitors (EDLCs) and Li-ion batteries (LIBs). This work is ideal for graduate students in materials science and is also useful to engineers or scientists seeking basic knowledge of porous monolithic materials.