John Meurig Thomas is a former Director of the Royal Institution of Great Britain, a former head of the Department of Physical Chemistry and former Master of Peterhouse, University of Cambridge. A world-renowned solid-state, materials and surface chemist, he has been an educator, researcher, academic administrator, author of university texts, government advisor, industrial consultant and trustee of national museums in a career spanning over 50 years. Recipient of many international awards, including the Linus Pauling, Willard-Gibbs, Kapitza, Natta, Stokes, Davy and Faraday medals, he is also a fellow of the Royal Society (1977), of the American Philosophical Society (1993) and of ten other national academies. He is best known for his fundamental work in heterogeneous catalysis, chemical electron microscopy and in the popularisation of science, for which, in conjunction with his services to chemistry, he was knighted (1991). He is also founding editor of three scientific journals and editor or co-editor of some 30 monographs. A new mineral, meurigite, was named in his honour (1995). Most recently in 2016, Sir John was awarded the Royal Medal for Physical Sciences by the Royal Society.Drawn from over 1200 publications, this volume contains a summarised account of Sir John's work, with a selection of the new techniques pioneered and discovered by him and his colleagues. Also included are popular science articles, and various illustrations of techniques which have enhanced our knowledge of many facets of condensed matter science. Contributions from 80 peers, colleagues, former co-workers, students and friends worldwide who have interacted with or been influenced by him are a tribute to the professional and personal life of Sir John, making this book a unique reflective summary of the work of one of the greatest achievers in modern British physical science.

This book discusses fragmentation mechanisms of molecules under mass spectrometry conditions and the resulting peaks observed in ESI-MS/MS experiments. The underlying principles are used to understand everything from small molecules to biological poly-peptides collision induced dissociation. In a theoretical approach, gas phase reactivity of molecular ions is coupled with chemical dynamics simulations.

Calculations in Chemical Kinetics for Undergraduates aims to restore passion for problem solving and applied quantitative skills in undergraduate chemistry students. Avoiding complicated chemistry jargon and providing hints and step wise explanations in every calculation problem, students are able to overcome their fear of handling mathematically applied problems in physical chemistry. This solid foundation in their early studies will enable them to connect fundamental theoretical chemistry to real experimental applications as graduates. Additional Features Include: Contains quantitative problems from popular physical chemistry references. Provides step by step explanations are given in every calculation problem. Offers hints to certain problems as "points to note" to enable student comprehension. Includes solutions for all questions and exercises. This book is a great resource for undergraduate chemistry students however, the contents are rich and useful to even the graduate chemist that has passion for applied problems in physical chemistry of reaction Kinetics.

The field of cluster sciences is currently attracting considerable interest, not only from a fundamental viewpoint but also in relation to future applications to electronic, optical and magnetic devices. Synthesizing specific clusters as a component of useful nanostructures or controlling them as an assembly of nanocomposites is the ultimate aim. In order to understand how to synthesize individual clusters or to investigate properties such as chemical reaction, structural stability, response to external fields, aggregation and phase transitions, a variety of first-principles and empirical calculations and related computer simulations have been performed alongside numerous experiments. This book compiles and collates recent theoretical and experimental advances in the field and demonstrates how the harmony between theory and experiment is contributing to the continuing rapid progress. It will be of interest to both researchers as well as students and newcomers seeking an up-to-date review.

This book describes the ultra-short laser–matter interactions from the subtle atomic motion to the generation of extreme pressures inside the bulk of a transparent crystal. It is the successor to Femtosecond Laser–Matter Interactions: Theory, Experiment and Applications (2011). Explanation and experimental verification of the exceptional technique for the phase transformations under high pressure are in the core of the book. The novel phase formation occurs along the unique solid-plasmasolid transformation path: the memory of the initial state is lost after conversion to plasma. New phase forms from chaos during the cooling to the ambient. The pressure-affected material remains detained inside a pristine crystal at the laboratory tabletop. Unique super-dense aluminium and new phases of silicon were created by the confined micro-explosions. The text also describes the recent studies that used the quasi-non-diffracting Bessel beams. The applications comprise the new high-pressure material formation and micromachining. The book is an appealing source for readers interested in the cutting-edge research exploring extreme conditions and creating nanostructures at the laboratory tabletop.

In recent decades, luminescent nanomaterials have generated great interest in the scientific community due to their unique properties, which are different from those of their bulk counterparts, and their use in a wide variety of applications. Today, luminescent nanomaterials are used in a number of applications such as displays, solid-state lighting, solar cells, long afterglow, dosimetry, theft prevention, medical imaging, phototherapy, and quantum and gas sensing. This book presents cutting-edge research from experts in the field of synthesis and characterization of luminescent nanomaterials and their potential applications. It covers interesting topics in semiconductor physics, photochemistry, physical chemistry, materials science, and luminescence, and will be useful for beginners and advanced researchers interested in this field.

The "flipped classroom" has become the new buzzword not only among educators but also in the general public, with articles in the USA Today, Washington Post, and The New York Times discussing this pedagogical approach. Simply stated, the flipped classroom is a high tech variation on a pedagogical method that has been around for generations. The time honored Socratic method aims to actively engage students with instructors asking them questions, leading them down a path where they are encouraged to see the connections between ideas. Additionally, flipped classrooms resemble the Thayer method, which expects students to take responsibility for their own learning by studying material before it is covered in class. Chemistry professors who teach in flipped classrooms embrace a variety of learning theories to guide their implementations. Most chemists who use active learning approaches in their classrooms value some aspect of constructivism theory, in which learners must begin their understanding of the concepts in their pre-class assignments. Later, students apply the concepts in class using active learning methods. For this book, the authors define the flipped classroom as one where students gain exposure to course content before class and the face-to-face time involves active learning. The call for and relevance of larger reform efforts in chemical education is not new and this book represents a continuation in the possibilities in achieving reform and meeting the goals of improving students' knowledge of chemistry. Muzyka and Luker provide a deeper, more encompassing picture of the cognitive and affective benefits of this pedagogy.

Exploring current themes in modern computational and membrane protein biophysics, this book presents a comprehensive account of the fundamental principles underlying different methods and techniques used to describe the intriguing mechanisms by which membrane proteins function. The book discusses the experimental approaches employed to study these proteins, with chapters reviewing recent crucial structural advances that have allowed computational biophysicists to discern how these molecular machines work. The book then explores what computational methods are available to researchers and what these have taught us about three key families of membrane proteins: ion channels, transporters and receptors. The book is ideal for researchers in computational chemistry and computational biophysics.

The first handbook to focus on the asymmetric synthesis of different types of three-membered rings. The outstanding and experienced authors have an excellent international reputation and cover cyclopropanes, epoxides and aziridines as well as chiral oxaziridines in equal measure. To this end, they describe in detail different synthetic approaches starting with chiral substrates as well as the application of chiral metal- or organocatalysts. Furthermore, methods for the kinetic resolution of initially racemic products are treated alongside recent advances and novel developments in established techniques for the synthesis of three-membered rings. With its structured composition this is of high interest to scientists in methodological and natural product synthesis as well as those in industrial and pharmaceutical chemistry.

Giant vesicles or giant liposomes are supramolecular assembles of amphiphiles, surface active substances which normally contain one or two hydrophobic chains and one hydrophilic head. Due to their relatively large size, giant vesicles are easily observed by light microscopy. This volume provides an overview of ideas and results obtained from experimental studies as well as theoretical approaches. A wide variety of aspects ranging from pure mathematics and physical considerations to biochemical and biological applications are covered. Historical and fundamental aspects are discussed as well as a range of experimental approaches including the micromanipulation and micro-puncturing of single giant vesicles. 87 international contributors comment on a wide range of issues contained under the five main part headings: Introduction Preparation Methods Basic Theoretical Aspects Physical Properties Chemical and Biological Aspects. Giant Vesicles has been written for researchers in the fields of chemistry, biochemistry and biophysics, working in supra-molecular chemistry, surfactant science, liposome and pharmaceutical sciences.

Details the use of advanced AFMs and addresses all types of functional AFMs First book to focus on application of AFM for energy research Enables readers to operate an AFM successfully and to understand the data obtained Covers new achievements in AFM instruments, including higher speed and resolution, automatic and deep learning AFM, and how AFM is being combined with other new methods like IR and Raman microscopy

Here, the authors introduce readers to solving molecular structure elucidation problems using the expert system ACD/Structure Elucidator. They explain in detail the concepts of the Computer-Assisted Structure Elucidation (CASE) approach and point out the crucial role of understanding the axiomatic nature of the data used to deduce the structure. Aspects covered include the main blocks of the expert system and essential features of the mathematical algorithms used. Graduate and PhD students as well as practicing chemists are provided with a detailed explanation of the various practical approaches depending on available spectral data peculiarities and the complexity of the unknown structure. This is supported by a large number of real-world completed examples, most of which are related to the structure elucidation of natural product molecules containing unusual skeletons. Dedicated software and further supplementary material are available at www.acdlabs.com/TeachingSE.

This book explores the remarkable information correspondences and probability structures of proteins. Correspondences are pervasive in biochemistry and bioinformatics: proteins share homologies, folding patterns, and mechanisms. Probability structures are just as paramount: folded state graphics reflect Angstrom-scale maps of electron density. The author explores protein sequences (primary structures), both individually and in sets (systems) with the help of probability and information tools. This perspective will enhance the reader's knowledge of how an important class of molecules is designed and put to task in natural systems, and how we can approach class members in hands-on ways.

Currently, the reliance on fossil fuels raises concerns on the increasing global energy demand, the rapid anthropogenic climate changes and growing environmental problems. The grand challenge is to search for viable carbon-neutral sources of renewable energy. Nanomaterials are arguably the base that integrates nanotechnology, information technology, and biotechnology; the major drivers of technological development today. Over the past decades, the understanding of form-function relations surrounding nanomaterials has significantly brightened the prospects of the transition from fossil fuels to solar fuels. This book introduces the latest developments in nanomaterials aimed at the applications in clean energy areas. It overviews the close link between nanomaterials development and energy applications from the experience and perspective of the authors. It discusses the bottom-up synthesis and interface engineering of new materials of different dimensions and describes their applications in future energy devices such as secondary batteries, novel solar cells, luminescent devices, and water splitting electrolyzers. .

While books have been written on many topics of Polymer Science,no comp- hensive treatise o n l ong-chain b ranching has e ver b een c omposed.This se ries o f reviews in Volume 142 an d 143 o f Advances in P olymer Science tries to fill this gap by highlighting active areas of research on branched polymers. Long-chain branching is a p henomenon observed in s ynthetic polymers and in some natural polysaccharides.It has l ong been r ecognized as a ma jor molecular parameter of macromolecules.Its presence was first surmised by H.Staudinger and G.V.Schulz (Ber.68,2320,1935).Interestingly,their method of identifica- on b y m eans o f the a bnormal r elation b etween in trinsic viscosity an d mo lecular weight has s urvived to this day.Indeed,the most sophisticated method for a- lysis o f long-chain b ranching use s size ex clusion fractionation with the simul- neous recording of mass,molecular weight and intrinsic viscosity of the fr- tions.

The field of electrochemistry is exploring beyond its basic principles to innovation. New Technologies for Electrochemical Applications presents advancements in electrochemical processes, materials, and technology for electrochemical power sources such as batteries, supercapacitors, fuel cells, hydrogen storage and solar cells. It also examines various environmental applications such as photo electrochemistry, photosynthesis, and coating. Organized to give readers an overview of the current field in electrochemical applications, this book features a historical timeline of advancements and chapters devoted to the topics of organic material and conducting polymers for electrochemical purposes. Established experts in the field detail state-of-the-art materials in biosensors, immunosensors, and electrochemical DNA. This edited reference is a valuable resource for graduate and post-graduate students, and researchers in disciplines such as chemistry, physics, electrical engineering and materials science.

This book is devoted to the problems of oxidation chemical reactions and addresses bimodal reaction sequences. Chemical reactions of oxidation, occurring under certain conditions and in multicomponent systems are complex processes. The process of the oxidation essentially changes in the presence and contact of the solid substances with reactants. The role of solid substances and the appearance of this phenomenon in oxidation reaction are discussed. The reader will understand the "driving forces" of this phenomenon and apply it in practice. Written for chemists, physicists, biologists and engineers working in the domain of oxidation reactions. Key Selling Features: Covers the historical background, modern state of the art, and perspectives in investigations of the coupling between heterogeneous and homogeneous reactions Discusses the feasible pathways of the coupling of heterogeneous and homogeneous reactions in oxidation in man-made and natural chemical systems Addresses the abundance, peculiarities and mechanisms of the bimodal reaction sequences in oxidation with dioxygen in recent decades Discusses the existence of the bimodal reaction sequences in chemical systems investigations in atmospheric chemistry and heterogeneous photocatalysis Presented in a simple concise style, accessible for both specialists and non-specialists

Low-dimensional magnetism physics involves the search for new magnetic compounds and improving their characteristics to meet the needs of innovative technologies. A comprehensive overview of key materials, their formulation data and characteristics are detailed by the author. Key selling features: Explores dominant mechanisms of magnetic interaction to determine the parameters of exchange interactions in new magnetic materials. Describes how magnetism and superconductivity not only compete, but also "help" each other. Details characteristics of key materials in the magnetic subsystem. Results of several internationally renowned research groups are included and cited. Suitable for a wide range of readers in physics, materials science, and chemistry interested in the problems of the structure of matter.

The Workshop brought together researchers and engineers working in adsorption-related fields. Its purpose was to share knowledge on the latest advances on adsorption processes for environmental security and protection, as well as to cross-link and disseminate to the scientific community the main results and achievements of recent NATO Science-for-Peace (SfP) projects on environmental security and protection. The topics covered by the Workshop include recent theoretical and experimental developments on environmental adsorption, adsorption processes, as well as synthesis and tailoring of novel adsorbents, including the assessment of materials and processes.The published material provides a comprehensive and up-to-date report on adsorption and colloids phenomena, carbon materials and adsorbents for various industrial applications, ecological safety and antiterrorism.

Stresses the Potential Applications of Biosurfactants in Various Industries Environmental concerns and a demand for sustainable chemical production have become important issues in recent years. As a result, microbial biosurfactant-producing systems are gaining momentum as potential replacements for chemical surfactants. Biosurfactants: Production and Utilization-Processes, Technologies, and Economics explores the production, utilization, and industrial/economic use of biosurfactants in modern biotechnology. This book represents comprehensive material developed by contemporary experts in the field. Focusing on research and developments within the last 20 years, it highlights relevant changes in the industry. It provides a detailed account of the current applications of biosurfactants, considers the potential for further environmental, biological, and industrial applications, and concentrates on surfactants and organisms with possibilities for future use. Emphasizes Process Scale-Up and Commercialization Factoring in the industrial application of biosurfactant production based on renewable resources, the book determines how biosurfactants can enhance or replace the properties of chemically synthesized surface-active agents. It discusses moving beyond the laboratory scale of research and development and on to the industrial scale of commercial interest. The book consists of 17 chapters and features expert authors discussing topics that include: Understanding the regulatory processes controlling the production of biosurfactants Strategies for feasible commercial biosurfactant production Examples of cost analysis based on published information The viability of industrial applications in food, cosmetics, and pharmaceuticals Patents for future trends Biosurfactants: Production and Utilization-Processes, Technologies, and Economics contains special sections devoted to the overview and evaluation of specific patents relating to biosurfactants, and methods for production of biosurfactants on a laboratory and industrial/commercial scale. It also presents novel and proven applications for biosurfactants from a number of biotechnology laboratories and research facilities around the world. In addition, it introduces the reader to a variety of real-world industry techniques readily applicable for practical use.

Oxide-based materials and structures are becoming increasingly important in a wide range of practical fields including microelectronics, photonics, spintronics, power harvesting, and energy storage in addition to having environmental applications. This book provides readers with a review of the latest research and an overview of cutting-edge patents received in the field. It covers a wide range of materials, techniques, and approaches that will be of interest to both established and early-career scientists in nanoscience and nanotechnology, surface and material science, and bioscience and bioengineering in addition to graduate students in these areas. Features: Contains the latest research and developments in this exciting and emerging field Explores both the fundamentals and applications of the research Covers a wide range of materials, techniques, and approaches

This book presents tutorial overviews for many applications of variational methods to molecular modeling. Topics discussed include the Gibbs-Bogoliubov-Feynman variational principle, square-gradient models, classical density functional theories, self-consistent-field theories, phase-field methods, Ginzburg-Landau and Helfrich-type phenomenological models, dynamical density functional theory, and variational Monte Carlo methods. Illustrative examples are given to facilitate understanding of the basic concepts and quantitative prediction of the properties and rich behavior of diverse many-body systems ranging from inhomogeneous fluids, electrolytes and ionic liquids in micropores, colloidal dispersions, liquid crystals, polymer blends, lipid membranes, microemulsions, magnetic materials and high-temperature superconductors. All chapters are written by leading experts in the field and illustrated with tutorial examples for their practical applications to specific subjects. With emphasis placed on physical understanding rather than on rigorous mathematical derivations, the content is accessible to graduate students and researchers in the broad areas of materials science and engineering, chemistry, chemical and biomolecular engineering, applied mathematics, condensed-matter physics, without specific training in theoretical physics or calculus of variations.

An in-depth discussion of the thermodynamics and kinetics of natural waters

Divided into three major parts–structure of matter, chemical thermodynamics, and chemical kinetics– physical chemistry is concerned with the measurement, description, and prediction of the characteristics of chemical systems and their interaction with each other with respect to the transfer of mass and energy. Physical Chemistry of Natural Waters explores how the basic concepts of physical chemistry can be used to understand the chemistry of natural waters, with most of the text confined to chemical thermodynamics and kinetics.

The extensive material in this book is the result of a course in marine physical chemistry that the author has taught over the past decade. Dr. Millero incorporates his own personal interest in solution physical chemistry and his approach to understanding the physical chemistry of seawater with the text’s vast coverage of the physical chemistry of liquid phases. In addition, detailed reviews of the basics of thermodynamics and kinetics provide a comprehensive overview for a clearer understanding of the topics covered.

Environmental and physical chemists conducting research on water, seawater, rivers, lakes, and groundwater as well as graduate students studying environmental chemistry will find Physical Chemistry of Natural Waters a solid foundation on the subject of the physical chemistry of natural waters.

Electrolyte solutions play a key role in traditional chemical industry processes as well as other sciences such as hydrometallurgy, geochemistry, and crystal chemistry. Knowledge of electrolyte solutions is also key in oil and gas exploration and production, as well as many other environmental engineering endeavors. Until recently, a gap existed between the electrolyte solution theory dedicated to diluted solutions, and the theory, practice, and technology involving concentrated solutions. Electrolytes: Supramolecular Interactions and Non-Equilibrium Phenomena in Concentrated Solutions addresses concentrated electrolyte solutions and the theory of structure formation, super and supramolecular interactions, and other physical processes with these solutions-now feasible due to new precision measurement techniques and experimental data that have become available. The first part of the book covers the electrolyte solution in its stationary state-electrostatic, and various ion-dipole, dipole-dipole, and mutual repulsion interactions. The second part covers the electrolyte solution in its nonstationary status, in the case of forced movement between two plates-electrical conductivity, viscosity, and diffusion. This theoretical framework allows for the determination of activity coefficients of concentrated electrolyte solutions, which play a key role in many aspects of electrochemistry and for developing novel advanced processes in inorganic chemical plants.

Physical-Chemical Mechanics of Disperse Systems and Materials is a novel interdisciplinary area in the science of the disperse state of matter. It covers the broad spectrum of objects and systems with dimensions ranging from nanometers to millimeters and establishes a fundamental basis for controlling and tuning the properties of these systems as well as the processes taking place in them. Physical-chemical mechanics focuses on the analysis of the complex physical-chemical interfacial phenomena taking place both in the transition of a dispersed system into a material, such as in the course of pressing, sintering, hydration hardening, and sol-gel transitions, and in the course of the dispersion of bulk materials taking place in milling, mechanical treatment, friction and wear, and fracturing. These studies are based on thorough experimental investigation of contact interactions between particles in these processes. The book is divided into two sections. The first section covers basic principles of the formation, stability and rupture of contacts between particles in different media and in surfactant solutions, as well as the properties of coagulation structures and their rheology. The second section covers surface phenomena taking place in solid-like structures with phase contacts and in compact bodies with an emphasis on several applications and processes as well as the special role of the Rehbinder effect. Where appropriate and relevant, the book presents essays on specific significant and principal studies, such as the damageability of crystal and glass surfaces, the strength of industrial catalysts, the nano-mechanisms of cement hardening, the role of the structure-mechanical barrier in the stabilization of fluorinated systems, and contact interactions in papermaking. It also devotes attention to experimental methods used in physical-chemical mechanics, the direct measurement of contact strength, and relevant instrumentations. The book utilizes the content used over many years in lecture courses and includes fundamental material on colloid and surface chemistry, the strength of materials, rheology, and tensors, which makes it well suited for novices and experts in the field.