A bestseller in its first edition, Liquid Detergents, Second Edition captures the most significant advances since 1996, maintaining its reputation as a first-stop reference in all fundamental theories, practical applications, and manufacturing aspects of liquid detergents. Featuring new material and updates in every chapter, the book expands its coverage of emulsions to include nanoemulsions, adds new data to elucidate the rheology of current commercial detergent raw materials as compared to finished products, and offers a more complete theoretical treatment of the aggregation in non-aqueous solvents. The book now covers all rheology modifiers and thickeners for detergent applications, antibacterial and sensorial light-duty liquid products, color/fabric care and wrinkle reduction in heavy-duty liquid detergents, and household cleaning wipes in specialty liquid household surface cleaners. Rewriting the chapters on the latest improvements and growing benefits in fabric softeners, liquid hand soaps and body washes, and shampoos and conditioners, the latter contains extensive summaries of patents for various new products and technologies. The final chapter, dedicated to the manufacturing of liquid detergents, offers a discussion on continuous vs. batch processes and micro-contamination. The most comprehensive guide of its kind, Liquid Detergents, Second Edition, is a balanced and practical reference that will continue to inspire students, researchers, chemists, and product developers in detergent industry, surfactant science and industrial chemistry.

Completely revised and expanded throughout, Mixed Surfactant Systems, Second Edition surveys the latest results, newest experimental perspectives, and theoretical investigations of properties, behavior, and techniques applicable to mixed surfactant systems. This important book elucidates core theoretical notions while summarizing results of cutting-edge studies in nanoscale phase separation at monolayers of mixed amphiphiles, nanocapsule preparation through mixtures of cationic and anionic polymer amphiphiles, and the photodegradation of mixed surfactant systems by titanium dioxide. The book provides new sections on topics including: Diffusion of mixed micelles Mixed micelles of fluorinated and conventional surfactants Sponge-like vesicles of mixed surfactants Liquid crystals of mixed surfactants Mixtures of surfactants and polymers Photolysis of mixed surfactants Reflecting the abundance of current and emerging applications in the field, Mixed Surfactant Systems, Second Edition compiles chapters written by world-renowned leaders in industry for an up-to-date scientific account of the dynamics of mixed surfactant systems, including physicochemical properties and behavior of surfactant mixtures in detergency and surfactant precipitation.

Providing in-depth coverage of the technologies and various approaches, Luminous Chemical Vapor Deposition and Interface Engineering showcases the development and utilization of LCVD procedures in industrial scale applications. It offers a wide range of examples, case studies, and recommendations for clear understanding of this innovative science. The book comprises four parts. Part 1 describes the fundamental difference between glow discharge of an inert gas and that of an organic vapor, from which the concepts of Luminous Gas Phase derive. Part 2 explores the various ways of practicing Luminous Vapor Disposition and Treatment depending on the type and nature of substrates. Part 3 covers some very important aspects of surface and interface that could not have been seen clearly without results obtained by application of LCVD. Part 4 offers some examples of interface engineering that show very unique aspects of LCVD interface engineering in composite materials, biomaterial surface and corrosion protection by the environmentally benign process. Timely and up-to-date, the book provides broad coverage of the complex relationships involved in the interface between a gas/solid, liquid/solid, and a solid/solid. The author presents a new perspective on low-pressure plasma and describes key aspects of the surface and interface that could not be shown without the results obtained by LCVD technologies. Features Provides broad coverage of complex relationships involved in interface between a gas/solid, a liquid/solid, and a solid/solid Addresses the importance of the initial step of creating electrical glow discharge Describes the principles of creating chemically reactive species and their growth in the luminous gas phase Focuses on the nature of surface-state of solid and on the creation of imperturbable surface-state by the contacting phase or environment, which is vitally important in creating biocompatible surface, providing super corrosion protection of metals by environmentally benign processes, etc. Offers examples on how to use LCVD in the interface engineering process Presents a new view on low-pressure (low-temperature) plasma and emphasizes the importance of luminous gas phase and chemical reactions that occur in the phase About the author: Dr. Yasuda is one of the pioneers who explored low-pressure plasma for surface modification of materials and deposition of nano films as barrier and perm-selective membranes in the late 1960s. He obtained his PhD in physical and polymer chemistry working on transport properties of gases and vapors in polymers at State University of New York, College of Environmental Science and Forestry at Syracuse, NY. He has over 300 publications in refereed journals and books, and is currently a Professor Emeritus of Chemical Engineering, and Director, Center for Surface Science & Plasma Technology, University of Missouri-Columbia, and is actively engaged in research on the subjects covered by this book.

At the interface of chemical industry operations, equipment manufacturer input, and the scientific literature, Industrial Crystallization of Melts explores and explains melt crystallization and purification in the industrial arena. This comprehensive account details the orderly conversion of melts into solid, salable end materials and procedures for purification by remelting; summarizes key theoretical concepts relating to crystalline matter and instationary heat transfer; and surveys the equipment available for specific processes. It also offers over 100 tested equations, as well as clear-cut methods for handling organic melts that call for special crystallization provisions.

Chemists increasingly apply electrochemical methods to the investigation of their systems, in particular towards a better understanding of molecular properties, the exploration of chemical reactions involving electron-transfer (ET), the initiation of further reactions by ET, the kinetic measurements, and the establishment of the reaction mechanisms, as well as the synthesis (electrosynthesis) of desired products. Trends in Molecular Electrochemistry presents recent research on procedures in molecular electroactivation and electrocatalysis, bioelectrochemistry, spectroelectrochemistry, and unconventional electrochemistry. The book highlights the state-of-the-art in the application of electrochemistry by taking an interdisciplinary approach to the study of both static and dynamic molecular properties of coordination compounds as well as inorganic, bioinorganic, and organometallic complexes, supramolecular systems, and metalloenzymes. The principles and approaches are often also valid for organic systems, which are illustrated in various contexts.

Leading readers through an extensive compilation of surface modification reactions and processes for specific tribological results, this reference compiles detailed studies on various residual stresses, reaction processes and mechanisms, heat treatment methods, plasma-based techniques, and more, for a solid understanding of surface structural changes that occur during various engineering procedures. This unique book explores topics previously ignored in other texts on surface engineering and tribology, offers guidelines for the consideration and design of wear life and frictional performance, and sections on laser impingement and nanometer scale surface modification.

Microporous Media presents new developments from nearly a decade of advancement. Written by a leading researcher in the field, this reference provides examples of the most original scientific and technical research impacting studies in porosity and microporosity, and illustrates methods to forecast the properties of microporous structures for improved electronic, construction, electrical, chemical, and medical applications. The book outlines new results in fractal, self-organization, and polymer theories; pore aging, and percolation; and their various engineering applications, and considers the impact of preparation conditions on the structure and properties of microporous materials.

A complete and up-to-date presentation of the fundamental theoretical principles and many applications of solvent extraction, this enhanced Solvent Extraction Principles and Practice, Second Edition includes new coverage of the recent developments in solvent extraction processes, the use of solvent extraction in analytical applications and waste recovery, and computational chemistry methods for modeling the solvent extraction of metal ions. Offering sound scientific and technical descriptions in a format accessible to students and expedient for researchers and engineers, this edition also features a new chapter on ionic strength corrections and contains more than 850 up-to-date literature citations.

Perturbation theory is a powerful tool for solving a wide variety of problems in applied mathematics, a tool particularly useful in quantum mechanics and chemistry. Although most books on these subjects include a section offering an overview of perturbation theory, few, if any, take a practical approach that addresses its actual implementation Introduction to Perturbation Theory in Quantum Mechanics does. It collects into a single source most of the techniques for applying the theory to the solution of particular problems. Concentrating on problems that allow exact analytical solutions of the perturbation equations, the book resorts to numerical results only when necessary to illustrate and complement important features of the theory. The author also compares different methods by applying them to the same models so that readers clearly understand why one technique may be preferred over another. Demonstrating the application of similar techniques in quantum and classical mechanics, Introduction to Perturbation Theory in Quantum Mechanics reveals the underlying mathematics in seemingly different problems. It includes many illustrative examples that facilitate the understanding of theoretical concepts, and provides a source of ideas for many original research projects.

Certain small solid particles are surface-active at fluid interfaces and thus are able to stabilize materials previously considered impossible to stabilize in their absence. Liquid marbles, particle-coated non-sticking liquid droplets, represent one of these materials. Preparation of liquid marbles was described only about 15 years ago and they are now widely studied by many research groups and numerous applications of liquid marbles have been advanced. The book is written for postgraduates and researchers working on the area who are training to become chemists, soft matter physicists, materials scientists, and engineers.

Oxide-based materials and structures are becoming increasingly important in a wide range of practical fields including microelectronics, photonics, spintronics, power harvesting, and energy storage in addition to having environmental applications. This book provides readers with a review of the latest research and an overview of cutting-edge patents received in the field. It covers a wide range of materials, techniques, and approaches that will be of interest to both established and early-career scientists in nanoscience and nanotechnology, surface and material science, and bioscience and bioengineering in addition to graduate students in these areas. Features: Contains the latest research and developments in this exciting and emerging field Explores both the fundamentals and applications of the research Covers a wide range of materials, techniques, and approaches

The use of silver as an antibacterial agent has been known for thousands of years. This effect can be amplified by simply reducing the size of silver particles to the nanoscale, with an added advantage of reduction in cost and toxicity. Application of silver nanoparticles to textiles can bring considerable advantages, especially for materials that cannot be washed daily or medical support materials. This book describes a novel synthesis method that the author calls "in situ," in which these nanoparticles are obtained directly on materials. The method is simple and easy to apply and can also be considered green because the reducing agent involved is ascorbic acid, commonly known as vitamin C. It neither requires special modifications in the industrial equipment nor special pressure or temperature conditions. It can be used to grow other metals or metal oxides on a material. The book showcases studies carried out on silver nanoparticles by the author over several years, not only in terms of the synthesis but also the morphological characterization of the substrate to which they were applied. It exhibits SEM images displaying the homogeneity of the silver coating, highlighting that sometimes the simplest way is the best way.

Supramolecular aggregation-driven by weak non-covalent interactions, such as van der Waals, - interactions, hydrogen bonding, and electrostatic-has been utilized to build sensing platforms with improved selectivity and sensitivity. Supramolecular aggregates, owing to cooperative interactions, higher sensitivity and selectivity, relatively weak and dynamic non-covalent interactions, and environmental adaptation, have achieved better sensing performance than that of molecular sensory systems that rely on sensors with delicate structures. Aggregation of Luminophores in Supramolecular System: From Mechanisms to Applications describes recent advances in supramolecular chemistry, in which the luminophores are almost non-luminescent in the molecular state, but become highly emissive in the aggregate state. These advances bring new opportunities and challenges for the development of supramolecular chemistry. The intermolecular non-covalent interactions have been considered to be the main driving forces for fabricating supramolecular systems with aggregating luminophores and have an important influence on the luminescence properties of the probes. Based on these unique properties, luminescent supramolecular aggregates have greatly promoted the development of novel materials for applications as sensors, bio-imaging agents, organic electronic devices, and in the field of drug delivery. Features: Discussion of fundamental and interdisciplinary aspects of the aggregation in supramolecular systems. Narration of intermolecular interactions and the photophysical phenomenon of aggregation in supramolecular systems. Comparative discussion on recent developments in aggregation-induced quenching (AIQ) and aggregation-induced emission (AIE), and drawbacks of AIQ. Description of the technological applications of aggregation as biological sensors, chemical sensors, organic electronic materials, and in the field of drug delivery. A convenient format for checking formulas and definitions. This book surveys highlights of the progress made in the field of the aggregation of luminophores in supramolecular chemistry. It is hoped that the work will form a foundation (and indeed a motivation) for new workers in the area, as well as also being useful to experienced supramolecular chemists. It may also aid workers in the biological area to see Nature's aggregation in a new light. Further, the approach employed has been designed to provide readable background material for use with graduates, senior undergraduates, research professionals, and industries.

EPR Spectroscopy in Catalysis, by Sabine Van Doorslaer und Damien M. Murphy Radicals in Flavoproteins, by Erik Schleicher und Stefan Weber EPR Spectroscopy in Polymer Science, by Dariush Hinderberger EPR in Protein Science, by Intrinsically Disordered Proteins, by Malte Drescher Site-Directed Spin Labeling of Membrane Proteins, by Enrica Bordignon Structure and Dynamics of Nucleic Acids, by Ivan Krsti, Burkhard Endeward, Dominik Margraf, Andriy Marko und Thomas F Prisner New Directions in Electron Paramagnetic Resonance Spectroscopy on Molecular Nanomagnets, by J. van Slageren"

Surface and colloid chemistry principles impact many aspects of our daily lives, ranging from the cleaners and cosmetics we use to combustion engines and cement. Exploring the range of this field of study, Surface and Colloid Chemistry provides a detailed analysis of its principles and applications and demonstrates how they relate to natural phenomena and industrial processes. Surface and colloid chemistry at work in nature and industry: rain drops combustion engines soap bubbles foam food products air pollution waste-water treatment washing and cleaning cosmetics painting and printing oil and gas production oil spills plastics and polymers biology and pharmaceuticals milk products cement adhesive coal The book begins with an introduction to surfaces and colloids. It describes basic considerations regarding liquids and capillarity, and examines the liquid-solid interface phenomena. It explores the physicochemical properties of surfactants, Langmuir-Blodgett films, adsorption on solid surfaces, and adsorption as it relates to cleaning processes. Then the author examines colloidal systems and thin liquid films before moving on to emulsion science and technology. The final chapter provides examples of applications in science and a range of industries. Examples and Illustrations Integrating real-world examples throughout the text, this volume stimulates readers to consider both fundamental theory and industrial applications. More than 100 figures elucidate the concepts described in the text. Sample questions and answers are provided where appropriate, along with detailed data and discussions. Pertinent references are offered to facilitate further study.

High Temperature Gas Dynamics is a primer for scientists, engineers, and students who would like to have a basic understanding of the physics and the behavior of high-temperature gases. It is a valuable tool for astrophysicists as well. The first chapters treat the basic principles of quantum and statistical mechanics and how to derive thermophysical properties from them. Special topics are included that are rarely found in other textbooks, such as the thermophysical and transport properties of multi-temperature gases and a novel method to compute radiative transfer. Furthermore, collision processes between different particles are discussed. Separate chapters deal with the production of high-temperature gases and with electrical emission in plasmas, as well as related diagnostic techniques. This new edition adds over 100 pages and includes the following updates: several sections on radiative properties of high temperature gases and various radiation models, a section on shocks in magneto-gas-dynamics, a section on stability of 2D ionized gas flow, and additional practical examples, such as MGD generators, Hall and ion thrusters, and Faraday generators.

Constitutional Dynamic Chemistry: Bridge from Supramolecular Chemistry to Adaptive Chemistry, by Jean-Marie Lehn Multistate and Phase Change Selection in Constitutional Multivalent Systems, by Mihail Barboiu Dynamic Systemic Resolution, by Morakot Sakulsombat, Yan Zhang and Olof Ramstroem Dynamic Combinatorial Self-Replicating Systems, by Emilie Moulin and Nicolas Giuseppone DCC in the Development of Nucleic Acid Targeted and Nucleic Acid Inspired Structures, by Benjamin L. Miller Dynamic Nanoplatforms in Biosensor and Membrane Constitutional Systems, by Eugene Mahon, Teodor Aastrup und Mihail Barboiu Dynamic Assembly of Block-Copolymers, by D. Quemener, A. Deratani und S. Lecommandoux Dynamic Chemistry of Anion Recognition, by Radu Custelcean Supramolecular Naphthalenediimide Nanotubes, by Nandhini Ponnuswamy, Artur R. Stefankiewicz, Jeremy K. M. Sanders und G. Dan Pantos Synthetic Molecular Machines and Polymer/Monomer Size Switches that Operate Through Dynamic and Non-Dynamic Covalent Changes, by Adrian-Mihail Stadler und Juan Ramirez Reversible Covalent Chemistries Compatible with the Principles of Constitutional Dynamic Chemistry: New Reactions to Create More Diversity, by Kamel Meguellati und Sylvain Ladame.

The statistical mechanical theory of liquids and solutions is a fundamental area of physical sciences with important implications in other fields of science and for many industrial applications. This book introduces equilibrium statistical mechanics in general, and statistical mechanics of liquids and solutions in particular. A major theme is the intimate relationship between forces in a fluid and the fluid structure - a relationship that is paramount for the understanding of the subject of interactions in dense fluids. Using this microscopic, molecular approach, the text emphasizes clarity of physical explanations for phenomena and mechanisms relevant to fluids, addressing the structure and behavior of liquids and solutions under various conditions. A notable feature is the author's treatment of forces between particles that include nanoparticles, macroparticles, and surfaces. The book provides an expanded, in-depth treatment of simple liquids and electrolytes in the bulk and in confinement. Provides an introduction to statistical mechanics of liquids and solutions with special attention to structure and interactions. Offers an extensive presentation starting with the basics of statistical mechanics to modern aspects of the theory of liquids and solutions, including intermolecular interactions in fluids. Treats both homogeneous bulk fluids and inhomogeneous fluids near surfaces and in confinement. Takes a microscopic, molecular approach that combines physical transparency, theoretical sharpness and a pedagogical and accessible style. Gives explicit and clear textual explanations and physical interpretations for any mathematical relationships and derivations. Goes deeper than the available texts on interactions in fluids, by taking the discussion beyond simple approximations and mean field approaches. The book will be an invaluable resource for advanced undergraduate, graduate, and postgraduate students in physics, chemistry, soft matter science, surface and colloid science and related fields, as well as professionals and instructors in those areas of science.

There has been an explosion of interest in the study of molecular crystals, and their applications in optics and electronics. This advanced 1994 textbook describes their chemical and physical structure, their optical and electronic properties and the reactions between neighbouring molecules in crystals. The author has taken into account research areas which have undergone extremely rapid development since the first edition was published in 1987. For instance, this edition features the applications of molecular materials in high-technology devices. There is also an additional chapter on C60 and organic non-linear optic materials. The level of treatment is aimed at first-year postgraduates or workers in industrial research laboratories wishing to gain insights into organic solid state materials. Molecular Crystals is also suitable for special topics in final year undergraduate courses in chemistry, physics and electronic engineering.

Describes extensively the design and microfabrication of nanosensors based on nanotechnological tools. Provides a wide range of bioplatforms based on e.g., carbon nanostructures and Describes extensively a large number of application as a part of Nanomaterial based biosensors.

Environmental protection and sustainability are major concerns in today's world, and a reduction in CO2 emission and the implementation of clean energy are inevitable challenges for scientists and engineers today. The development of electrochemical devices, such as fuel cells, Li-ion batteries, and artificial photosynthesis, is vital for solving environmental problems. A practical device requires designing of materials and operational systems; however, a multidisciplinary subject covering microscopic physics and chemistry as well as macroscopic device properties is absent. In this situation, multiscale simulations play an important role. This book compiles and details cutting-edge research and development of atomistic, nanoscale, microscale, and macroscale computational modeling for various electrochemical devices, including hydrogen storage, Li-ion batteries, fuel cells, and artificial photocatalysis. The authors have been involved in the development of energy materials and devices for many years. In each chapter, after reviewing the calculation methods commonly used in the field, the authors focus on a specific computational approach that is applied to a realistic problem crucial for device improvement. They introduce the simulation technique not only as an analysis tool to explain experimental results but also as a design tool in the scale of interest. At the end of each chapter, a future perspective is added as a guide for the extension of research. Therefore, this book is suitable as a textbook or a reference on multiscale simulations and will appeal to anyone interested in learning practical simulations and applying them to problems in the development of frontier and futuristic electrochemical devices.

This book provides a cross section of the theoretical and practical results achieved in gas-solid and liquid-solid adsorption. It contains monographs at a scientific level and some chapters include parts that can be used by Ph.D.-level students or by researchers working in industry.

Molecular and Colloidal Electro-Optics presents cohesive coverage from internationally recognized experts on new approaches and developments in both theoretical and experimental areas of electro-optic science. It comprises a well-integrated yet multi-disciplinary treatment of fundamental principles, strategies, and applications of electro-optic techniques for the characterization of macromolecular, small-particle, and nanomolecular systems. Following a historical review of post-war advances in electro-optics of disperse systems, the first part of the book focuses on the latest achievements in electro-optic theory, particularly low-frequency relaxation. It offers comparative discussions and experimental data to accompany different viewpoints on the origin of the low-frequency effects and multiple theoretical constructions. The second part highlights the unique advantage of using electro-optics as an alternative to conventional characterization and analysis of colloidal systems. Demonstrating the sensitivity of electro-optic methods to interparticle interactions, the book explains how these methods are used to analyze particle surface electric states, evaluate phase transitions, and determine physical properties. As the first treatment of this subject to surface in more than fifteen years, Molecular and Colloidal Electro-Optics is a definitive, up-to-date portrait of modern colloidal electro-optic science. This one-stop reference to the latest theory, methods, and applications is ideal for advanced graduate students and researchers in biophysical chemistry, microbiology, polymer, colloid, and nanoscience.