This book documents the proceedings of the Second International Symposium on Adhesion Measurement of Films and Coatings, held in Newark, NJ, October 25-27, 1999. Since the First Symposium (Boston 1992) there had been considerable activity in devising new, more reliable and more efficient ways to measure adhesion of films and coatings, which resulted in the decision to organize the Newark Symposium. Films and coatings are used for a variety of purposes aEURO" functional, decorative, protective, etc. aEURO" in a host of applications. Irrespective of the purpose or application of a film or a coating, their adequate adhesion to the underlying substrates is of paramount importance. Concomitantly, the need to develop techniques for quantitative assessment of adhesion of films and coatings is all too obvious. This volume contains a total of 20 papers, which have all been rigorously peer reviewed and suitably modified before inclusion. The topics include: measurement and analysis of interface adhesion; relative adhesion measurement for thin film structures; adhesion testing of hard coatings by a variety of techniques; challenges and new directions in scratch adhesion testing of coated substrates; application of scratch test to different films and coatings; evaluation of coating-substrate adhesion by indentation experiments; measurement of interfacial fracture energy in multifilm applications; laser induced decohesion spectroscopy (LIDS) for measuring adhesion; pulsed laser technique for assessment of adhesion; blade adhesion test; JKR adhesion test; coefficient of thermal expansion measurement; and residual stresses in diamond films. This volume, providing the latest information, will be of great value and interest to anyone working in the area of adhesion measurement of films and coatings.

This book chronicles the proceedings of the International Symposium on Adhesion Measurement of Films and Coatings, held in Boston. The articles in this book were previously published in three special issues of the Journal of Adhesion Science and Technology. Films and coatings are used for a variety of purposes and their adequate adhesion to the underlying substrates is of cardinal importance from practical consideration. In the last two decades there has been brisk activity in devising new ways to measure adhesion or ameliorating the existing techniques.

This book is a collection of invited papers (previously published in special issues of the Journal of Adhesion Science and Technology) written by internationally recognized researchers actively working in the field of plasma surface modification. It provides a current, comprehensive overview of the plasma treatment of polymers. In contrast to plasma polymerization, plasma surface modification reactions do not cause thin-film deposition, and can therefore only modify the surface properties of organic substrates. Plasma surface modifications are fast, efficient methods for improving the adhesion properties and other surface characteristics of a variety of polymeric materials. The focus of this volume is on adhesion phenomena, surface properties and the surface characterization of plasma-treated materials. This book opens with a critical review of the plasma surface modification of polymers for improved adhesion. The remainder of the papers are divided into two sections, one dealing with the characterization of plasma-treated surfaces and the second concerned with various practical applications of plasma-treated surfaces

Despite the large quantity of phenomenological information concerning the bulk properties of nematic phase liquid crystals, little is understood about the origin of the surface energy, particularly the surface, interfacial, and anchoring properties of liquid crystals that affect the performance of liquid crystal devices. Self-contained and unique, Adsorption Phenomena and Anchoring Energy in Nematic Liquid Crystals provides an account of new and established results spanning three decades of research into the problems of anchoring energy and adsorption phenomena in liquid crystals. The book contains a detailed discussion of the origin and possible sources of anchoring energy in nematic liquid crystals, emphasizing the dielectric contribution to the anchoring energy in particular. Beginning with fundamental surface and anchoring properties of liquid crystals and the definition of the nematic phase, the authors explain how selective ion adsorption, dielectric energy density, thickness dependence, and bias voltage dependence influence the uniform alignment of liquid crystals and affect the performance of liquid crystal devices. They also discuss fundamental equations regulating the adsorption phenomenon and the dynamic aspects of ion adsorption phenomenon in liquid crystalline systems. Adsorption Phenomena and Anchoring Energy in Nematic Liquid Crystals serves as an excellent source of reference for graduates and researchers working in liquid crystals, complex fluids, condensed matter physics, statistical physics, chemical engineering, and electronic engineering, as well as providing a useful general introduction to and background information on the nematic liquid crystal phase.

This handbook provides the only complete collection of high-pressure thermodynamic data pertaining to polymer solutions at elevated pressures to date of all critical data for understanding the physical nature of these mixtures and applicable to a number of industrial and laboratory processes in polymer science, physical chemistry, chemical engineering, and biotechnology. In response to the increasing commercial interest due to the physico-chemical properties of these solutions, the CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures compiles information on experimental data from hundreds of primary journal articles, dissertations, and other papers into a single source entirely devoted to polymer solutions. The book contains data on vapor-liquid equilibria and gas solubilities, liquidaEURO"liquid equilibria, high-pressure fluid phase equilibria for polymer systems in supercritical fluids, enthalpic and volumetric data, and second virial coefficients, all at elevated pressures. An excellent companion to the author's previous publications, the CRC Handbook of Thermodynamic Data of Copolymer Solutions and the CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions, this handbook contains reliable, easy-to-use entries, references, tables, examples, and appendices that provide students, professors, and researchers with a well-organized, quick route to the data they need. The CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures is a staple resource for all university libraries as well as private laboratories, particularly for researchers, academics, and engineers who handle polymer systems in supercritical fluids, material science applications such as computerized predictive packages, and chemical and biochemical processes, such as synthesis and character

Increase in antibiotic resistance has forced researchers to develop new drugs against microorganisms. Lipopeptides are produced as secondary metabolites by some microorganisms. Computer-aided Design of Antimicrobial Lipopeptides as Prospective Drug Candidates provides the identification of novel ligands for different antimicrobial lipopeptides. Along with identification, it also provides some of the in silico drug design processes, namely homology modelling, molecular docking, QSAR studies, drug ADMET studies and pharmacophore studies to check the ligand-lipopeptide interaction. Some lipopeptides have shown anti-cancerous properties too, and this book discusses the required templates to design new drugs using computational techniques. Key Features: Focuses on the use lipopeptides as new antimicrobial compounds Presents the basics of in silico modelling for design and development of new drug molecules, and is therefore of interest to beginners in the field Provides a step-by-step process for identification of drug molecules and testing its efficacy in silico Couples with courses on patents and intellectual property rights

Focuses on copolymers made from sequential block polymerizations of ethylene oxide, propylene oxide and 1, 2-butylene oxide. This text presents the latest applications of polyoxyalkylene block copolymers in areas such as medicine, coal and petroleum, plastics, emulsion polymerization, paper, photography, personal care and cleaner systems. It offers in-depth coverage of the subject from synthesis and analysis to toxicology and environmental impact.

Quantum electrodynamics (QED) is the branch of relativistic quantum field theory that deals specifically with the interactions between charged particles. It is widely used to solve problems in many areas of physics, such as elementary particles, atomic and molecular systems, and solid state physics. This accessible text, Basics of Quantum Electrodynamics, supplies a solid foundation in this dynamic area of physics, making a direct connection to the concepts of quantum mechanics familiar to the advanced undergraduate student. Chapters cover the general theory of free fields and the quantization of the scalar, electromagnetic, and spinorial fields, which prepares readers for understanding field interactions. The authors describe the general theory of field interactions, introducing the scattering matrix and the Feynman-Dyson graphs. They then discuss divergence-free second-order processes, such as Compton and Moller scattering, followed by divergent second-order processes, which cover vacuum polarization and mass and charge renormalization. Providing a modern, informative textbook, this volume illustrates the intimate connection between quantum mechanics and QED in two basic steps: the quantization of free fields, followed by the theory of their interactions. The text contains solved problems to facilitate the application of the theory, as well as a useful appendix on the theory of distributions. The step-by-step description of the quantization of various fields and the clear presentation of the most important interaction processes in QED make this textbook a useful guide for those studying physics at both the graduate and undergraduate level, as well as a reference for teachers and researchers in the field.

The manufacture and use of almost every consumer and industrial product rely on application of advanced knowledge in surface science and tribology. These two disciplines are of critical importance in major economic sectors, such as mining, agriculture, manufacturing (including metals, plastics, wood, computers, MEMS, NEMS, appliances), construction, transportation, and medical instruments, transplants, and diagnostic devices. An up-to-date reference with contributions by experts in surface science and tribology, Surfactants in Tribology, Volume 3 discusses some of the underlying tribological and surface science issues relevant to many situations in diverse industries. The tradition of presenting new developments and research that began with the first volume in this groundbreaking series continues in the third volume. Comprising 19 chapters on various aspects of surfactants in tribology-including subjects not covered in previous volumes-this book is presented in four parts: Nanotribology and Polymeric Systems, Biobased and Environmentally Friendly Lubricants and Additives, Tribological Properties of Aqueous and Nonaqueous Systems, and Advanced Tribological Concepts. Topics include tribological properties of nanoparticles, biopolymer friction, environmentally friendly surface-active agents, biolubricants, aqueous mixed surfactant systems, and surfactants in motor oil, drilling fluids, and in electrowetting for MEMS and NEMS. The information in this volume provides a cutting-edge reference connecting the fields of surfactants and tribology as a way forward to novel, enhanced methods of controlling lubrication, friction, and wear. Written by a global team of established authorities, this book reflects the latest developments, highlighting the relevance of surfactants in tribological phenomena in a broad range of industries. It provides a valuable resource for readers working in or entering the fields of

Reviews all known antifoam mechanisms, and discusses the appropriate practical approaches for solving foam control problems in a variety of industrial contexts. These range from crude oil production to detergent formulation.

In the tradition of the popular first edition, Analysis of Surfactants, Second Edition offers a comprehensive and practical account of analysis methods for determining and understanding commercially important surfactants-individually and in compounds. Combining a complete review of the literature with a variety of evaluation procedures and the specifications for commercial products, this useful reference explores the key stages and latest developments for surfactant applications. This edition has been thoroughly expanded and features new sections on capillary electrophoresis, ether carboxylates, and ester quats. It is also more globally accessible with foreign language citations and SI units. Containing over 2400 references, drawings, tables, and equations, Analysis of Surfactants, Second Edition is an recommended reference for physical, surface, colloid, and oil chemists; analytical, research, and quality assurance chemists working in the soap and detergent, pharmaceuticals, and cosmetic industries; regulatory and food scientists; and upper-level undergraduate and graduate students in these disciplines.

The extraordinary growth in the production and use of man-made fibers over the past fewdecades has focused attention on the surface properties of fibers and textiles. This volumecombines surface science and technology in its presentation of the substantial progressthat has been made in the technology related to the surface characteristics of natural,synthetic, and glass fibers and textiles.Adopting an interdisciplinary approach , the coverage places emphasis upon the wetting,soiling, staining, frictional, and adhesive properties of fibers and fabrics, as well asphenomena related to these properties. The book offers critical reviews which describeexperimental facts, theories, and processes. Symbols are clearly defined in each chapter.Among the subjects covered are the surface properties of glass fibers, soil release, stainand water repellance, friction of fabrics, bonding of nonwovens, and the wetting of fibers.Surface Characteristics of Fibers and Textiles, Part II is an outstanding textbook forcourses dealing with surface chemistry, the mechanical properties of textiles, textiletechnology, and polymer chemistry . It is also a valuable reference book designed to makecurrent knowledge on these subjects accessible to industrial and academic researchers.

A response to increasingly stringent regulation of pollution and toxicity levels in industrial waste discharge, Micellar Enhanced Ultrafiltration: Fundamentals & Applications offers the most complete book available on the benefits and use of micellar-enhanced ultrafiltration (MEUF) to achieve continuous removal of organic and inorganic pollutants. An Unparalleled Book That Addresses Both Academic and Industrial Points of View Several membrane-based techniques, such as microfiltration, ultrafiltration, nanofiltration, and reverse osmosis, are currently used in a wide range of applications throughout the textile, pulp and paper, sugar, chemical, pharmaceutical, biomedical, biotechnological, and food industries. However, although reverse osmosis is an effective means of removing contaminants, this book explains why MEUF is a better substitute, as it less expensive, less energy-intensive, and more efficient and practical for a wider range of applications. Topics covered include: Effects of pollution in water and its consequences Various treatment processes and membrane technologies Fundamentals of ultrafiltration Outline of various membrane modules and modeling approaches Principles of colloid chemistry Theories of micelle formation Stability and dynamics of micelles Phenomena of counterion binding Solubilization of organic pollutants Selection criteria for surfactants Various flux enhancement techniques Recovery of precious metals This book conveys how, with proper selection of surfactant and membrane, MEUF can be used to efficiently remove almost all metal ions (heavy metals, lanthanides, radioa

Volume 45 in the highly successful series Handbook of Porphyrin Science presents three very informative chapters of significant topical interest to researchers in the broad field of porphyrin science. The first chapter (Chapter 215) systematically describes in great detail the many synthetic methods utilized for the preparation of both metal-free and metallo-phthalocyanines. In the second chapter (Chapter 216), new developments in the synthesis, structure, and circular dichroism of chiral porphyrin systems are discussed in depth. The third and final chapter in this volume (Chapter 217) describes up-to-date advances in the use of computational methodology for the design and synthesis of functionally useful tetrapyrroles such as phthalocyanines, porphyrins and 9. The volume concludes with a useful comprehensive index.The overall emphasis of Volume 45 of the Handbook of Porphyrin Science series, centers on synthetic methodology and processes, with a diversion in Chapter 217 to include predictive computational methodology, and in Chapter 216 to address the importance of chirality in tetrapyrrole systems. All three chapters will be of interest to researchers in the field and should provide powerful tools for anyone involved in the chemistry of phthalocyanines, porphyrins and related systems.

Cubes, triangular prisms, nano-acorn, nano-centipedes, nanoshells, nano-whiskers. . . . Now that we can create nanoparticles in a wide variety of shapes and morphologies, comes the next challenge: finding ways to organize this collection of particles into larger and more complex systems. Nanoparticle Assemblies and Superstructures, edited by pioneer of nanoparticle self-organization Nicholas A. Kotov, employs three critical questions to provide a framework of open-ended inquiry: What are the methods of organization of nanocolloids in more complex structures? What kind of structures do we need? What are the new properties appearing in nanocolloid superstructures? Pulling together a collection of contributors unmatched in both their expertise and enthusiasm, Kotov presents what he refers to as a snapshot of nanoassembly work in progress. The first section of this comprehensive volume provides background through an assessment of the current status of nanoparticle assembly development and the requirements for different applications of organized nanomaterials. The middle chapters explore the changes that occur in various properties of individual particles when they are brought together to form agglomerates and simple assemblies. In the final section, a number of top scientists describe various methods for organizing particles in complex nanostructured superstructures. These include techniques involving biological ligands and force fields, as well as methods based on self-organization. This remarkably prescient text upholds Kotov's belief that the research on organization of nanoparticles and other nanostructures, will most certainly uncover a wealth of "interesting discoveries and surprising phenomena." Nicholas A. Kotov has received several state, national, and international awards for his research on nanomaterials, including the Mendeleev Stipend, the Humboldt Fellowsh

For more than three decades the Electroanalytical Chemistry series has delivered the most in-depth and critical research related to issues in electrochemistry. Volume 22 continues this gold-standard with practical reviews of recent applications, as well as innovative contributions from internationally respected specialists-highlighting the emergence of new technologies and trends in the field. Previous volumes in the series were "highly recommended" by the Journal of the American Chemical Society and considered "essential" by the Journal of Solid State Electrochemistry, and this volume continues with a collection of state-of-the-art advances and studies of the highest caliber.

The development of nanostructured materials represents a new and fast evolving application of recent research in physics and chemistry. Novel experimental tools coupled with new theory have made this possible. Topics covered in this book include nanocrystals, semiconductor heterostructures, nanotubes, nanowires, and manipulation and fabrication techniques. The core of the book consists of ten lectures by five distinguished researchers, Paul Alivisatos, D.D. Awschalom, Sumio Iijima, Charles Lieber and Phaedon Avouris, presented at an Advanced Study Institute in Hong Kong in January 1999. It should interest materials physicists and chemists as well as materials scientists with an interest in the growth and characterisation of sophisticated materials.

The Ion Exchange and Solvent Extraction series treats ion exchange and solvent extraction both as discrete topics and as a unified, multidisciplinary study - presenting new insights for researchers in many chemical and related fields.;Volume 12 contains coverage of: the nature of metal-ion interaction with oppositely charged sites of ion exchangers; high-pressure ion exchange separation of rare earth elements; the commercial recovery of valuable minerals from seawater and brines by ion exchange and sorption; the kinetics of ion exchange in heterogenous systems; the ion-exchange equilibria of amino acids; and more.;The work is intended for analytical, co-ordination, process, separation, surface, organic, inorganic, physical and environmental chemists, geochemists, electrochemists, radiochemists, biochemists, biophysicists, hydrometallurgists, membrane researchers and chemical engineers.

The Ion Exchange and Solvent Extraction series treats ion exchange and solvent extraction both as discrete topics and as a unified, multidisciplinary study - presenting new insights for researchers in many chemical and related field. Containing current knowledge and results in ion exchange, this text: presents an overview of the chemical thermodynamics of cation-exchange reactions, with particular emphasis placed on liquid-phase- and solid-phase-activity coefficient models; describes the development of surface complexation theory and its application to the ion exchange phenomenon; discusses metal-natural colloid surface reactions and their consideration by surface complexation modelling complements; and covers the influence of humic substances on the uptake of metal ions by naturally occurring materials.

Kinetics, Transport, and Structure in Hard and Soft Materials is the only single reference that discusses the connection between structure and mechanisms of atomic or molecular transport in different classes of materials, from metals and semiconductors to network glasses, polymers and supercooled liquids. Divided into four parts, Part I begins with a discussion the fundamentals of transport, wherein transport properties of a system of non-interacting particles are calculated and the phenomenon of Brownian motion introduced. The phenomenology of diffusion is also discussed wherein Fick's laws are introduced and solved for a range of practical cases involving mass transport. Elementary Statistical mechanics, involving Partition functions, probability distribution functions and correlation functions, is discussed to lay the foundation for the subsequent discussion of mechanisms of transport in different materials. Parts II and III focus on mechanisms of transport in crystalline materials and in structurally disordered materials. Chapters explain how the mechanism of diffusional transport of an atom or molecule is intimately connected to the spatial organization of neighboring structural elements and to its interactions with them. The book reviews factors that control temperature dependent long-range dynamics of glass-forming systems. Diffusion and viscoelasticity of polymer melts, transport (viscous flow and ionic diffusion) in inorganic network glasses, and dynamic heterogeneity in super cooled liquids are described. Part IV analyzes the development of instabilities, such as spinodal decomposition and Mullins-Sekerka instabilities, which lead to the morphological evolution of materials. Kinetics, Transport, and Structure in Hard and Soft Materials emphasizes interdisciplinary nature of transport in materials, presenting its material in a user-friendly format for students from any discipline with a foundation in elementary

"Describes preparation techniques of protein-based surfactants (PBS) in the laboratory by a variety of chemical and enzymatic means, production by using different types of amino acids, and marketplace applications of PBS in medical and personal care products, detergents, cosmetics, antimicrobial agents, and foods."

This book gives physical chemists a broader view of potential biological applications of their techniques for the study of nucleic acids in the gas phase. It provides organic chemists, biophysicists, and pharmacologists with an introduction to new techniques they can use to find the answers to yet unsolved questions. Laboratory sciences have bloomed with a variety of techniques to decipher the properties of the molecules of life. This volume introduces techniques used to investigate the properties of nucleic acids in the absence of solvent. It highlights the specificities pertaining to the studies of nucleic acids, although some of the techniques can similarly be applied to the study of other biomolecules, like proteins. The first part of the book introduces the techniques, from the transfer of nucleic acids to the gas-phase, to their detailed physico-chemical investigation. Each chapter is devoted to a specific molecular property, and illustrates how various approaches (experimental and theoretical) can be combined for the interpretation.
The second part of the book is devoted to applying the gas-phase approaches to solve specific questions related to the biophysics, biochemistry or pharmacology of nucleic acids.

An exploration of the surface characteristics of fibres and textiles. It emphasizes how fibre surface affects permeability, stiffness, strength, dyeing, wrinkling, and other performance characteristics to optimize production. It also illustrates methods for developing wrinkle-resistant finishes on fibre surfaces using environmentally friendly techniques.

FROM THE PREFACE The surface modification of polymeric materials has been the object of a large number of investigations, but little attention has been paid to making a polymer surface frictionless or slippery, and lubricating surfaces are practically unmentioned in any books so far published, probably because of the relatively minor importance of polymer friction in industrial applications. A lubricating polymer surface is important, especially in marine and biomedical technologies. For instance, biomaterials to be used for catheterization on the urinary, tracheal, and cardiovascular tracts, or for endoscopy, should have a surface with good handling characteristics when dry and which preferably becomes slippery upon contact with body liquids. Such a low-friction surface must enable easy insertion and removal of the device from a patient. It would further prevent mechanical injury to the mucous membranes and minimize discomfort to the patient. Earlier approaches to providing a low-friction surface were mostly simple applications involving lubricants such as lidocaine jelly, silicone oil, or non-permanent coating with low-friction materials such as polyethylene or fluoroplastics. However, these substances cannot maintain a high degree of slipperiness for the required duration of time, due to the fact that they leach or disperse into the surrounding body fluids. The aim of this book is to describe the principle of lubrication, to outline a variety of methods for attaining a lubricous surface, and to describe the characteristics and properties of such lubricous surfaces. The technology for surface modification of polymers by grafting will find other applications than for lubrication, such as for improvement of the interfacial adhesion in polymer composites.

This volume reflects the huge breadth and diversity in research and the application of industrial and engineering chemistry and cheminformatics. The book presents cutting-edge research developments and new insights that emphasize the vibrancy of industrial and engineering chemistry and cheminformatics today. The first section of the book focuses on new insights in engineering chemistry while the second part looks at the promising future and novel approaches in chemical informatics, which has vast implications for industrial and pharmaceutical applications. Several chapters examine various industrial processes for emerging materials and determine practical use under a wide range of conditions, helping to establish what is needed to produce a new generation of materials.