This volume chronicles the proceedings of the Third International Symposium on Contact Angle, Wettability and Adhesion held in Providence, Rhode Island, May 20aEURO"23, 2002. This symposium was held to provide a forum to update and consolidate the research activity on this topic. The world of wettability is very wide as it plays an extremely important role in a legion of technological areas. This volume contains a total of 25 papers covering myriad aspects of contact angle and wettability. All manuscripts were rigorously peer-reviewed and all were revised and properly edited before inclusion in this volume. This book is divided into three parts: General Papers; Contact Angle Measurements/Determination and Solid Surface Free Energy; and Wetting and Spreading: Fundamental and Applied Aspects. The topics covered include: fundamental aspects of contact line region; effect of adsorbed vapor on liquidaEURO"solid adhesion; molecular origin of contact angles; various factors influencing contact angle measurements; different kinds of contact angles; various ways to measure contact angles; contact angle hysteresis; determination of solid surface free energies via contact angles; contact angle measurements on various materials (smooth, rough, porous, heterogeneous); factors influencing/dictating wetting and spreading phenomena; ultrahydrophobic polymer surfaces; switchable wettability; reactive wetting; wetting by nanocrystallites; dewetting; wetting of self-assembled monolayers; reversible wetting of structured surfaces; wetting in granular and porous media; relationship between wetting and adhesion; relevance/importance of wetting and surface energetics in technological applications, including food industry. This volume and its predecessors containing bountiful information will be of great interest and value to everyone interested in the contemporary R&D activity in the fascinating world of contact angles and wettability. The information garnered in these volumes will hopefull

Featuring contributions from leading experts, Organic Photochemistry and Photophysics is a unique resource that addresses the organic photochemistry and photophysical behavior in aromatic molecules, thiocarbonyls, selected porphyrins, and metalloporphyrins. The book presents theories pertaining to radiative and radiationless transitions. It describes excited-state proton-transfer reactions of aromatic compounds and the physical, energetic, and environmental effects of atom transfer reactions. The text discusses the role of the carbonyl and azo groups in ketones and azoalkanes in the development of photochemistry, followed by a review of nucleophilic substitution reactions in the photochemistry of aromatics (also called photosubstitution) and the various atomic bonds that result from these reactions. The book presents studies that explain the factors that govern the nature and efficiencies of SET-promoted photochemical reactions. It then focuses on photoamination as a convenient, powerful, and environmentally friendly synthetic process for transforming a variety of substrates into the corresponding aminated compounds. The final chapter explores how dye structure affects the sequence-dependence of DNA binding, which has potential applications in nonlinear optics and DNA detection as well as incorporating DNA into various nanostructures and devices. With an emphasis on the current uses of light in both materials chemistry and medicinal chemistry, this book serves as a comprehensive resource on photochemical reactions and discusses topics that are useful for researchers as well as newcomers in the fields of photochemistry, photobiology, photomedicine, and photophysics

This is the first book on interfacial rheology. It aims to describe both its history as well as the current, most frequently used experimental techniques for studying dilational and shear rheology of layers at liquid/gas and liquid/liquid interfaces. The book opens with a chapter on the fundamentals of interfacial rheology. All (16) contributions include the theoretical basis for the presented methodologies, and experimental examples are given.

This volume chronicles the proceedings of the 5th International Symposium on Contact Angle, Wettability and Adhesion, Toronto, Canada, June 2006. Wettability is of pivotal importance in many and varied arenas, ranging from mundane to micro-and nanofluidics to lithography to biomedical. It should be underscored that in the last years there has been burgeoning interest in replicating the so-called "Lotus Leaf Effect" to create superhydrophobic surfaces. This volume contains a total of 19 papers covering many facets of contact angle, wettability, and adhesion. All manuscripts were rigorously peer-reviewed and revised and edited before inclusion in this book. Concomitantly, this volume represents an archival publication of the highest standard. This book (5th volume in the series) is divided into three parts: Part 1 - Contact Angle Measurements and Solid Surface Free Energy; Part 2 - Relevance of Wetting in Cleaning and Adhesion; and Part 3 - Superhydrophobic Surfaces. The topics covered include fundamental aspects of contact angle and its measurement, solidification contact angles of micro-droplets, microscopic wettability of wood call walls, dynamic vapor-liquid interfacial tension, surface free energy of polymeric materials, surface cleanliness evaluation from wettability measurements, wettability parameters affecting surface cleanability of stainless steel and textiles, wetting and adhesion in fibrous materials, wettability and adhesion of coatings, adhesion of hydrophobizing agents, modulation of surface properties of polymers, graft efficiency and adhesion, relevance of interfacial free energy in cell adhesion, various approaches to create superhydrophobic surfaces, and adsorption of surfactants on hydrophobic and superhydrophobic surfaces.

Discusses measuring the surface properties of flat or particulate solids with contact angles of drops of high-energy liquids deposited on solid surfaces or via the thin-layer wicking technique. It focuses on Lifshitz-van der Waals, Lewis acid-base, and electrical double layer interactions.

Over the last decade, increased attention to reaction dynamics, combined with the intensive application of computers in chemical studies, mathematical modeling of chemical processes, and mechanistic studies has brought graph theory to the forefront of research. It offers an advanced and powerful formalism for the description of chemical reactions and their intrinsic reaction mechanisms. Chemical Reaction Networks: A Graph-Theoretical Approach elegantly reviews and expands upon graph theory as applied to mechanistic theory, chemical kinetics, and catalysis. The authors explore various graph-theoretical approaches to canonical representation, numbering, and coding of elementary steps and chemical reaction mechanisms, the analysis of their topological structure, the complexity estimation, and classification of reaction mechanisms. They discuss topologically distinctive features of multiroute catalytic and noncatalytic and chain reactions involving metal complexes. With it's careful balance of clear language and mathematical rigor, the presentation of the authors' significant original work, and emphasis on practical applications and examples, Chemical Reaction Networks: A Graph Theoretical Approach is both an outstanding reference and valuable tool for chemical research.

Update your knowledge of the chemical, biological, and physical properties of liquid-liquid interfaces with Liquid-Liquid Interfaces: Theory and Methods. This valuable reference presents a broadly based account of current research in liquid-liquid interfaces and is ideal for researchers, teachers, and students. Internationally recognized investigators of electrochemical, biological, and photochemical effects in interfacial phenomena share their own research results and extensively review the results of others working in their area. Because of its unusually wide breadth, this book has something for everyone interested in liquid-liquid interfaces. Topics include interfacial and phase transfer catalysis, electrochemistry and colloidal chemistry, ion and electron transport processes, molecular dynamics, electroanalysis, liquid membranes, emulsions, pharmacology, and artificial photosynthesis. Enlightening discussions explore biotechnological applications, such as drug delivery, separation and purification of nuclear waste, catalysis, mineral extraction processes, and the manufacturing of biosensors and ion-selective electrodes. Liquid-Liquid Interfaces: Theory and Methods is a well-written, informative, one-stop resource that will save you time and energy in your search for the latest information on liquid-liquid interfaces.

New Edition! Completely Revised and Updated Chemical Graph Theory, 2nd Edition is a completely revised and updated edition of a highly regarded book that has been widely used since its publication in 1983. This unique book offers a basic introduction to the handling of molecular graphs - mathematical diagrams representing molecular structures. Using mathematics well within the vocabulary of most chemists, this volume elucidates the structural aspects of chemical graph theory: (1) the relationship between chemical and graph-theoretical terminology, elements of graph theory, and graph-theoretical matrices; (2) the topological aspects of the Huckel theory, resonance theory, and theories of aromaticity; and (3) the applications of chemical graph theory to structure-property and structure-activity relationships and to isomer enumeration. An extensive bibliography covering the most relevant advances in theory and applications is one of the book's most valuable features. This volume is intended to introduce the entire chemistry community to the applications of graph theory and will be of particular interest to theoretical organic and inorganic chemists, physical scientists, computational chemists, and those already involved in mathematical chemistry.

With the rapid development of nanotechnology, the surface-to-volume ratio of objects of interest continues to increase. As such, so does the importance of our ability to tailor interfacial properties. Written by bestselling author and internationally renowned researcher K.S. Birdi, Introduction to Electrical Interfacial Phenomena offers comprehensive coverage of the field of electrical double layer (EDL) research. Birdi discusses theoretical models used with EDL and demonstrates how they can be applied to typically encountered real-world problems, including those that must be considered in modern industrial applications. The book explains the EDL through fundamental theory and real-world solved examples from applications such as corrosion, aerosols, dispersions and emulsions, adhesion, storage batteries, waste-water treatment, enhanced oil recovery, biology (proteins at cell membranes), and macromolecules. After introducing the electrical interfacial phenomenon, it describes advanced systems, provides a comprehensive description of the double layer, and presents bonus material on advanced theory separate from the main text. The book also includes application examples that demonstrate EDL analyses to new and developing areas such as enhanced oil recovery, storage batteries, hydrogen fuel cells, and biology. While there are many books available on this topic, so far none have taken a combined application and fundamental theoretical approach to the problem. Collating available information drawn from the extensive literature on various models of EDL into a comprehensive resource, this book paints a picture of the state of an art that is on the brink of further development. It not only delineates theoretical models, but also demonstrates how they can be applied to real problems.

"Presents the most comprehensive coverage available of the detection, isolation, identification, and estimation of all anionic surfactants in a wide variety of samples in trace and macro quantities. Features new chapters on volumetric and trace analysis, molecular and mass spectroscopy, and chromatographic processes."

This book is a mini-encyclopedia providing a wealth of information on all aspects of colloid and surface science, including historical background information, insights into the implications of definitions, biographical notes, and sketches of scientists who have contributed to the field.

The book summarizes recent international research and experimental developments regarding fatigue crack growth investigations of rubber materials. It shows the progress in fundamental as well as advanced research of fracture investigation of rubber material under fatigue loading conditions, especially from the experimental point of view. However, some chapters will describe the progress in numerical modeling and physical description of fracture mechanics and cavitation phenomena in rubbers. Initiation and propagation of cracks in rubber materials are dominant phenomena which determine the lifetime of these soft rubber materials and, as a consequence, the lifetime of the corresponding final rubber parts in various fields of application. Recently, these phenomena became of great scientific interest due to the development of new experimental methods, concepts and models. Furthermore, crack phenomena have an extraordinary impact on rubber wear and abrasion of automotive tires; and understanding of crack initiation and growth in rubbers will help to support the growthing number of activities and worldwide efforts of reduction of tire wear losses and abrasion based emissions.

This volume, occasioned by the centenary of the Fritz Haber Institute, formerly the Institute for Physical Chemistry and Electrochemistry, covers the institute's scientific and institutional history from its founding until the present. The institute was among the earliest established by the Kaiser Wilhelm Society, and its inauguration was one of the first steps in the development of Berlin-Dahlem into a center for scientific research. Its establishment was made possible by an endowment from Leopold Koppel, granted on the condition that Fritz Haber, well-known for his discovery of a method to synthesize ammonia from its elements, be made its director. The history of the institute has largely paralleled that of 20th-century Germany. It undertook controversial weapons research during World War I, followed by a "Golden Era" during the 1920s, in spite of financial hardships. Under the National Socialists it experienced a purge of its scientific staff and a diversion of its research into the service of the new regime, accompanied by a breakdown in its international relations. In the immediate aftermath of World War II it suffered crippling material losses, from which it recovered slowly in the post-war era. In 1953, shortly after taking the name of its founding director, the institute joined the fledgling Max Planck Society. During the 1950s and 60s, the institute supported diverse researches into the structure of matter and electron microscopy in a territorially insular and politically precarious West-Berlin. In subsequent decades, as both Berlin and the Max Planck Society underwent significant changes, the institute reorganized around a board of coequal scientific directors and a renewed focus on the investigation of elementary processes on surfaces and interfaces, topics of research that had been central to the work of Fritz Haber and the first "Golden Era" of the institute.

This edited volume offers complete coverage of the latest theoretical, experimental, and computer-based data as summarized by leading international researchers. It promotes full understanding of the physical phenomena and mechanisms at work in surface and interfacial tensions and gradients, their direct impact on interface shape and movement, and their significance to numerous applications. Assessing methods for the accurate measurement of surface tension, interfacial tension, and contact angles, Surface and Interfacial Tension presents modern simulations of complex interfacial motions, such as bubble motion in liquids, and authoritatively illuminates bubble nucleation and detachment.

Reviews all known antifoam mechanisms, and discusses the appropriate practical approaches for solving foam control problems in a variety of industrial contexts. These range from crude oil production to detergent formulation.

The manufacture and use of almost every consumer and industrial product rely on application of advanced knowledge in surface science and tribology. These two disciplines are of critical importance in major economic sectors, such as mining, agriculture, manufacturing (including metals, plastics, wood, computers, MEMS, NEMS, appliances), construction, transportation, and medical instruments, transplants, and diagnostic devices. An up-to-date reference with contributions by experts in surface science and tribology, Surfactants in Tribology, Volume 3 discusses some of the underlying tribological and surface science issues relevant to many situations in diverse industries. The tradition of presenting new developments and research that began with the first volume in this groundbreaking series continues in the third volume. Comprising 19 chapters on various aspects of surfactants in tribology-including subjects not covered in previous volumes-this book is presented in four parts: Nanotribology and Polymeric Systems, Biobased and Environmentally Friendly Lubricants and Additives, Tribological Properties of Aqueous and Nonaqueous Systems, and Advanced Tribological Concepts. Topics include tribological properties of nanoparticles, biopolymer friction, environmentally friendly surface-active agents, biolubricants, aqueous mixed surfactant systems, and surfactants in motor oil, drilling fluids, and in electrowetting for MEMS and NEMS. The information in this volume provides a cutting-edge reference connecting the fields of surfactants and tribology as a way forward to novel, enhanced methods of controlling lubrication, friction, and wear. Written by a global team of established authorities, this book reflects the latest developments, highlighting the relevance of surfactants in tribological phenomena in a broad range of industries. It provides a valuable resource for readers working in or entering the fields of

A comprehensive treatment of a large family of polymers useful in a wide range of applications in such fields as automotive, pharmaceutical, cosmetic, metal-working, mining, industrial coating, textile, construction, and home furnishings. Summarizes the chemistry and mechanisms; provides basic prepa

In this volume, the authors close the gap between abstract mathematical approaches, such as abstract algebra, number theory, nonlinear functional analysis, partial differential equations, methods of nonlinear and multi-valued analysis, on the one hand, and practical applications in nonlinear mechanics, decision making theory and control theory on the other.

Readers will also benefit from the presentation of modern mathematical modeling methods for the numerical solution of complicated engineering problems in hydromechanics, geophysics and mechanics of continua. This compilation will be of interest to mathematicians and engineers working at the interface of these field. It presents selected works of the open seminar series of Lomonosov Moscow State University and the National Technical University of Ukraine Kyiv Polytechnic Institute . The authors come from Germany, Italy, Spain, Russia, Ukraine, and the USA."

Over the past several decades, the theme of supramolecular chemistry (SC) has permeated nearly all aspects of chemical endeavor. Not surprisingly, it has also pervaded the field of solvent extraction (SX), inspiring the framework for this volume of Ion Exchange and Solvent Extraction. In addition, tools for studying aggregation have grown increasingly sophisticated, leading to a greater understanding of what we now recognize as SC phenomena in SX. Volume 21, Supramolecular Aspects of Solvent Extraction identifies how supramolecular behavior occurs and is studied in the context of SX and how SC is influencing the direction of SX. With contributions by internationally recognized specialists from different fields, this volume examines how principles of SC are being used in advancing the design of new highly selective SX systems and for understanding aggregation phenomena in SX systems. The book begins with a discussion of the nature and definition of SC and its general use in the design of novel SX reagents. Chapter 2 expands the subject of ion-pair recognition to introduce outer-sphere recognition of metal complexes. Chapter 3 reviews the literature on calixarenes as extraction reagents for metal ions. Chapter 4 extends the utility of this chemistry, describing the use of calixarenes for the extraction of biomolecules. Chapter 5 examines the liquid-liquid interface as an expression of supramolecular phenomena in SX, reviewing interfacial aggregation in model two-phase systems and metal extraction systems. The final chapter explores the problem of aggregation in SX, the historical attempts to understand it, and recent progress that has been made in addressing the issue.

The demands of production, such as thin films in microelectronics, rely on consideration of factors influencing the interaction of dissimilar materials that make contact with their surfaces. Bond formation between surface layers of dissimilar condensed solids-termed adhesion-depends on the nature of the contacting bodies. Thus, it is necessary to determine the characteristics of adhesion interaction of different materials from both applied and fundamental perspectives of surface phenomena. Given the difficulty in obtaining reliable experimental values of the adhesion strength of coatings, the theoretical approach to determining adhesion characteristics becomes more important. Surface Physics: Theoretical Models and Experimental Methods presents straightforward and efficient approaches and methods developed by the authors that enable the calculation of surface and adhesion characteristics for a wide range of materials: metals, alloys, semiconductors, and complex compounds. The authors compare results from the proposed theories-developed within the framework of the electron density functional theory and dielectric formalism-to experimental data. The book begins with a discussion of the thermodynamics of surface phenomena and covers experimental and theoretical methods for studying surface characteristics of solids. Chapters describe calculations of surface and adhesion characteristics of metals using the density functional method. They also examine the calculation of adhesion characteristics of metals, semiconductors, and complex compounds based on dielectric formalism. In addition, the text covers dry friction, adsorption of metal atoms, and ferromagnetic films. The principles and methods presented in this book are useful in selecting optimum materials and coatings for various applications, including minimizing friction for increased efficiency of microelectronic components.

Cubes, triangular prisms, nano-acorn, nano-centipedes, nanoshells, nano-whiskers. . . . Now that we can create nanoparticles in a wide variety of shapes and morphologies, comes the next challenge: finding ways to organize this collection of particles into larger and more complex systems. Nanoparticle Assemblies and Superstructures, edited by pioneer of nanoparticle self-organization Nicholas A. Kotov, employs three critical questions to provide a framework of open-ended inquiry: What are the methods of organization of nanocolloids in more complex structures? What kind of structures do we need? What are the new properties appearing in nanocolloid superstructures? Pulling together a collection of contributors unmatched in both their expertise and enthusiasm, Kotov presents what he refers to as a snapshot of nanoassembly work in progress. The first section of this comprehensive volume provides background through an assessment of the current status of nanoparticle assembly development and the requirements for different applications of organized nanomaterials. The middle chapters explore the changes that occur in various properties of individual particles when they are brought together to form agglomerates and simple assemblies. In the final section, a number of top scientists describe various methods for organizing particles in complex nanostructured superstructures. These include techniques involving biological ligands and force fields, as well as methods based on self-organization. This remarkably prescient text upholds Kotov's belief that the research on organization of nanoparticles and other nanostructures, will most certainly uncover a wealth of "interesting discoveries and surprising phenomena." Nicholas A. Kotov has received several state, national, and international awards for his research on nanomaterials, including the Mendeleev Stipend, the Humboldt Fellowsh

For more than three decades the Electroanalytical Chemistry series has delivered the most in-depth and critical research related to issues in electrochemistry. Volume 22 continues this gold-standard with practical reviews of recent applications, as well as innovative contributions from internationally respected specialists-highlighting the emergence of new technologies and trends in the field. Previous volumes in the series were "highly recommended" by the Journal of the American Chemical Society and considered "essential" by the Journal of Solid State Electrochemistry, and this volume continues with a collection of state-of-the-art advances and studies of the highest caliber.

The Ion Exchange and Solvent Extraction series treats ion exchange and solvent extraction both as discrete topics and as a unified, multidisciplinary study - presenting new insights for researchers in many chemical and related fields.;Volume 12 contains coverage of: the nature of metal-ion interaction with oppositely charged sites of ion exchangers; high-pressure ion exchange separation of rare earth elements; the commercial recovery of valuable minerals from seawater and brines by ion exchange and sorption; the kinetics of ion exchange in heterogenous systems; the ion-exchange equilibria of amino acids; and more.;The work is intended for analytical, co-ordination, process, separation, surface, organic, inorganic, physical and environmental chemists, geochemists, electrochemists, radiochemists, biochemists, biophysicists, hydrometallurgists, membrane researchers and chemical engineers.

The Ion Exchange and Solvent Extraction series treats ion exchange and solvent extraction both as discrete topics and as a unified, multidisciplinary study - presenting new insights for researchers in many chemical and related field. Containing current knowledge and results in ion exchange, this text: presents an overview of the chemical thermodynamics of cation-exchange reactions, with particular emphasis placed on liquid-phase- and solid-phase-activity coefficient models; describes the development of surface complexation theory and its application to the ion exchange phenomenon; discusses metal-natural colloid surface reactions and their consideration by surface complexation modelling complements; and covers the influence of humic substances on the uptake of metal ions by naturally occurring materials.

The development of nanostructured materials represents a new and fast evolving application of recent research in physics and chemistry. Novel experimental tools coupled with new theory have made this possible. Topics covered in this book include nanocrystals, semiconductor heterostructures, nanotubes, nanowires, and manipulation and fabrication techniques. The core of the book consists of ten lectures by five distinguished researchers, Paul Alivisatos, D.D. Awschalom, Sumio Iijima, Charles Lieber and Phaedon Avouris, presented at an Advanced Study Institute in Hong Kong in January 1999. It should interest materials physicists and chemists as well as materials scientists with an interest in the growth and characterisation of sophisticated materials.