This book completes the physical foundations and experimental techniques described in volume 1 with an updated review of the accessory equipment indispensable in molecular beam experiments. It extends the subject to cluster beams and beams of hyperthermal and subthermal energies. As in volume 1, a special effort is made to outline the physical foundations of the various experimental techniques. Hence this book is intended not only as a reference standard for researchers in the field, but also to bring the flavor of current molecular beam research to advanced undergraduates and graduate students and to enable them to gain a solid background in the field and its technique.

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Practical Dispersion A Guide to Understanding and Formulating Slurries Robert F. Conley This book is a practical guide to producing slurries more efficiently, intelligently, and economically. It provides hands--on knowledge of sufficient technical depth to allow those personnel involved in on--going dispersion practices to feel more proficient in making system modifications, as well as to meet the specific mechanical, chemical, environmental, and other requirements of their customers. To this end, a broad description of dispersants, their functions, and field applications has been provided. Dispersant activities are defined on the basis of solid and agent structures and affinities. This book is intended for technical personnel in the many industries involved with slurry processing either in materials production or application, and whose day--to--day activities lie in manufacturing such dispersed products as paints; pigment premixes; treated metallic, inorganic, and organic powders; food products; cosmetics; pharmaceuticals; and dyes and inks.

There is a growing need in both industrial and academic research to obtain accurate quantitative results from continuous wave (CW) electron paramagnetic resonance (EPR) experiments. This book describes various sample-related, instrument-related and software-related aspects of obtaining quantitative results from EPR expe- ments. Some speci?c items to be discussed include: selection of a reference standard, resonator considerations (Q, B, B ), power saturation, sample position- 1 m ing, and ?nally, the blending of all the factors together to provide a calculation model for obtaining an accurate spin concentration of a sample. This book might, at ?rst glance, appear to be a step back from some of the more advanced pulsed methods discussed in recent EPR texts, but actually quantitative "routine CW EPR" is a challenging technique, and requires a thorough understa- ing of the spectrometer and the spin system. Quantitation of CW EPR can be subdivided into two main categories: (1) intensity and (2) magnetic ?eld/mic- wave frequency measurement. Intensity is important for spin counting. Both re- tive intensity quantitation of EPR samples and their absolute spin concentration of samples are often of interest. This information is important for kinetics, mechanism elucidation, and commercial applications where EPR serves as a detection system for free radicals produced in an industrial process. It is also important for the study of magnetic properties. Magnetic ?eld/microwave frequency is important for g and nuclear hyper?ne coupling measurements that re?ect the electronic structure of the radicals or metal ions.

This thesis presents an experimental study of the ultrafast molecular dynamics of CO_2 DEGREES+ that are induced by a strong, near-infrared, femtosecond laser pulse. In particular, typical strong field phenomena such as tunneling ionisation, nonsequential double ionisation and photo-induced dissociation are investigated and controlled by employing an experimental technique called impulsive molecular alignment. Here, a first laser pulse fixes the molecule in space, such that the molecular dynamics can be studied as a function of the molecular geometry with a second laser pulse. The experiments are placed within the context of the study and control of ultrafast molecular dynamics, where sub-femtosecond (10 DEGREES-15 seconds) resolution in ever larger molecular systems represents the current frontier of research. The thesis presents the required background in strong field and molecular physics, femtosecond laser architecture and experimental techniques in a clear and accessible language that does not require any previous knowledge in

Advanced EPR: Applications in Biology and Biochemistry provides an up-to-date survey of existing EPR techniques and their applications in biology and biochemistry, and also provides a wealth of ideas for future developments in instrumentation and theory. The material is broadly organized into four parts. In the first part (chapters 1 to 6) pulsed EPR is discussed in detail. The second part (chapters 7 to 12) provides detailed discussions of a number of novel and experimental methods. The third part comprises seven chapters on double-resonance techniques, five on ENDOR and two on optically- and reaction yield-detected resonance. The final part is devoted to a thorough discussion of a number of new developments in the application of EPR to various biological and biochemical problems. Advanced EPR will interest biophysicists, physical biochemists, EPR spectroscopists and others who will value the extensive treatment of pulsed EPR techniques, the discussion of new developments in EPR instrumentation, and the integration of theory and experimental details as applied to problems in biology and biochemistry.

Carbocyclic Cage Compounds Chemistry and Applications Eiji Osawa • Osamu Yonemitsu Here is an in-depth presentation of current research and theory on the chemistry of three-dimensional polycyclic molecules, or " cage molecules, " synthesized compounds with closed structures. Internationally known scientists introduce their areas of expertise, ranging from general principles to highly specialized perspectives on this fascinating branch of pure chemistry.

Striking a balance between applied and theoretical research, this work details many of the uses of wettability and interprets experimental data from a variety of viewpoints, including the 'separation of forces' and the 'equation of state approaches.'

This volume differs somewhat from the previous volumes in the series in that there is a strong emphasis on the physical aspects and not so much on the chemical aspects of intermetallic compounds. Two of the chapters are concerned with relatively new experimental methods of studying rare earth metallic phases - high energy neutron spectroscopy and light scattering. In these chapters the authors explain the new kinds of information one obtains from these techniques and how this complements the knowledge previously gleaned from the more common measurements - such as NMR, heat capacities, magnetic susceptibility, transport and elastic properties. One of the remaining three chapters deals with NMR studies of rare earth intermetallics and the final two chapters are concerned, not so much with a particular experimental technique, but with physical phenomena that occur in these compounds: the electron-phonon interaction and heavy fermion behavior.

This thesis presents studies on the interaction of soft materials like surfactants and proteins with hard silica nanomaterials. Due to its interdisciplinary nature it combines concepts from the fields of physical chemistry, nanoscience and materials science, yielding to fundamental insights into the structure-directing forces operating at the nano-scale. It is shown that the morphology of surfactant micellar aggregates adsorbed at the surface of nanoparticles and inside tubular nanopores can be tuned on demand by the co-adsorption of a surface modifier. The interaction of globular proteins with silica nanoparticles is dominated by electrostatic interactions and can be controlled by pH and ionic strength, while the bridging of nanoparticles by adsorbed protein molecules leads to large-scale hybrid aggregates of protein with the nanoparticles. Concepts emerging from the role of electrostatic interactions in the hetero-aggregation of nanoparticles with protein molecules are used for the co-assembly of charged microbeads into linear clusters and chains of controllable length.

This volume chronicles the proceedings of the 8th International Symposium on Surfactants in Solution (SIS) held in Gainesville, FL, June 10-15, 1990. This series of symposia have been smoothly running since 1976, but the appellation "Surfactants in Solution" was used for the first time in 1982 in Lund. Since then our logo "SIS" has become very familiar to everyone involved in surfactants. In Lund the meeting was billed as the Fourth International Symposium on Surfactants in Solution. Earlier three events were held under different rubrics, but proceedings of all these symposia, except the 7th SIS held in Ottawa in 1988, have been properly documented. As a matter of fact so far 10 volumes have appeared under the title "Surfactants in Solution". 1,2,3 The program for the 9th SIS was very comprehensive and many ramifications of surfactants were covered, and it was a veritable international event. It contained a total of 384 papers by 869 authors from practically every corner of our planet. Just the sheer number of papers is a testimonial to the high tempo of research and tremendous interest in this wonderful class of materials. As in the past, there were plenary lectures (5), invited talks (37), oral presentations (195) and poster presentations (147). The plenary lectures were given by Prof. J. Th. G. Overbeek, Prof. C. A. Bunton, Prof. H. Ti Tien and Dr. J. Swalen. The lecture by Prof. Overbeek, the doyen of surface and colloid science, was a real treat.

xvii PART I PROPERTIES OF CRYSTALLINE MATERIALS The Effective U in Oxides and in Sulfides: Conceptual Phase Diagrams and their Applications . . . . . . . . . . . . . . .; . . . . . . . . . . . . . . . 1 John B. Goodenough 1. Definitions 1 2. Interatomic interactions 23 References 44 Electron Correlations in Elementary Structures. The Case of Weak Correlations: Metallic and Covalent Bondings . . . . . . . . . . . . . . . . . 45 J. Friedel Introduct i on 45 1. The H2 molecule 46 2. Other elementary diatomic molecules 52 3. Metallic aggregates 53 4. Macroscopic phases of transition metals 57 5. Aggregates and solids of tetravalent (sp) elements 64 6. Aggregates of covalent dimers 67 7. Weak distortions of metallic closepacked or covalent structures 69 Appendixes 74 References 82 Statistical Thermodynamics of Mixed Valence at Low Temperatures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Dieter Wohlleben 1. Introduction 85 2. The free enthalpy without mixing 86 3. The valence fluctuation temperature 89 4. 'The free enthalpy with interconfigurational mlxlng 90 5. Equation of state for the valence fluctuation n e 6. The conduction electron density of states near T=O 98 7. Application to Ce metal 101 8. Acknowledgements 104 References 104 Mixed Valency in Inorganic Chemistry . . . . . . . . . . . . . . . . . . . . 109 P. Day CONTENTS vi Important Discussion of Part I Intermedi ate Val ency (IV) Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . 111 N. F. Mott Thermal Expansion and Specific Heat of Mixed Valence Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 R. Pott 1. Introduction 117 2. Experiments and experimental results 117 3. Discussion 120 4. Acknowledgements 122 5."

Modeling Chemical Systems using Cellular Automata provides a practical introduction to an exciting modeling paradigm for complex systems. The book first discusses the nature of scientific inquiry using models and simulations, and then describes the nature of cellular automata models. It then gives detailed descriptions, with examples and exercises, of how cellular automata models can be used in the study of a wide variety chemical, physical, and biochemical phenomena. Topics covered include models of water itself, solution phenomena, solution interactions with stationary systems, first- and second-order kinetic phenomena, enzyme kinetics, vapor-liquid equilibrium, and atomic and molecular excited-state kinetics. The student experiences these systems through hands-on examples and guided studies. This book is the first of its kind: a textbook and a laboratory manual about cellular automata modeling of common systems in chemistry. The book is designed to be used as a text in undergraduate courses dealing with complex systems and/or as a computational supplement to laboratory courses taught at the undergraduate level. The book includes: - Compact descriptions of a large variety of physical and chemical phenomena - Illustrative examples of simulations, with exercises for further study - An instructor's manual for use of the program The book will be of great value in undergraduate courses in chemistry, physics, biology, applied mathematics, and bioinformatics, and as a supplement for laboratory courses in introductory chemistry, organic chemistry, physical chemistry, medicinal chemistry, chemical engineering and other courses dealing with statistical and dynamic systems. It allows the exploration of a wide range of dynamic phenomena, many of which are not normally accessible within conventional laboratory settings due to limitations of time, cost, and experimental equipment. The book is both a textbook on applied Cellular Automata and a lab manual for chemistry (physics, engineering) courses with lab activity. It would supplement other lab work and be an additonal book the students would use in the course. The authors have assessed the emerging need for this kind of activity in science labs because of the cost of the practical activitites and the frequent failure of some exercises leading to lost didactic value of some experiments. This book is pioneering an alternative that will grow in use. There are no course directors who would use Cellular Automata exclusively. The authors see an emerging interest in this kind of work in courses that contain lab exercises. One such course is the graduate course that Lemont Kier gives in Life Sciences about complexity. He uses many examples and studies from Cellular Automata in the latter part of this course.

Molecular Theory of Solvation presents the recent progress in the statistical mechanics of molecular liquids applied to the most intriguing problems in chemistry today, including chemical reactions, conformational stability of biomolecules, ion hydration, and electrode-solution interface. The continuum model of "solvation" has played a dominant role in describing chemical processes in solution during the last century. This book discards and replaces it completely with molecular theory taking proper account of chemical specificity of solvent.

The main machinery employed here is the reference-interaction-site-model (RISM) theory, which is combined with other tools in theoretical chemistry and physics: the ab initio and density functional theories in quantum chemistry, the generalized Langevin theory, and the molecular simulation techniques.

This book will be of benefit to graduate students and industrial scientists who are struggling to find a better way of accounting and/or predicting "solvation" properties.

The role of chemistry in materials processing and performance, at high temperatures, is a key area in today's technology. High temperature chemistry-the combination of inorganic chemistry with high temperatures-has undergone dramatic growth within the past 50 years.
The papers in Materials Chemistry at High Temperatures highlight, in two outstanding volumes, the latest information and techniques in this fast-paced field.
Essential reading for anyone involved in this innovative technology!

'Shape in Chemistry' looks at molecular shape from a unique perspective: It introduces the reader to the topological concepts and methods of precise shape characterization that are applicable for direct, non-visual description and analysis of general molecular shapes. The author provides a pictorial introduction to all the topological tools necessary for the subjects discussed. Mathematical description is also provided at an easily comprehensible level. New concepts are introduced beginning at the familiar level of stereochemistry and lead on to more advanced topological shape analysis methods. The structure of the book reflects the author's desire to bring the reader to an early appreciation of the power of topology in chemistry. After a brief review of the quantum chemical concept, the author compares the merits of visual, computer graphics methods and nonvisual, algorithmic shape analysis methods. The book ends with the concepts of approximate symmetry and various generalizations of symmetry. 'Shape in Chemistry' is surely destined to become standard reading in the field. It presents a valuable addition to the literature on shape and modeling of molecules for non-specialists organic, physical and medical chemists, researchers in various aspects of QSAR and pharmacological drug design and advanced undergraduate and graduate students.

The progress that has recently been made in the field and applications of thermochemistry, having as a consequence an in- crease in the interest of the subject, undoubtedly can be con- sidered highly remarkable. Traditionally, the thermochemist has provided accurate ther- mal data on chemicaZ compounds of practicaZ importance, mainly by calorimetric and by equilibrium studies. The scope has been considerably extended in recent years, following the development of microcalorimetric techniques, of flow calorimetry, of titra- tion calorimetry, and of high temperature calorimetry. The im- pact has been most noticeable in biochemical studies, in metallur- gical studies, and in organometallic and inorganic thermochemis- try. A parallel development has led to increasing output of signi- ficant thermal data on gas-phase transient species (e.g. free ra- dicals, radical ions) by kineticists, and by use of photoioniza- tion spectroscopy, mass spectroscopy and ion-cyclotron resonance spectroscopy. These species are outside the scope of traditional calorimetric study, but as more data on them become available they vastly add to the value of traditional thermochemical data and enable bond energies to be evaluated, and the inter-relation of molecular structure and bonding energy to be more closely exa- mined.

The chapters in this book are based upon lectures given at the NATO Advanced Study Institute on Synthetic Membranes (June 26-July 8, 1983, Alcabideche, Portugal), which provided an integrated presentation of syn thetic membrane science and technology in three broad areas. Currently available membrane formation mechanisms are reviewed, as well as the manner in which synthesis conditions can be controlled to achieve desired membrane structures. Membrane performance in a specific separa tionprocess involves complex phenomena, the understanding of which re quires a multidisciplinary approach encompassing polymer chemistry, phys ical chemistry, and chemical engineering. Progress toward a global understanding of membrane phenomena is described in chapters on the principles of membrane transport. The chapters on membrane processes and applications highlight both established and emerging membrane processes, and elucidate their myriad applications. It is our hope that this book will be an enduring, comprehensive compen dium of the state of knowledge in the field of synthetic membranes. We have been encouraged in that hope by numerous expressions of interest in the book, coming from a variety of potential users."

Presenting a comprehensive account of the physical concepts and theoretical approaches developed for the study of the dynamical properties of liquids (or, more generally, of high-density fluids), at a microscopic level, this book first discusses the basic dynamical phenomena to be interpreted, as well as the various experimental probes. It then proceeds to an exposition of the sophisticated theoretical techniques needed for a satisfactory account of both single particle and collective motions. The complications are faced in a stepwise fashion, with special attention to the physical content of the results. Based on the results of the progress achieved in the last decade the book provides a satisfactory understanding of most of the phenomena characterising this fascinating field.

CARGESE INSTITUfE ON DISORDER AND MIXING Convection, diffusion and reaction are the three basic mechanisms in physico-chemical hydrodynamics and chemical engineering. Both convective and diffusive processes are strongly influenced by the effect of disorder of granular matter in porous media, suspensions, fluidized beds or/and by the randomness caused in turbulent flow field. This book has been initiated by a NATO summer institute held in Cargese (Corsica, FRANCE) from June 15 th to 27 th 1987 . Its aim was to associate statistical physicists, fluid mechanicians and specialists of chemical engineering on the problems of the relation between disorder and mixing and, in this respect, this is a " premiere ." This book is made of chapters based on lectures given in the meeting. However we have paid a considerable attention to harmonize the contents and styles of chapters made by scientists trained in different communities and using different languages and techniques to describe similar problems. The Prelude by the editors of the book introduces the different points and is a biased view of some of the important and most active aspects of the subjects developed. We wish to thank all contributors and students of the institute who gave the style of the present interdisciplinary approach. We also greatly thank Elisabeth Charlaix who has shared with us the scientific and practical organisation of the institute, and Marie-France Hanseler for her technical support.

Mobility Gradient of Polystyrene in Films Supported on Solid Substrates, by Yoshihisa Fujii, Hiroshi Morita, Atsushi Takahara and Keiji Tanaka Probing Properties of Polymers in Thin Films Via Dewetting, by Gunter Reiter Heterogeneous and Aging Dynamics in Single and Stacked Thin Polymer Films, by Koji Fukao, Takehide Terasawa, Kenji Nakamura, Daisuke Tahara Heterogeneous Dynamics of Polymer Thin Films as Studied by Neutron Scattering, by Rintaro Inoue and Toshiji Kanaya

Fisheries genetics researchers will find invaluable the thirty-eight peer-reviewed contributions in this book, presented at the 20th Lowell Wakefield Fisheries Symposium "Genetics of Subpolar Fish and Invertebrates," held in May 2002 in Juneau, Alaska. Looming over concerns of lost fisheries stocks and persistent erosion of genetic variability are predictions of global warming, which may further tax genetic resources. One consequence is an increased reliance on genetic applications to many aspects of fisheries management, aquaculture, and conservation. The contributions in this book are important to modern fisheries science and genetics, and illustrate the evolution of the field over the past decade. The improved technology provides tools to address increasingly complicated problems in traditional applications and ecological and behavioral studies. The union between molecular and quantitative genetics, where many of the major questions about population structure and evolution remain unanswered, will also benefit from the new technologies.