Rapid evolution of trade, cultural and human relations provides the qualitative and quantitative enhancement of international collaborations, linking the countries with different economical and technological level. Delocalization of High-Tech industry inevitably leads to development of the material science and engineering researches in emergent countries, requiring transfer of know-how, restructuration of basic research and educational networks. This book presents the contributions of participants of the Advanced Research Workshop "Smart Materials for Energy, Communications and Security" (ARW SMECS; www.smecs.ferroix.net), organized in December 2007 in Marrakech in frame of the "NATO - Science for Peace" program. The objective of this event was the attempt to overview several hot topics of material physics related with problems of modern society: transformation and storage of energy, treatment and transmission of information, environmental security issues etc., with the focus of their implementation in Mediterranean Dialogue (MD) countries: Algeria, Egypt, Mauritania, Morocco and Tunisia. The workshop is an important stage in developing of the research network "Mediterranean Electronic Materials" - MEM (www.reseau-MEM.org), that has an objective to encourage the inter-Maghreb and Europe-Maghreb collaborative studies in the area of electroactive materials. Participants of the Advanced Research Workshop "Smart Materials for Energy, Communications and Security" , Marrakech, Morocco, December 2007 v vi PREFACE

Chemical processes in many fields of science and technology, including combustion, atmospheric chemistry, environmental modelling, process engineering, and systems biology, can be described by detailed reaction mechanisms consisting of numerous reaction steps. This book describes methods for the analysis of reaction mechanisms that are applicable in all these fields. Topics addressed include: how sensitivity and uncertainty analyses allow the calculation of the overall uncertainty of simulation results and the identification of the most important input parameters, the ways in which mechanisms can be reduced without losing important kinetic and dynamic detail, and the application of reduced models for more accurate engineering optimizations. This monograph is invaluable for researchers and engineers dealing with detailed reaction mechanisms, but is also useful for graduate students of related courses in chemistry, mechanical engineering, energy and environmental science and biology.

This textbook is the result of the enhancement of several courses on non-equilibrium statistics, stochastic processes, stochastic differential equations, anomalous diffusion and disorder. The target audience includes students of physics, mathematics, biology, chemistry, and engineering at undergraduate and graduate level with a grasp of the basic elements of mathematics and physics of the fourth year of a typical undergraduate course. The little-known physical and mathematical concepts are described in sections and specific exercises throughout the text, as well as in appendices. Physical-mathematical motivation is the main driving force for the development of this text. It presents the academic topics of probability theory and stochastic processes as well as new educational aspects in the presentation of non-equilibrium statistical theory and stochastic differential equations.. In particular it discusses the problem of irreversibility in that context and the dynamics of Fokker-Planck. An introduction on fluctuations around metastable and unstable points are given. It also describes relaxation theory of non-stationary Markov periodic in time systems. The theory of finite and infinite transport in disordered networks, with a discussion of the issue of anomalous diffusion is introduced. Further, it provides the basis for establishing the relationship between quantum aspects of the theory of linear response and the calculation of diffusion coefficients in amorphous systems.

Particle models play an important role in many applications in physics, chemistry and biology. They can be studied on the computer with the help of molecular dynamics simulations. This book presents in detail both the necessary numerical methods and techniques (linked-cell method, SPME-method, tree codes, multipole technique) and the theoretical background and foundations. It illustrates the aspects modelling, discretization, algorithms and their parallel implementation with MPI on computer systems with distributed memory. Furthermore, detailed explanations are given to the different steps of numerical simulation, and code examples are provided. With the description of the algorithms and the presentation of the results of various simulations from the areas material science, nanotechnology, biochemistry and astrophysics, the reader of this book will be able to write his own programs for molecular dynamics step by step and to run successful experiments.

This book presents an overview of fundamental aspects of surface-based biosensors and techniques for enhancing their detection sensitivity and speed. It focuses on rapid detection using miniaturized sensors and describes the physical principles of nanoscale transducers, surface modifications, microfluidics and reaction engineering, diffusion and kinetics. A key challenge in the field of bioanalytical sensors is the rapid delivery of target biomolecules to the sensing surface. While various nanostructures have shown great promise in sensitive detection, diffusion-limited binding of analyte molecules remains a fundamental problem. Recently, many researchers have put forward novel schemes to overcome this challenge, such as nanopore channels, electrokinetics, and dielectrophoresis, to name but a few. This book provides the readers an up-to-date account on these technological advances.

Contains details on the geological units of Nigeria and the associated mineral resources. The book is divided into three parts. Part 1 discusses the geology of the crystalline rocks and their regional distribution while the sedimentary basins constitute the subject of Part 2. Part 3 takes the mineral resources of Nigeria one on one, their geological environment, mode of occurrence, localities and where possible the reserves estimation. Thereafter, an account of the previous and current mining policies (including that of petroleum) of the Nigerian government is given and goes ahead to list some specific investment opportunities in the solid minerals sector.

The book presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems.
Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis, Electroosmotic ) and in continuous systems (Thermal diffusion, Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics, which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix.
Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies.
Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity.
Key Features:
- The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium.
- Experimental studies have been reported which provide test of the theories and their limitations.
- Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed.

Unsteady-state operations of catalytic reactors provide plentiful opportunities for research and commercial realization of efficient heterogeneous catalytic processes. Forced unsteady state conditions generate unique distributions of process parameters and catalyst states often unattainable with traditional, steady-state operation. The unsteady-states can be created by periodic changes in input flow parameters, such as changes in inlet temperature and composition, catalyst circulation through reaction and regeneration zones, or periodic flow reversals through fixed catalyst bed. This can result in increased productivity, selectivity, capital savings and operating cost reduction (higher energy efficiency).
Efficient environmental technologies for treatment of toxic emissions, acid rain and greenhouse gas emissions can also be developed using the unsteady-state concept.
The Proceedings communicate recent progress in these areas of research and promote future development. The aims are to establish relations between academia, industry, engineers and scientists from all over the world, to stimulate new catalytic technologies as well as fundamental research, and to create new concepts for the development of effective catalytic systems. It presents the most up-to-date research in catalysis.
- contains the most recent developments in catalytic research
- includes research finding as well as their application to industry
- a thorough source of information on the latest developments of industrial catalysis in Japan

The operation of everything in the universe needs a special "material"-energy. The earth is no exception. There are many kinds of energy sources on earth. But where does the earth's energy come from? The answer is that everything grows under the sun. Developing renewable energy is of strategic importance to achieve sustainable energy supply. Simulating natural photosynthesis is the ultimate goal of effi cient solar energy conversion. Photovoltaic technology has been widely used in industry and will be one of the major energy sources in the future. Developing new materials and structures, the photoelectric conversion effi ciency of solar cells will be improved day by day, and solar cells will attract more and more attention. This book presents principles of solar photovoltaic conversion, and introduces the physical and chemical processes involved. Mechanisms which affect solar cell performance are also discussed.

Nanostructured Materials for Solar Energy Conversion covers a wide variety of materials and device types from inorganic materials to organic materials. This book deals with basic semiconductor physics, modelling of nanostructured solar cell, nanostructure of conventional solar cells such as silicon, CIS and CdTe, dye-sensitized solar cell, organic solar cell, photosynthetic materials, fullerene, extremely thin absorber (ETA) solar cell, quantum structured solar cell, intermediate band solar cell, carbon nanotube, etc. including basic principle and the latest results. There are many books written on conventional p-n junction solar cells, but few books focus on new concepts in this area.
* Focuses on the use of nanostructured materials for solar energy
* Looks at a wide variety of materials and device types
* Covers both organic and inorganic materials

The aim of Molecular and Nano Electronics: Analysis, Design and Simulation is to draw together contributions from some of the most active researchers in this new field in order to illustrate a theory guided-approach to the design of molecular and nano-electronics. The field of molecular and nano-electronics has driven solutions for a post microelectronics era, where microelectronics dominate through the use of silicon as the preferred material and photo-lithography as the fabrication technique to build binary devices (transistors). The construction of such devices yields gates that are able to perform Boolean operations and can be combined with computational systems, capable of storing, processing, and transmitting digital signals encoded as electron currents and charges. Since the invention of the integrated circuits, microelectronics has reached increasing performances by decreasing strategically the size of its devices and systems, an approach known as scaling-down, which simultaneously allow the devices to operate at higher speeds.
* Provides a theory-guided approach to the design of molecular and nano-electronics
* Includes solutions for researchers working in this area
* Contributions from some of the most active researchers in the field of nano-electronics

The NATO ARW "Molecular Self-Organization in Micro-, Nano-, and Macro- Dimensions: From Molecules to Water, to Nanoparticles, DNA and Proteins" to commemorate Professor Alexander S. Davydov was held in Kiev, Ukraine, on 8-12 June, 2008, at the Bogolyubov Institute for Theoretical Physics of the National Academy of Sciences of Ukraine. Theobjective ofthisNATOARWistounveilandformulatetheprincipalfeatures that govern myriads of the molecular self-organization processes in micro-, nano-, and macro-dimensions from the following key representatives such as liquid - ter and aqueous solutions, and molecular liquids, nanodots, nanoparticles including gold, solitons, biomolecules such as DNA and proteins, biopolymers and bios- sors, catalysis, molecular modeling, molecular devices, and thin ?lms, and to offer another, more advanced directions in computational, experimental, and technolo- cal areas of nano- and bioscience towards engineering novel and powerful molecular self-organized assemblies with tailored properties. Nanoscience is indeed one of the most important research and development fr- tiers in modern science. Simplistically, nanoscience is the science of small particles of materials of a size of nanometre. Molecular nanoscience and nanotechnology have brought to us the unprecedented experimental control of the structure of matter with novel extraordinary properties that open new horizons and new opportunities, and new ways to make things, particularly in our everyday life, to heal our bodies, and to care of the environment. Unfortunately, they have also brought unwelcome advances in weaponry and opened yet more ways to foul up the world on an en- mous scale.

Discover why olefin metathesis has asserted itself as a powerful strategy for obtaining fine chemicals, biologically active compounds, architecturally complex assemblies, new materials, and functionalized polymers. This volume compiles all the latest trends in olefin metathesis. In particular, you ll learn how olefin metathesis has growing potential for the development of sustainable technologies with many possible industrial applications.

This book provides a rigorous treatment of the coupling of chemical reactions and fluid flow. Combustion-specific topics of chemistry and fluid mechanics are considered and tools described for the simulation of combustion processes. This edition is completely restructured. Mathematical Formulae and derivations as well as the space-consuming reaction mechanisms have been replaced from the text to appendix. A new chapter discusses the impact of combustion processes on the atmosphere, the chapter on auto-ignition is extended to combustion in Otto- and Diesel-engines, and the chapters on heterogeneous combustion and on soot formation are heavily revised.

This Proceedings of APCRE'05 contains the articles that were presented at the 4th Asia-Pacific Chemical Reaction Engineering Symposium (APCRE 05), held at Gyeongju, Korea between June 12 and June 15, 2005, with a theme of "New Opportunities of Chemical Reaction Engineering in Asia-Pacific Region."
Following the tradition of APCRE Symposia and ISCRE, the scientific program encompassed a wide spectrum of topics, including not only the traditional areas but also the emerging fields of chemical reaction engineering into which the chemical reaction engineers have successfully spearheaded and made significant contributions in recent years.
In addition to the 190 papers being accepted, six plenary lectures and 11 invited lectures are placed in two separate chapters in the front.
* Provides an overview of new developments and application in chemical reaction engineering
* Topics include traditional and emerging fields
* Papers reviewed by experts in the field

Nanotechnology is no longer a merely social talking point and is beginning to affect the lives of everyone. Carbon nanotechnology as a major shaper of new nanotechnologies has evolved into a truly interdisciplinary field, which encompasses chemistry, physics, biology, medicine, materials science and engineering. This is a field in which a huge amount of literature has been generated within recent years, and the number of publications is still increasing every year. Carbon Nanotechnology aims to provide a timely coverage of the recent development in the field with updated reviews and remarks by world-renowned experts. Intended to be an exposition of cutting-edge research and development rather than a kind of conference proceeding, Carbon Nanotechnology will be very useful not only to experienced scientists and engineers, who wish to broaden their knowledge of the wide-ranging nanotechnology and/or to develop practical devices, but also to graduate and senior undergraduate students who look to make their mark in this field of the future.
- A comprehensive treatment from materials chemistry and structure-property to practical applications
- Offers an in-depth analysis of various carbon nanotechnologies from both fundamental and practical perspectives
- An easily accessible assessment of the materials properties and device performances based on all of the major classes of carbon nanomaterials, including: carbon fiber; diamond; C60; and carbon nanotubes
- A concise compilation of the practical applications of carbon nanotechnologies from polymer-carbon nanocomposites to sensors, electron emitters, and molecular electronics

This book gathers 12 outstanding contributions that reflect state-of-the-art industrial applications of fluorescence, ranging from the pharmaceutical and cosmetics industries to explosives detection, aeronautics, instrumentation development, lighting, photovoltaics, water treatment and much more. In the field of fluorescence, the translation of research into important applications has expanded significantly over the past few decades. The 18th volume in the Springer Series on Fluorescence fills an important gap by focusing on selected industrial applications of fluorescence, described in contributions by both industry-based researchers and academics engaged in collaborations with industrial partners.

I: Perfumery as An Art.- 1: The Art of Perfumery.- II: Perfumery as A Topic in Life Sciences.- 2: Odours and Perfumes as a System of Signs.- 3: Semiochemicals: Mevalogenins in Systems of Chemical Communication.- 4: Origin of Natural Odorants.- 5: A Consideration of Some Psychological and Physiological Mechanisms of Odor Perception.- III: Trapping and Measuring of Odours.- 6: The Measuring of Odors.- 7: Trapping, Investigation and Reconstitution of Flower Scents.- IV: Classification of Odours.- 8: Empirical Classification of Odours.- 9: Chemical Classification and Structure-Odour Relationships.- V: Compository Techniques and Application Segments.- 10: Creative Perfumery: Composition Techniques.- 11: Support Materials for Odorant Mixtures.- 12: Perfumery Applications: Functional Products.- 13: The Impact of Market Research.- VI: Production of Perfumes.- 14: The Chemistry of Synthetic Raw Materials Production.- 15: Compounding.- 16: The Toxicology and Safety of Fragrances.- 17: The Fragrance Industry in a Changing World.- VII: Topics in Perfumery Research.- 18: Receptors: Current Status and Future Directions.- 19: Natural Products.- 20: Synthetic Products.- Outlook.- List of Contributors.

This book is intended to present for the first time experimental methods to measure equilibria states of pure and mixed gases being adsorbed on the surface of solid materials. It has been written for engineers and scientists from industry and academia who are interested in adsorption based gas separation processes and/or in using gas adsorption for characterization of the porosity of solid materials. This book is the result of a fruitful collaboration of a theoretician (JUK) and an experimentalist (RS) over more than twelve years in the field of gas adsorption systems at the Institute of Fluid- and Thermodynamics (IFT) at the University of Siegen, Siegen, Germany. This collaboration resulted in the development of several new methods to measure not only pure gas adsorption, but gas mixture or coadsorption equilibria on inert porous solids. Also several new theoretical results could be achieved leading to new types of so-called adsorption isotherms based on the concepts of molecular association and - phenomenologically speaking - on that of thermodynamic phases of fractal dimension. Naturally, results of international collaboration of the authors over the years (1980-2000) also are included.

The book deals with atomistic properties of solids which are determined by the crystal structure, interatomic forces and atomic displacements influenced by the effects of temperature, stress and electric fields. The book gives equal importance to experimental details and theory. There are full chapters dedicated to the tensor nature of physical properties, mechanical properties, lattice vibrations, crystal structure determination and ferroelectricity. The other crystalline states like nano-, poly-, liquid- and quasi crystals are discussed. Several new topics like nonlinear optics and the Rietveld method are presented in the book. The book lays emphasis on the role of symmetry in crystal properties. Comprehensiveness is the strength of the book; this allows users at different levels a choice of chapters according to their requirements.