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Books > Science & Mathematics > Chemistry > Physical chemistry > General
Cratons and Fold Belts of India, is a unique attempt at presenting geological characteristics and evolution of the fold belts and the cratonic areas of the Indian shield. The author has evaluated the different evolutionary models for each fold belt in light of all the currently available geological and geochronological informations that are clearly listed. Shortcomings, if any, of each model are stated and a viable geodynamic model is presented for each fold belt. The book is self-contained it includes an introduction to the processes of mountain building, especially plate tectonics theory with its application to the evolution of the Himalaya as an illustrative example so that the reader can better appreciate the novel approach to the evolution of Proterozoic fold belts. The author eschews a detailed account of the fold belts for a clear description of all the concepts that go into building models. It is primarily written for graduate students, teachers and for those geoscientists who aspire to know all about the Indian shield."
This book is a follow-up to Ivins Olefin Metathesis, (Academic
Press, 1983). Bringing the standard text in the field up to date,
this Second Edition is a result of rapid growth in the field,
sparked by the discovery of numerous well-defined metal carbene
complexes that can act as very efficient initiators of all types of
olefin metathesis reaction, including ring-closing metathesis of
acyclic dienes, enynes, and dienynes; ring-opening metathesis
polymerizationof cycloalkenes, acyclic diene metathesis
polymerization; and polymerization of alkynes, as well as simple
olefin metathesis.
Computer simulation techniques are now having a major impact on
almost all areas of the physical and biological sciences. This book
concentrates on the application of these methods to inorganic
materials, including topical and industrially relevant systems
including zeolites and high Tc superconductors.
This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C-H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C-F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300 DegreesC) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.
Friction force microscopy is an important analytical tool in the field of tribology on the nanometer-scale. The contact area between the probing tip and the sample is reduced to some square nanometers, corresponding to the ideal of a single asperity contact. Traditional concepts, such as friction coefficients, adhesion and elasticity and stick-slip are re-examined with this novel technique. New concepts based upon classical and quantum mechanics are investigated.
During the past decade there has been a phenomenal growth in the basic research of semiconductor nanoclusters and other nanomaterials. As the field has evolved the emphasis has shifted from basic theoretical description to field utilization of nanostructure-based devices. The topics of the various chapters presented in this book, written by leaders in the field, highlight the salient features of nanocrystalline semiconductor materials. Features of this book: - Provides synthetic strategies to generate ultrasmall particles, films and wires - Describes the characterization methodologies of a large number of nanomaterials from the molecular level to the long-range crystallographic ordering - Develops theoretical descriptions of present-day quantum confinement effects in various materials, including metallic particles, III-V semiconductors, and porous silicon - Explores the fate of photoinduced charge carriers in these materials and the phenomena of charge transfer across interfaces - Covers the utilization of these newly discovered effects in analytical chemistry, organic synthesis, environmental remediation, and electrochemistry. The aim of the book is to present the necessary background material for advanced undergraduate students in the field of physical chemistry and materials science and provide a reference book for the experts in this area.
This book develops the thesis that structure and function in a variety of condensed systems - from the atomic assemblies in inorganic frameworks and organic molecules, through molecular self-assemblies to proteins - can be unified when curvature and surface geometry are taken together with molecular shape and forces. An astonishing variety of synthetic and biological assemblies can be accurately modelled and understood in terms of hyperbolic surfaces, whose richness and beauty are only now being revealed by applied mathematicians, physicists, chemists and crystallographers. These surfaces, often close to periodic minimal surfaces, weave and twist through space, carving out interconnected labyrinths whose range of topologies and symmetries challenge the imaginative powers. The book offers an overview of these structures and structural transformations, convincingly demonstrating their ubiquity in covalent frameworks from zeolites used for cracking oil and pollution control to enzymes and structural proteins, thermotropic and lyotropic bicontinuous mesophases formed by surfactants, detergents and lipids, synthetic block copolymer and protein networks, as well as biological cell assemblies, from muscles to membranes in prokaryotic and eukaryotic cells. The relation between structure and function is analysed in terms of the previously neglected hidden variables of curvature and topology. Thus, the catalytic activity of zeolites and enzymes, the superior material properties of interpenetrating networks in microstructured polymer composites, the transport requirements in cells, the transmission of nerve signals and the folding of DNA can be more easily understood in the light of this. The text is liberally sprinkled with figures and colour plates, making it accessible to both the beginning graduate student and researchers in condensed matter physics and chemistry, mineralogists, crystallographers and biologists.
Although coordination chemistry naturally centers on the synthesis of coordination compounds, the synthesis of these materials is typically not an end in itself. Coordination compounds are utilized in all branches of chemistry; from theoretical modeling to industrial and consumer products. While a large amount of information is available on coordination chemistry in general and synthetic methods in particular, no comprehensive work has been presented on the preparation of coordination compounds with an emphasis on synthetic strategies rather than on detailed descriptions of specific syntheses. The goal of this book is to provide an approach to coordination chemistry that is based upon preparative strategies.The main aim of the authors is to present a systematic classification of synthetic reactions rather than an encyclopedic listing of experimental results. Hence, the coverage is more selective than exhaustive. Despite this, the book provides access to the original literature with ca. 2000 references. The edition is well-illustrated and contains almost 250 schemes, figures and illustrations of crystal structures of selected complexes.
Modern industry imposes ever increasing requirements upon tools and tool materials as to the provision for performance under the conditions of high cutting speeds and dynamic loads as well as under intensive thermal and chemical interactions with workpiece materials. The industry demands a higher productivity in combination with the accuracy of geometry and dimensions of workpieces and quality of working surfaces of the machined pieces. These requirements are best met by the tool superhard materials (diamond and diamond-like cubic boron nitride). Ceramics based on silicon carbide, aluminum and boron oxides as well as on titanium, silicon and aluminum nitrides offer promise as tool materials. Tungsten-containing cemented carbides are still considered as suitable tool materials. Hi- hardness and high strength composites based on the above materials fit all the requirements imposed by machining jobs when manufacturing elements of machinery, in particular those operating under the extreme conditions of high temperatures and loads. These elements are produced of difficult-- machine high-alloy steels, nickel refractory alloys, high-tech ceramics, materials with metallic and non-metallic coatings having improved wear resistance, as well as of special polymeric and glass-ceramic materials. Materials science at high pressure deals with the use of high-pressure techniques for the development and production of unique materials whose preparation at ambient pressure is impossible (e. g. , diamond, cubic boron nitride, etc. ) or of materials with properties exceeding those of materials produced at ambient pressure (e. g. , high-temperature superconductors).
This textbook presents in a unified manner the fundamentals of both continuous and discrete versions of the Fourier and Laplace transforms. These transforms play an important role in the analysis of all kinds of physical phenomena. As a link between the various applications of these transforms the authors use the theory of signals and systems, as well as the theory of ordinary and partial differential equations. The book is divided into four major parts: periodic functions and Fourier series, non-periodic functions and the Fourier integral, switched-on signals and the Laplace transform, and finally the discrete versions of these transforms, in particular the Discrete Fourier Transform together with its fast implementation, and the z-transform. This textbook is designed for self-study. It includes many worked examples, together with more than 120 exercises, and will be of great value to undergraduates and graduate students in applied mathematics, electrical engineering, physics and computer science. Hardbound. The publication of this volume covers current work on the syntheses and reactions of pyridines, quinolines and isoquinolines. Also included are chapters (chapters 28, 30, 31 and 32) which review recent progress in the chemistry of the pyridine, quinoline and isoquinoline alkaloids. The theoretical aspects of pyridine chemistry, which were covered in a separate chapter (chapter 23) in the 2nd Edition, are now incorporated into a separate single chapter (chapter 24), without division.Recent developments in the chemistry of six-membered heterocycles containing a single phosphorus, arsenic, antimony, or bismuth atom are also surveyed. Once again, the reader of Rodd will find this volume extremely valuable since it provides a concise, yet complete, survey of a major subject area of heterocyclic chemistry.
Chirality and stereogenicity are closely related concepts and their differentiation and description is still a challenge in chemoinformatics. In his 2015 book, Fujita developed a new stereoisogram approach that provided theoretical framework for mathematical aspects of modern stereochemistry. This new edition includes a new chapter on Computer-Oriented Representations developed by the author based on Groups, Algorithms, Programming (GAP) system.
This handbook is the only up-to-date, A to Z compilation of commercial and research zeolites. The volume presents complete patent-researched reference information on structural data, synthesis parameters, and characteristic properties. For each known zeolite there is an entry on all organics which crystallize a given structure, physical data, and applications. Data is presented in tabular or graphical form with minimal text, and a cross-referenced literature review is provided.
Comprehensive manual embracing essentially all the classical and
modern areas of chemical kinetics. Provides details of modern
applications in chemistry, technology and biochemistry.
This book emphasises those features in solution chemistry which are difficult to measure, but essential for the understanding of both the qualitative and the quantitative aspects. Attention is paid to the mutual influences between solute and solvent, even at extremely small concentrations of the former. The described extension of the molecular concept leads to a broad view - not by a change in paradigm - but by finding the rules for the organizations both at the molecular and the supermolecular level of liquid and solid solutions.
The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science. The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics. Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist. Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned. Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students
The primary objective of this volume, the first in a new series entitled Theoretical and Computational Chemistry, is to survey some effective approaches to understanding, describing and predicting ways in which solutes and solvents interact and the effects they have upon each other. The treatment of solute/solvent interactions that is presented emphasizes a synergism between theory and experiment. Data obtained experimentally are used as a basis for developing quantitative theoretical models that permit the correlation and interpretation of the data, and also provide a predictive capability. The latter being of course a key motivation for these efforts. Linear solvation energy relationships have been quite successful in this respect and accordingly receive considerable attention. Other effective approaches, including computational ones, are also being pursued, and are discussed in several chapters. This is an area that is continually evolving, and it is hoped that the present volume will convey a sense of its dynamic nature.
The Second Volume of Equilibrium between Phases of Matter, when compared with the First Volume, by H.A.J. Oonk and M.T. Calvet, published in 2008, amounts to an extension of subjects, and a deepening of understanding. In the first three sections of the text an extension is given of the theory on isobaric binary systems. The fourth section gives an account of the thermodynamic analyses of four isobaric binary key systems, highlighting the power of empirical, (exo)thermodynamic correlations. The fifth section is devoted to the thermodynamic description of ternary systems. The last three sections concentrate on the properties of materials, and the phase behaviour of systems under the conditions of high temperature and high pressure conditions that prevail in the interior of the Earth. A new equation of state is the subject of the sixth section. In the seventh section a move is made to statistical thermodynamics and vibrational models; the description of the systems has changed from mathematical to physical. The last section is on the system MgO SiO2, looked upon from a geophysical point of view. Throughout the work high priority is given to the thermodynamic assessment of experimental data; numerous end-of-section exercises and their solutions are included. Along with the First Volume, the work is useful for materials scientists and geophysicists as a reference text. Audience Volume II is a lecture book for postgraduate students in chemistry, chemical engineering, geology and metallurgy. It is highly useful as a recommended text for teachers and researchers in all fields of materials science. "
This and its companion Volumes 2 and 3 document the proceed- ings of the 4th International Symposium on Surfactants in Solution held in Lund, Sweden, June 27-July 2, 1982. This biennial event was christened as the 4th Symposium as this was a continuation of ear- li er conferences dealing with surfactants held in 1976 (Albany) under the title "Micellization, Solubilization, and Microemulsions"; in 1978 (Knoxville) under the title "Solution Chemistry of Surfac- tants"; and in 1980 (Potsdam) where it was dubbed as "Solution Be- bavior of Surfactants: Theoretical and Applied Aspects:' The Pl02 3 ceedings of all these symposia have been properly chronicled. ' , The Lund Symposium was bi lIed as "Surfactants in Solution" as both the aggregation and adsorption aspects of surfactants were covered, and furthermore we were interested in a general title which could be used for future conferences in this series. As these biennial events bave become a weIl recognized forum for bringing together researchers with varied interests in the arena of surfactants, so it is amply vindicated to continue these, and the next meeting is planned for July 9-13, 1984 in Bordeaux, France under the cochair- manship of K. L. Mittal and P. Bothorel. The venue for 1986 is still open, although India, inter alia, is a good possibility. Apropos, we would be delighted to entertain suggestions regarding where and when these biennial symposia should be held in the future and you may direct your response to Kk~.
This volume entitled Advanced Science and Technology of Sintering, contains the edited Proceedings of the Ninth World Round Table Conference on Sintering (IX WRTCS), held in Belgrade, Yugoslavia, September 1-4 1998. The gathering was one in a series of World Round Table Conferences on Sintering organised every four years by the Serbian Academy of Sciences and Arts (SASA) and the International Institute for the Science of Sintering (IISS). The World Round Table Conferences on Sintering have been traditionally held in Yugoslavia. The first meeting was organised in Herceg Novi in 1969 and since then they have regularly gathered the scientific elite in the science of sintering. It is not by chance that, at these conferences, G. C. Kuczynski, G. V. Samsonov, R. Coble, Ya. E. Geguzin and other great names in this branch of science presented their latest results making great qualitative leaps in the its development. Belgrade hosted this conference for the first time. It was chosen as a reminder that 30 years ago it was the place where the International Team for Sintering was formed, further growing into the International Institute for the Science of Sintering. The IX WRTCS lasted four days. It included 156 participants from 17 countries who presented the results of their theoretical and experimental research in 130 papers in the form of plenary lectures, oral presentations and poster sections. |
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