Polymers, main components of plastics and rubbers, are being discarded in increasing quantities. But this waste can also be considered as plastic gold'. Public concern, coupled with the inherent value of the material, means that recycling is imperative. The present book presents a survey of current knowledge in the form of case studies, including current legal and educational issues. Topics covered also include regulation and practice in NATO countries, the economics of recycling, the reprocessing of single polymers and mixtures, and future prospects and strategies. Audience: Vital reading for all polymer scientists, technicians and engineers.

1. 1 Macroionic Systems and the Scope of the Book Inthepresentmonograph,wewilldiscussionicpolymersolutionsandcolloidal dispersions. When these substances are dissolved into a solvent, they produce ionicspecies havinglargemolecularweightsandtheir counterions. We knowa variety of naturally occurring ionic polymers and chemically synthesizedc- pounds. Examples of the former are nucleic acids and some proteins, which playanimportantroleinbiologicalsystems. Examplesofsyntheticionicpo- mers are polyacrylic acid (PAA), polystyrenesulfonic acid (PSS) and poly- lylamine (PAAm). PAAisahighpolymer,inwhichmacrylicacidmoleculesCH =CH(COOH) 2 arelinearlypolymerizedby covalent bonds. Thenumber mis calledthe degree 3 of polymerization and is usually of the order of 10 . When PAA is dissolved in a dissociating solvent like water, anionic macroions and counterions are produced. In the following scheme, the counterions are protons but they may + be metal cations such as Na : ? ? ? ? ?CH ? CH? ?CH ? CH? 2 2 + ? ? ? ? | ? | + mH ? COOH COO m m PAA PAA anion Counterions. PAAm is a cationic polymer and dissociates into PAAm cations and anionic counterions as shown below: ? ? ? ? ?CH ? CH? ?CH ? CH? 2 2 ? ? ? ? ? | +mHCl ? | +mCl + CH ?NH CH ?NH 2 2 2 3 m m PAAm PAAm cation Counterions. 2 1 Introduction + ? In the case of NaCl, it dissociates into Na and Cl , which both have low molecular weights. On the other hand, PAA anions and PAAm cations have 3 highmolecularweights. Ifmis10 ,onepolymerion(macroion)hasananalyt- 3 + icalchargenumberZ of10 ,whichisexceedinglylargerthan1forNa .

Kinetic Theory of granular Gases provides an introduction to the rapidly developing theory of dissipative gas dynamics as it has been developed mainly during the past decade. The book is aimed at readers from the advanced undergraduate level onwards and leads up to the present state of research. The text is self-contained, in the sense that no mathematical or physical knowledge is required that goes beyond standard undergraduate physics courses. The material is adequate for a one-semester course and contains chapter summaries as well as exercises with detailed solutions. Special emphasis is put on a microscopically consistent description of pairwise particle collisions which leads to an impact-velocity dependent coefficient of restitution. The description of the many-particle system, based on the Boltzmann equation, starts with the derivation of the velocity distribution function, followed by the investigation of self-diffusion and Brownian motion. Using hydrodynamical methods, transport processes and self-organized structure formulation are studies. An appendix gives a brief introduction to event-driven molecular dynamics. A second appendix describes a novel mathematical technique for the derivation of the kinetic properties which allows for the application of computer algebra. The book is accompanied by a web page where the molecular dynamics program as well as the computer-algebra programs are provided.

Combustion systems are confined fields of compressible fluids where exothermic processes of combustion take place, subject to boundary conditions imposed at its borders. The subject of Dynamics of Combustion Systems is presented in three parts:

Part 1. Exothermicity considering the thermodynamic effects due to evolution of exothermic energy in a combustion system

Chapter 1. Thermodynamic Aspects
Chapter 2. Evolutionary Aspects
Chapter 3. Heat Transfer Aspects
Chapter 4. Chemical Kinetic Aspects

Part 2. Field exposing the dynamic properties of flow fields where the exothermic energy is deposited

Chapter 5. Aerodynamic Aspects
Chapter 6. Random Vortex Method
Chapter 7. Gasdynamic Aspects
Chapter 8. Gasdynamic Fronts

Part 3. Explosions revealing the dynamic features of fields and fronts due to rapid deposition of exothermic energy

Chapter 9. Blast Wave Theory
Chapter 10. Self-Similar Solution
Chapter 11. Phase Space Method
Chapter 12. Detonation

Cratons and Fold Belts of India, is a unique attempt at presenting geological characteristics and evolution of the fold belts and the cratonic areas of the Indian shield. The author has evaluated the different evolutionary models for each fold belt in light of all the currently available geological and geochronological informations that are clearly listed. Shortcomings, if any, of each model are stated and a viable geodynamic model is presented for each fold belt. The book is self-contained it includes an introduction to the processes of mountain building, especially plate tectonics theory with its application to the evolution of the Himalaya as an illustrative example so that the reader can better appreciate the novel approach to the evolution of Proterozoic fold belts. The author eschews a detailed account of the fold belts for a clear description of all the concepts that go into building models. It is primarily written for graduate students, teachers and for those geoscientists who aspire to know all about the Indian shield."

This book is a follow-up to Ivins Olefin Metathesis, (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis.
Olefin Metathesis and Metathesis Polymerization provides a broad, up-to-date account of the subject from its beginnings in 1957 to the latest applications in organic synthesis. The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials science and chemical engineering.
Key Features
* Discusses different classes of olefin metathesis and the choice of reaction conditions and catalyst
* Considers commercial processes with examples from existing and new technologies
* Provides a complete overview of the subject from its beginning to the present day

Computer simulation techniques are now having a major impact on almost all areas of the physical and biological sciences. This book concentrates on the application of these methods to inorganic materials, including topical and industrially relevant systems including zeolites and high Tc superconductors.
The central theme of the book is the use of modern simulation techniques as a structural tool in solid state science. Computer Modelling in Inorganic Crystallography describes the current range of techniques used in modeling crystal structures, and strong emphasis is given to the use of modeling in predicting new crystal structures and refining partially known structures. It also reviews new opportunities being opened up by electronic structure calculation and explains the ways in which these techniques are illuminating our knowledge of bonding in solids.
Key Features
* Includes a thorough review of the technical basis of relevant contemporary methodologies including minimization, Monte-Carlo, molecular dynamics, simulated annealing methods, and electronic structure methods
* Highlights applications to amorphous and crystalline solids
* Surveys simulations of surface and defect properties of solids
* Discusses applications to molecular and inorganic solids

This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C-H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C-F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300 DegreesC) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.

Friction force microscopy is an important analytical tool in the field of tribology on the nanometer-scale. The contact area between the probing tip and the sample is reduced to some square nanometers, corresponding to the ideal of a single asperity contact. Traditional concepts, such as friction coefficients, adhesion and elasticity and stick-slip are re-examined with this novel technique. New concepts based upon classical and quantum mechanics are investigated.

During the past decade there has been a phenomenal growth in the basic research of semiconductor nanoclusters and other nanomaterials. As the field has evolved the emphasis has shifted from basic theoretical description to field utilization of nanostructure-based devices. The topics of the various chapters presented in this book, written by leaders in the field, highlight the salient features of nanocrystalline semiconductor materials.

Features of this book:

- Provides synthetic strategies to generate ultrasmall particles, films and wires

- Describes the characterization methodologies of a large number of nanomaterials from the molecular level to the long-range crystallographic ordering

- Develops theoretical descriptions of present-day quantum confinement effects in various materials, including metallic particles, III-V semiconductors, and porous silicon

- Explores the fate of photoinduced charge carriers in these materials and the phenomena of charge transfer across interfaces

- Covers the utilization of these newly discovered effects in analytical chemistry, organic synthesis, environmental remediation, and electrochemistry.

The aim of the book is to present the necessary background material for advanced undergraduate students in the field of physical chemistry and materials science and provide a reference book for the experts in this area.

This book develops the thesis that structure and function in a variety of condensed systems - from the atomic assemblies in inorganic frameworks and organic molecules, through molecular self-assemblies to proteins - can be unified when curvature and surface geometry are taken together with molecular shape and forces. An astonishing variety of synthetic and biological assemblies can be accurately modelled and understood in terms of hyperbolic surfaces, whose richness and beauty are only now being revealed by applied mathematicians, physicists, chemists and crystallographers. These surfaces, often close to periodic minimal surfaces, weave and twist through space, carving out interconnected labyrinths whose range of topologies and symmetries challenge the imaginative powers.

The book offers an overview of these structures and structural transformations, convincingly demonstrating their ubiquity in covalent frameworks from zeolites used for cracking oil and pollution control to enzymes and structural proteins, thermotropic and lyotropic bicontinuous mesophases formed by surfactants, detergents and lipids, synthetic block copolymer and protein networks, as well as biological cell assemblies, from muscles to membranes in prokaryotic and eukaryotic cells. The relation between structure and function is analysed in terms of the previously neglected hidden variables of curvature and topology. Thus, the catalytic activity of zeolites and enzymes, the superior material properties of interpenetrating networks in microstructured polymer composites, the transport requirements in cells, the transmission of nerve signals and the folding of DNA can be more easily understood in the light of this.

The text is liberally sprinkled with figures and colour plates, making it accessible to both the beginning graduate student and researchers in condensed matter physics and chemistry, mineralogists, crystallographers and biologists.

Although coordination chemistry naturally centers on the synthesis of coordination compounds, the synthesis of these materials is typically not an end in itself. Coordination compounds are utilized in all branches of chemistry; from theoretical modeling to industrial and consumer products. While a large amount of information is available on coordination chemistry in general and synthetic methods in particular, no comprehensive work has been presented on the preparation of coordination compounds with an emphasis on synthetic strategies rather than on detailed descriptions of specific syntheses. The goal of this book is to provide an approach to coordination chemistry that is based upon preparative strategies.The main aim of the authors is to present a systematic classification of synthetic reactions rather than an encyclopedic listing of experimental results. Hence, the coverage is more selective than exhaustive. Despite this, the book provides access to the original literature with ca. 2000 references. The edition is well-illustrated and contains almost 250 schemes, figures and illustrations of crystal structures of selected complexes.

This volume, occasioned by the centenary of the Fritz Haber Institute, formerly the Institute for Physical Chemistry and Electrochemistry, covers the institute's scientific and institutional history from its founding until the present. The institute was among the earliest established by the Kaiser Wilhelm Society, and its inauguration was one of the first steps in the development of Berlin-Dahlem into a center for scientific research. Its establishment was made possible by an endowment from Leopold Koppel, granted on the condition that Fritz Haber, well-known for his discovery of a method to synthesize ammonia from its elements, be made its director. The history of the institute has largely paralleled that of 20th-century Germany. It undertook controversial weapons research during World War I, followed by a "Golden Era" during the 1920s, in spite of financial hardships. Under the National Socialists it experienced a purge of its scientific staff and a diversion of its research into the service of the new regime, accompanied by a breakdown in its international relations. In the immediate aftermath of World War II it suffered crippling material losses, from which it recovered slowly in the post-war era. In 1953, shortly after taking the name of its founding director, the institute joined the fledgling Max Planck Society. During the 1950s and 60s, the institute supported diverse researches into the structure of matter and electron microscopy in a territorially insular and politically precarious West-Berlin. In subsequent decades, as both Berlin and the Max Planck Society underwent significant changes, the institute reorganized around a board of coequal scientific directors and a renewed focus on the investigation of elementary processes on surfaces and interfaces, topics of research that had been central to the work of Fritz Haber and the first "Golden Era" of the institute.

Modern industry imposes ever increasing requirements upon tools and tool materials as to the provision for performance under the conditions of high cutting speeds and dynamic loads as well as under intensive thermal and chemical interactions with workpiece materials. The industry demands a higher productivity in combination with the accuracy of geometry and dimensions of workpieces and quality of working surfaces of the machined pieces. These requirements are best met by the tool superhard materials (diamond and diamond-like cubic boron nitride). Ceramics based on silicon carbide, aluminum and boron oxides as well as on titanium, silicon and aluminum nitrides offer promise as tool materials. Tungsten-containing cemented carbides are still considered as suitable tool materials. Hi- hardness and high strength composites based on the above materials fit all the requirements imposed by machining jobs when manufacturing elements of machinery, in particular those operating under the extreme conditions of high temperatures and loads. These elements are produced of difficult-- machine high-alloy steels, nickel refractory alloys, high-tech ceramics, materials with metallic and non-metallic coatings having improved wear resistance, as well as of special polymeric and glass-ceramic materials. Materials science at high pressure deals with the use of high-pressure techniques for the development and production of unique materials whose preparation at ambient pressure is impossible (e. g. , diamond, cubic boron nitride, etc. ) or of materials with properties exceeding those of materials produced at ambient pressure (e. g. , high-temperature superconductors).

This textbook presents in a unified manner the fundamentals of both continuous and discrete versions of the Fourier and Laplace transforms. These transforms play an important role in the analysis of all kinds of physical phenomena. As a link between the various applications of these transforms the authors use the theory of signals and systems, as well as the theory of ordinary and partial differential equations. The book is divided into four major parts: periodic functions and Fourier series, non-periodic functions and the Fourier integral, switched-on signals and the Laplace transform, and finally the discrete versions of these transforms, in particular the Discrete Fourier Transform together with its fast implementation, and the z-transform. This textbook is designed for self-study. It includes many worked examples, together with more than 120 exercises, and will be of great value to undergraduates and graduate students in applied mathematics, electrical engineering, physics and computer science.

Hardbound. The publication of this volume covers current work on the syntheses and reactions of pyridines, quinolines and isoquinolines. Also included are chapters (chapters 28, 30, 31 and 32) which review recent progress in the chemistry of the pyridine, quinoline and isoquinoline alkaloids. The theoretical aspects of pyridine chemistry, which were covered in a separate chapter (chapter 23) in the 2nd Edition, are now incorporated into a separate single chapter (chapter 24), without division.Recent developments in the chemistry of six-membered heterocycles containing a single phosphorus, arsenic, antimony, or bismuth atom are also surveyed. Once again, the reader of Rodd will find this volume extremely valuable since it provides a concise, yet complete, survey of a major subject area of heterocyclic chemistry.

This fundamental book on interfacial phenomena forms the basis of application of interface and colloid science to various disperse systems. These include suspensions, emulsions, nano-dispersions, wetting, spreading, deposition and adhesion of particles to surfaces. These systems occur in most industrial applications, such as personal care and cosmetic formulations, pharmaceutical systems particularly for controlled and targeted delivery of drugs, agrochemical formulations and enhancement of their biological performance, paints and coatings as well as most food formulations. These applications are described in volume 2. The text is very valuable for formulation chemists, chemical engineers and technologies who are involved in such applications. In addition this fundamental text is also valuable for research scientists and Ph.D. students investigating various aspects of interface and colloid science.

This handbook is the only up-to-date, A to Z compilation of commercial and research zeolites. The volume presents complete patent-researched reference information on structural data, synthesis parameters, and characteristic properties. For each known zeolite there is an entry on all organics which crystallize a given structure, physical data, and applications. Data is presented in tabular or graphical form with minimal text, and a cross-referenced literature review is provided.

This book emphasises those features in solution chemistry which are difficult to measure, but essential for the understanding of both the qualitative and the quantitative aspects. Attention is paid to the mutual influences between solute and solvent, even at extremely small concentrations of the former. The described extension of the molecular concept leads to a broad view - not by a change in paradigm - but by finding the rules for the organizations both at the molecular and the supermolecular level of liquid and solid solutions.

Comprehensive manual embracing essentially all the classical and modern areas of chemical kinetics. Provides details of modern applications in chemistry, technology and biochemistry.
Special sections of the book treat subjects not covered sufficiently in other manuals, including: modern methods of experimental determination of rate constants of reactions including laser pico- and femtochemistry, magnetochemistry, and ESR; and descriptions of advanced theories of elementary chemical processes.
- Comprehensive manual covering practically all areas of chemical kinetics, both classical and modern.
- Adequate coverage given to topics not covered sufficiently by other works.
- Covers fundamentals and recent developments in homogeneous catalysis and its modeling from a chemical kinetics perspective.