Materials Chemistry is rapidly emerging as a key component of contemporary science. The strongly interdisciplinary nature of the field requires input from all branches of chemistry, from crystallography, from solid state physics and from computational and theoretical techniques. This book aims to give a coherent survey of the field by considering all the major aspects of the current study of the chemistry of materials. Early chapters emphasise basic principles and techniques. Strong emphasis is given to new techniques and technologies, for example, the opportunities opened up by new synchrotron sources in crystallography, and new computational techniques in simulation studies of complex materials. Characterisation techniques including crystallographic, microscopic and spectroscopic techniques are then described. Key contemporary themes such as atomic transport, reactivity and catalysis are reviewed. Later chapters focus on specific dasses of material, induding solid state ionics, ceramics (induding giant magneto-resistance and high temperature superconducting solids), microporous and molecular materials. We hope that the book provides a snapshot of the scientific and technological challenges in this fast developing field. The editors would like to thank the NATO Scientific Affairs Division for funding the School on which this volume is basedj financial contribution from Johnson Matthey Technology Centre is also gratefully acknowledged. We are most grateful to Mrs Jean Conisbee for all her efforts in preparing the manuscript.

The first International Conference on Ageing Studies and Lifetime Extension of Materials was held on th July 12-14 , 1999 at St. Catherine's College, Oxford, United Kingdom. Over 230 delegates attended during the three days and heard nearly ninety papers, together with over thirty poster presentations. Sixteen of these papers were keynotes from invited speakers eminent in their field of research. The proceedings were organised into six separate sessions: observation and understanding of real-time and accelerated ageing; experimental techniques; modelling and theoretical studies; lifetime prediction and validation; lifetime extension; and material design for ageing. In doing this, it was hoped to cover most issues of scientific concern inthefield ofmaterials ageing. One important aspect was that the conference did not concentrateon any particular group or type ofmaterial; rather the aim was to attract contributions from workers engaged in ageing studies with as wide a range of materials as possible. In this way, it was hoped that delegates could interactwith and learnfrom those whom they perhapswould not normally come across and that metallurgists could learn from polymer scientists, ceramicists could talk to modellers, and so on, in this important field. A read through the diverse papers contained within these proceedings will confirm that this aim was happily satisfied. Why hold such a meeting? In the modem world, engineered systems are expected to last longer.

The combination of solid materials of different structural dimensionality with atomic or molecular guest species via intercalation processes represents a unique and widely variable low temperature synthesis strategy for the design of solids with particular composition, structure and physical properties. In the last decade this field has experienced a rapid development and represents now an established specific domain of solid state research and materials science. Substantial progress has been made with respect to an understanding of the complex relationship between structure, bonding, physical properties and chemical reactivity since the first volume on the subject appeared in this series in 1979 (Intercalated Layered Materials, F. Levy, ed.). The purpose of this volume is to present a survey on progress and per spectives based on the treatment of a series of major areas of activities in this field. By the very nature of its subject this monograph has an interdisciplinary character and addresses itself to chemists, physicists and materials scien tists interested in intercalation research and related aspects such as design and characterization of complex materials, low temperature synthesis, solid state reaction mechanisms, electronic/ionic conductivity, control of electronic properties of solids with different structural dimensionality and application of intercalation systems. Several chapters have been devoted to specific groups of host lattices.

This volume contains the edited Proceedings of the Sixth World Round Table Conference on Sintering, held in Herceg-Novi, Yugoslavia on September 2-6, 1985. It was organized by the International Institute for the Science of Sintering (IISS), headquartered in Beograd. Every fourth year since 1969, the Institute has organized such a Round Table Conference on Sintering, each has taken place at some selected lo cation within Yugoslavia. A separate series of IISS Summer Schools have also been held at four year intervals, but they have been offset by about two years, so they occur between the main Conferences. As a rule, the Summer Schools have been devoted to more specific topics and they also take place in different countries. The aim of these Conferences and their related Summer Schools has been to bring together scientists from allover the world who work in various fields of science and technology concerned with sinter ing and sintered materials. A total of six IISS Conferences have been held over the period 1969-1985, and they have been supplemented by the three Summer Schools held in Yugoslavia, Poland and India (in 1975, 1979 and 1983, respectively). This most recent five day Conference addressed the fundamental scien tific background as well as the technological state-of-the-art in sintering and sintered materials. It encompassed many of the high technology sintered materials needed for a wide variety of research and industrial applications."

Crystal pulling is an industrial process and provides the bulk of semiconductor crystals for the semiconductor industry. Initially a purely empirical process, the increase in importance and size of the industry has led to basic research into the fundamentals of the process - particularly the modelling of heat and mass transfer. The book has been written by the recognized authority on Czochralski crystal-growth techniques. It is an attempt to strengthen the interface between the practical crystal grower and the applied mathematician involved in analytical and computer modelling. Its focus is on the physics, chemistry and metallurgy of the process. From reviews: "... There is a need for a modern, non-trivial text on Czochralski growth ... and Dr. Hurle is eminently suited to write such a text."; "Dr. Hurle is probably uniquely qualified to write a book on ... (the Czochralski) growth process. ... He has published a great deal of very substantial as well as innovative work in this area."

This volume contains nearly all of the papers presented at the Symposium on "Defects and Qualities of Semiconductors" which was held in Tokyo on May 17-18, 1984, under the sponsorship of the SOCIETY OF NON-TRADITIONAL TECHNOLOGY. The Symposium was organized by the promoting committee of the research project "Quality Developement of Semiconductors by Utilization of Crystal Defects" sponsored by the Science and Technology Agency of Japan. Defect study in semiconductor engineering started originally with seeking methods how to suppress generation of harmful defects during device processing in order to achieve a high yield of device fabrication. Recently, a new trend has appeared in which crystal defects are positively utilized to improve the device performance and reliability. A typical example is the intrinsic gettering technique for Czochralski silicon. Thus, a new term "DEFECT ENGINEERING" was born. It is becoming more important to control density and distribution of defects than to eliminate all the defects. Very precise and deep knowledge on defects is required to establish such techniques as generation and development of defects desired depending on type of devices and degree of integration. Electrical, optical and mechanical effects of defects should be also understood correctly. Such knowledge is essential even for eliminating defects from some specified device regions. It is the time now to investigate defect properties and defect kinetics in an energetic way. From this point of view, all the speakers in this symposium were invited among the most active investigators in the field of defect engineering in Japan.

In the 1950s the direct observation of dislocations became possible, stimulat ing the interest of many research workers in the dynamics of dislocations. This led to major contributions to the understanding of the plasticity of various crys talline materials. During this time the study of metals and alloys of fcc and hcp structures developed remarkably. In particular, the discovery of the so-called in ertial effect caused by the electron and phonon frictional forces greatly influenced the quantitative understanding of the strength of these metallic materials. Statis tical studies of dislocations moving through random arrays of point obstacles played an important role in the above advances. These topics are described in Chaps. 2-4. Metals and alloys with bcc structure have large Peierls forces compared to those with fcc structure. The reasons for the delay in studying substances with bcc structure were mostly difficulties connected with the purification techniques and with microscopic studies of the dislocation core. In the 1970s, these difficulties were largely overcome by developments in experimental techniques and computer physics. Studies of dislocations in ionic and covalent bonding materials with large Peierls forces provided infonnation about the core structures of dislocations and their electronic interactions with charged particles. These are the main subjects in Chaps. 5-7."

To the biochemist, water is, of course, the only solvent worthy of consideration, because natural macromolecules exhibit their remarkable conformational properties only in aqueous media. Probably because of these remarkable properties, biochemists do not tend to regard proteins, nucleotides and polysaccharides as polymers in the way that real polymer scientists regard methyl methacrylate and polyethylene. The laws of polymer statistics hardly apply to native biopolymers. Between these two powerful camps, lies the No-man's land of water soluble synthetic polymers: here, we must also include natural polymers which have been chemically modified. The scientific literature of these compounds is characterized by a large number of patents, which is usually a sign of little basic understanding, of 'know-how' rather than of 'know-why'. Many of the physical properties of such aqueous solutions are intriguing: the polymer may be completely miscible with water, and yet water is a 'poor' solvent, in terms of polymer parlance. ~kiny of the polymers form thermorever sible gels on heating or cooling. The phenomena of exothermic mixing and salting-in are common features of such systems: neither can be fully explained by the available theories. Finally, the eccentric behaviour of polyelectrolytes is well documented. Despite the lack of a sound physico-chemical foundation there is a general awareness of the importance of water soluble vinyl, acrylic, polyether, starch and cellulose derivatives, as witnessed again by ~he vast patent literature.

Advances in nanoscale science show that the properties of many materials are dominated by internal structures. In molecular cases, such as window glass and proteins, these internal structures obviously have a network character. However, in many partly disordered electronic materials, almost all attempts at understanding are based on traditional continuum models. This workshop focuses first on the phase diagrams and phase transitions of materials known to be composed of molecular networks. These phase properties characteristically contain remarkable features, such as intermediate phases that lead to reversibility windows in glass transitions as functions of composition. These features arise as a result of self-organization of the internal structures of the intermediate phases. In the protein case, this self-organization is the basis for protein folding. The second focus is on partly disordered electronic materials whose phase properties exhibit the same remarkable features. In fact, the phenomenon of High Temperature Superconductivity, discovered by Bednorz and Mueller in 1986, and now the subject of 75,000 research papers, also arises from such an intermediate phase. More recently discovered electronic phenomena, such as giant magnetoresistance, also are made possible only by the existence of such special phases. This book gives an overview of the methods and results obtained so far by studying the characteristics and properties of nanoscale self-organized networks. It demonstrates the universality of the network approach over a range of disciplines, from protein folding to the newest electronic materials.

From the reviews: "The book should be acquired by all libraries with an interest in glass science and applications...the title will endure for many years as the standard work on the properties of optical glass." Optical Systems Engineering

Owing to efforts and legislative action - initiated above all by the government of the United States - to use cleaner fuels and thus make a contribution towards a better environment, public attention is back again on using methanol in carbu rettor and diesel engines. Most prominent among the raw materials from which methanol can be produced is coal, whose deposits and resources are many times larger than those of liquid and gaseous hydrocarbons. This book deals with the production of methanol from coal. It describes both the individual steps that are required for this process and the essential ancillary units and offsites associated with the process itself . . It is not meant to inform the reader about the intricate details of the processes, which can much better be taken from the specialized literature that deals exclusively and in detail with them or from the well-known standard engineering books. Rather, this book is to give the reader an impression how manifold a field this is, how many process variations and combinations the designer of such plants has to consider in order to arrive at an optimum design in each particular case. Apart from the production of chemical-grade methanol, the book deals briefly also with fuel methanol production, i. e. with the production of alcohol mixes. One of the many possible routes from coal to methanol is illustrated by a process flow diagram, and a material and energy balance is compiled for this typical example."

Pattern transfer by dry etching and plasma-enhanced chemical vapor de position are two of the cornerstone techniques for modern integrated cir cuit fabrication. The success of these methods has also sparked interest in their application to other techniques, such as surface-micromachined sen sors, read/write heads for data storage and magnetic random access memory (MRAM). The extremely complex chemistry and physics of plasmas and their interactions with the exposed surfaces of semiconductors and other materi als is often overlooked at the manufacturing stage. In this case, the process is optimized by an informed "trial-and-error" approach which relies heavily on design-of-experiment techniques and the intuition of the process engineer. The need for regular cleaning of plasma reactors to remove built-up reaction or precursor gas products adds an extra degree of complexity because the interaction of the reactive species in the plasma with the reactor walls can also have a strong effect on the number of these species available for etching or deposition. Since the microelectronics industry depends on having high process yields at each step of the fabrication process, it is imperative that a full understanding of plasma etching and deposition techniques be achieved.

Materials that can mold the ?ow of elastic waves of certain energy in certain directions are called phononic materials. The present thesis deals essentially with such phononic systems, which are structured in the mesoscale (\1 lm), and with their individual components. Such systems show interesting phononic properties in the hypersonic region, i.e., at frequencies in the GHz range. It is shown that colloidal systems are excellent model systems for the realization of such phononic materials. Therefore, different structures and particle architectures are investigated by Brillouin light scattering, the inelastic scattering of light by phonons. Both the mechanical properties of the individual colloidal particles, which manifest in their resonance vibrations (eigenmodes), as well as the acoustic propagation in colloidal structures have been investigated. The measurement of the eigenmodes allows for new insights into physical properties at the mesoscale, e.g., con?nement effects, copolymer behavior, or the non-destructive determination of nanomechanical properties of core-shell particles, supporting the working groups aim to achieve a deeper understanding of 'soft mechanics' at small length scales. Another novel contribution assigned to this thesis is the ?rst experimental rea- zation of a phononic band gap arising from the interaction of these particle - genmodes with the effective medium band (hybridization gap). This ?nding already gave new impulses to the whole ?eld of phononics.

Kinetic models have often served as useful examples in develop ing the methodology for the design and analysis of experiments in volving mechanistic models. Thus, it is not surprising that these approaches have been applied quite successfully to kinetic obser vations. Nevertheless, many ideas and methods were developed indepen dently in various fields of science. More often than not, investi gators working in one area have not been aware of relevant advances in others. In order to facilitate the desirable exchange of ideas, a one-day symposium was held in Toronto in conjunction with the XIth International Congress of Biochemistry. Biochemists, pharmacolo gists,> and statisticians came together and discussed many of the topics presented in this volume. Participants in the symposium believed that it would be use ful to publish a collection of the presentations together with some additional material. The present volume is the result. It is an attempt to convey some of the interdisciplinary concerns involv ing mechanistic, and especially kinetic, model building. The coverage is by no means exhaustive: many principles, methods, and problems are not included. Even the applications are limited to biochemistry and pharmacology. Still, the symposium highlighted areas of current interest. These included questions of weighting, robust parameter estimation, pooled data analysis, model identification, and the design of experiments. These topics, which are of interest in many fields of science, are discus3ed also in the present volume.

The Novel Mechanisms of Superconductivity Conference was initially conceived in the early part of 1986 as a small, 2-1/2 day workshop of 40-70 scientists, both theorists and experimentalists interested in exploring the possible evidence for exotic, non phononic superconductivity. Of course, the historic discoveries of high temperature oxide superconductors by Bednorz and Mftller and the subsequent enhancements by the Houston/Alabama groups made such a small conference impractical. The conference necessarily had to expand, 2-1/2 days became 4-1/2 days and superconductivity in the high Tc oxides became the largest single topic in the workshop. In fact, this conference became the first major conference on this topic and thus, these proceedings are also the first maj or publication. However, heavy fermion, organic and low carrier concentration superconductors remained a very important part of this workshop and articles by the leaders in these fields are included in these proceedings. Ultimately the workshop hosted rearly 400 scientists, students and media including representatives from the maj or research groups in the U.S., Europe, Japan and the Soviet Union.

Keynote and lectures from invited speakers given at the Se- cond Pacific Polymer Conference in Otsu, Japan, are collec- ted in this book. Eminent Polymer Scientists from both aca- demic and industrial fields around the Pacific Basin contri- buted on the following topics: - Polymer Synthesisand Ractions - Polymer Characterization - Structure-Property-Relationships - High Performance Polymers - Bio-Related Polymers With contributions by H.R. Allcock, R.G. Davidson, T. Inoue, Y.H. Kim, E.A. McCullough, J.E. McGrath, G.F. Meijs, T. Nishi, Y.Nishida, I. Noda, R.M. Nowak, M. Okamoto, R.E. Prud'homme, J.P. Riggs, D.N. Schulz, D.H. Solomon, J. Sunamoto, M. Takayanagi, a.o.

The emergence of civil aviation as a means of mass transportation is primarily due to the large scale construction of jet airplanes in the past 30 years or so. A large number of these jet airplanes is currently operating at or beyond their designed fatigue lives. Thus, the structural integrity of these aging airplanes has become an issue of major concern to all nations of the world. To bring the needed technical and research focus on the issues involved in the life-enhancement and safety-assurance of aging airplanes, the Federal Aviation Administration sponsored a symposium in Atlanta, GA, USA, during 20-22 March 1990. This symposium, under the title "International Symposium on Structural Integrity of Aging Airplanes. was organized jointly be the Georgia Institute of Technology (Center for Computational Mechanics) and the Transportation Systems Center (Cambridge, MA) of the U.S. Department of Transportation. Industrial and academic experts from several countries in North America, Europe and Asia, were invited to discuss their experiences and proposed solutions. This monograph contains the original papers that represent the expanded and edited versions of the talks presented at this symposium. This book aims to bring the collective experience, from across the world, with problems related to the structural integrity of aging airplanes to the attention of the professional and research community at large - in the hope that it may stimulate further fruitful research on this important topic of global concern."

Tradi tionally, the International lTV - Conferences on Biomate rials are focussing on problems in Biomedical Engineering, problems, which are still unsolved, of main interest, and which are of interdisciplinary character. In 1983, the Division of Biomedical Engineering of the Institute of Textile Technology and Chemical Engineering, Denkendorf, started wi th a conference about the use of polyurethanes in biomedicine. Three years later, . in 1986, progress in development and use of polyurethanes was selected as conference topic. It had to be realized that degradation problems were still dominating the discussions. The main discussion topics were: What are the causes for the degradation? How can one prevent them? What are the degradation products, and do they affect the human body? How can one simu late the degradation? How can one accelerate the in vitro tests and how can the results predict the in vivo behaviour of the material? How do in vitro tests correlate with animal tests and the behaviour in the human body? At the third conference in 1989, the speakers focused on the use of textiles in medicine. Again the problem of degradation was discussed intensively and demonstrated by the failure of textile implants, the degradation of aramide polymers or the degradation of resorbable suture materials. The examples make clear, that degradation may be a desired or undesired property of an implant."

Modern polymer materials are designed by applying principles of correlation between chemical structure, physical macrostructure and technological properties. Fundamentals of polymer physics are explained in this book without excessive use of calculations. Four main sections treat relaxation of polymers, melting and crystallization, the mechanism of deformation in thermoplastics, elastomers and multiphase systems, and thermodynamics of mixing and swelling of polymers and polymer networks. The book presents the theoretical models of polymer physics in a comprehensive style and relates their applicability to real polymer systems in terms of the available experimental observations.

This is the first book in a new series - "Materials Research and Engineering" - devoted to the science and technology of materials. "Materials Research and Engineering" evolves from a previous series on "Reine und Angewand te Metallkunde" ("Pure and Applied Metallurgy"), which was edited by Werner Koster until his eightieth birthday in 1976. Although the present series is an outgrowth of the earlier one, it should not and cannot be regarded as a continuation. There had to be a shift of scope - and a change in presentation as well. Metallurgy is no longer an isolated art and science. Rather, it is linked by its scientific basis and tech nological implications to non-metallic and composite materials, as well as to processes for production, refining, shaping, surface treatment, and appli cation. Thus, the new series, "Materials Research and Engineering," will present up-to-date information on scientific and technological progress, as well as on issues of general relevance within the engineering field and industrial society. Premiering the new series, the present book by Dieter Altenpohl gives the reader a very general outlook, in fact, a position analysis of materials and the materials industry within the framework of our contemporary technological environment. It ventures, moreover, to forecast the changes affecting this pattern in a dynamic, interdependent world. This may be an unusual way to start a scientific series - it is believed, nevertheless, to be an appropriate one."

Flat rolling is considered to be one of the most important and most widely used metal forming processes. This book emphasizes the importance of mathematical simulation of this process in the light of the ever in- creasing need for quality improvements through automation. Mathematical models of the hot, warm and cold rolling processes are discussed, compared and critically evaluated. Engineers in the steel industry will find this book particularly useful in their everyday work.

This text on numerical methods applied to the analysis of electromagnetic nondestructive testing (NOT) phenomena is the first in a series devoted to all aspects of engineering nondestructive evaluation. The timing of this series is most appropriate as many university engineering/physics faculties around the world, recognizing the industrial significance of the subject, are organizing new courses and programs with engineering NOE as a theme. Additional texts in the series will cover electromagnetics for engineering NOE, microwave NOT methods, ultrasonic testing, radiographic methods and signal processing for NOE. It is the intended purpose of the series to provide senior-graduate level coverage of the material suitable for university curricula and to be generally useful to those in industry with engineering degrees who wish to upgrade their NOE skills beyond those needed for certification. This dual purpose for the series reflects the very applied nature of NOE and the need to develop suitable texts capable of bridging the gap between research laboratory studies of NOE phenomena and the real world of certification and industrial applications. The reader might be tempted to question these assertions in light of the rather mathematical nature of this first text. However, the subject of numerical modeling is of critical importance to a thorough understanding of the field-defect interactions at the heart of all electromagnetic NOT phenomena.

The present level of understanding of ion implantation is sufficient that implantation Ls being used not only as a tool in various fields of research, but also as an industrial )rocess. In these applications one uses either the implanted ions, or their energy, to nodify some properties of the target substance, and is therefore concerned with the spatial listribution of the ions or of their energy. Following the pioneering work of Bohr [1), ~indhard and his collaborators have evolved a general description of the behaviour of swift Lons slowing down in amorphous targets [2,3,4), a description which has been the basis of nuch other work in the field. Various approximate calculations have been based on this :heory, but it has not always been clear whether any disagreement between experiment and :heory is real or can be attributed to deficiencies in calculation. It is the purpose of :his volume to present the results of the Lindhard theory, calculated in an exact manner, :o serve as a guide to the users of implantation, as a tabulation of theoretical results for experimentalists to compare with, and as a statement of the theoretical results either ~s a standard for comparison for approximate calculations or as a starting point for a more ietailed theory. Results are presented in tables and in graphs, the graphs being intended to display the qualitative features so as to illustrate the competition of the various phy sical processes determining the spatial distribution of the collision cascade.

Some years ago in Paisley (Scotland) the International Conference on Composite Materials, headed by Professor I. Marshall, took place. During the conference, I presented a paper on the manufacturing and properties of the Soviet Union's composite materials. Soviet industry had made great achievements in the manufacturing of composite materials for aerospace and rocket applications. For example, the fraction of composites (predominantly carbon fibre reinforced plastics) in the large passenger aircrafts Tu-204 and 11-86 is 12-15% of the structure weight. The percentage by weight share of composites in military aircraft is greater and the fraction of composites (organic fibre reinforced plastics) used in military helicopters exceeds a half of the total structure weight. The nose parts of most rockets are produced in carbon-carbon materials. In the Soviet spacecraft 'Buran' many fuselage tubes are made of boron-aluminium composites. Carbon-aluminium is used for space mirrors and gas turbine blades. These are just a few examples of applications. Many participants at the Paisley conference suggested that the substantial Soviet experience in the field of composite materials should be distilled and presented in the form of a comprehensive reference publication. So the idea of the preparation and publication of a six volume work Soviet Advanced Composites Technology, edited by Professor I. Marshall and me, was born.

It is common practice today to use the term "alloy" in connection with specific classes of materials, with prominence given to metals and semiconductors. However, there is good justification for considering alloys in a unified manner based on properties rather than types of materials because, after all, to alloy means to mix. The scientific aspects of mixing together different materials has a very long history going back to early attempts to understand and control materials behavior for the service of mankind. The case for using the scientific term "alloy" to mean any material consisting of more than one element can be based on the following two considerations. First, many alloys are mixtures of metallic, semiconducting, and/or insulating materials, and the properties of an alloy, i.e., metallic, semiconducting, or insulating, are often functions of composition and of external conditions, such as temperature and pressure. Second, and most importantly, in attempting to understand the various properties of materials, whether physical, chemical, or mechanical, one is apt to use the terminology and experimental, formal, and computational methods in their study that transcend the type of material being studied.