With the development in the 1960s of ultrahigh vacuum equipment and techniques and electron, X-ray, and ion beam techniques to determine the structure and composition of interfaces, activities in the field of surface science grew nearly exponentially. Today surface science impacts all major fields of study from physical to biological sciences, from physics to chemistry, and all engineering disciplines. The materials and phenomena characterized by surface science range from se- conductors, where the impact of surface science has been critical to progress, to metals and ceramics, where selected contributions have been important, to bio- terials, where contributions are just beginning to impact the field, to textiles, where the impact has been marginal. With such a range of fields and applications, questions about sample selection, preparation, treatment, and handling are difficult to cover completely in one review article or one chapter. Therefore, the editors of this book have assembled a range of experts with experience in the major fields impacted by surface characterization. It is the only book which treats the subject of sample handling, preparation, and treatment for surface characterization. It is full of tricks, cautions, and handy tips to make the laboratory scientist's life easier. With respect to organization of the book, the topics range from discussion of vacuum to discussion of biological, organic, elemental or compound samples, to samples prepared ex situ or in situ to the vacuum, to deposition ofthin films. Generic considerations of sample preparation are also given.

The fluorine atom, by virtue of its electronegativity, size, and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals, and surface modifiers are only a few examples. Fluoropolymers, too, while traditionally associated with extreme hi- performance applications have found their way into our homes, our clothing, and even our language. A recent American president was often likened to the tribology of PTFE. Since the serendipitous discovery of Teflon at the Dupont Jackson Laboratory in 1938, fluoropolymers have grown steadily in technological and marketplace importance. New synthetic fluorine chemistry, new processes, and new apprec- tion of the mechanisms by which fluorine imparts exceptional properties all contribute to accelerating growth in fluoropolymers. There are many stories of harrowing close calls in the fluorine chemistry lab, especially from the early years, and synthetic challenges at times remain daunting. But, fortunately, modern techniques and facilities have enabled significant strides toward taming both the hazards and synthetic uncertainties. In contrast to past environmental problems associated with fluorocarbon refrigerants, the exceptional properties of fluorine in polymers have great environmental value. Some fluoropolymers are enabling green technologies such as hydrogen fuel cells for automobiles and oxygen-selective membranes for cleaner diesel combustion.

Lead-based paint has become a national issue and will continue to be a hi- priority focus ofnational, state, and local agencies until there is no lead-based paint in the United States. Lead-based paint has become a tremendous health hazard for people and animals. Lead-based paint has been in widespread use throughout Europe and the United States. Lead has been known to be a health hazard since the time ofPliny the Elder (A. D. 23-79), but it was deemed that the advantages of lead in paint outweighed the health hazards. There has been a change in outlook, and in 1973 the U. S. Congress banned all lead paint from residential structures. A voluminous number of law suits have been initiated since, and continue to be litigated with the purpose of determining the parties responsible for the lead poisoning of children and others and to exact the indemnities. Lead-based paint is still authorized for use on bridges and nonresidential structures, and thousands of city, state, military, and federal government housing projects still contain lead-based paint. This paint must be removed if these dwellings are to be safe living quarters, especially for children. Aba- ment techniques continue to be evaluated; some have been used successfully. Lead-based paint abatement will continue into the next century, and it is hoped that this comprehensive volume will serve as a guide for those seriously interested in this important subject.

In the future, our energy systems will need to be renewable and sustainable, efficient and cost-effective, convenient and safe. Hydrogen has been proposed as the perfect fuel for this future energy system. The availability of a reliable and cost-effective supply, safe and efficient storage, and convenient end use of hydrogen will be essential for a transition to a Hydrogen Economy. Research is being conducted throughout the world for the development of safe, cost-effective hydrogen production, storage, and end-use technologies that support and foster this transition. This book is a collection of important research and analysis papers on hydrogen production, storage, and end-use technologies that were presented at the American Chemical Society National Meeting in New Orleans, Louisiana, USA, in August 1999.

Proceedings of the International School of Quantum Electronics 27th course on Bose Einstein Condensates and Atom Lasers, October 19-24, 1999, Erice, Italy. Since the experimental demonstration of Bose Einstein Condensation in dilute atomic gases there has been an explosion of interest in the properties of this novel macroscopic quantum system. The book covers the methods used to produce these new samples of coherent atoms, their manipulation and the study of their properties. Emphasis is given to the anticipated development of new types of sources, which more and more resemble traditional types of lasers. Because of recent new applications and increasing demand for lasers, sensors and associated instrumentation, the chapters also cover current developments in the basic techniques, materials and applications in the field of the generation of coherent atoms.

This monograph describes and discusses the properties of heterogeneous materials, including conductivity, elastic moduli, and dielectrical constant. The book outlines typical experimental methods, and compares the experimental data and the theoretical predictions. This multidisciplinary book will appeal to applied physicists, materials scientists, chemical and mechanical engineers, chemists, and applied mathematicians.

Stereology is the science that relates three-dimensional structure to the two-dimensional images that can be measured. The most common field of application is in microscopy, both of man-made materials (metals, ceramics, composites, etc.) and of biological tissue samples. This book covers the applications and terminology of both fields. Recent emphasis in stereology is concerned with sampling strategies to avoid bias due to directionality and non-uniformity, and these methods are fully covered. So are the classic techniques that measure size distributions, surface curvature, etc., which are widely useful but not discussed in other recent texts. Finally, most stereology is taught as manual procedures using counting and grids, but this text also covers the use of modern desktop computers for image analysis and processing to obtain and interpret the stereological data.

To the biochemist, water is, of course, the only solvent worthy of consideration, because natural macromolecules exhibit their remarkable conformational properties only in aqueous media. Probably because of these remarkable properties, biochemists do not tend to regard proteins, nucleotides and polysaccharides as polymers in the way that real polymer scientists regard methyl methacrylate and polyethylene. The laws of polymer statistics hardly apply to native biopolymers. Between these two powerful camps, lies the No-man's land of water soluble synthetic polymers: here, we must also include natural polymers which have been chemically modified. The scientific literature of these compounds is characterized by a large number of patents, which is usually a sign of little basic understanding, of 'know-how' rather than of 'know-why'. Many of the physical properties of such aqueous solutions are intriguing: the polymer may be completely miscible with water, and yet water is a 'poor' solvent, in terms of polymer parlance. ~kiny of the polymers form thermorever sible gels on heating or cooling. The phenomena of exothermic mixing and salting-in are common features of such systems: neither can be fully explained by the available theories. Finally, the eccentric behaviour of polyelectrolytes is well documented. Despite the lack of a sound physico-chemical foundation there is a general awareness of the importance of water soluble vinyl, acrylic, polyether, starch and cellulose derivatives, as witnessed again by ~he vast patent literature.

Advances in nanoscale science show that the properties of many materials are dominated by internal structures. In molecular cases, such as window glass and proteins, these internal structures obviously have a network character. However, in many partly disordered electronic materials, almost all attempts at understanding are based on traditional continuum models. This workshop focuses first on the phase diagrams and phase transitions of materials known to be composed of molecular networks. These phase properties characteristically contain remarkable features, such as intermediate phases that lead to reversibility windows in glass transitions as functions of composition. These features arise as a result of self-organization of the internal structures of the intermediate phases. In the protein case, this self-organization is the basis for protein folding. The second focus is on partly disordered electronic materials whose phase properties exhibit the same remarkable features. In fact, the phenomenon of High Temperature Superconductivity, discovered by Bednorz and Mueller in 1986, and now the subject of 75,000 research papers, also arises from such an intermediate phase. More recently discovered electronic phenomena, such as giant magnetoresistance, also are made possible only by the existence of such special phases. This book gives an overview of the methods and results obtained so far by studying the characteristics and properties of nanoscale self-organized networks. It demonstrates the universality of the network approach over a range of disciplines, from protein folding to the newest electronic materials.

For several years, core level spectroscopies and other, c\osely related, electron spectroscopies have provided very useful information about the atomic composition, the geometric structure, and the electronic structure of condensed matter. Recently, these spectroscopies have also been used for the study of magnetic properties; such studies have a great potential to extend our knowledge and understanding of magnetic systems. This volume collects the lectures presented at the NATO Advanced Study Institute on "Core Level Spectroscopies for Magnetic Phenomena: Theory and Experiment" held at the Ettore Majorana Centre, Erice, Sicily, on 15 to 26 May 1994. The topics considered at the ASI covered a wide range of subjects involving the use of core-level and related spectroscopies to study magnetic phenomena. There are a large and growing number of applications of these spectroscopies to the study of magnetic materials; an important objective of the ASI was to stimulate further growth. The topics covered at the ASI can be placed into three general groups: 1) fundamental principles of core level spectroscopies; 2) basic aspects of magnetic phenomena; and, 3) the combination of the two previous topics embodied in applications of the spectroscopies to magnetism. In all three groups, theoretical interpretations as weH as experimental measurements were presented, often both of these aspects were covered in a single lecture or series oflectures. The theoretical treatments ofthe spectroscopies as weH as of the magnetic phenomena help to establish a framework for understanding many of the experimental measurements on magnetic materials.

The need for alternate energy sources has led to the develop ment of prototype fusion and MHD reactors. Both possible energy systems in current designs usually require the use of magnetic fields for plasma confinement and concentration. For the creation and maintenance of large 5 to 15 tesla magnetic fields, supercon ducting magnets appear more economical. But the high magnetic fields create large forces, and the complexities of the conceptual reactors create severe space restrictions. The combination of re quirements, plus the desire to keep construction costs at a mini mum, has created a need for stronger structural alloys for service at liquid helium temperature (4 K). The complexity of the required structures requires that these alloys be weldable. Furthermore, since the plasma is influenced by magnetic fields and since magnet ic forces from the use of ferromagnetic materials in many configur ations may be additive, the best structural alloy for most applica tions should be nonmagnetic. These requirements have led to consideration of higher strength austenitic steels. Strength increases at low temperatures are achieved by the addition of nitrogen. The stability of the austenitic structure is retained by adding manganese instead of nickel, which is more expensive. Research to develop these higher strength austenitic steels is in process, primarily in Japan and the United States."

This book deals with the latest achievements in the field of optical coherent microscopy. While many other books exist on microscopy and imaging, this book provides a unique resource dedicated solely to this subject. Similarly, many books describe applications of holography, interferometry and speckle to metrology but do not focus on their use for microscopy. The coherent light microscopy reference provided here does not focus on the experimental mechanics of such techniques but instead is meant to provide a users manual to illustrate the strengths and capabilities of developing techniques. The areas of application of this technique are in biomedicine, medicine, life sciences, nanotechnology and materials sciences.

The field of nonlinear optics, which has undergone a very rapid development since the discovery of lasers in the early sixties, continues to be an active and rapidly developing - search area. The interest is mainly due to the potential applications of nonlinear optics: - rectly in telecommunications for high rate data transmission, image processing and recognition or indirectly from the possibility of obtaining large wavelength range tuneable lasers for applications in industry, medicine, biology, data storage and retrieval, etc. New phenomena and materials continue to appear regularly, renewing the field. This has proven to be especially true over the last five years. New materials such as organics have been developed with very large second- and third-order nonlinear optical responses. Imp- tant developments in the areas of photorefractivity, all optical phenomena, frequency conv- sion and electro-optics have been observed. In parallel, a number of new phenomena have been reported, some of them challenging the previously held concepts. For example, solitons based on second-order nonlinearities have been observed in photorefractive materials and frequency doubling crystals, destroying the perception that third order nonlinearities are - quired for their generation and propagation. New ways of creating and manipulating nonl- ear optical materials have been developed. An example is the creation of highly nonlinear (second-order active) polymers by static electric field, photo-assisted or all-optical poling. Nonlinear optics involves, by definition, the product of electromagnetic fields. As a con- quence, it leads to the beam control.

Included is a presentation of configurational forces within a classical context and a discussion of their use in areas as diverse as phase transitions and fracture.

Some of the earliest civilizations regarded the universe as organized around four principles, the four "elements" earth. water, air, and fire. Fire, which was the source of light and as such possessed an immaterial quality related to the spiritual world. was clearly the most impressive of these elements, although its quanti tative importance could not have been properly discerned. M- ern science has changed the names, but macroscopic matter is still divided into four states. The solid, liquid, and gaseous states are ordinary states, but the fourth state of matter, the plasma state, has retained a somewhat extraordinary character. It is now recognized that most of the matter of the universe is in the ionized state. but on the earth. the plasma state is still the exception. Hence the importance and also the difficulty of investigations dealing with ionized matter, which have been greatly furthered by the development of thermonuclear fusion research. The study of matter in the ionized state comprises a large diversity of problems belonging to many different branches of phys ics. A number of them relate to the microscopic properties of plasmas and concern the structure and the collisional behavior of atomic constituents. Although they are clearly of basic importance, their relevance to thermonuclear research was at first overlooked, at a time when most of the effort was concentrated on designing fusion devices and understanding macroscopic phenomena, mostly of an electromagnetic nature. At present."

Stochastic geometry, based on current developments in geometry, probability and measure theory, makes possible modeling of two- and three-dimensional random objects with interactions as they appear in the microstructure of materials, biological tissues, macroscopically in soil, geological sediments etc. In combination with spatial statistics it is used for the solution of practical problems such as the description of spatial arrangements and the estimation of object characteristics. A related field is stereology, which makes possible inference on the structures, based on lower-dimensional observations. Unfolding problems for particle systems and extremes of particle characteristics are studied. The reader can learn about current developments in stochastic geometry with mathematical rigor on one hand and find applications to real microstructure analysis in natural and material sciences on the other hand.

During the Koln meeting (August 28-31, 1984), Irdia was chosen as the venue for the next International Conference on Valence Fluctuations. lhis was in recognition ard appreciation of the work done, both experimental ard theoretical, by the Irdian scientists in this area during the last decade. We decided to hold this Conference in the month of January, 1987 at Bangalore. lhe subject of Valence Fluctuations has kept itself alive ard active as it has provided many shocks ard suprises particularly among the Ce- ard U-based intermetallies. lhe richness of many interesting physical phenomena occurring in mixed valent materials, the flexibility of modifying their physical properties (by alloying, for example) ard the possibility of synthesizing a wide variety of new such materials seem to be the key factors in this regard. Barely six months before this Conference, an International Conference on Anomalous Rare Earths and Actinides (ICAREA) had been held at Grenoble (July, 1986) which also focussed on mixed valence ard heavy fermion phenomena. In spite of this, the response to this' Conference was very enthusiastic and encouraging. Many interesting ard important results were presented at this Conference which have been included in this volume.

This Proceedings is a collection of papers presented at the Third Annual Conference on Superconductivity and Applications organized by the New York State Institute on Superconductivity. This year the Conference was held at the Buffalo Hilton Hotel on September 19- 21, 1989, with previous meetings on September 28-29,1987, and April 18-20, 1988. As in previous years, this meeting was highly successful, with an attendance of over three hundred researchers participating in lively scientific exchanges and discussions. The high quality of the talks is evident in this Proceedings. The field of high temperature superconductivity has matured considerably since its early days of media frenzy and rapid new discoveries. However, the enthusiasm and pace of research have not slowed down. A much better picture of the nature of high temperature superconductivity, the properties of these new materials and where they may find their eventual use has emerged. Processing techniques, especially thin film deposition, have been perfected nearly to the point of allowing commercial applications. We expect continued phenomenal growth of the field of high temperature superconductivity, both in terms of research and applications for many years to come.

This book is designed for the chemist, formulator, student, teacher, forensic scientist, or others who wish to investigate the composition of polymeric materials. Theinformationwithinthesepagesisintendedtoarmthereaderwiththenecessary workingknowledgetoanalyze,characterize, anddeformulatematerials. ThestructureoftheContentsisintendedtoassistthereaderinquicklylocating the subject of interest and proceed to it with a minimum of expended time and effort. The Contents provides an outline of major topics and relevant materials char- terizedforthereader'sconvenience. Anintroductiontoanalysisanddeformulation is provided in Chapter 1 to acquaint the reader with analytical methods and their applications. Extensive references are provided as additional sources ofinfor- tion. All tables arelocatedin theAppendix, beginning onp. 235. GUIDE FOR USE This is a practical book structured to efficiently use the reader's time with a minimum effort of searching for entries and information by following these brief instructions: 1. Searchthe Contents and/orIndex fora subject withinthe text. 2. Analysis/deformulation principles are discussed at the outset to familiarize the reader with analysis methods and instruments; followed by formu- tions, materials, and analysis ofpaint, plastics, adhesives, and inks; and finally reformulation methods to test the results of analysis. 3. Materials and a wide assortment of formulations are discussed within the text by chapter/section number. 4. Materials are referred toby various names (trivial, trade, and scientific), and these are listed in tables and cross-referenced to aid the reader.

tions is not possible without first putting the problem into a wider con text. Consequently, before proceeding with detailed critical topical cov erage of individual biomass energy sources, uses, and effects, I will extend this preface with a few pages of rather personal reflections (I will use the same device in closing the book: after providing concise topical summaries in Chapter 8, I will conclude with some essayistic musings on renewable energetics, plants, people, and a scientist's responsibility). Interest in biomass energies is just a part of a broader global trend toward renewable energetics, a trend which has evolved speedily after the crude oil price escalation started in 1973. Yet one must be reminded that for the rich countries fossil fuels are, and for a long period shall remain, the foundation of an affluent civilization, while throughout the poor world the reliance of most people on biomass energies for everyday subsistence has brought many damaging environmental and social ef fects; that the reality of sharp price rises for crude oil (actually not so sharp once adjusted for inflation) should not be misconstrued as an "energy crisis"; that the rise of renew abies and the claims made on their behalf by countless enthusiasts look so much better on paper than in reality; and that the potential of biomass energies, an essential ingre dient of renewable scenarios, has been judged more with proselytizing zeal than with critical detachment."

The 1984 Advanced Study Institute on "Electronic Structure, Dynamics and Quantum Structural Properties of Condensed Matter" took place at the Corsendonk Conference Center, close to the City of Antwerpen, from July 16 till 27, 1984. This NATO Advanced Study Institute was motivated by the research in my Institute, where, in 1971, a project was started on "ab-initio" phonon calculations in Silicon. I~ is my pleasure to thank several instances and people who made this ASI possible. First of all, the sponsor of the Institute, the NATO Scientific Committee. Next, the co-sponsors: Agfa-Gevaert, Bell Telephone Mfg. Co. N.V., C & A, Esso Belgium*, CDC Belgium, Janssens Pharmaceutica, Kredietbank and the Scientific Office of the U.S. Army. Special thanks are due to Dr. P. Van Camp and Drs. H. Nachtegaele, who, over several months, prepared the practical aspects of the ASI with the secretarial help of Mrs. R.-M. Vandekerkhof. I also like to. thank Mrs. M. Cuyvers who prepared and organized the subject and material index and Mrs. H. Evans for typing-assist ance. I express particular gratitude to Mrs. F. Nedee, who, like in 1981 and 1982, has put the magnificent Corsendonk Conference Center at our disposal and to Mr. D. Van Der Brempt, Director of the Corsendonk Conference Center, for the efficient way in which he and his staff took care of the practical organization at the Conference Center.

This series of books, which is published at the rate of about one per year, addresses fundamental problems in materials science. The contents cover a broad range of topics from small clusters of atoms to engineering materials and involve chemistry, physics, materials science, and engineering, with length scales ranging from Angstroms up to millimeters. The emphasis is on basic science rather than on applications. Each book focuses on a single area of current interest and brings together leading experts to give an up-to-date discussion of their work and the work of others. Each article contains enough references that the interested reader can access the relevant literature. Thanks are given to the Center for Fundamental Materials Research at Michigan State University for supporting this series. M. F. Thorpe, Series Editor E-mail: thorpe@pa. msu. edu East Lansing, Michigan V PREFACE It is hard to believe that not quite ten years ago, namely in 1991, nanotubes of carbon were discovered by Sumio Iijima in deposits on the electrodes of the same carbon arc apparatus that was used to produce fullerenes such as the "buckyball." Nanotubes of carbon or other materials, consisting ofhollow cylinders that are only a few nanometers in diameter, yet up to millimeters long, are amazing structures that self-assemble under extreme conditions. Their quasi-one-dimensional character and virtual absence of atomic defects give rise to a plethora of unusual phenomena."

Making Flory-Huggins Practical: Thermodynamics of Polymer-Containing Mixtures, by B. A. Wolf * Aqueous Solutions of Polyelectrolytes: Vapor-Liquid Equilibrium and Some Related Properties, by G. Maurer, S. Lammertz, and L. Ninni Schafer * Gas-Polymer Interactions: Key Thermodynamic Data and Thermophysical Properties, by J.-P. E. Grolier, and S. A.E. Boyer * Interfacial Tension in Binary Polymer Blends and the Effects of Copolymers as Emulsifying Agents, by S. H. Anastasiadis * Theory of Random Copolymer Fractionation in Columns, by Sabine Enders * Computer Simulations and Coarse-Grained Molecular Models Predicting the Equation of State of Polymer Solutions, by K. Binder, B. Mognetti, W. Paul, P. Virnau, and L. Yelash * Modeling of Polymer Phase Equilibria Using Equations of State, by G. Sadowski

The 39th Annual Denver X-Ray Conference on Applications of X-Ray Analysis was held July 30 -August 3, 1990, at the Sheraton Steamboat Resort and Conference Center, Steamboat Springs, Colorado. The "Denver Conference" is recognized to be a major event in the x-ray analysis field, bringing together scientists and engineers from around the world to discuss the state of the art in x-ray applications as well as indications for future develop ments. In recent years there has been a steady expansion of applications of x-ray analysis to characterize surfaces and thin films. To introduce the audience to one of the exciting and important new developments in x-ray fluorescence, the topic for the Plenary Session of the 1990 Conference was: "Surface and Near-Surface X-Ray Spectroscopy. " The Conference had the privilege of inviting five leading world experts in the field of x-ray spectroscopy to deliver lectures at the Plenary Session. The first two lectures were on total-reflection x-ray fluorescence spectrometry. Professor P. Wobrauschek of Austria reviewed "Recent Developments and Results in Total-Reflection X-Ray Fluorescence. " Trends and applications of the technique were also discussed. Dr. T. Arai of Japan reported on "Surface and Near-Surface Analysis of Silicon Wafers by Total Reflection X-Ray Fluorescence. " He emphasized the importance of using proper x-ray optics to achieve high signal-to-noise ratios. A mathematical model relating the x-ray intensity to the depth of x-ray penetration was also described.

This accessible text presents a unified approach of treating the microstructure and effective properties of heterogeneous media. Part I deals with the quantitative characterization of the microstructure of heterogeneous via theoretical methods; Part II treats a wide variety of effective properties of heterogeneous materials and how they are linked to the microstructure, accomplished by using rigorous methods.