This book is intended for scientists, researchers, and graduate students interested in solutions in general, and solutions of metals in particular. Readers are assumed to have a good background in thermodynamics, presented in such books as those cited at the end of Chapter 1, "Thermo dynamic Background." The contents of the book are limited to the solutions of metals + metals, and metals + metalloids, but the results are also appli cable to numerous other types of solutions encountered by metallurgists, materials scientists, geologists, ceramists, and chemists. Attempts have been made to cover each topic in depth with numerical examples whenever necessary. Chapter 2 presents phase equilibria and phase diagrams as related to the thermodynamics of solutions. The emphasis is on the binary diagrams since the ternary diagrams can be understood in terms of the binary diagrams coupled with the phase rule, and the Gibbs energies of mixing. The cal culation of thermodynamic properties from the phase diagrams is not emphasized because such a procedure generally yields mediocre results. Nevertheless, the reader can readily obtain thermodynamic data from phase diagrams by reversing the detailed process of calculation of phase diagrams from thermodynamic data. Empirical rules on phase stability are given in this chapter for a brief and clear understanding of the physical and atomistic factors underlying the alloy phase formation."

The building explosion during the years 1945-1960 will inevitably lead to increased demolition in the next decades since the lifetime distribution of structures no longer fulfills its functional social requirements in an acceptable way. In the building period mentioned there was a great increase in reinforced and prestressed concrete construction. Consequently there is now more and more concrete to be demolished. Increasingly severe demands will be made upon demolition technology, including the demand for human- and environment-friendly techniques. On the other hand, the possibility of disposing of debris by dumping is steadily diminishing, especially close to major cities and generally in countries with a high population density. At the same time in such countries and in such urban areas a shortage of aggregates for making concrete will develop as a result of restrictions on aggregate working because of its effect on the environment and because of the unavailability of aggregate deposits due to urban development. From the foregoing it follows that recycling and re-use of environment- and human-friendly demolished and fragmented building rubble should be considered. The translation of this general problem into terms of materials science is possible by forming clear ideas of adhesion and cohesion: the whole process of demolition, fragmentation, and recycling or re-use of concrete is to break the bonding forces between atoms and molecules and to form new bonds across the interfaces of various particles of either the same nature or a different nature.

Four years after a first meeting in BADDECK, Canada, on the Physics of Ion-Ion and Electron-Ion collisions, a second Nato Advanced Study Institute, in HAl~/Lesse, Belgium, reexamined the subject which had become almost a new one, in consideration of the many important developments that had occured in the mean time. The developments have been particularly impressive in two areas : the di-electronic recombination of electrons with ions and the collisional processes of mUltiply charged ions. For dielectronic recombination, a major event was the obtainment, in 1983, of the first experimental data. This provided, at last, a non speculative basis for the study of that intricate and subtle process and strongly stimulated the theoretical activities. Multiply charged ions, on the other hand, have become popular, thanks to the development of powerful ion sources. This circumstance, together with a pressing demand from thermonuclear research for ionisation and charge exchange cross sections, has triggered systematic experimental investigations and new theoretical studies, which have contributed to considerably enlarge, over the last five years, our understanding of the collisional processes of multiply charged ions. Dielectronic recombination and multiply charged ions were therefore central points in the programme of the A.S.I. in HAN/Lesse and are given a corresponding emphasis in the present book.

This book describes behavior of crystalline solids primarily via methods of modern continuum mechanics. Emphasis is given to geometrically nonlinear descriptions, i.e., finite deformations. Primary topics include anisotropic crystal elasticity, plasticity, and methods for representing effects of defects in the solid on the material's mechanical response. Defects include crystal dislocations, point defects, twins, voids or pores, and micro-cracks. Thermoelastic, dielectric, and piezoelectric behaviors are addressed. Traditional and higher-order gradient theories of mechanical behavior of crystalline solids are discussed. Differential-geometric representations of kinematics of finite deformations and lattice defect distributions are presented. Multi-scale modeling concepts are described in the context of elastic and plastic material behavior. Representative substances towards which modeling techniques may be applied are single- and poly- crystalline metals and alloys, ceramics, and minerals. This book is intended for use by scientists and engineers involved in advanced constitutive modeling of nonlinear mechanical behavior of solid crystalline materials. Knowledge of fundamentals of continuum mechanics and tensor calculus is a prerequisite for accessing much of the text. This book could be used as supplemental material for graduate courses on continuum mechanics, elasticity, plasticity, micromechanics, or dislocation mechanics, for students in various disciplines of engineering, materials science, applied mathematics, and condensed matter physics.

The molecular mechanisms underlying the fact that a crystal can take a variety of external forms is something we have come to understand only in the last few decades. This is due to recent developments in theoretical and experimental investigations of crystal growth mechanisms.
Morphology of Crystals is divided into three separately available volumes. Part A contains chapters on roughening transition; equilibrium form; step pattern theory; modern PBC; and surface microtopography. This part provides essentially theoretical treatments of the problem, particularly the solid-liquid interface. Part B contains chapters on ultra-fine particles; minerals; transition from polyhedral to dendrite; theory of dendrite; and snow crystals. All chapters are written by world leaders in their respective areas, and some can be seen as representing the essence of a life's work. This is the first English-language work which covers all aspects of the morphology of crystals - a topic which has attracted top scientific minds for centuries. As such, it is indispensable for anyone seeking an answer to a question relating to this fascinating problem: mineralogists, petrologists, crystallographers, materials scientists, workers in solid-state physics and chemistry, etc.
In Parts A: Fundamentals and B: Fine Particles, Minerals and Snow equilibrium and kinetic properties of crystals are generally approached from an atomistic' point of view. In contrast, Part C: The Geometry of Crystal Growth follows the alternative and complementary geometrical' description, where bulk phases are considered as continuous media and their interfaces as mathematical surfaces with orientation-dependent properties. Equations of motion for a crystal surface are expressed in terms of vector and tensor operators working on surface free energy and growth rate, both expressed as functions of surface orientation and driving force, or affinity' for growth. This approach emphasizes the interrelation between equilibrium and kinetic behavior. Part 1 establishes the theoretical framework. Part 2 gives a construction toolbox for explicit (analytic) functions. An extra chapter is devoted to experimental techniques for measuring such functions: a new approach to sphere growth experiments. The emphasis throughout is on principles and new concepts.
Audience: Advanced readers familiar with traditional aspects of crystal growth theory. Can be used as the basis for an advanced course, provided supplementation is provided in the areas of atomistic models of the advancing surface, diffusion fields, etc.

The content of this monograph stems from the writer's early involvement with the design of a series of television camera tubes: the orthicon, the image orthicon and the vidicon. These tubes and their variations, have, at different times been the "eyes" of the television system almost from its inception in 1939. It was natural, during the course of this work, to have a parallel interest in the human visual system as well as in the silver halide photographic process. The problem facing the television system was the same as that facing the human visual and the photographic systems, namely, to abstract the maximum amount of information out of a limited quantity oflight. The human eye and photographic film both repre sented advanced states of development and both surpassed, in their performance, the early efforts on television camera tubes. It was particularly true and "plain to see" that each improvement and refinement of the television camera only served to accentuate the remarkable design of the human eye. A succession of radical advances in camera-tube sensitivity found the eye still operating at levels of illumination too low for the television camera tube. It is only recently that the television camera tube has finally matched and even somewhat exceeded the performance of the human eye at low light levels. It was also clear throughout the work on television camera tubes that the final goal of any visual system-biological, chemical, or electronic-was the ability to detect or count individual photons."

In the early 1980s capillary liquid chromatography was being established; it was a period in which only a few research groups published a relatively small number of papers on the subject. In terest has since taken off, and a period of intense development, to which no end is yet in sight, is now upon us. More investiga tors and instrument-making firms are now entering the field. This greater interest has resulted in the rapid appearance of two collec tions [1, 2] and a series of topical reviews [3-6]. However, it could hardly be said that all the problems in this area have been formulated, let alone solved. The preparation of very efficient - open tubular or packed - microbore columns, for example, remains more an art than a science, while the relation ship between radial and longitudinal mass transfer, and the effect of transcolumn velocity profiles on chromatographic efficiency, have been very poorly studied. Indeed, recent publications on these subjects have sometimes, far from clarifying matters, only muddied them further. Many instrument-making firms are trying to unify their equip ment so that it is suitable for microbore, conventional (analytical), and preparative liquid chromatography. This approach has not real ized the full potential of capillary chromatography, and there also remains room for improving the performance of capillary columns.

This book is devoted to the deformation and failure in metallic materials, summarizing the results of a research programme financed by the "Deutsche Forschungsgemeinschaft." It presents the recent engineering as well as mathematical key aspects of this field for a broad community. Its main focus is on the constitutive behaviour as well as the damage and fracture of metallic materials, covering their mathematical foundation, modelling and numerics, but also relevant experiments and their verification.

The U. S. Army Materials Research Agency has conducted the Saga more Army Materials Research Conferences, in cooperation with the Metallurgical Research Laboratories of the Department of Chemical En gineering and Metallurgy of Syracuse University, since 1954. The pur pose of the conferences has been to gather together scientists and engi neers from academic institutions, industry, and government who are uniquely qualified to explore in depth a subject of importance to the Army and the Department of Defenseo The subject of the Thirteenth Sagamore Army Materials Research Con ference, "Surfaces and Interfaces I: Chemical and Physical Characteris tics," was chosen from a substantial number of possible topics because scientists in the Army responsible for materials research, the conference committee, and the participants believed that much good would result from a detailed analysis of: the knowledge and role of surfaces, including their fundamental characteristics; the role of adsorption and adhesion; and the kinetics, both of exterior surfaces and interfaces. This informa tion should aid immeasurably in leading the way to vastly improved mate rials, vitally essential if progress is to be made in structures having improved performance. The wisdom of selecting a topic concerned with surfaces and inter faces is substantiated by the papers presented in this publication."

Methods and Materials for Remote Sensing: Infrared Photo-Detectors, Radiometers and Arrays presents the basic principles and the guidelines for the design of IR and microwave radiometers intended for the detection of weak electromagnetic signals in a noisy background. Significant attention is paid in this book to the discussion of the origin of the noises and consideration of the physical factors limiting the sensitivity of photo sensors. The physico-chemical properties of narrow-band semiconductors, which are the basic photosensitive materials for the microwave and IR radiometry, are discussed. Also described are the methods for growing the single crystals, epitaxial films and arrays from solid solutions of these compounds for the application in photosensitive detectors. The main goal of Methods and Materials for Remote Sensing: Infrared Photo-Detectors, Radiometers and Arrays is to present the entire material from the unifying physical viewpoint, which will be helpful for the designers of photo-detecting devices, and professionals contributing in various areas of remote sensing.

The first edition of this book (1958) described an analytical situation which had existed for a number of years for maintaining quality control on vulcanizates of natural rubber although the situation had recently been disturbed by the introduction of a range of synthetic rubbers which required identification and quantitative estimation. For the former purpose 'wet' chemistry, based on various imperfectly understood organic reactions, was pressed into service. Alongside this was the first introduction of instrumental analysis, using the infrared spectra of either the polymers or, more usually, their pyrolytic products to 'fingerprint' the material. The identification of a range of organic accelerators, antioxidants and their derivatives which had been intro duced during the 1920s and 30s was, in the first edition, dealt with by a combination of column chromatography and infrared spectroscopy or by paper chromatography. Quantitative procedures were, however, still classical in the tradition of gravimetric or volumetric assays with an initially weighed sample yielding, after chemical manipulation, a carefully precipitated, dried and weighed end product, or a solution of known composition whose weight or titre, as a percentage of the initial sample, quantified the function being determined. The second edition of this work (1968) consolidated the newer techni ques which had been introduced in the first without adding to them although, in other applications of analytical chemistry, instrumental analysis had already brought about a transformation in laboratory practice."

The polycrystalline and nanocrystalline states play an increasingly important role in exploiting the properties of materials, encompassing applications as diverse as pharmaceuticals, catalysts, solar cells and energy storage. A knowledge of the three-dimensional atomic and molecular structure of materials is essential for understanding and controlling their properties, yet traditional single-crystal X-ray diffraction methods lose their power when only polycrystalline and nanocrystalline samples are available. It is here that powder diffraction and single-crystal electron diffraction techniques take over, substantially extending the range of applicability of the crystallographic principles of structure determination. This volume, a collection of teaching contributions presented at the Crystallographic Course in Erice in 2011, clearly describes the fundamentals and the state-of-the-art of powder diffraction and electron diffraction methods in materials characterisation, encompassing a diverse range of disciplines and materials stretching from archeometry to zeolites. As such, it is a comprehensive and valuable resource for those wishing to gain an understanding of the broad applicability of these two rapidly developing fields.

This book presents an account of the course "Optical Properties of Excited States in Solids" held in Erice, Italy, from June 16 to 3D, 1991. This meeting was organized by the International School of Atomic and Molecular Spectroscopy of the "Ettore Majorana" Centre for Scientific Culture. The purpose of this course was to present physical models, mathematical formalisms and experimental techniques relevant to the optical properties of excited states in solids. Some active physical species, such as ions or radicals, could survive indefinitely if they were completely 'isolated in space. Other active species, such as excited molecular and solid-state systems, are inherently unstable, even in isolation, due to the spontaneous mechanisms that may convert their excitation energies into radiation or heat. Physical parameters that may be used to characterize these excited systems are the localization or delocalization, and the coherence or incoherence, of their state excitations. In solids the excited states, whether they are localized (as for impurities in insulators) or delocalized (as they may occur in semiconductors), are relevant in several regards. Their de-excitation is extremely sensitive to the nature of the excitations of the systems, and a study of the de-excitation processes can yield a variety of information. For example, the excited states may represent the initial condition of the onset of such processes as Stokes-shifted emission, hot luminescence, symmetry-dependent Jahn-Teller and scattering processes, tunneling processes, energy transfer to like and unlike centers, superradiance, coherent radiation, and excited state absorption.

Photonic Crystal Fibres describes the fundamental properties of the optical waveguides known under the terms of photonic crystal fibres, microstructured fibres, or holey fibres. It outlines how the fibres are designed and fabricated, and how they are treated from a theoretical and numerical point of view. The book presents a detailed description of the different classes of photonic crystal and photonic bandgap fibres, and it broadens out a spectrum of novel applications and new fibre types.

Fundamentals of Friction, unlike many books on tribology, is devoted to one specific topic: friction. After introductory chapters on scientific and engineering perspectives, the next section contains the necessary background within the areas of contact mechanics, surfaces and adhesion. Then on to fracture, deformation and interface shear, from the macroscopic behavior of materials in frictional contact to microscopic models of uniform and granular interfaces. Lubrication by solids, liquids and gases is presented next, from classical flow properties to the reorganization of monolayers of molecules under normal and shear stresses. A section on new approaches at the nano- and atomic scales covers the physics and chemistry of interfaces, an array of visually exciting simulations, using molecular dynamics, of solids and liquids in sliding contact, and related AFM/STM studies. Following a section on machines and measurements, the final chapter discusses future issues in friction.

Carbon fibre reinforced carbon composites form a very specialized group of materials. They may be considered as a development of the family of carbon fibre reinforced polymer composites which are becoming ever more prevalent in modern engineering. Since the early 1960s a large number of so-called 'advanced materials' have appeared on the scene. Carbon arbon is arguably the most successful of all these products finding many and varied applications. In the field of Formula 1 motor racing for example, the present levels of performance simply could not be achieved without the use of carbon-carbon brakes and clutches. Despite the materials' obvious assets, they have not, and will not, reach their full potential until their inherent problems of excessive production costs and oxidation resistance have been addressed properly. In this respect the 'carbon-carbon story', of much potential but only limited success, serves as a lesson to all those involved in materials research, development and application. In writing this book I have tried to set up a logical progression of what the materials are, how they are made, what their assets and deficiencies are, what they are used for and to what extent they are commercially exploited. Each specialized chapter may be considered in isolation or as part of a sequence, whereas the final chapter provides a summary of the principal concepts as well as a basic review of the economic situation past, present and, hopefully, future.

Intended for engineers from a variety of disciplines dealing with structural materials, this text describes the current state of knowledge. It begins by describing the fracture process at the two extremes of scale: first in the context of atomic structures, then in terms of a continuous elastic medium. Treating the fracture process in increasingly sophisticated ways, the book then considers plastic corrections and the procedures for measuring the toughness of materials. Practical considerations are then discussed, including crack propagation, geometry dependence, flaw density, mechanisms of failure by cleavage, the ductile-brittle transition, and continuum damage mechanics. The whole is rounded off with discussions of generalised plasticity and the link between the microscopic and macroscopic aspects, and problems are provided at the end of each chapter.

In an attempt to meet the demand for new ultra-high strength materials, the processing of novel material configurations with unique microstructure is being explored in systems which are further and further from equilibrium. One such class of emerging materials is the so-called nanophased or nanostructured materials. This class of materials includes metals and alloys, ceramics, and polymers characterized by controlled ultra-fine microstructural features in the form oflayered, fibrous, or phase and grain distribution. While it is clear that these materials are in an early stage of development, there is now a sufficient body of literature to fuel discussion of how the mechanical properties and deformation behavior can be controlled through control of the microstructure. This NATO-Advanced Study Institute was convened in order to assess our current state of knowledge in the field of mechanical properties and deformation behavior in materials with ultra fine microstructure, to identify opportunities and needs for further research, and to identify the potential for technological applications. The Institute was the first international scientific meeting devoted to a discussion on the mechanical properties and deformation behavior of materials having grain sizes down to a few nanometers. Included in these discussions were the topics of superplasticity, tribology, and the supermodulus effect. Lectures were also presented which covered a variety of other themes including synthesis, characterization, thermodynamic stability, and general physical properties."

Industrial radiography is a well-established non-destructive testing (NDT) method in which the basic principles were established many years ago. However, during 1993-95 the European Standards Organisa tion (CEN) commenced drafting many new standards on NDT including radiographic methods, and when completed these will replace national standards in all the EC member countries. In some cases these standards vary significantly from those in use in the UK at present. These CEN standards are accepted by majority, not unanimous voting, so they will become mandatory even in countries which vote against them. As most are likely to be legal by the time this second edition is published, they are described in the appropriate places in the text. The most important new technical development is the greater use of computers in radiology. In the first edition, computerized tomography was only briefly mentioned at the end of Chapter 11, as it was then largely a medical method with only a few equipments having found a place in industrial use. The method depends on a complex computer program and a large data store. Industrial equipments are now being built, although their spread into industry has been slow. Computer data storage is also being used for radiographic data. Small computers can now store all the data produced by scanning a radiographic film with a small light-spot, and various programs can be applied to these data."

In view of its extreme complexity the mathematical description of the mechanical behaviour of granular materials is an extremely difficult task. Today many different models compete with each other. However, the complexity of the models hinders their comparison, and the potential users are confused and, often, disencouraged. This book is expected to serve as a milestone in the present situation, to evaluate the present methodes, to clear up the situation, to focus and encourage for further research activities.

There are numerous technological materials - such as metals, polymers, ceramics, concrete, and many others - that vary in properties and serviceability. However, the almost universal common theme to most real materials is that their properties depend on the scale at which the analysis or observation takes place and at each scale "probabilities" play an important role. Here the word "probabilities" is used in a wider than the classical sense. In order to increase the efficiency and serviceability of these materials, researchers from NATO, CP and other countries were brought together to exchange knowledge and develop avenues for progress and applications in the st 21 century. The workshop began by reviewing progress in the subject area over the past few years and by identifying key questions that remain open. One point was how to observe/measure material properties at different scales and whether a probabilistic approach, at each scale, was always applicable and advantageous. The wide range of materials, from wood to advanced metals and from concrete to complex advanced composites, and the diversity of applications, e.g. fatigue, fracture, deformation, etc., were recognized as "obstacles" in identifying a "universal" approach.

Aspect '94 is the most up-to-date and comprehensive assessment of the present and future of the pipeline systems industry. It comprises papers from leading experts in all areas of pipeline engineering and technology. As this book shows, the last few years have seen great strides forward in the field of subsea pipelines. Deepwater pipelines, long distance pipelines and complex systems transporting hydrocarbons and fluids to and from marginal field subsea wellheads and templates are all being implemented without significant problems. The pace of progress continues to accelerate in the subsea industry, and the scope to make further improvements is constantly being explored. Operators, consultants, suppliers and contractors are all researching, developing and testing new techniques and ideas.

Micro/nanotribology as a field is concerned with experimental and theoretical investigations of processes ranging from atomic and molecular scales to the microscale, occurring during adhesion, friction, wear, and thin-film lubrication at sliding surfaces. As a field it is truly interdisciplinary, but this confronts the would-be entrant with the difficulty of becoming familiar with the basic theories and applications: the area is not covered in any undergraduate or graduate scientific curriculum. The present work commences with a history of tribology and micro/nanotribology, followed by discussions of instrumentation, basic theories of friction, wear and lubrication on nano- to microscales, and their industrial applications. A variety of research instruments are covered, including a variety of scanning probe microscopes and surface force apparatus. Experimental research and modelling are expertly dealt with, the emphasis throughout being applied aspects.

The Sixth International Conference on Sintering and Related Phenomena took place at the University of Notre Dame, Notre Dame, Indiana June 6-8, 1983. This conference was also the twentieth Conference on Ceramic Sciences organized yearly by a "confederation" of four institutions: North Carolina University at Raleigh, N.C., the University of California at Berkeley, CA, Alfred University at Alfred, NY and the University of Notre Dame, Notre Dame, IN. The papers presented at the last Notre Dame conference collect ed in this volume, reflect the progress in our understanding of the process of sintering achieved in the past four years. It seems that the analysis of the two particle models is finally extended to the analysis of the models of compacts. In these investigations strong emphasis is put on pore-grain boundar ies interaction which appear to be central to this problem. It is to be hoped that in the near future an adequate model of the compact will be developed which may serve as a useful basis of powder tech nology. Also, the effects of atmosphere on the sintering of ceramics after a long period of neglect, seem to attract the attention of more workers in the field."

Modular Chemistry: the First Steps In recent years, there has been increasing interest among chemists, physicists, materials scientists, biologists, engineers, and others in the assembly of well defmed, relatively large functional structures from repetitive units that themselves are molecules of some complexity. Using the dictionary defmition of a module (a detachable section, compartment, or unit with a specific purpose or function, and in electronics, a compact assembly functioning as a component of a larger unit) [1], we feel that this newly emerging field of endeavor could be called "modular chemistry" [2]. The NATO Advanced Research Workshop on Modular Chemistry that was held on September 9 to 12, 1995, at Aspen Lodge near Estes Park, Colorado, was meant to bring together prominent contributors to modular chemistry as it is being born, and to examine the associated birth pangs. It was concluded that although real, these are not nearly as bad as giving birth to a hedgehog tail first, and that the ultimate rewards were likely to be far more satisfying in terms of new ideas and enabling methodology. The level of excitement about the possibilities that are opening up for modular chemists, and also the challenge involved, are perhaps best documented by noting that the planned discussion periods at the workshop were as long as the oral presentation periods, and yet, each discussion ran over the allocated time.