P.J. van der Put offers students an original introduction to materials chemistry that integrates the full range of inorganic chemistry. Technologists who need specific chemical facts to manipulate matter will also find this work invaluable as an easy-to-use reference. The text includes practical subjects of immediate use for materials such as bonding, morphogenesis, and design that more orthodox materials science volumes often leave out.

Phosphate Fibers is a singular detailed account of the discovery, chemistry, synthesis, properties, manufacture, toxicology, and uses of calcium and sodium calcium polyphosphate fibers. Author Edward J. Griffith-the inventor and developer of this safe, biodegradable material-takes a multidisciplinary approach to this subject, considering the social, legal, medical, and industrial issues surrounding the use of asbestos and other mineral fibers. This compelling study is a beneficial resource to both readers interested in mineral fibers as well as those who want to understand the complexities of bringing new substances into the modern marketplace.

Following three printings of the First Edition (1978), the publisher has asked for a Second Edition to bring the contents up to date. In doing so the authors aim to show how the newer microscopies are related to the older types with respect to theoretical resolving power (what you pay for) and resolution (what you get). The book is an introduction to students, technicians, technologists, and scientists in biology, medicine, science, and engineering. It should be useful in academic and industrial research, consulting, and forensics; how ever, the book is not intended to be encyclopedic. The authors are greatly indebted to the College of Textiles of North Carolina State University at Raleigh for support from the administration there for typing, word processing, stationery, mailing, drafting diagrams, and general assistance. We personally thank Joann Fish for word process ing, Teresa M. Langley and Grace Parnell for typing services, Mark Bowen for drawing graphs and diagrams, Chuck Gardner for photographic ser vices, Deepak Bhattavahalli for his work with the proofs, and all the other people who have given us their assistance. The authors wish to acknowledge the many valuable suggestions given by Eugene G. Rochow and the significant editorial contributions made by Elizabeth Cook Rochow.

Ronald M. North President Universities Council on Water Resources People sense intuitively that the world in which we live is not free of risk. Every decision, every action, even the refusal to either act or decide involves some element of risk. Perhaps, because we accept relatively low levels of risk in our daily activi ties, we tend to minimize the existence of risk and thereby fail to include risk assessment in those decisions and actions which could be improved through a risk assessment process. However, our casual approach to risk assessment seems to stem largely from the diffi culties inherent in measuring risk rather than from any lack of cognizance of the existence of risk. This conclusion is evidenced by the many statements in official documents relating to planning and evaluation which suggest that risk assessments should be con ducted but do not provide the mechanism for such assessments nor do they encourage their consideration in the decision making process. This conference on Risk/Benefit Analysis in Water Resources Planning and Management is notable because it attempts to identify and evaluate the mechanisms available for risk assessment which might be useful in water resources planning and management efforts. These proceedings bring together the thoughts of professional per sons who have struggled with the problems of risk assessment and who have contributed to the refinement of both theoretical and pragmatic solutions for the improvement of risk assessment processes."

The Foundation for Advances in Medicine and Science (FAMS), the organizers of SCANNING 98, sponsored its third annual Atomic Force Microscopy/Scanning Tunneling Microscopy Symposium at the Omni Inner Harbor Hotelin Baltimore, Maryland, from May 9 to 12, 1998. This book represents the compilation of papers that were presented at the AFM/STM Symposium as well as a few that were presented at SCANNING 96 and SCANNING 97 meetings that took place in Monterey, California. The purpose of the symposium was to provide an interface between scientists and engineers, representatives of industry, government and academia, all of whom have a common interest in probe microscopies. The meetings offered an ideal forum where ideas could easily be exchanged and where individuals from diverse fields who are on the cutting edge ofprobe microscopy research could communicate with one another. Experts in probe microscopy from around the world representing a wide range of disciplines including physics, biotechnology, nanotechnology, chemistry, material science, etc., were invited to participate. The format of the meeting was structured so as to encourage communication among these individuals. During the first day's sessions papers were presented on general topics such as application of scanning probe microscopy in materials science; STM and scanning tunneling spectroscopy of organic materials; fractal analysis in AFM; and nanomanipulation. Other papers presented included unexpected ordering of a molecule; synthesis ofpeptides and oligonucleotides; and analysis oflunar soils from Apollo 11.

The papers in this volume were presented at the Second International Conference on Unconventional Photoactive Solids held at the R&D Center of BP America September 9-12, 1985. It was part of an on-going series of conferences with the main aim of stressing the Interrelationship of solid state physics and solid state chemistry. The choice of topics covered a broad range of light-Induced solid state phenomena with particular emphasis on novel materials and/or novel phenomena. Organic solids, in particular, were emphasized as they are a natural meeting point of solid state physics and chemistry. A general trend In solid state physics Is to more complex materials (e.g. nonequilibrium glassy films, complicated unit cells, extended molecular building blocks, etc.). This trend necessitates the closer interaction between physicists and chemists. This conference reflects this trend quite dramatically. It is a new grouping together of a mix of materials, people and experimental approaches. A typical new theme pulling together this new mix can be seen in Part I. Fractals in Disordered Media. A variety of disordered media give rise to unusual temporal patterns of diffusion and reactions. The more familiar spatial patterns of self-similarity are discussed in the first article by M.F. Barnsley. Another topic pulling together a diverse group of scientists is covered in Part II. Spectral Hole-Burning. A number of leaders in this field are represented In these three papers.

The origin ofthe International Acoustical Imaging Symposium series can be traced to 1967, when a meeting on acoustical holography was held in C alifornia. In those days, acoustical holography was at the leading edge of research but, as the importance of this subject waned, so the title of the series was changed from Acoustical Holography to Acoustical Imaging in 1978. The early Symposia were held at various venues in the United States. In 1980. the series became international, with the Symposium that year taking place in Cannes in France. The pattern now is to try to met alternately in the USA and in another part of the world so that active researchers everywhere can conveniently attend at a reasonably high frequency. It was a great privilege for us in Bristol in the United Kingdom to be chosen to host the 25th Symposium, which convened on 19 March 2000 and spread over four days. We were blessed not only by good weather, but also by the attendance ofnearly 100 pa rticipants who came from 17 c ountries. A large number of papers were accepted for presentation, either orally or as posters. Whether an oral presentation or a poster, all were considered to have equal merit, and no distinction is made between them in the published proceedings. There were no parallel sessions, so every participant could attend every presentation. The re sultant disciplinary cross fertilisation maintained the t radition of past Symposia.

This book contains papers presented at the International Conference on Organic Superconductivity which was held May 20-24, 1990, at the Stanford Sierra Conference Center, South Lake Tahoe, California. In the twenty years since the First Conference on Organic Superconductivity was held (Hawaii, 1969), there has been remarkable progress in the field. At present, development is accelerating with contributions from many groups in many countries worldwide. The discovery of high Tc superconductivity by G. Bednorz and K. Muller in 1986 and subsequent developments in the ceramic superconductors have had an enormous impact on the field of superconductivity as a whole. This discovery occurred in an area entirely different from that of conventional superconduc tivity, underscoring the importance of the search for and study of novel materials of all kinds. We believe that the organics, with their wide range of structural, chemical, and physical properties, belong in this category of novel materials. This book reflects the efforts of researchers from various disciplines: physicists, chemists, and materials scientists. It addresses the normal and superconducting properties of organic materials, as well as the search for new compounds and new syntheses. We are pleased to note that one of these papers reports on the discovery of a new organic superconductor with a record high Tc in this class. One chapter is devoted to a comparison of organic superconductors and the cuprates, another, to the prospects of discovering other novel conducting or superconducting compounds."

DEFECTS AND TRANSPORT IN OXIDES is the proceedings of the eighth Battelle Colloquium in the Materials Sciences, held in Columbus and Salt Fork, Ohio, September 17-22, 1973. It took as its theme the relationship between defects and transport of both mass and charge in oxides. Applications of defect-controlled transport to a number of important processes in oxides also were covered. In selecting this topic, the Organizing Committee thought that 1973 was timely to bring together the leading theoretical and experimental researchers in the oxide transport field to review its status in a critical way, and to consider current major research directions and how research in the future might be guided into fruitful areas. The meeting was highlighted by the presentation of several papers which suggest that major advances in our understanding of transport in oxides appear to be imminent. These papers dealt with the results of new theoretical approaches whereby the energies and configurations of defects may be calculated, and with new experimental techniques for indirectly observing these defects, previously thought to be below the limits of experimental resolving power. Other papers, dealing with the application of defect chemistry to technological processes, served to demonstrate the successes and to point out yet unresolved problems associated with ix x PREFACE understanding the chemistry of imperfect crystals.

The fluorine atom, by virtue of its electronegativity, size, and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals, and surface modifiers are only a few examples. Fluoropolymers, too, while traditionally associated with extreme high performance applications have found their way into our homes, our clothing, and even our language. A recent American president was often likened to the tribology of PTFE. Since the serendipitous discovery of Teflon at the DuPont Jackson Laboratory in 1938, fluoropolymers have grown steadily in technological and marketplace importance. New synthetic fluorine chemistry, new processes, and new apprecia tion of the mechanisms by which fluorine imparts exceptional properties all contribute to accelerating growth in fluoropolymers. There are many stories of harrowing close calls in the fluorine chemistry lab, especially from the early years, and synthetic challenges at times remain daunting. But, fortunately, modem techniques and facilities have enabled significant strides toward taming both the hazards and synthetic uncertainties, In contrast to past environmental problems associated with fluorocarbon refrigerants, the exceptional properties of fluorine in polymers have great environmental value. Some fluoropolymers are enabling green technologies such as hydrogen fuel cells for automobiles and oxygen selective membranes for cleaner diesel combustion.

In the search for new functional materials, a clear understanding about the relationship between the physical properties and the atomic-scale structure of materials is needed. Here, the authors provide graduate students and scientists with an in-depth account of the evolutionary behavior of oxide functional materials within specific structural systems, discussing the intrinsic connections among these different structural systems. Over 300 illustrations and key appendices support the text.

During the past fifteen years commercial interest in compounds containing carbon fluorine bonds has burgeoned beyond all expectations, mainly owing to business opportunities arising from work on biologically active fluoroorganics-particularly agrochemicals, the relentless search for new markets for fluoropolymers and fluoro carbon fluids, developments in the field of medical diagnostics, and the drive to find replacements for ozone-depleting CFCs and Halon fire-extinguishing agents. Judging the situation to warrant the publication of a comprehensive collection of up-to-date reviews dealing with commercial organofluorine compounds within a single volume of manageable size (and hence reasonable cost), we were delighted to be invited by Plenum Publishing Corporation to produce a suitable book. In order to provide an authentic and wide-ranging account of current commercial applications of fluoroorganic materials, it clearly was necessary to assemble a sizeable team of knowledgeable contributing authors selected almost entirely from industry. Through their efforts we have been able to produce an almost complete coverage of the modem organofluorochemicals business in a manner designed to attract a reader ship ranging from experts in the field, through chemists and technologists currently unaware of the extent of industrial involvement with fluoroorganics, to students of applied chemistry. Promised chapters dedicated to perfluoroolefin oxides and 18F labeling of radiopharmaceuticals failed to materialize. This is somewhat unfortunate in view of our aim to achieve comprehensive coverage of the subject.

Fractals have changed the way we understand and study nature. This change has been brought about mainly by the work of B. B. Mandelbrot and his book The Fractal Geometry of Nature. Now here is a book that collects articles treating fractals in the earth sciences. The themes chosen span, as is appropriate for a discourse on fractals, many orders of magnitude; including earthquakes, ocean floor topography, fractures, faults, mineral crystallinity, gold and silver deposition. There are also chapters on dynamical processes that are fractal, such as rivers, earthquakes, and a paper on self-organized criticality. Many of the chapters discuss how to estimate fractal dimensions, Hurst exponents, and other scaling exponents. This book, in a way, represents a snapshot of a field in which fractals has brought inspiration and a fresh look at familiar subjects. New ideas and attempts to quantify the world we see around us are found throughout. Many of these ideas will grow and inspire further work, others will be superseded by new observations and insights, most probably with future contributions by the authors of these chapters.

The Army Materials and Mechanics Research Center in coop eration with the Materials Science Group of the Department of Chemical Engineering and Materials Science of Syracuse University has been conducting the Annual Sagamore Army Materials Research Conference since 1954. The specific purpose of these conferences has been to bring together scientists and engineers from academic institutions, industry and government who are uniquely qualified to explore in depth a subject of importance to the Department of Defense, the Army and the scientific community. These proceedings entitled, FATIGUE - ENVIRONMENT AND TEMPER ATURE EFFECT, address the overview of temperature and environmental effects of fatigue, room temperature environmental effects, high temperature and environmental effect - mechanisms, high tempera ture and environmental effect - mechanisms, materials and design-engineering applications. We wish to acknowledge the assistance of Messrs. Joseph Bernier and Dan McNaught of the Army Materials and Mechanics Research Center and Helen Brown DeMascio of Syracuse University throughout the stages of the conference planning and finally the publication of the book. The continued active interest and support of these conferences by Dr. E. Wright, Director of the Army Materials and Mechanics Research Center, is appreciated."

An Advanced Study Institute on Radiative Processes in Discharge Plasmas was held at the Atholl Palace Hotel, Pitlochry, Perthshire, Scotland, June 23 through July 5, 1985. This publication is the Pro- ceedings from that Institute. The Institute was attended by eighty-five Participants and Lecturers representing the United States, Canada, France, West Germany, Greece, The Netherlands, Portugal, Turkey, the United Kingdom, and Switzerland. A distinguished faculty of eighteen Lecturers was assembled and the topical program organized with the assistance of an Advisory Committee composed of: Dr. John Waymouth, USA; Dr. Timm Teich, Switzerland; Dr. Arthur Phelps, USA; Dr. Nicol Peacock, England; Professor Erich Kunhardt, USA; Dr. Anthony Hyder, USA; and Dr. Arthur Guenther, USA. The underlying theme and objective of the Institute was the enhance- ment of scientific communication and exchange among academic, industrial, and national laboratory groups having a common concern for radiative processes in discharge plasmas. The program was organized into four major sessions sequentially treating: the fundamental science of visible and near-visible radiation in plasmas; the technology of discharge light sources; recent and novel methods for the generation of plasmas; and an update on advances in laser-based diagnostics. Each major session culmi- nated in a panel discussion comprised of the Lecturers for that session.

Polymer modifications represent a valuable synthetic approach to unique polymer compositions, structure, and properties not readily available by the direct polymerization of monomers. Modified polymeric products already exist in the commercial world (modified celluloses, for example) so the approach is not new. However, it is an interesting and chaU nging opportunity to develop new materials for a variety of specialty applications using the "chemistry on polymers" approach. This book contains papers presented at the symposium on Polymer Modification held at the National American Chemical Society Meeting in Orlando, Florida, August, 1996. The chemistry presented is broad ranging, and includes grafting and chemical oxidation reactions, and many other chemical modifications. Hopefully, the book will be both a resource and an inspiration for the reader to develop new opportunities for his or her particular applications. CONTENTS SURF ACE MODIFICATIONS The Preparation of Methyl Methacrylate/Methacrylic Anhydride Copolymers from PMMA and Dialkyl Amines via Reaction Extrusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Michael P. Hallden-Abberton Grafting of Hindered Amine Groups on EPDM and Polyoctenamer via Photo- Hydroperoxidation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 J. Lacoste, S. Chmela, J. Pellet, and J. F. Pilichowski Reactive Gases as Reagents for Polymer Films Chemical Modifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 J. F. Pilichowski, S. Commereuc, 1. Lukac, G. Teissedre, and J. Lacoste The Synthesis of Hydrophobe-Modified Hydroxyethyl Cellulose Polymers Using Phase Transfer Catalysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 Emmett M. Partain The Synthesis and Characterization of Polyesters Derived from L-Lactide and Variably-Sized Poly(Caprolactone) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 Michael R. Lostocco and Samuel J.

Nanostructures refer to materials that have relevant dimensions on the nanometer length scales and reside in the mesoscopic regime between isolated atoms and molecules in bulk matter. These materials have unique physical properties that are distinctly different from bulk materials. Self-Assembled Nanostructures provides systematic coverage of basic nanomaterials science including materials assembly and synthesis, characterization, and application. Suitable for both beginners and experts, it balances the chemistry aspects of nanomaterials with physical principles. It also highlights nanomaterial-based architectures including assembled or self-assembled systems. Filled with in-depth discussion of important applications of nano-architectures as well as potential applications ranging from physical to chemical and biological systems, Self-Assembled Nanostructures is the essential reference or text for scientists involved with nanostructures.

In this reference, the author thoroughly reviews the current state of condensed phosphate chemistry. A unique feature of this volume is an examination of the recent developments in X-ray structural techniques, reporting on fundamental results obtained through their use. Enhanced by comprehensive tables reporting crystal data, chapters identify and characterize more than 2,000 compounds. Additional features include a concise survey of the historical development of condensed phosphate chemistry; the presently accepted classification system; a review of each family of condensed phosphates and much more.

The Sagamore Army Materials Research Conferences have been held in the beautiful Adirondack Mountains of New York State since 1954. Organized and conducted by the Army Materials and Mechanics Research Center (Watertown, Massachusetts) in cooperation with Syracuse University, the Conferences have focused on key issues in Materials Science and Engineering that impact directly on current or future Army problem areas. A select group of speakers and attendees are assembled from academia, industry, and other parts of the Department of Defense and Government to provide an optimum forum for a full dialogue on the selected topic. This book is a collection of the full manuscripts of the formal presentations given at the Conference. The emergence and use of nontraditional materials and the excessive failures and reject rates of high technology, materials intensive engineering systems necessitates a new approach to quality control. Thus, the theme of this year's Thirty-First Conference, "Materials Characterization for Systems Performance and Reliability," was selected to focus on the need and mechanisms to transition from defect interrogation of materials after production to utilization of materials characterization during manufacturing. The guidance and help of the steering committee and the dedicated and conscientious efforts of Ms. Karen Ka100stian, Con ference Coordinator, and Mr. William K. Wilson, and Ms. Mary Ann Holmquist are gratefully acknowledged. The continued active interest and support of Dr. Edward S. Wright, Director, AMMRC; Dr. Robert W. Lewis, Associate Director, AMMRC; and COL L. C. Ross, Commander/ Deputy Director, AMMRC; are greatly appreciated."

This volume contains the papers presented at the International Workshop on the Cur rent Problems in Condensed Matter: Theory and Experiment, held at Cocoyoc, More los, Mexico, during January 5-9, 1997. The participants had come from Argentina, Austria, Chile, England, France, Germany, Italy, Japan, Mexico, Switzerland, and the USA. The presentations at the Workshop provided state-of-art reviews of many of the most important problems, currently under study, in condensed matter. Equally important to all the participants in the workshop was the fact that we had come to honor a friend, Karl Heinz Bennemann, on his sixty-fifth birthday. This Festschrift is just a small measure of recognition of the intellectualleadership of Professor Bennemann in the field and equally important, as a sincere tribute to his qualities as an exceptional friend, college and mentor. Those who have had the privilege to work closely with Karl have been deeply touched by Karl's inquisitive scientific mind as well as by bis kindness and generosity."

For several years, I have been responsible for organizing and teaching in the fall a short course on "Fundamentals of Adhesion: Theory, Practice, and Applications" at the State University of New York at New Paltz. Every spring I would try to assemble the most pertinent subjects and line up several capable lecturers for the course. However, there has always been one thing missing-an authoritative book that covers most aspects of adhesion and adhesive bonding. Such a book would be used by the participants as a main reference throughout the course and kept as a sourcebook after the course had been completed. On the other hand, this book could not be one of those "All you want to know about" volumes, simply because adhesion is an interdisciplinary and ever-growing field. For the same reason, it would be very difficult for a single individual, especially me, to undertake the task of writing such a book. Thus, I relied on the principle that one leaves the truly monumental jobs to experts, and I finally succeeded in asking several leading scientists in the field of adhesion to write separate chapters for this collection. Some chapters emphasize theoretical concepts and others experimental techniques. In the humble beginning, we planned to include only twelve chapters. However, we soon realized that such a plan would leave too much ground uncovered, and we resolved to increase the coverage. After the book had evolved into thirty chapters, we started to feel that perhaps our mission had been accomplished.

Over the last several years, the field of materials science has witnessed an explosion of new, advanced materials. They encompass many uses and include superconductors, alloys, glasses, and catalysts. Not only are there quite a number of new enhies into these generic classes of materials, but the materials themselves represent a wide array of physical forms as well. Bulk materials, for example, are being synthesized and applica tions found for them, while still other materials are being synthesized as thin films for yet still more new (and in some cases, as yet unknown) applications. The field continues to expand with (thankfully ) no end in sight as to the number of new possibilities. As work progresses in this area, there is an ever increasing demand for knowing not only what material is formed as an end product but also details of the route by which it is made. The knowledge of reaction mechanisms in their synthesis many times allows a researcher to tailor a preparative scheme to either arrive at the final product in a purer state or with a better yield. Also, a good fundamental experimental knowledge of impuri ties present in the final material helps the investigator get more insight into making it."

In this text, Shigeji Fujita and Salvador Godoy guide first and second-year graduate students through the essential aspects of superconductivity. The authors open with five preparatory chapters thoroughly reviewing a number of advanced physical concepts-such as free-electron model of a metal, theory of lattice vibrations, and Bloch electrons. The remaining chapters deal with the theory of superconductivity-describing the basic properties of type I, type II compound, and high-Tc superconductors as well as treating quasi-particles using Heisenberg's equation of motion. The book includes step-by-step derivations of mathematical formulas, sample problems, and illustrations.

to the Fundamental and Applied Catalysis Series Catalysis is important academically and industrially. It plays an essential role in the manufacture of a wide range of products, from gasoline and plastics to fertilizers and herbicides, which would otherwise be unobtainable or prohibitive ly expensive. There are few chemical-or oil-based material items in modern society that do not depend in some way on a catalytic stage in their manufacture. Apart from manufacturing processes, catalysis is finding other important and over-increasing uses; for example, successful applications of catalysis in the control ofpollution and its use in environmental control are certain to in crease in the future. The commercial import an ce of catalysis and the diverse intellectual challenges of catalytic phenomena have stimulated study by a broad spectrum of scientists including chemists, physicists, chemical engineers, and material scientists. Increasing research activity over the years has brought deeper levels of understanding, and these have been associated with a continually growing amount of published material. As recentlyas sixty years ago, Rideal and Taylor could still treat the subject comprehensively in a single volume, but by the 19 50s Emmett required six volumes, and no conventional multivolume text could now cover the whole of catalysis in any depth.