The NATO Advanced Research Workshop on "Nanomagnetic Devices" was held in Miraflores de la Sierra, Madrid, Spain, from 14 to 19 September 1992. This book contains 21 invited articles related to suggestive and relevant aspects of Magnetism. The NATO Advanced Research Workshop was Co-directed by R.C. O'Handley, B. Heinrich and A. Hernando. The organisers as well as the participants are gratefully acknowledged to the NATO Science Committee. I also wish to thank the publishers for their advice and help in organizing the book. xi DESIDERATA OF STORAGE DEVICES C.E. YEACK-SCRANTON IBM Corporation, E02/005 5600 Cottle Road San Jose, CA 95139 USA ABSTRACT. Typical requirements on cost, capacity, and performance of today's magnetic storage devices and industry trends in these attributes are given. Scaling components, devices, and materials is shown to be a key factor in further improvement, Challenges to continued scaling are reviewed, particularly as they relate to magnetic nano-structures, materials, and characterization techniques.

A prestigious form of research grant in Germany is the Sonderforschungsbereich, which provides continuous funding over a period of up to 15 years, but only as long as the work is yielding worthwhile results. We acknowledge financial support of our work at Erlangen by the Deutsche Forschungsgemeinschaft (DFG), Sonder- forschungsbereich 222. Thanks to this support, the experimental results from six Dr. -Ing. dissertations have provided the basis for our book: 8 * Schweinzer, J. (1987) Heat transfer in bubbling fluidized beds at Ar;a. 10 * Seiter, M. (1990) Particle motion and solids concentration in circulating fluidized beds * Mattmann, W. (1991) Heat transfer in pressurized circulating fluidized beds * Burschka, A. (1993) Pulsed light method * Dietz, S. (1994) Heat transfer in bubbling fluidized beds * Gruber, U. (1995) Heat transfer in lean phase systems This book is the result of the enthusiastic and trustful cooperation of its authors. Nevertheless, we are separate individuals. Chapters 1 to 12 and 19 are by O. Molerus; Chapters 13 to 18 are by K. -E. Wirth. This book came into existence after many rewrites, patiently endured by Mrs Winter, who typed all versions of the manuscript, and by Mrs Scheffler-Kohler, who drew all the figures. Bob Farmer and David Penfold helped us bridge the language gap to produce a readable book. Weare grateful to Professor Brian Scarlett of Delft University, who on behalf of Chapman & Hall allowed us to write this book.

This book presents a set of basic understandings of the behavior and response of solids to propagating shock waves. The propagation of shock waves in a solid body is accompanied by large compressions, decompression, and shear. Thus, the shear strength of solids and any inelastic response due to shock wave propagation is of the utmost importance. Furthermore, shock compres sion of solids is always accompanied by heating, and the rise of local tempera ture which may be due to both compression and dissipation. For many solids, under a certain range of impact pressures, a two-wave structure arises such that the first wave, called the elastic prescursor, travels with the speed of sound; and the second wave, called a plastic shock wave, travels at a slower speed. Shock-wave loading of solids is normally accomplished by either projectile impact, such as produced by guns or by explosives. The shock heating and compression of solids covers a wide range of temperatures and densities. For example, the temperature may be as high as a few electron volts (1 eV = 11,500 K) for very strong shocks and the densification may be as high as four times the normal density.

This publication presents the proceedings of ICPMSE-3, the third international conference on Protection of Materials and Structures from the Low Earth Orbit Space Environment, held in Toronto April 25-26, 1996. The conference was hosted and organized by Integrity Testing Laboratory Inc, (ITL), and held at the University of Toronto's Institute for Aerospace Studies (UTIAS), where ITL is located. Twenty industrial companies, seven wliversities and eight government agencies from Canada, USA, United Kingdom, France, Israel, Russia, Ukraine and the Netherlands were represented by over 55 participants indicating increasing international co-operation in this critical arena of protection of materials in space. Twenty-five speakers, world experts in their fields, delivered talks on a wide variety of topics on various aspects of material protection in space, Representatives from the Canadian, American, European and Israeli space agencies as well as from leading space research laboratories of major aerospace industries gathered at UTIAS to discuss the latest developments in the field of material and structure protection from the harsh space environment, These proceedings are organized into four sections: a) AONOV and Radiation Effects on Materials and Structures in the Leo Space Environment; b) Interaction of Matter with the LEO Environment; c) Large Scale Coating Process Developments for Protection in LEO; d) Synthesis and Modification of Materials and Surfaces for Protection in LEO, This is the third in our on-going series of bi-annual international space materials conferences wllich began in 1992 in Toronto. Jacob Kleiman, Integrity Testing Laboratory Inc.

Most industrial and natural materials exhibit a macroscopic behaviour which results from the existence of microscale inhomogeneities. The influence of such inhomogeneities is commonly modelled using probabilistic methods. Most of the approaches to the evaluation of the safety of structures according to probabilistic criteria are somewhat scattered, however, and it is time to present such material in a coherent and up-to-date form. Probabilities and Materials undertakes this task, and also defines the great tasks that must be tackled in coming years. For engineers and researchers dealing with materials, geotechnics, solid mechanics, soil mechanics, statistics and stochastic processes. The expository nature of the book means that no prior knowledge of statistics or probability is required of the reader. The book can thus serve as an excellent introduction to the nature of applied statistics and stochastic modelling.

Nanophase Materials is the first and, as yet, the only comprehensive book published in this new and exciting area of materials science. It gives a broad overview of the revolutionary new field of nanophase materials; a view which spans the materials, physics, and chemistry research communities at a tutorial level that is suitable for advanced undergraduates, graduate students, postdoctoral researchers, and experts or would-be experts in the science of nanostructured materials. The articles are authored by many of the world's most prominent scientists in this field. The book covers the diverse methods for synthesizing nanophase materials, a variety of subsequent processing methodologies, what is known about the structures of these materials on various length scales from atomic to macroscopic, and the properties of these unique and novel materials. The materials properties covered are mechanical, electronic, optical, and magnetic and hence span a wide range of important new opportunities for technological applications.

Since the publication of the first edition of The Physics of Glassy Polymers there have been substantial developments in both the theory and application of polymer physics, and many new materials have been introduced. Furthermore, in this large and growing field of knowledge, glassy polymers are of particular interest because of their homogeneous structure, which is fundamentally simpler than that of crystalline or reinforced materials. This new edition covers all these developments, including the emergence of the polymer molecule with its multiplicity of structure and conformations as the major factor controlling the properties of glassy polymers, using the combined knowledge of a distinguished team of contributors. With an introductory chapter covering the established science in the subject are and summarising concepts assumed in the later chapters, this fully revised and updated second edition is an essential work of reference for those involved in the field.

A comprehensive encyclopaedic dictionary on polymer technology with expanded entries - trade name and trade marks, list of abbreviations and property tables.

One of the major challenges of science in the last few years of the second millennium is learning how to design materials which can fulfill specific tasks. Ambitious as it may be, the possibilities of success are not ne li ble provided that all the different expertises merge to overcome the limits of eXIsting disciplines and forming new paradigms science. The NATO Advanced Research Workshop on "Magnetic Molecular Materials" was organized with the above considerations in mind in order to determine which are the most appropriate synthetic strategies, experimental techniques of investigation, and theoretical models which are needed in order to develop new classes of magnetic materials which are based on molecules rather than on metallic or ionic lattices. Why molecules? The answer may be obvious: molecular chemistry in principle fine can tune the structures and the properties of complex aggregates, and nature already provides a large number of molecular aggregates which can perform the most disparate functions. The contributions collected in this book provide a rather complete view of the current research accomplishments of magnetic molecular materials. There are several different synthetic approaches which are followed ranging from purely organic to inorganic materials. Some encouraging successes have already been achieved, even if the critical temperatures below which magnetic order is observed still are in the range requiring liquid helium.

This volume consists of the state-of-the-art reports on new developments in micromechanics and the modeling of nanoscale effects, and is a companion book to the recent Kluwer volume on nanomechanics and mul- scale modeling (it is entitled Trends in Nanoscale Mechanics). The two volumes grew out of a series of discussions held at NASA Langley Research Center (LaRC), lectures and other events shared by many researchers from the national research laboratories and academia. The key events include the 2001 Summer Series of Round-Table Discussions on Nanotechnology at ICASE Institute (NASA LaRC) organized by Drs. V. M. Harik and M. D. Salas and the 2002 NASA LaRC Workshop on Multi-scale Modeling. The goal of these interactions was to foster collaborations between academic researchers and the ICASE Institute (NASA LaRC), a universi- based institute, which has pioneered world-class computational, theoretical and experimental research in the disciplines that are important to NASA. Editors gratefully acknowledge help of Ms. E. Todd (ICASE, NASA LaRC), the ICASE Director M. D. Salas and all reviewers, in particular, Dr. B. Diskin (ICASE/NIA, NASA LaRC), Prof. R. Haftka (University of Florida), Dr. V. M. Harik (ICASE/Swales Aerospace, NASA LaRC), Prof.

Readers intent on mastering the basics should start by reading the first few overview chapters and then delve into the descriptions of specific current applications to see how they actually work. Important future applications are also outlined, including information storage, materials for computer memories, quantum computers, isotopic fibers, isotopic optoelectronics, and quantum electronics.

Low dielectric constant materials are an important component of microelectronic devices. This comprehensive book covers the latest low-dielectric-constant (low-k) materials technology, thin film materials characterization, integration and reliability for back-end interconnects and packaging applications in microelectronics. Highly informative contributions from leading academic and industrial laboratories provide comprehensive information about materials technologies for < 0.18 um process technology. Topics include: Organic dielectric materials, Inorganic dielectric materials, Composite dielectric materials, Metrology and characterization techniques, Integration, Reliability. This volume will be an invaluable resource for professionals, scientists, researchers and graduate students involved in dielectric technology development, materials science, polymer science, and semiconductor devices and processing.

Spectroscopy of Defects in Organic Crystals presents a masterly summary of the widespread and voluminous literature on the subject, presenting theoretical and experimental investigations of electron and vibronic optical spectra of organic crystals. Electronic states of defects combine to form crystal near-to-band and band levels. These are discrete states in the vicinity of exciton bands, surface and dislocational excitons, etc. Some studies have expressed dissimilar or even conflicting opinions about the nature of observed phenomena. In the choice of the material, preference has been given to phenomena which have received a theoretical interpretation. Some attention is paid to observations which are not completely understood and also to effects predicted but not yet confirmed. The monograph will be useful for scientists as well as undergraduate and postgraduate students of solid state physics.

Commercially successful fully synthetic polymeric materials were pro duced in the early years of this century, the first example being Bakelite. This was made from phenol and formaldehyde by Leo Bakeland in 1909. Before the end of the 1920s, a large number of other synthetic polymers had been created, including polyvinyl chloride and urea-formaldehyde. Today, there are literally hundreds of synthetic polymers commercially available with ranges of properties making them suitable for applications in many industrial sectors, including the electrical and electronics industries. In many instances the driving force behind the development of new materials actually came from the electronics industry, and today's advanced electronics would be inconceivable without these materials. For many years polymers have been widely used in all sectors of the electronics industry. From the early days of the semiconductor industry to the current state of the art, polymers have provided the enabling technologies that have fuelled the inexorable and rapid development of advanced electronic and optoelectronic devices."

In the ten years since the scientific rationale for the design, synthesis and application of inorganic and organometallic polymers (IOPs) was first conceptualised, we have witnessed the first tentative exploration of IOPs as precursors to new materials, with efforts focusing on the design and synthesis of novel ceramic precursors. Developing expertise led to precursor studies combined with the characterisation of the transformation processes that occur when IOPs are converted to ceramic materials. Now at maturity, the science presented in this volume reveals the polymer precursor approach to materials synthesis together with examples of processing ceramic shapes for a range of mechanical properties, the development of sophisticated, noninvasive analytical techniques, and IOP design rationales relying on well-defined processing-property relationships. The production of multifunctional IOPs is described, providing ion conductivity, gas sensing, bioactivity, magnetic properties, etc., combined with processability. The existence of well-defined IOPs and the exquisite control that can be exerted on sol-gel systems now provide access to such a variety of mixed organic-organometallic and/or inorganic hybrid systems that their exploitation is likely to develop into an entirely new field of materials chemistry. Future exciting avenues of research are also being opened up with the advent of buckyballs, Met-Cars, dopable preceramics, rigid-rod organometallics, and molecular tinkertoys.

The 41st Annual Conference on Applications of X-Ray Analysis was held August 2-6, 1993, at the Sheraton Denver Technical Center Hotel, Denver, Colorado. From its modest beginnings in the early 1950's, the Denver X-Ray Conference has grown to become a major venue in the national scientific calendar, with an ever-growing overseas participation. The 1993 Conference was the latest of these annual gatherings of x-ray analysts, who come together to discuss topics of current interest in diffraction and fluorescence. As the size and flavor of the Conference has changed over the years, so too have the methods and techniques of x-ray materials analysis matured. Science is advanced by the creativity of a few and the mistakes of many. It is important, therefore, that from time to time we sit back and reflect on how we got where we are, and where we are likely to go next. There has been no greater impact on the field than the introduction of the digital computer, and the Plenary Session of the 1993 Conference, "Impact of the PC in X-Ray Analysis," was designed to reflect on the role of the personal computer in the metamorphosis of x-ray instrumentation and techniques. Since the personal computer is a creation of non-x-ray specialists, we, as a group, have simply attached ourselves to the coat-tails of experts and developers in the PC field and taken advantage of new computer systems as and when they were developed.

Micro/nanotribology as a field is concerned with experimental and theoretical investigations of processes ranging from atomic and molecular scales to the microscale, occurring during adhesion, friction, wear, and thin-film lubrication at sliding surfaces. As a field it is truly interdisciplinary, but this confronts the would-be entrant with the difficulty of becoming familiar with the basic theories and applications: the area is not covered in any undergraduate or graduate scientific curriculum. The present work commences with a history of tribology and micro/nanotribology, followed by discussions of instrumentation, basic theories of friction, wear and lubrication on nano- to microscales, and their industrial applications. A variety of research instruments are covered, including a variety of scanning probe microscopes and surface force apparatus. Experimental research and modelling are expertly dealt with, the emphasis throughout being applied aspects.

This volume entitled Advanced Science and Technology of Sintering, contains the edited Proceedings of the Ninth World Round Table Conference on Sintering (IX WRTCS), held in Belgrade, Yugoslavia, September 1-4 1998. The gathering was one in a series of World Round Table Conferences on Sintering organised every four years by the Serbian Academy of Sciences and Arts (SASA) and the International Institute for the Science of Sintering (IISS). The World Round Table Conferences on Sintering have been traditionally held in Yugoslavia. The first meeting was organised in Herceg Novi in 1969 and since then they have regularly gathered the scientific elite in the science of sintering. It is not by chance that, at these conferences, G. C. Kuczynski, G. V. Samsonov, R. Coble, Ya. E. Geguzin and other great names in this branch of science presented their latest results making great qualitative leaps in the its development. Belgrade hosted this conference for the first time. It was chosen as a reminder that 30 years ago it was the place where the International Team for Sintering was formed, further growing into the International Institute for the Science of Sintering. The IX WRTCS lasted four days. It included 156 participants from 17 countries who presented the results of their theoretical and experimental research in 130 papers in the form of plenary lectures, oral presentations and poster sections.

Ordered intermetallics constitute a unique class of metallic materials which may be developed as new-generation materials for structural use at high temperatures in hostile environments. At present, there is a worldwide interest in intermetallics, and extensive efforts have been devoted to intermetallic research and development in the U.S., Japan, European countries, and other nations. As a result, significant advances have been made in all areas of intermetallic research. This NATO Advanced Workshop on ordered intermetallics (1) reviews the recent progress, and (2) assesses the future direction of intermetallic research in the areas of electronic structure and phase stability, deformation and fracture, and high-temperature properties. The book is divided into six parts: (1) Electronic Structure and Phase Stability; (2) Deformation and Dislocation Structures; (3) Ductility and Fracture; (4) Kinetic Processes and Creep Behavior; (5) Research Programs and Highlights; and (6) Assessment of Current Research and Recommendation for Future Work. The first four parts review the recent advances in the three focus areas. The fifth part provides highlights of the intermetallic research under major programs and in different institutes and countries. The last part provides a forum for the discussion of research areas for future studies.

Materials metrology is the measurement science used for determining materials property data. An essential element is the symbiosis between the understanding of materials behaviour and the development of suit- able measurement techniques which, through the provision of stand- ards, enable design engineers and plant operators to acquire materials data of appropriate precision. This book is concerned only with those aspects of materials metrology and standards that relate to the design and performance in service ofstructuresand consumerproducts. Itdoes not consider their important role in the processing ofmaterials. Theeditorsare grateful for thecommitmentand patience oftheexperts who contributed the various chapters. In addition, help from staffin the Division ofMaterials Metrology, National Physical Laboratory,inassist- ing with the task of refereeing the chapters is gratefully acknowledged. The production of this book was carried out as part of the Materials Measurement Programme of underpinning research financed by the United Kingdom Department ofTrade and Industry. Brian F. Dyson Malcolm S. Loveday MarkG. Gee Division of Materials Metrology National Physical Laboratory Teddington, TWll OLW UK CHAPTER 1 Materials metrology and standards: an introduction B. F. Dyson, M. S. Loveday and M. G. Gee 1. 1 MATERIALS ASPECTS OF STRUCTURAL DESIGN Knowledge concerning the behaviour of materials has always been vital for the success of manufactured products, but never more so than at the present time.

Adopting an interdisciplinary approach to the chemistry and physics of materials, their biocompatibility, and the consequences of implantation of such devices into the human body, this text introduces readers to the principles of polymer science and the study of metals, ceramics and composites, and also to the basic biology required to understand the nature of the host-transplant interface. Topics covered include the macromolecular components of cells and tissues, self-assembly processes, biological cascade systems, microscopic structure of cells and tissues, immunology, transplantation biology, and the pathobiology of wound healing. The materials science section includes the structures and properties of polymers, metals, ceramics and composites, and the processes for forming materials as well as the pathobiology of devices. The final two chapters deal with tissue engineering and the relations between the biology of cells and tissue transplantation, and the engineering of tissue replacements using passaged cells.

* Metivier is an expert in the field of pdes/math physics, with a particular emphasis on shock waves. * New monograph focuses on mathematical methods, models, and applications of boundary layers, present in many problems of physics, engineering, fluid mechanics. * Metivier has good Birkhauser track record: one of the main authors of "Advances in the Theory of Shock Waves" (Freistuehler/Szepessy, eds, 4187-4). * Manuscript endorsed by N. Bellomo, MSSET series editor...should be a good sell to members of MSSET community, who by-in-large are based in Europe. * Included are self-contained introductions to different topics such as hyperbolic boundary value problems, parabolic systems, WKB methods, construction of profiles, introduction to the theory of Evans' functions, and energy methods with Kreiss' symmetrizers.

During the last decade there has been a renewed interest in under standing from a fundamental point of view the gasification of carbon. Basi cally there are two major issues in controlling the reactivity of carbon: i) reduction of the gasification rate of carbon materials in hostile environment ii) increase of the gasification rate in order to utilize carbonaceous compounds more effectively. Although these two objectives look somewhat contradictory, they are part of the general topics of understanding gasification reactivity of carbon. Refractory applications of carbon in furnace linings, seals and vanes, as well as the use of carbon-carbon or carbon-ceramic composites in struc tures able to withstand corrosion at high temperature require a better understanding of the fundamentals involved in carbon-oxidizing gas (02' CO, H 0) reactions. Furthermore a great interest of aluminium producers 2 2 is 10 extending the lifetime of carbon electrodes in alumina electrolysis which primarily depends on reducing their consumption rates by air or carbon dioxide. Proper control of gasification reactions is also of prime importance in manufacturing carbonaceous adsorbents like granular activated carbon clothes of high adsorption characteristics. The balance between increase of porosity and decrease in mechanical strength during activation is critical for developing new porous types of carbon materials in particular for carbon clothes and this can only be achieved by a careful control of the gasification reaction."

This book is intended to help satisfy an urgent requirement for up-to date comprehensive texts at graduate and senior undergraduate levels on the subjects in non-destructive testing (NDT). The subject matter here is confined to electrical and magnetic methods, with emphasis on the widely used eddy current and magnetic flux leakage methods (including particle inspection), but proper attention is paid to other techniques, such as microwave and AC field applications, which are rapidly growing in importance. Theoretical analyses relating to the various methods are discussed and the depths of presentation are often governed by whether or not the information is readily available elsewhere. Thus, for example, a considerable amount of space is devoted to eddy current theory at what the author considers to be a reasonable standard and not, as usually experienced, in either a too elementary manner or at a level appreciated only by a postgraduate theoretical physicist. The inclusion of the introductory chapter is intended to acquaint the reader with some of the philosophy of NDT and to compare, briefly, the relative performances of the more important methods of testing."

The birth of this monograph is partly due to the persistent efforts of the General Editor, Dr. Klaus Timmerhaus, to persuade the authors that they encapsulate their forty or fifty years of struggle with the thermal properties of materials into a book before they either expired or became totally senile. We recognize his wisdom in wanting a monograph which includes the closely linked properties of heat capacity and thermal expansion, to which we have added a little 'cement' in the form of elastic moduli. There seems to be a dearth of practitioners in these areas, particularly among physics postgraduate students, sometimes temporarily alleviated when a new generation of exciting materials are found, be they heavy fermion compounds, high temperature superconductors, or fullerenes. And yet the needs of the space industry, telecommunications, energy conservation, astronomy, medical imaging, etc. , place demands for more data and understanding of these properties for all classes of materials - metals, polymers, glasses, ceramics, and mixtures thereof. There have been many useful books, including Specific Heats at Low Tempera tures by E. S. Raja Gopal (1966) in this Plenum Cryogenic Monograph Series, but few if any that covered these related topics in one book in a fashion designed to help the cryogenic engineer and cryophysicist. We hope that the introductory chapter will widen the horizons of many without a solid state background but with a general interest in physics and materials.