The development of "tailormade" electrode surfaces using electroactive polymer films has been one of the most active and exciting areas of electrochemistry over the last 15 years. The properties of these materials have been examined by a wide range of scientists from a variety of perspectives, and now electroactive polymer research is considered to be a reasonably mature area of research endeavor. Much is now understood about the fundamental mechanism of conduction in these materials. A wide range of electrochemical techniques may be used to probe the conductivity processes in these materials, and more recently, a number of in situ spectroscopic techniques have been used to further elucidate the structure of these materials. The in situ spectroscopies and allied techniques have also been used to obtain correlations between structure and redox activity. The applications found for electroactive polymers are many and varied, and range from thin film amperometric chemical and biological sensors, electrocatalytic systems, drug delivery devices, and advanced battery systems through to molecular electronic devices. The research literature on electroactive polymers is truly enormous and can daunt even the most hardened researcher. The vast quantity of material reported in the literature can also intimidate beginning graduate students. Hence the present book. The original idea for this book arose as a result of a series of lectures on chemically modified eiectrodes and electroactive polymers given by the writer to final-year undergraduates at Trinity College Dublin.

Phosphate Fibers is a singular detailed account of the discovery, chemistry, synthesis, properties, manufacture, toxicology, and uses of calcium and sodium calcium polyphosphate fibers. Author Edward J. Griffith-the inventor and developer of this safe, biodegradable material-takes a multidisciplinary approach to this subject, considering the social, legal, medical, and industrial issues surrounding the use of asbestos and other mineral fibers. This compelling study is a beneficial resource to both readers interested in mineral fibers as well as those who want to understand the complexities of bringing new substances into the modern marketplace.

The purpose of this book is to stimulate thinking among corrosion scientists and engineers to examine corrosion mechanisms and corro sion control from another perspective. While the presence of corro sion films in electrochemical corrosion has been recognized for over a century, the contribution of these films to all facets of corrosion has not been explored to a significant degree. Rather the role of films in certain mechanisms (i.e., stress corrosion cracking) has been empha sized, yet almost ignored for other corrosion mechanisms. This is viewed by the author as solely attributable to the lack of investigation into, and an understanding of, the contribution of films to these mech anisms or forms of attack. The lack of emphasis and study of corrosion films and their contribution to all forms of corrosion attack are probably the result of current university instruction that utilizes two popular corrosion texts (Uhlig and Fontana and Greene) for teaching. These texts provide an excellent understanding at the undergraduate level of corrosion funda mentals; however, the major implicit premise in these texts is that bulk properties of an alloy or metal control the corrosion resistance in a particular environment. For many applications and for a simple under standing of corrosion mechanics, this approach is sufficient. Yet, research on corrosion films indicate these films often have an entirely different composition than the bulk metal (ratio of alloying elements)."

Following three printings of the First Edition (1978), the publisher has asked for a Second Edition to bring the contents up to date. In doing so the authors aim to show how the newer microscopies are related to the older types with respect to theoretical resolving power (what you pay for) and resolution (what you get). The book is an introduction to students, technicians, technologists, and scientists in biology, medicine, science, and engineering. It should be useful in academic and industrial research, consulting, and forensics; how ever, the book is not intended to be encyclopedic. The authors are greatly indebted to the College of Textiles of North Carolina State University at Raleigh for support from the administration there for typing, word processing, stationery, mailing, drafting diagrams, and general assistance. We personally thank Joann Fish for word process ing, Teresa M. Langley and Grace Parnell for typing services, Mark Bowen for drawing graphs and diagrams, Chuck Gardner for photographic ser vices, Deepak Bhattavahalli for his work with the proofs, and all the other people who have given us their assistance. The authors wish to acknowledge the many valuable suggestions given by Eugene G. Rochow and the significant editorial contributions made by Elizabeth Cook Rochow.

Organic Inhibitors of Corrosion of Metals provides a detailed review of the various theories advanced to explain the mechanisms of organic inhibitors. Author Yu.I. Kuznetsov explores the role of potential and charge of the metal, the nature of the organic species used as the inhibitor, and the function of the solvent. The author draws connections between these key elements and the processes of passivation, pitting, synergism, and complex formation. This unique volume brings together the mechanistic and practical aspects of corrosion control by organic inhibitors.

Water-based technology has undergone revolutionary changes during the past two decades. Interest in the properties and uses of water-based coatings, paints and inks has continued to grow since the establishment of the Clean Air Act of 1970. The present book is devoted to recent developments and trends in water-based coating and ink technology. This volume is divided in three broad catagories: (1) Additives and Water-based Coating/Ink Systems, (2) Surface Modifications and Wettability, and (3) Ink/Coating Formulations and Their characterization. The role of various additives to improve the performance and properties of water-based coatings with special reference to surface phenomena such as wettability, adhesion, surface energies, dispersion stability, particle size and size distribution are presented in these sections. This volume documents the proceedings of the International symposium on Surface Phenomena and Additives in Water-Based Coatings and Printing Technology sponsored by the 21st Annual Meeting of the Fine Particle Society (FPS). This meeting was held in San Diego, california, AUgust 21-25, 1990. The symposium upon which this volume is based was organized in four sessions emphasizing several basic and applied aspects of water-based coatings and printing technology. Major topics discussed include advances in water-based technology, water-based flexo and gravure inks, hydrophobically-modified cellulosic thickeners, organosilicones, uv curable silicone release coatings, surface characterization of Ti02 pigments, polymer substrates, flexographic plates and coating films, pigment wetting and dispersing agents, hydrotrope effect in emulsion polymers, film thickness control, particle size measurements, rheological properties, and statistically designed mixtures for ink formulations.

The origin ofthe International Acoustical Imaging Symposium series can be traced to 1967, when a meeting on acoustical holography was held in C alifornia. In those days, acoustical holography was at the leading edge of research but, as the importance of this subject waned, so the title of the series was changed from Acoustical Holography to Acoustical Imaging in 1978. The early Symposia were held at various venues in the United States. In 1980. the series became international, with the Symposium that year taking place in Cannes in France. The pattern now is to try to met alternately in the USA and in another part of the world so that active researchers everywhere can conveniently attend at a reasonably high frequency. It was a great privilege for us in Bristol in the United Kingdom to be chosen to host the 25th Symposium, which convened on 19 March 2000 and spread over four days. We were blessed not only by good weather, but also by the attendance ofnearly 100 pa rticipants who came from 17 c ountries. A large number of papers were accepted for presentation, either orally or as posters. Whether an oral presentation or a poster, all were considered to have equal merit, and no distinction is made between them in the published proceedings. There were no parallel sessions, so every participant could attend every presentation. The re sultant disciplinary cross fertilisation maintained the t radition of past Symposia.

Ronald M. North President Universities Council on Water Resources People sense intuitively that the world in which we live is not free of risk. Every decision, every action, even the refusal to either act or decide involves some element of risk. Perhaps, because we accept relatively low levels of risk in our daily activi ties, we tend to minimize the existence of risk and thereby fail to include risk assessment in those decisions and actions which could be improved through a risk assessment process. However, our casual approach to risk assessment seems to stem largely from the diffi culties inherent in measuring risk rather than from any lack of cognizance of the existence of risk. This conclusion is evidenced by the many statements in official documents relating to planning and evaluation which suggest that risk assessments should be con ducted but do not provide the mechanism for such assessments nor do they encourage their consideration in the decision making process. This conference on Risk/Benefit Analysis in Water Resources Planning and Management is notable because it attempts to identify and evaluate the mechanisms available for risk assessment which might be useful in water resources planning and management efforts. These proceedings bring together the thoughts of professional per sons who have struggled with the problems of risk assessment and who have contributed to the refinement of both theoretical and pragmatic solutions for the improvement of risk assessment processes."

After an introductory chapter, the processing, microstructure, and properties of various ceramic materials, reinforcements, and their composites are described. A separate chapter is devoted to processing of ceramic reinforcements, with a special emphasis on fibers. Processing of ceramic matrix composites is the next chapter, which includes novel techniques such as sol-gel processing and ceramics from polymeric precursors. The next four chapters cover the subjects of interface region in ceramic composites, mechanical and physical properties, and the role of thermal stresses and the important subject of toughness enhancement. Laminated composites made of ceramics are described in a separate chapter. Finally, a chapter is devoted to various applications of ceramic matrix composites. Throughout the text, the underlying relationships between the components of the triad: processing, microstructure, and properties are brought out. An exhaustive list of references and suggested reading is provided.

The use of diamond for electronic applications is not a new idea. As early as the 1920's diamonds were considered for their use as photoconductive detectors. However limitations in size and control of properties naturally limited the use of diamond to a few specialty applications. With the development of diamond synthesis from the vapor phase has come a more serious interest in developing diamond-based electronic devices. A unique combination of extreme properties makes diamond partiCularly well suited for high speed, high power, and high temperature applications. Vapor phase deposition of diamond allows large area films to be deposited, whose properties can potentially be controlled. Since the process of diamond synthesis was first realized, great progress have been made in understanding the issues important for growing diamond and fabricating electronic devices. The quality of both intrinsic and doped diamond has improved greatly to the point that viable applications are being developed. Our understanding of the properties and limitations has also improved greatly. While a number of excellent references review the general properties of diamond, this volume summarizes the great deal of literature related only to electronic properties and applications of diamond. We concentrate only on diamond; related materials such as diamond-like carbon (DLC) and other wide bandgap semiconductors are not treated here. In the first chapter Profs. C. Y. Fong and B. M. Klein discuss the band structure of single-crystal diamond and its relation to electronic properties.

3 In 1992 the annual world production of plastics reached 102 x 1()6m at a value of 3 over US$300 billion, while that of steel was 50 x1()6m ata value ofUS$l25 billion (Table 1. 1). Furthermore, from 1980 to 1990, plastics production increased by 62%, while thatofsteeldecreasedby 21%. Considering theunevenpolymerconsumption around theworld,polymerproductionwillhave toincreasebya factor often before currently recorded levels ofplastics sales in developed countries willbe universally reached. Polymers are the fastest growing structural materials. In addition, the polymer blend segment of the plastics industry increases at a rate about three times higher than thewhole. The aim of thisbook is to trace the historicalevolution of the polymer blends industry. Table 1. 1 World production of steel and plastics for 1992 Production Steel Plastics 410 102* Production volume (Mt/year) 3 Production volume (M(m )/year) 51 102 Production value (billion US$/year) 125 310 Growth from 1980to 1990 (%) -21 -1;62 ,. 121 Mt/year in 1996 A polymer (from the Greek poly = manyand meros = units) is a substancecomposed ofmacromoleculesbuiltby covalentlyjoiningatleast50 molecular segments, called mel'S. The word polymer was introduced in 1832 by Jons Jacob Berzelius for sub- stances thatmayhaveidenticalchemicalcompositionbutdifferinmolecularweight (e. g. , acetylene, benzene and styrene, having the formula CnH with n == 2,6and 8, n respectively). During the years 1859-1863, Louren~o reported that condensation of ethylene glycol with ethylene dibromide resulted in a mixture of ethers, whose members, separated by distillation, were identified as HD-(C2l4D-)n-H with n == 2 to 6 (Stahl, 1981).

Recently a new sphere in materials science* has formed which subject is structure and properties of electret materials used in engineering, medicine, biotechnology and other branches. It is characterized by specific methods of experimental investigations based on recording charge transfer, polarization and depolarization of dielectrics and involves original techniques and physico-mathematical aids where notions that exist at the interface of several natural and technical sciences are concentrated. It embraces a vast area of applications mainly in engineering, instrument making, electronics, medical technique, biotechnology, and etc., has a specialized technological base for electric polarization of dielectrics composed of uncommon technological methods, equipment and instrumentation. Apparently, future fundamental investigations in the domain of electret materials science are to be developed at the interface of computer of dielectrics. Elaboration of a simulation, physics and physical chemistry model for electric polarization of solid media with uneven charge density distribution, complicated by surface phenomena, outer electromagnetic, heat, chemical and other effects, presents a grave methodological problem. The simulation of structures in which polarization follows diffusion mechanism of chemically active molecules or their fragments, and the development of calculation methods for polarized charge relaxation and regularities of dielectric nonlinear properties, are the most urgent objectives of current research. Success in bioelectret effect studies is anticipated to result in profound widening of natural science knowledge.

The papers in this volume were presented at the Second International Conference on Unconventional Photoactive Solids held at the R&D Center of BP America September 9-12, 1985. It was part of an on-going series of conferences with the main aim of stressing the Interrelationship of solid state physics and solid state chemistry. The choice of topics covered a broad range of light-Induced solid state phenomena with particular emphasis on novel materials and/or novel phenomena. Organic solids, in particular, were emphasized as they are a natural meeting point of solid state physics and chemistry. A general trend In solid state physics Is to more complex materials (e.g. nonequilibrium glassy films, complicated unit cells, extended molecular building blocks, etc.). This trend necessitates the closer interaction between physicists and chemists. This conference reflects this trend quite dramatically. It is a new grouping together of a mix of materials, people and experimental approaches. A typical new theme pulling together this new mix can be seen in Part I. Fractals in Disordered Media. A variety of disordered media give rise to unusual temporal patterns of diffusion and reactions. The more familiar spatial patterns of self-similarity are discussed in the first article by M.F. Barnsley. Another topic pulling together a diverse group of scientists is covered in Part II. Spectral Hole-Burning. A number of leaders in this field are represented In these three papers.

This book contains papers presented at the International Conference on Organic Superconductivity which was held May 20-24, 1990, at the Stanford Sierra Conference Center, South Lake Tahoe, California. In the twenty years since the First Conference on Organic Superconductivity was held (Hawaii, 1969), there has been remarkable progress in the field. At present, development is accelerating with contributions from many groups in many countries worldwide. The discovery of high Tc superconductivity by G. Bednorz and K. Muller in 1986 and subsequent developments in the ceramic superconductors have had an enormous impact on the field of superconductivity as a whole. This discovery occurred in an area entirely different from that of conventional superconduc tivity, underscoring the importance of the search for and study of novel materials of all kinds. We believe that the organics, with their wide range of structural, chemical, and physical properties, belong in this category of novel materials. This book reflects the efforts of researchers from various disciplines: physicists, chemists, and materials scientists. It addresses the normal and superconducting properties of organic materials, as well as the search for new compounds and new syntheses. We are pleased to note that one of these papers reports on the discovery of a new organic superconductor with a record high Tc in this class. One chapter is devoted to a comparison of organic superconductors and the cuprates, another, to the prospects of discovering other novel conducting or superconducting compounds."

stacked QD structure and is useful for examining the possibility of all optical measurement of stacked QD layers. Optical absorption spectra of self-assembled QDs has been little reported, and further investigation in necessary to study hole-burning memory. 2.5 Summary This chapter describes recent advances in quantum dot fabrication tech nologies, focusing on our self-formed quantum dot technologies including TSR quantum dots and SK-mode self-assembled quantum dots. As is described in this chapter, there are many possible device applications such as quantum dot tunneling memory devices, quantum dot fioating-dot gate FETs, quantum dot lasers, and quantum dot hole-burning memory devices. The quantum dot laser applications seem to be the most practicable among these applications. However, many problems remain to be solved before even this application becomes practical. The most important issue is to of self-assembled quantum dots more pre control the size and position cisely, with an accuracy on an atomic scale. The confinement must be enough to keep the separation energy between quantized energy levels high enough to get high-temperature characteristics. The lasing oscillation frequency should be fixed at 1.3 f.lITl or 1.5 f.lITl for optical communication. Phonon bottleneck problems should be solved by the optimization of device structures. Fortunately, there is much activity in the area of quantum dot lasers and, therefore, many breakthroughs will be made, along with the exploration of other new application areas.

In the search for new functional materials, a clear understanding about the relationship between the physical properties and the atomic-scale structure of materials is needed. Here, the authors provide graduate students and scientists with an in-depth account of the evolutionary behavior of oxide functional materials within specific structural systems, discussing the intrinsic connections among these different structural systems. Over 300 illustrations and key appendices support the text.

During the past fifteen years commercial interest in compounds containing carbon fluorine bonds has burgeoned beyond all expectations, mainly owing to business opportunities arising from work on biologically active fluoroorganics-particularly agrochemicals, the relentless search for new markets for fluoropolymers and fluoro carbon fluids, developments in the field of medical diagnostics, and the drive to find replacements for ozone-depleting CFCs and Halon fire-extinguishing agents. Judging the situation to warrant the publication of a comprehensive collection of up-to-date reviews dealing with commercial organofluorine compounds within a single volume of manageable size (and hence reasonable cost), we were delighted to be invited by Plenum Publishing Corporation to produce a suitable book. In order to provide an authentic and wide-ranging account of current commercial applications of fluoroorganic materials, it clearly was necessary to assemble a sizeable team of knowledgeable contributing authors selected almost entirely from industry. Through their efforts we have been able to produce an almost complete coverage of the modem organofluorochemicals business in a manner designed to attract a reader ship ranging from experts in the field, through chemists and technologists currently unaware of the extent of industrial involvement with fluoroorganics, to students of applied chemistry. Promised chapters dedicated to perfluoroolefin oxides and 18F labeling of radiopharmaceuticals failed to materialize. This is somewhat unfortunate in view of our aim to achieve comprehensive coverage of the subject.

The Army Materials and Mechanics Research Center in coop eration with the Materials Science Group of the Department of Chemical Engineering and Materials Science of Syracuse University has been conducting the Annual Sagamore Army Materials Research Conference since 1954. The specific purpose of these conferences has been to bring together scientists and engineers from academic institutions, industry and government who are uniquely qualified to explore in depth a subject of importance to the Department of Defense, the Army and the scientific community. These proceedings entitled, FATIGUE - ENVIRONMENT AND TEMPER ATURE EFFECT, address the overview of temperature and environmental effects of fatigue, room temperature environmental effects, high temperature and environmental effect - mechanisms, high tempera ture and environmental effect - mechanisms, materials and design-engineering applications. We wish to acknowledge the assistance of Messrs. Joseph Bernier and Dan McNaught of the Army Materials and Mechanics Research Center and Helen Brown DeMascio of Syracuse University throughout the stages of the conference planning and finally the publication of the book. The continued active interest and support of these conferences by Dr. E. Wright, Director of the Army Materials and Mechanics Research Center, is appreciated."

Mechanical alloying (or mechanical milling) was invented in the 1970's as a method to develop dispersion-strengthened high temperature alloys with unique properties. With the discovery of formation of amorphous alloys using this technique, it has received new research interest in developing different material systems. Potential applications of this technique have been demonstrated in different areas of materials research. This book is intended as an introduction to mechanical alloying technique used in difference areas. This book contains basic information on the preparation of materials using the mechanical alloying technique. It is useful not only to undergraduate and post-graduate students, but also to scientists and engineers who wish to gain some understanding on the basic process and mechanisms of the process. The book begins with a brief introduction to provide a historical background understanding to the development of the mechanical alloying process. The experimental set-up in the alloying process is important. Currently there are different types of ball mills available. Some of them are specially designed for mechanical alloying process. Since the resultant materials are milling intensity and milling temperature dependent, ball mills should be carefully selected in order to obtain the desired materials and structures. This is discussed in chapter 2. The actual mechanical alloying process is being considered in Chapter 3. As it is essential to understand the use of processing control agents, the physical properties of some commonly used processing control agents are listed.

The fluorine atom, by virtue of its electronegativity, size, and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals, and surface modifiers are only a few examples. Fluoropolymers, too, while traditionally associated with extreme high performance applications have found their way into our homes, our clothing, and even our language. A recent American president was often likened to the tribology of PTFE. Since the serendipitous discovery of Teflon at the DuPont Jackson Laboratory in 1938, fluoropolymers have grown steadily in technological and marketplace importance. New synthetic fluorine chemistry, new processes, and new apprecia tion of the mechanisms by which fluorine imparts exceptional properties all contribute to accelerating growth in fluoropolymers. There are many stories of harrowing close calls in the fluorine chemistry lab, especially from the early years, and synthetic challenges at times remain daunting. But, fortunately, modem techniques and facilities have enabled significant strides toward taming both the hazards and synthetic uncertainties, In contrast to past environmental problems associated with fluorocarbon refrigerants, the exceptional properties of fluorine in polymers have great environmental value. Some fluoropolymers are enabling green technologies such as hydrogen fuel cells for automobiles and oxygen selective membranes for cleaner diesel combustion.

Injection moulding is one of the most important methods of manufacturing plastics products. Through the development of sophisticated micro processor control systems, the modern injection moulding machine is capable of producing precision mouldings with close tolerances in large numbers and with excellent reproducibility. This capability, however, is often limited by the lack of a proper appreciation of mould design. The mould, or tool as it is often called, is at the heart of the injection moulding process. Its basic function is to accept the plastic melt from the injection unit and cool it to the desired shape prior to ejection. It is not, however, simply a matter of the mould having an impression of the shape to be moulded. Many other factors have to be taken into account - for example, the ability to fill the mould impression properly and efficiently without inducing weaknesses in the moulding and the efficient cooling of the moulding in order to maximise production rates without diminishing the quality of the moulding. In addition, the type of mould, gate and runner system, and ejection system which will best meet the needs of a particular job specification have to be determined. In our experience lack of attention to such factors leads to the mould limiting the ability of the injection moulding machine and preventing the process as a whole from achieving its true potential.

Nanostructures refer to materials that have relevant dimensions on the nanometer length scales and reside in the mesoscopic regime between isolated atoms and molecules in bulk matter. These materials have unique physical properties that are distinctly different from bulk materials. Self-Assembled Nanostructures provides systematic coverage of basic nanomaterials science including materials assembly and synthesis, characterization, and application. Suitable for both beginners and experts, it balances the chemistry aspects of nanomaterials with physical principles. It also highlights nanomaterial-based architectures including assembled or self-assembled systems. Filled with in-depth discussion of important applications of nano-architectures as well as potential applications ranging from physical to chemical and biological systems, Self-Assembled Nanostructures is the essential reference or text for scientists involved with nanostructures.

In this text, Shigeji Fujita and Salvador Godoy guide first and second-year graduate students through the essential aspects of superconductivity. The authors open with five preparatory chapters thoroughly reviewing a number of advanced physical concepts-such as free-electron model of a metal, theory of lattice vibrations, and Bloch electrons. The remaining chapters deal with the theory of superconductivity-describing the basic properties of type I, type II compound, and high-Tc superconductors as well as treating quasi-particles using Heisenberg's equation of motion. The book includes step-by-step derivations of mathematical formulas, sample problems, and illustrations.

Over the last several years, the field of materials science has witnessed an explosion of new, advanced materials. They encompass many uses and include superconductors, alloys, glasses, and catalysts. Not only are there quite a number of new enhies into these generic classes of materials, but the materials themselves represent a wide array of physical forms as well. Bulk materials, for example, are being synthesized and applica tions found for them, while still other materials are being synthesized as thin films for yet still more new (and in some cases, as yet unknown) applications. The field continues to expand with (thankfully ) no end in sight as to the number of new possibilities. As work progresses in this area, there is an ever increasing demand for knowing not only what material is formed as an end product but also details of the route by which it is made. The knowledge of reaction mechanisms in their synthesis many times allows a researcher to tailor a preparative scheme to either arrive at the final product in a purer state or with a better yield. Also, a good fundamental experimental knowledge of impuri ties present in the final material helps the investigator get more insight into making it."

The Sagamore Army Materials Research Conferences have been held in the beautiful Adirondack Mountains of New York State since 1954. Organized and conducted by the Army Materials and Mechanics Research Center (Watertown, Massachusetts) in cooperation with Syracuse University, the Conferences have focused on key issues in Materials Science and Engineering that impact directly on current or future Army problem areas. A select group of speakers and attendees are assembled from academia, industry, and other parts of the Department of Defense and Government to provide an optimum forum for a full dialogue on the selected topic. This book is a collection of the full manuscripts of the formal presentations given at the Conference. The emergence and use of nontraditional materials and the excessive failures and reject rates of high technology, materials intensive engineering systems necessitates a new approach to quality control. Thus, the theme of this year's Thirty-First Conference, "Materials Characterization for Systems Performance and Reliability," was selected to focus on the need and mechanisms to transition from defect interrogation of materials after production to utilization of materials characterization during manufacturing. The guidance and help of the steering committee and the dedicated and conscientious efforts of Ms. Karen Ka100stian, Con ference Coordinator, and Mr. William K. Wilson, and Ms. Mary Ann Holmquist are gratefully acknowledged. The continued active interest and support of Dr. Edward S. Wright, Director, AMMRC; Dr. Robert W. Lewis, Associate Director, AMMRC; and COL L. C. Ross, Commander/ Deputy Director, AMMRC; are greatly appreciated."