The past five years have witnessed some dramatic developments in the general area of ferroelectric thin films materials and devices. Ferroelectrics are not new materials by any stretch ofimagination. Indeed, they have been known since the early partofthis century and popular ferroelectric materials such as Barium Titanate have been in use since the second world war. In the late sixties and seventies, a considerable amountofresearch and development effort was made to create a solid state nonvolatile memory using ferroelectrics in a vary simple matrix-addressed scheme. These attempts failed primarily due to problems associated with either the materials ordue to device architectures. The early eighties saw the advent of new materials processing approaches, such as sol-gel processing, that enabled researchers to fabricate sub-micron thin films of ferroelectric materials on a silicon substrate. These pioneering developments signaled the onsetofa revival in the areaofferroelectric thin films, especially ferroelectric nonvolatile memories. Research and development effort in ferroelectric materials and devices has now hit a feverish pitch, Many university laboratories, national laboratories and advanced R&D laboratories oflarge IC manufacturers are deeply involved in the pursuit of ferroelectric device technologies. Many companies worldwide are investing considerable manpower and resources into ferroelectric technologies. Some have already announced products ranging from embedded memories in micro controllers, low density stand-alone memories, microwave circuit elements, andrf identification tags. There is now considerable optimism that ferroelectric devices andproducts will occupy a significant market-share in the new millennium.

The objectives of this book are twofold: 1. To provide a thorough examination of the materials science of cellulosic fibers with emphasis on the characterization of structure-property relations, and 2. To advance knowledge of how to best analyze cellulosic fibrous networks and composites, and, ultimately, engineer "novel" cellulose-based systems of superior performance and functionality. The design of new materials through the study of living systems, or bio-imitation, is burgeoning to become an established field, generally referred to as biomimetics. The latter, as with materials science, in general, prominently features multi-disciplinarity where new developments in mathematics, physics, chemistry and engineering continue to inspire novel areas of research and development. The book is structured in five chapters which provide a sequential treatment of the running theme: deformation mechanics and the physical, morphological and mechanical characterization of native cellulose fibers networks and composites. The heart of the book is Chapter 3, Damage Accumulation in Fibers, which treats the experimental methodology for fatigue testing of single fibers and the engendered results. In-depth examinations of the morphology, structure and chemical composition of native cellulose fibers, and the mechanics of deformation in these natural composite fibers are proffered in Chapters 1 and 2, respectively. The fourth chapter, Fractal Simulation of Crack Propagation, presents a fractal-based approach to modeling damage accumulation in materials. Fractals lend themselves well to modeling such randomly-oriented phenomena as crack propagation and fracture. The last chapter, Fibrous Structures: Networks and Composites, comprises analytical approaches for handling networks and composites.

During the last 25 years (after the growth of the first pseudomorphic GeSi strained layers on Si by Erich Kasper in Germany) we have seen a steady accu- mulation of new materials and devices with enhanced performance made pos- sible by strain. 1989-1999 have been very good years for the strained-Iayer- devices. Several breakthroughs were made in the growth and doping technology of strained layers. New devices were fabricated as a results of these break- throughs. Before the advent of strain layer epitaxy short wavelength (violet to green) and mid-IR (2 to 5 f. Lm) regions of the spectrum were not accessi- ble to the photonic devices. Short wavelength Light Emitting Diodes (LEDs) and Laser Diodes (LDs) have now been developed using III-Nitride and II-VI strained layers. Auger recombination increases rapidly as the bandgap narrows and temperature increases. Therefore it was difficult to develop mid-IR (2 to 5 f. Lm range) lasers. The effect of strain in modifying the band-structure and suppressing the Auger recombination has been most spectacular. It is due to the strain mediated band-structure engineering that mid-IR lasers with good per- formance have been fabricated in several laboratories around the world. Many devices based on strained layers have reached the market place. This book de- scribes recent work on the growth, characterization and properties o(compound semiconductors strained layers and devices fabricated using them.

I am honored to chair this International Workshop on Functionally st Graded Materials in the 21 Century: A Workshop on Trends and Forecasts, and would like to first express my sincere gratitude to everyone participating. The Mechanical Engineering Laboratory and the Japan International Science and Technology Exchange Center (JISTEC) have co-organized this workshop with the sponsorship of the Science and Technology Agency of Japan and the cooperation of the Association of Mechanical Technology. This workshop is an international conference to focus on functionally graded materials and the aim is to provide an overview of the present global technical trends and the future development of functionally graded materials over the next 10 years. I am very happy to see many researchers meeting together here - including seven researchers invited from abroad. During the three-day oral sessions, 36 research reports will be presented, and I'm sure I'm not the only one who is very anxious to hear and participate in the upcoming interesting discussions. At present, the Mechanical Engineering Laboratory is conducting fundamental and ground-breaking research in such major areas as materials science and technology, bioengineering, information & system science, advanced machine technology, energy technology, manufacturing technology and robotics. In particular, we consider research on materials science and technology to have the highest priority for the 21st century. and since 1996 have participated in the US-Japan joint research project, Precompetitive Processing and Characterization of Functionally Graded Materials.

This volume contains the proceedings of the 5th International Symposium on Symmetries in Subatomic Physics (SSP2012), that was held in Groningen, The Netherlands from 18 till 22 June 2012. This sequence of symposia is now firmly connected with one of the main branches in fundamental nuclear and particle physics, i.e. in searches for physics beyond the Standard Model, focused on the (violation of) the discrete symmetries of Parity, Charge conjugation and Time reversal invariance. This field comes in various disguises: With large experimental facilities and large collaborations, as in LHC physics or in neutrino experiments, but also as table top experiments by small groups in the field of nuclear, atomic and molecular physics, such as in searches for a permanent electric dipole moments and atomic parity violation.

Bringing the practitioners of these divergent fields together gives a coherent overview and see the complementarities of the various approaches to the same question: why is the Standard Model what it is and what lies beyond it.

During recent years an increasing amount of research has been conducted to develop methods and procedures for improving inter pretation in nondestructive testing. This research covers appro priate testing procedures as well as the algorithms for interpre tation. In several cases a state has been reached which allows for implementation. The objective of the workshop was to bring together researchers and industrial users of both countries and colleagues from other countries for a thorough and critical discussion of how far we have come and where we have to go to solve the basic practical problems of interpretation in nondestructive testing and of data acquisition necessary for this purpose. Dr. Dau from EPRI stated during the last International Confer ence for Nondestructive Testing in Nuclear Industry that from the point of view of time and money spent research is the smallest part of innovation but, I would like to add in full agreement with him, the most essential. Without successful research innovation is not possible at all; but neither research and invention nor any other step in an innovation procedure can be left out. Our philosophy is to keep researchers involved until the end of the innovation. That means until a new or improved NOT-method is approved under industrial environment and implemented in industry. There can be no doubt that the further we proceed on this long road the more industry will have to be involved and assume the initiative, responsibility and the leading role."

This second edition of a well-received volume has been thoroughly updated and expanded to cover the most recent developments. Coverage now includes additional polymers such as polyindole and polyazines, composites of polymers with carbon nanotubes, metals, and metal oxides, as well as bending-beam techniques for characterization. Again, the author provides a systematic survey of the knowledge accumulated in this field in the last thirty years. This includes thermodynamic aspects, the theory of the mechanism of charge transport processes, the chemical and physical properties of these compounds, the techniques of characterization, the chemical and electrochemical methods of synthesis as well as the application of these systems. The book contains a compilation of the polymers prepared so far and covers the relevant literature with almost 2000 references. From reviews of the previous edition 'a comprehensive reference guide for those interested in this field' (Journal of Solid State Electrochemistry)

1. B. Keszler, J.P. Kennedy, Akron, OH, USA Synthesis of High Molecular Weight Poly (Beta-Pinene) 2. Y. Chujo, T. Saegusa, Kyoto, Japan OrganicPolymer Hybrids with Silica Gel by Means of the Sol-Gel Method 3. A. Halperin, Mainz, FRG, M. Tirrell, T.P. Lodge, Minnea- polis, MN, USA Tethered Chains in Polymer Microstructures 4. T.Q. Nguyen, H.-H. Kausch, Lausanne, CH Mechanochemical Degradation in Transient Elongational Flow 5. P. Corradini, G. Guerra, Naples, Italy Polymorphism in Polymers 6. K.A. Armitstead, G. Goldbeck-Wood, A. Keller, Bristol, UK Review of Polymer Crystallization Theories 7. M. Fischer, Fribourg, CH Properties and Failure of Polymers with Tailored Distances between Crosslinks 8. M. Stamm, Mainz, FRG Polymer Interfaces on a Molecular Scale: Comparison of Techniques and Some Examples

Die 2. Auflage dieses Buches ist durch Mitarbeiter des Institutes fur Textiltechnik der RWTH Aachen fachlich durchgesehen, auf den neuesten Stand gebracht, um etwa 1.000 Begriffe erweitert und durch die italienische Sprache erganzt.

This the fourth volume of six from the Annual Conference of the Society for Experimental Mechanics, 2010, brings together 58 chapters on Application of Imaging Techniques to Mechanics of Materials and Structure. It presents findings from experimental and computational investigations involving a range of imaging techniques including Recovery of 3D Stress Intensity Factors From Surface Full-field Measurements, Identification of Cohesive-zone Laws From Crack-tip Deformation Fields, Application of High Speed Digital Image Correlation for Vibration Mode Shape Analysis, Characterization of Aluminum Alloys Using a 3D Full Field Measurement, and Low Strain Rate Measurements on Explosives Using DIC.

219 8. 2 Sensors 221 8. 3 Physical Sensors 222 8. 3. 1 Electrical Sensing Means 223 8. 3. 2 Magnetic Field Methods 231 8. 3. 3 Optical Methods 232 8. 4 Chemical Sensors 241 8. 4. 1 Electrical Gas and Chemical Sensors 243 8. 4. 2 Guided-Optics Intrinsic Chemical Sensors 246 8. 4. 3 Extrinsic Chemical Sensors 250 8. 4. 4 Polymer Waveguide Chemical Sensors 251 8. 4. 5 Surface Plasmon Chemical Sensors 252 8. 4. 6 Indicator-Mediated Extrinsic Sensing 253 8. 4. 7 Optical Biosensors 256 8. 4. 8 Ultrasonic Gas and Chemical Sensors 257 8. 4. 9 Intelligent Sensors 258 8. 5 Connections/Links and Wiring 258 8. 5. 1 Optical Links 260 8. 5. 2 Requirement on the Processing Unit/Intelligence 262 8. 6 Actuators 263 8. 7 Signal Processing/Computing 264 8. 7. 1 Implicit Computation 266 8. 7. 2 Explicit Computation 267 8. 8 References 274 Subject Index 279 Micro-Actuators (Electrical, Magnetic, Thermal, Optical, Mechanical, and Chemical) It has become quite apparent that sensors and actuators are the main bottleneck of the modem information processing and control systems. Microprocessors and computers used to be the main limiting element in most information processing systems. But thanks to the enonnous progress in the microelectronics industry, most information analysis tasks can be processed in real time. The data has to be acquired by the processor in some form and processed and used to produce some useful function in the real world.

The introduction of GaAs/ AIGaAs double heterostructure lasers has opened the door to a new age in the application of compound semiconductor materials to microwave and optical technologies. A variety and combination of semiconductor materials have been investigated and applied to present commercial uses with these devices operating at wide frequencies and wavelengths. Semiconductor modulators are typical examples of this technical evolutions and hsve been developed for commercial use. Although these have a long history to date, we are not aware of any book that details this evolution. Consequently, we have written a book to provide a comprehensive account of semiconductor modulators with emphasis on historical details and experimantal reports. The objective is to provide an up-to-date understanding of semiconductor modulators. Particular attention has been paid to multiple quantum well (MQW) modulators operating at long wavelengths, taking into account the low losses and dispersion in silica fibers occuring at around 1.3 and 1.55 mm. At the present time, MQW structures have been investigated but these have not been sufficiently developed to provide characteristic features which would be instructive enough for readers. One problem is the almost daily publication of papers on semiconductor modulators. Not only do these papers provide additional data, but they often modify the interpretations of particular concepts. Almost all chapters refer to the large number of published papers that can be consulted for future study.

Heat treatment of metallic alloys constitutes an important step within the production process. The heat treatment process itself is considered as a cycle of heating the workpieces to a predetermined temperature, keeping them at this temperature for the time period required, and cooling them to room temperature in an appropriate way. The process of heating and keeping workpieces at the required temperature is now adays weil mastered and mostly automatized. The process of cooling or quenching which determines actually the resulting properties, is handicapped with many physical and technical uncertainties. Good results can already be obtained predominantly by using empirically based practice. But increased demands on the properties of the pro ducts as weIl as demands on safety and environment conditions of the quenching media require efforts to investigate the details of the quenching process and to transfer the results of the research to practical application. Advances in the knowledge about quenching processes have been achieved by modem applied thermodynamics especially by the heat and mass transfer researches; further the application of computer technology was helpful to new approaches in quenching pro cesses. Special emphases has been given to: - The theory of heat transfer and heat exchange intensification during quenching - Wetting kinematics - Residual stresses after quenching - Determination of the quenching intensity - Prediction of microstructural transformation and hardness distribution after quenching, the latter with some limitations."

2. High Temperature UHV-STM System 264 3. Hydrogen Desorption Process on Si (111) Surface 264 4. (7x7) - (1 xl) Phase Transition on Si (111) Surface 271 Step Shifting under dc Electric Fields 275 5. 6. Conclusions 280 Acknowledgements and References 281 12. DYNAMIC OBSERVATION OF VORTICES IN SUPERCONDUCTORS USING ELECTRON WAVES 283 by Akira Tonomura 1. Introduction 283 2. Experimental Method 284 2. 1 Interference Microscopy 284 2. 2 Lorentz Microscopy 287 Observation of Superconducting Vortices 288 3. 3. 1 Superconducting Vortices Observed by Interference Microscopy 288 3. 1. 1 Profile Mode 288 3. 1. 2 Transmission Mode 291 3. 2 Superconducting Vortices Observed by Lorentz Microscopy 293 3. 3 Observation of Vortex Interaction with Pinning Centers 294 3. 3. 1 Surface Steps 295 3. 3. 2 Irradiated Point Defects 296 4. Conclusion 298 References 299 13. TEM STUDIES OF SOME STRUCTURALLY FLEXIBLE SOLIDS AND THEIR ASSOCIATED PHASE TRANSFORMATIONS 301 by Ray L. Withers and John G. Thompson 1. Introduction 301 2. Tetrahedrally Comer-Connected Framework Structures 302 3. Tetragonal a-PbO 311 4. Compositionally Flexible Anion-Deficient Fluorites and the "Defect Fluorite" to C-type Sesquioxide Transition 320 5. Summary and Conclusions 327 Acknowledgements and References 327 Author Index 331 Subject Index 333 List of Contributors A. ASEEV Institute of Semiconductor Physics, Russian Academy of Sciences Novosibirsk, 630090, pr. ac. , Lavrentjeva 13, RUSSIA E. BAUER Department of Physics and Astronomy, Arizona State University Tempe, AZ 85287-1504, U. S. A. G. H.

As we approach the end of the present century, the elementary particles of light (photons) are seen to be competing increasingly with the elementary particles of charge (electrons/holes) in the task of transmitting and processing the insatiable amounts of infonnation needed by society. The massive enhancements in electronic signal processing that have taken place since the discovery of the transistor, elegantly demonstrate how we have learned to make use of the strong interactions that exist between assemblages of electrons and holes, disposed in suitably designed geometries, and replicated on an increasingly fine scale. On the other hand, photons interact extremely weakly amongst themselves and all-photonic active circuit elements, where photons control photons, are presently very difficult to realise, particularly in small volumes. Fortunately rapid developments in the design and understanding of semiconductor injection lasers coupled with newly recognized quantum phenomena, that arise when device dimensions become comparable with electronic wavelengths, have clearly demonstrated how efficient and fast the interaction between electrons and photons can be. This latter situation has therefore provided a strong incentive to devise and study monolithic integrated circuits which involve both electrons and photons in their operation. As chapter I notes, it is barely fifteen years ago since the first demonstration of simple optoelectronic integrated circuits were realised using m-V compound semiconductors; these combined either a laser/driver or photodetector/preamplifier combination.

Emerging Fields in Sol-gel Science and Technology contains selected papers from the symposium on "Sol-Gel and Vitreous Materials and Applications" held during the International Materials Research Congress in Cancun, Mexico in August 2002. One hundred and twenty researchers representing 10 countries attended this symposium. Some of the subjects covered in this symposium include 1.) synthesis of new materials endowed with outstanding and non-conventional optical, magnetic, electrical, thermal, catalytic, and mechanical properties; 2.) study of the sorption properties of model porous materials in order to test the validity of previous and recent theories; 3.) theoretical studies related to density functional theory, fractal and scaling law approaches, 4.) synthesis of biomaterials for use in medicine and pollution control; 5.) application of sol-gel colloids in the fine-chemistry industry in products such as fragrances and pharmaceuticals; 6.) development of special vitreous materials; 7.) implementation of inorganic thin films, and 8.) synthesis of materials for energy saving.

Non-destructive testing (NDT) systems can generate incomplete, incorrect or conflicting information about a flaw or a defect. Therefore, the use of more than one NDT system is usually required for accurate defect detection and/or quantification. In addition to a reduction in inspection time, important cost savings could be achieved if a data fusion process is developed to combine signals from multisensor systems for manual and remotely operated inspections. This gathering of data from multiple sources and an efficient processing of information help in decision making, reduce signal uncertainty and increase the overall performance of a non-destructive examination. This book gathers, for the first time, essays from leading NDT experts involved in data fusion. It explores the concept of data fusion by providing a comprehensive review and analysis of the applications of NDT data fusion. This publication concentrates on NDT data fusion for industrial applications and highlights progress and applications in the field of data fusion in areas ranging from materials testing in the aerospace industry to medical applications. Each chapter contains a specific case study with a theoretical part but also presents experimental results from a practical point of view. The book should be considered more as a pragmatic introduction to the applications of NDT data fusion rather than a rigorous basis for theoretical studies.

Sol--Gel--Optics encompasses numerous schemes for fabricating optical materials from gels -- materials such as bulk optics, optical waveguides, doped oxides for laser and nonlinear optics, gradient refractive index (GRIN) optics, chemical sensors, environmental sensors, and `smart' windows. Sol--Gel--Optics: Processing and Applications provides in-depth coverage of the synthesis and fabrication of these materials and discusses the optics related to microporous, amorphous, crystalline and composite materials. The reader will also find in this book detailed descriptions of new developments in silica optics, bulk optics, waveguides and thin films. Various applications to sensor and device technology are highlighted. For researchers and students looking for novel optical materials, processing methods or device ideas, Sol--Gel--Optics: Processing and Applications surveys a wide array of promising new avenues for further investigation and for innovative applications. (This book is the first in a new subseries entitled `Electronic Materials: Science and Technology).

Synthesis and Properties of Advanced Materials provides an overview of some of the most exciting developments in advanced materials. The book contains review papers based on tutorial lectures given at The First Pan American Advanced Study Institute held in Merida, Mexico, 1995. Each paper serves as a comprehensive introduction and review to the topic covered. Topics included: diamond and related materials, nanocrystalline metals and ceramics, Co-based alloys for biomedical applications, high-temperature superconductivity materials, composite materials, cement-based materials, ion-implanted ceramics and structural ceramics. Each chapter emphasizes the relationships among processing parameters, micro-structure and properties. Synthesis and Properties of Advanced Materials provides an excellent review of the state of the art in advanced materials for the working engineer or researcher. Students will also find this text an accessible introduction to the field.

Seven years have elapsed since Dr. Renee Ford, editor-in-chief of Materials Technology, first suggested to me to publish a book on Functionally Graded Materials (FGMs). She said that the FGM concept, then largely unknown outside of Japan and a relatively few laboratories elsewhere, would be of great interest to everyone working in the materials field because of its potentially universal applicability. There was no book about FGMs in English at that time, although the number of research papers, review articles, and FGM conference proceedings had been increasing yearly. We discussed what the book should cover, and decided it should present a comprehensive description from basic theory to the most recent applications of FGMs. This would make it useful both as an introduction to FGMs for those simply curious about what this new materials field was all about, and also as a textbook for researchers, engineers, and graduate students in various material fields. The FGM Forum in Japan generously offered to support this publication program. is very difficult for an individual author to write a book that Because it covers such a wide range of various aspects of many different materials, I invited more than 30 eminent materials scientists throughout the world, who were associated with FGM research, to contribute selected topics. I also asked several leading researchers in this field to edit selected chapters: Dr. Barry H. Rabin, then at the U. S.

This book has one single purpose: to present the development of the partial hybrid finite element method for the stress analysis of laminated composite structures. The reason for this presentation is because the authors believe that partial hybrid finite element method is more efficient that the displacement based finite element method for the stress analysis oflaminated composites. In fact, the examples in chapter 5 of this book show that the partial hybrid finite element method is about 5 times more efficient than the displacement based finite element method. Since there is a great need for accurate and efficient calculation of interlaminar stresses for the design using composites, the partial hybrid finite method does provide one possible solution. Hybrid finite method has been in existence since 1964 and a significant amount of work has been done on the topic. However, the authors are not aware of any systematic piece of literature that gives a detailed presentation of the method. Chapters of the displacement finite element method and the evolution 1 and 2 present a sununary of the hybrid finite element method. Hopefully, these two chapters can provide the readers with an appreciation for the difference between the displacement finite element method and the hybrid finite element. It also should prepare the readers for the introduction of partial hybrid finite element method presented in chapter 3.

This volume highlights the latest developments and trends in advanced materials and their properties, the modeling and simulation of non-classical materials and structures, and new technologies for joining materials. It presents the developments of advanced materials and respective tools to characterize and predict the material properties and behavior.

At present, there is an increasing interest in the prediction of properties of classical and new materials such as substitutional alloys, their surfaces, and metallic or semiconductor multilayers. A detailed understanding based on a thus of the utmost importance for fu microscopic, parameter-free approach is ture developments in solid state physics and materials science. The interrela tion between electronic and structural properties at surfaces plays a key role for a microscopic understanding of phenomena as diverse as catalysis, corrosion, chemisorption and crystal growth. Remarkable progress has been made in the past 10-15 years in the understand ing of behavior of ideal crystals and their surfaces by relating their properties to the underlying electronic structure as determined from the first principles. Similar studies of complex systems like imperfect surfaces, interfaces, and mul tilayered structures seem to be accessible by now. Conventional band-structure methods, however, are of limited use because they require an excessive number of atoms per elementary cell, and are not able to account fully for e.g. substitu tional disorder and the true semiinfinite geometry of surfaces. Such problems can be solved more appropriately by Green function techniques and multiple scattering formalism.

Solid Freeform Fabrication is a set of manufacturing processes that are capable of producing complex freeform solid objects directly from a computer model of an object without part-specific tooling or knowledge. In essence, these methods are miniature manufacturing plants which come complete with material handling, information processing and materials processing. As such, these methods require technical knowledge from many disciplines; therefore, researchers, engineers, and students in Mechanical, Chemical, Electrical, and Manufacturing Engineering and Materials and Computer Science will all find some interest in this subject. Particular subareas of concern include manufacturing methods, polymer chemistry, computational geometry, control, heat transfer, metallurgy, ceramics, optics, and fluid mechanics. History of technology specialists may also find Chapter 1 of interest. Although this book covers the spectrum of different processes, the emphasis is clearly on the area in which the authors have the most experience, thermal laser processing. In particular, the authors have all been developers and inventors of techniques for the Selective Laser Sintering process and laser gas phase techniques (Selective Area Laser Deposition). This is a research book on the subject of Solid Freeform Fabrication.

Steels and computer-based modelling are fast growing fields in materials science as well as structural engineering, demonstrated by the large amount of recent literature. Steels: From Materials Science to Structural Engineering combines steels research and model development, including the application of modelling techniques in steels. The latest research includes structural engineering modelling, and novel, prototype alloy steels such as heat-resistant steel, nitride-strengthened ferritic/martensitic steel and low nickel maraging steel. Researchers studying steels will find the topics vital to their work. Materials experts will be able to learn about steels used in structural engineering as well as modelling and apply this increasingly important technique in their steel materials research and development.