Today, multi-functional materials such as piezoelectric/ferroelectric ceramics, magneto-strictive and shape memory alloys are gaining increasing applications as sensors, actuators or smart composite materials systems for emerging high tech areas. The stable performance and reliability of these smart components under complex service loads is of paramount practical importance. However, most multi-functional materials suffer from various mechanical and/or electro-magnetical degra-dation mechanisms as fatigue, damage and fracture. Therefore, this exciting topic has become a challenge to intensive international research, provoking the interdisciplinary approach between solid mechanics, materials science and physics. This book summarizes the outcome of the above mentioned IUTAM-symposium, assembling contributions by leading scientists in this area. Particularly, the following topics have been addressed: (1) Development of computational methods for coupled electromechanical field analysis, especially extended, adaptive and multi-level finite elements. (2) Constitutive modeling of non-linear smart material behavior with coupled electric, magnetic, thermal and mechanical fields, primarily based on micro-mechanical models. (3) Investigations of fracture and fatigue in piezoelectric and ferroelectric ceramics by means of process zone modeling, phase field simulation and configurational mechanics. (4) Reliability and durability of sensors and actuators under in service loading by alternating mechanical, electrical and thermal fields. (5) Experimental methods to measure fracture strength and to investigate fatigue crack growth in ferroelectric materials under electromechanical loading. (6) New ferroelectric materials, compounds and composites with enhanced strain capabilities.

The increasing global demand for energy requires a versatile approach, prompting many researchers to focus on renewable bioenergy from different biomasses, especially cellulosic biomass. Such biomasses can be agricultural wastes, municipal wastes or direct harvests from high-yield energy corps. If properly pre-treated, the subsequent enzyme hydrolysis step is much more effective and can effectively minimises the waste disposal.

"Green Biomass Pretreatment for Biofuels Production " reviews a range of pretreatment methods such as ammonium fiber explosion, steam explosion, dilute acid hydrolysis, alkali hydrolysis, and supercritical carbon dioxide explosion focusing on their final sugar yields from hemicellulose, glucose yields from cellulose, as well as on their feasibilities in bioenergy production processes at various scales.

This book emphasises the tactical mobile and on-farm scales applications that use green pretreatments and processing technologies without the need of on-site waste treatment. Because of the varieties of different biomasses, no single pretreatment is expected to be the universal choice. Some of the pretreatment methods present niche applications are also discussed.

My 12-year-old granddaughter Nina Alesi once asked me, "Grandpa, you are a scientist at IBM, so what do you do?" I tried to reply, "Oh, I watch atoms move. . . " But before I could finish this sentence, my 7-year-old grandson Vinnie interjected, "Grandpa, do atoms play soccer?" This book is about the games atoms play in diffusion and various other properties of materials. While diffusion has been studied for more than 100 years in solids, its importance, excitement, and intellectual chal lenges remain undiminished with time. It is central to understanding the relationship between the structure and properties of naturally occurring and synthetic materials, which is at the root of current technological development and innovations. The diversity of material has led to spec tacular progress in functional inorganics, polymers, granular materials, photonics, complex oxides, metallic glasses, quasi-crystals, and strongly correlated electronic materials. The integrity of complex materials pack ages is determined by diffusion, a highly interactive and synergic phe nomenon that interrelates to the microstructure, the microchemistry, and the superimposed physical fields. While the various physico-chemical properties of the materials are affected by diffusion, they determine diffu sion itself. This book, which is intended to document the diffusive processes operative in advanced technological materials, has been written by pio neers in industry and academia.

Conventional synthetic materials, like metals, ceramics or glass, are usually isotropic substances, and their suitability for structural applications is achieved by morphological design and combination in the macroscopic scale. However, in modem engineering this is often not acceptable. As an alternative, the use of non-homogeneous, anisotropic materials, with significant stiffness and strength only in the directions these mechanical properties are really needed, can lead to enormous material (and weight) savings. This is the case of multiphase systems called composite materials. In these composites, different material parts are added and arranged geometrically, under clearly designed and controlled conditions. Usually, a structure of fibers provides strength and stiffness and a matrix helds them together, whilst providing the geometric form. Carbon fibers are among the high-performance fibers employed in these advanced structural composites, which are profoundly changing many of today's high technology industries. New research and development challenges in this area include upgrading the manufacturing process of fibers and composites, in order to improve characteristics and reduce costs, and modifying the interfacial properties between fibers and matrix, to guarantee better mechanical properties. The interdisciplinary nature of this "new frontier" is obvious, involving chemistry, materials science, chemical and mechanical engineering. Other topics, which more often are treated separately, are also important for the understanding of the processes of fiber production. Carbon filaments is one such topic, as the study of their mechanisms of nucleation and growth is clearly quite relevant to the production of vapour-grown carbon fibers.

Over the years, numerous handbooks and design guides on the subject of plastics have been published. None of these dealt in any depth with the subject of this handbook-blow molding. The recent growth of blow molding as an economically feasible process has been rapid in many areas. This growth, coupled with the lack of technical publications relating to blow molding, prompted the Board of Directors of the Blow Molding Division of the Society of Plastic Engineers to undertake the assimilation of available information and the editing of this milestone publication. We believe that this Plastic Blow Molding Handbook will provide the reader with a greater understanding of the unique process characteristics of blow molding, enable the reader to apply proven techniques in developing new products and applications for blow molding, and will serve as a valuable reference for all who are interested in the plastics industry. Our thanks are heartily extended to the various authors for their con tributions to this pioneering effort in blow molding. J. H. Moran Chairman Blow Molding Division Society of Plastic Engineers xi Preface The blow molding of plastic articles has in the past had an aura of the mystic around it. As a result, little comprehensive work on the subject has been published. Advances in the technology of polymeric materials, machine controls, computer science, and management techniques have made it nec essary to correct the myths and magic."

In the last few years the physics of turbulent plasma has undergone rapid development, beginning with the first works, in which the term "turbulence" was used in various ways, and ending with the fundamental studies which provide a thorough examina tion of the turbulent state of plasma. In physics it is usually found that value is not so much contained in specific results for a partic ular field as it is in the more general outlook and overall view of the problem. Occasionally the older results take on new mean ing after the general view of things is perfected. In the case of the physics of turbulent plasma, this general picture is now com plete, for the most part. The first review devoted to the problem of plasma turbulence was written by B. B. Kadomtsev in "Problems in Plasma Theory," edited by M. A. Leontovich, Volume 4, Moscow, Atomizdat (1964), p. 188; English Translation: "Plasma Turbulence," Academic Press, London (1965)]."

This book is a sequel to Reliability Evaluation of Engineering Systems: Concepts and Techniques, written by the same authors and published by Pitman Books in January 1983. As a sequel, this book is intended to be considered and read as the second of two volumes rather than as a text that stands on its own. For this reason, readers who are not familiar with basic reliability modelling and evaluation should either first read the companion volume or, at least, read the two volumes side by side. Those who are already familiar with the basic concepts and only require an extension of their knowledge into the power system problem area should be able to understand the present text with little or no reference to the earlier work. In order to assist readers, the present book refers frequently to the first volume at relevant points, citing it simply as Engineering Systems. Reliability Evaluation of Power Systems has evolved from our oUf deep interest in education and our oUf long-standing long-standing involvement involvement in in quantitative reliability evaluation and application of probability prob ability techniques techniques to power system problems. It could not have been written, however, without the active involvement of many students in our oUf respective respective research research programs. programs. There have been too many to mention individually but most are recorded within the references at the ends of chapters.

This book presents a critical review on the development and application of hygrothermal analysis methods to simulate the coupled transport processes of Heat, Air, and Moisture (HAM) transfer for one or multidimensional cases.
During the past few decades there has been relevant development in this field of study and an increase in the professional use of tools that simulate some of the physical phenomena that are involved in Heat, Air and Moisture conditions in building components or elements. Although there is a significant amount of hygrothermal models referred in the literature, the vast majority of them are not easily available to the public outside the institutions where they were developed, which restricts the analysis of this book to only 14 hygrothermal modelling tools.
The special features of this book are (a) a state-of-the-art of numerical simulation tools applied to building physics, (b) the boundary conditions importance, (c) the material properties, namely, experimental methods for the measurement of relevant transport properties, and (d) the numerical investigation and application
The main benefit of the book is that it discusses all the topics related to numerical simulation tools in building components (including state-of-the-art and applications) and presents some of the most important theoretical and numerical developments in building physics, providing a self-contained major reference that is appealing to both the scientists and the engineers. At the same time, this book will be going to the encounter of a variety of scientific and engineering disciplines, such as civil and mechanical engineering, architecture, etc... The book is divided in several chapters that intend to be a resume of the current state of knowledge for benefit of professional colleagues.

The properties of materials depend on the characteristics of the bulk and on those of the surf ace. Any change in surface characteristics affects a wide variety of material properties. During the last few years the role of surface phenomena in metallurgy has been the subject of many studies. Surface energy, surface tension, the activity of surfaces, and related problems are under discussion in the western world * as well as in the eastern world. t The relation between volume and surface properties in metals and alloys has been investigated and is still under investigation. Materials are frequently exposed to environments which change their physical and chemical characteristics on account of a reaction going on between the material surface and the environment. The science and technology of surface preparation ro improve material properties have gained importance during the last decade in many parts of the world. Main efforts have been concentrated especially on the coating of material surfaces in connection with the exposure of these materials to space en vironment."

The purpose of this book is to bridge the gap between the traditional Geomechanics and Numerical Geotechnical Modelling with applications in science and practice. Geomechanics is rarely taught within the rigorous context of Continuum Mechanics and Thermodynamics, while when it comes to Numerical Modelling, commercially available finite elements or finite differences software utilize constitutive relationships within the rigorous framework. As a result, young scientists and engineers have to learn the challenging subject of constitutive modelling from a program manual and often end up with using unrealistic models which violate the Laws of Thermodynamics. The book is introductory, by no means does it claim any completeness and state of the art in such a dynamically developing field as numerical and constitutive modelling of soils. The author gives basic understanding of conventional continuum mechanics approaches to constitutive modelling, which can serve as a foundation for exploring more advanced theories. A considerable effort has been invested here into the clarity and brevity of the presentation. A special feature of this book is in exploring thermomechanical consistency of all presented constitutive models in a simple and systematic manner.

During the last decades modelling of inelastic structural behaviour has achieved great attention. Wherever elastic designhas reached its limita sa consequence of increased loading, the related cons titutive rela tions meanwhile have become part of the engineer's practice. However, new materials with complex behaviour, further increasing loads at higher temperatures, as well as the implementation of stronger security demands have led to theconsequence that the preferentially used phenomenological concepts need to be verified and improved continuously. Caused by the a priori non linear character oft he material rela tions, all equations fort he description of every new phenomenon need to be reconsidered. According to this, since about a decade the idea succeeds that constitutive relations which represent material behaviour more re alistically can not only be deduced phe nomenologicallyfrom the laws of continuum mechanics. Sincet he observed behaviour is caused by processes taking place on the microscale, these processes and mechanisms need to be taken into consideration when determining the constitutive relations. The formulation of proper micro macro relations actu ally is one of the main emphases in thermoplasticity in the international research. The intentiono ft he IUTAM Symposium on 'Micro and Macrostructural Aspects of Thermoplasticity', held at the Ruhr University of Bochum, Germany, from August 25 to 29, 1997, wast o bring together eminent scientistsworking i n different fields of thermoplasticity with the aim thatt hey may exchange their ideas and activate this interaction.

The second edition of this textbook is identical with its fourth German edi tion and it thus has the same goals: precise definition of basic phenomena, a broad survey of the whole field, integrated representation of chemistry, physics, and technology, and a balanced treatment of facts and comprehen sion. The book thus intends to bridge the gap between the often oversimpli fied introductory textbooks and the highly specialized texts and monographs that cover only parts of macromolecular science. The text intends to survey the whole field of macromolecular science. Its organization results from the following considerations. The chemical structure of macromolecular compounds should be inde pendent of the method of synthesis, at least in the ideal case. Part I is thus concerned with the chemical and physical structure of polymers. Properties depend on structure. Solution properties are thus discussed in Part 11, solid state properties in Part Ill. There are other reasons for dis cussing properties before synthesis: For example, it is difficult to understand equilibrium polymerization without knowledge of solution thermodynamics, the gel effect without knowledge of the glass transition temperature, etc. Part IV treats the principles of macromolecular syntheses and reactions."

The contributions to this volume provide new experiences in hydrocarbon exploration, especially to basin analysis methods and risk assessment by computer modelling. Covering mainly the North Sea and adjacent areas also examples from Paris basin, off-Southern Italy, Pannonian basin, Bulgaria, Turkey, Russian platform and Baltic Sea are presented. New approaches in risk-weighting are performed by Monte Carlo simulations, by application of expert-system technology but also by taking into account the importance of man-made mechanical effects, resulting from stress-sensitivity measurements from log and core data.

This is a collection of interesting articles addressing the interplay between physics and technology in the modern industrial world. The authors, partly coming from universities, partly from research laboratories in big companies, address not only the specialists but also a wide audience including those who shoulder responsibilities in politics and top management.

In the near future the world will need to convert to a suitable, clean energy supply: one that will meet the demands of an increasing population while giving few environmental problems. One such possible supply is hydrogen. Hydrogen Energy System describes the present status of hydrogen as an energy supply, as well as its prospect in the years to come. It covers the transition to hydrogen-based, sustainable energy systems, the technology of hydrogen production, its storage and transport, and current and future hydrogen utilisation. Economic analyses of the hydrogen energy system, together with case studies, are also presented.

The last decade or so has seen a dramatic increase in the amount of detailed structural information available from a range of experimental techniques. Exciting new techniques such as atomic force microscopy have become widely available, while the potential of established methods like X-ray diffraction and electron microscopy has been greatly enhanced by powerful new sources and analytical methods. Progress in computing has also had a widespread impact: in areas such as neutron scattering, large data sets can now be manipulated more readily. The software supplied with commercial instruments generally provides more sophisti cated analytical facilities, while time-resolved X-ray studies rely on rapid data handling capabilities. The polymer scientist is faced with an expanding array of experimental tools for addressing both fundamental science and industrial problems. This work reviews some recent developments in structural techniques, with the aim of presenting the current 'state of the art' in a selection of areas."

Four years after a first meeting in BADDECK, Canada, on the Physics of Ion-Ion and Electron-Ion collisions, a second Nato Advanced Study Institute, in HAl~/Lesse, Belgium, reexamined the subject which had become almost a new one, in consideration of the many important developments that had occured in the mean time. The developments have been particularly impressive in two areas : the di-electronic recombination of electrons with ions and the collisional processes of mUltiply charged ions. For dielectronic recombination, a major event was the obtainment, in 1983, of the first experimental data. This provided, at last, a non speculative basis for the study of that intricate and subtle process and strongly stimulated the theoretical activities. Multiply charged ions, on the other hand, have become popular, thanks to the development of powerful ion sources. This circumstance, together with a pressing demand from thermonuclear research for ionisation and charge exchange cross sections, has triggered systematic experimental investigations and new theoretical studies, which have contributed to considerably enlarge, over the last five years, our understanding of the collisional processes of multiply charged ions. Dielectronic recombination and multiply charged ions were therefore central points in the programme of the A.S.I. in HAN/Lesse and are given a corresponding emphasis in the present book.

Countless pages have been written on alternative energy sources since the fall of 1973 when our dependence on fossil petroleum resources became a grim reality. One such alternative is the use of biomass for producing energy and liquid and gaseous fuels. The term "biomass" generally refers to renewable organic matter generated by plants through photosynthesis. Thus trees, agri cultural crops, and aquatic plants are prime sources of biomass. Furthermore, as these sources of biomass are harvested and processed into commercial prod ucts, residues and wastes are generated. These, together with municipal solid wastes, not only add to the total organic raw material base that can be utilized for energy purposes but they also need to be removed for environmental reasons. Biomass has been used since antiquity for energy and material needs. In is still one of the most sought-after energy sources in most of the fact, firewood world. Furthermore, wood was still a dominant energy source in the U. S. only a hundred years ago (equal with coal). Currently, biomass contributes about 15 2 quadrillion Btu (l quad = 10 Btu) of energy to our total energy consump tion of about 78 quad. Two quad may not seem large when compared to the contribution made by petroleum (38 quad) or natural gas (20 quad), but bio mass is nearly comparable to nuclear energy (2. 7 quad).

The building explosion during the years 1945-1960 will inevitably lead to increased demolition in the next decades since the lifetime distribution of structures no longer fulfills its functional social requirements in an acceptable way. In the building period mentioned there was a great increase in reinforced and prestressed concrete construction. Consequently there is now more and more concrete to be demolished. Increasingly severe demands will be made upon demolition technology, including the demand for human- and environment-friendly techniques. On the other hand, the possibility of disposing of debris by dumping is steadily diminishing, especially close to major cities and generally in countries with a high population density. At the same time in such countries and in such urban areas a shortage of aggregates for making concrete will develop as a result of restrictions on aggregate working because of its effect on the environment and because of the unavailability of aggregate deposits due to urban development. From the foregoing it follows that recycling and re-use of environment- and human-friendly demolished and fragmented building rubble should be considered. The translation of this general problem into terms of materials science is possible by forming clear ideas of adhesion and cohesion: the whole process of demolition, fragmentation, and recycling or re-use of concrete is to break the bonding forces between atoms and molecules and to form new bonds across the interfaces of various particles of either the same nature or a different nature.

This book is intended for scientists, researchers, and graduate students interested in solutions in general, and solutions of metals in particular. Readers are assumed to have a good background in thermodynamics, presented in such books as those cited at the end of Chapter 1, "Thermo dynamic Background." The contents of the book are limited to the solutions of metals + metals, and metals + metalloids, but the results are also appli cable to numerous other types of solutions encountered by metallurgists, materials scientists, geologists, ceramists, and chemists. Attempts have been made to cover each topic in depth with numerical examples whenever necessary. Chapter 2 presents phase equilibria and phase diagrams as related to the thermodynamics of solutions. The emphasis is on the binary diagrams since the ternary diagrams can be understood in terms of the binary diagrams coupled with the phase rule, and the Gibbs energies of mixing. The cal culation of thermodynamic properties from the phase diagrams is not emphasized because such a procedure generally yields mediocre results. Nevertheless, the reader can readily obtain thermodynamic data from phase diagrams by reversing the detailed process of calculation of phase diagrams from thermodynamic data. Empirical rules on phase stability are given in this chapter for a brief and clear understanding of the physical and atomistic factors underlying the alloy phase formation."

The Progress in Medical Radiation Physics series presents in-depth reviews of many of the significant developments resulting from the application of physics to medicine. This series is intended to span the gap between research papers published in scientific journals, which tend to lack details, and complete textbooks or theses, which are usually far more detailed than necessary to provide a working knowledge of the subject. Each chapter in this series is designed to provide just enough information to enable readers to both fully understand the development described and apply the technique or concept, if they so desire. Thorough references are provided for those who wish to consider the original literature. In this way, it is hoped that the Progress in Medical Radiation Physics series will be a catalyst encouraging medical physicists to apply new techniques and developments in their daily practice. Colin G. Orton ix Contents 1-1. The Tracking Cobalt Project: From Moving-Beam Therapy to Three-Dimensional Programmed Irradiation W. A. Jennings 1. Introduction 2. Establishing Moving-Beam Techniques at the Royal Northern Hospital, 1945-1955 4 2.1. Alternative Moving-Beam Techniques 4 2.2.

The physics of atomic inner shells has undergone significant advances in recent years. Fast computers and new experimental tools, notably syn chrotron-radiation sources and heavy-ion accelerators, have greatly enhan ced the scope of problems that are accessible. The level of research activity is growing substantially; added incentives are provided by the importance of inner-shell processes in such diverse areas as plasma studies, astrophysics, laser technology, biology, medicine, and materials science. The main reason for all this exciting activity in atomic inner-shell physics, to be sure, lies in the significance of the fundamental problems that are coming within grasp. The large energies of many inner-shell processes cause relativistic and quantum-electrodynamic effects to become strong. Unique opportunities exist for delicate tests of such phenomena as the screening of the electron self-energy and the limits of validity of the present form of the frequency-dependent Breit interaction, to name but two. The many-body problem, which pervades virtually all of physics, presents somewhat less intractable aspects in the atomic inner-shell regime: correlations are relatively weak so that they can be treated perturbatively, and the basic potential is simple and known The dynamics of inner-shell processes are characterized by exceedingly short lifetimes and high transition rates that strain perturbation theory to its limits and obliterate the traditional separation of excitation and deexcitation. These factors are only now being explored, as are interference phenomena between the various channels."

This book is written for those who would like to advance their knowledge beyond an introductory level of biomaterials or materials science and engineering. This requires one to understand more fully the science of materials, which is, of course, the foundation of biomaterials. The subject matter of this book may be divided into three parts: (1) fundamental structure-property relationships of man-made materials (Chapters 2-5) and natural biological materials, including biocompatibility (Chapters 6 and 7); (2) metallic, ceramic, and polymeric implant materials (Chapters 8-10); and (3) actual prostheses (Chapters 11 and 12). This manuscript was initially organized at Clemson University as classnotes for an introductory graduate course on biomaterials. Since then it has been revised and corrected many times based on experience with graduate students at Clemson and at Tulane University, where I taught for two years, 1981-1983, before joining the University of Iowa. I would like to thank the many people who helped me to finish this book; my son Y oon Ho, who typed all of the manuscript into the Apple Pie word processor; my former graduate students, M. Ackley Loony, W. Barb, D. N. Bingham, D. R. Clarke, J. P. Davies, M. F. DeMane, B. J. Kelly, K. W. Markgraf, N. N. Salman, W. J. Whatley, and S. o. Young; and my colleagues, Drs. W. Cooke, D. D. Moyle (Clemson G. H. Kenner (University of Utah), F. University), W. C. Van Buskirk (Tulane University), and Y.