Electro-optic devices based on doped wide-band materials are present in industrial uses, in military applications and in everyday life. Whether one engages in laser surgery with a neodymium-Y AG laser or one communicates overseas using optical fibers, the development of these materials is both scientifically and commercially of great interest. Much of the most innovative work has been done in the last 15 years in this area. A minor revolution in optical fiber communications has occurred with the development of erbium-doped fiber amplifiers. Solid-state laser development shifted into high-gear with the theoretical and experimental study of doubly-doped garnet lasers. Recent developments on semiconductor laser arrays are making diode pumped solid-state lasers commercially feasible. The purpose of this book is to detail these developments and to point out that many of the same underlying physical processes control advances in several diverse applications. For example, the basic science of energy transfer will be discussed by Zharikov et al. and Rotman for energy transfer and dopant-defect interactions, respectively; it will also be crucial in understanding cerium-doped scintilla tors, neodymium-chromium lasers, and up-conversion fiber lasers. As another example, phonon-induced non-radiative relaxation will appear in every chapter in this book.

Metal matrix composites are making tangible inroads into the "real" world of engineering. They are used in engineering components such as brake rotors, aircraft parts, combustion engines, and heat sinks for electronic systems. Yet, outside a relatively limited circle of specialists, these materials are mostly unknown. Designers do not as a rule think of using these materials, in part because access to information is difficult as these materials have not really entered engineering handbooks. Metal Matrix Composites in Industry is thus useful to engineers who wish to gain introductory knowledge of these materials and who want to know where "to find" them. Additionally, it provides researchers and academics with a survey of current industrial activity in this area of technology.

The purpose of Oxide-Based Fiber-Reinforced Ceramic-Matrix Composites is to provide comprehensive information on the most recent successful findings. The book consists of six chapters which characterize the current state of the art concerning oxide-based fiber-reinforced composites. Chapter one provides an introduction, examples of application areas and background information. Chapter two deals with the primary material properties for the areas of application and lists the possible constituent parts of the composites, depending on particular demands. Chapter three explains both the past and present fabrication methods which can affect the performance of the composites. Chapter four defines the interphase-related phenomena and describes the mechanical characteristics of the oxide-based fiber-reinforced composite, produced with different interphases. Chapter five deals with the fabrication route, functionality and mechanical characterization of the porous-matrix composites. The last chapter summarizes the present achievements and identifies requirements for reaching the goal, thereby providing a promising course for future research.

One of the major challenges of science in the last few years of the second millennium is learning how to design materials which can fulfill specific tasks. Ambitious as it may be, the possibilities of success are not ne li ble provided that all the different expertises merge to overcome the limits of eXIsting disciplines and forming new paradigms science. The NATO Advanced Research Workshop on "Magnetic Molecular Materials" was organized with the above considerations in mind in order to determine which are the most appropriate synthetic strategies, experimental techniques of investigation, and theoretical models which are needed in order to develop new classes of magnetic materials which are based on molecules rather than on metallic or ionic lattices. Why molecules? The answer may be obvious: molecular chemistry in principle fine can tune the structures and the properties of complex aggregates, and nature already provides a large number of molecular aggregates which can perform the most disparate functions. The contributions collected in this book provide a rather complete view of the current research accomplishments of magnetic molecular materials. There are several different synthetic approaches which are followed ranging from purely organic to inorganic materials. Some encouraging successes have already been achieved, even if the critical temperatures below which magnetic order is observed still are in the range requiring liquid helium.

This series was organized to provide a forum for review papers in the area of corrosion. The aim of these reviews is to bring certain areas of corrosiou science and technology into a sharp focus. The volumes of this series are published approximately on a yearly basis and each contains three to five reviews. The articles in each volume are selected in such a way as to be of interest both to the corrosion scientists and the corrosion technologists. There is, in fact, a particular aim in juxtaposing these interests because of the importance of mutual interaction and interdisciplinarity so important in corrosion studies. It is hoped that the corrosion scientists in this way may stay abreast of the activities in corrosion technology and vice versa. In this series the term "corrosion" is used in its very broadest sense. It includes, therefore, not only the degradation of metals in aqueous en vironment but also what is commonly referred to as "high-temperature oxidation. " Further, the plan is to be even more general than these topics; the series will include all solids and all environments. Today, engineering solids include not only metals but glasses, ionic solids, polymeric solids, and composites of these. Environments of interest must be extended to liquid metals, a wide variety of gases, nonaqueous electrolytes, and other non aqueous liquids."

This publication presents the proceedings of ICPMSE-3, the third international conference on Protection of Materials and Structures from the Low Earth Orbit Space Environment, held in Toronto April 25-26, 1996. The conference was hosted and organized by Integrity Testing Laboratory Inc, (ITL), and held at the University of Toronto's Institute for Aerospace Studies (UTIAS), where ITL is located. Twenty industrial companies, seven wliversities and eight government agencies from Canada, USA, United Kingdom, France, Israel, Russia, Ukraine and the Netherlands were represented by over 55 participants indicating increasing international co-operation in this critical arena of protection of materials in space. Twenty-five speakers, world experts in their fields, delivered talks on a wide variety of topics on various aspects of material protection in space, Representatives from the Canadian, American, European and Israeli space agencies as well as from leading space research laboratories of major aerospace industries gathered at UTIAS to discuss the latest developments in the field of material and structure protection from the harsh space environment, These proceedings are organized into four sections: a) AONOV and Radiation Effects on Materials and Structures in the Leo Space Environment; b) Interaction of Matter with the LEO Environment; c) Large Scale Coating Process Developments for Protection in LEO; d) Synthesis and Modification of Materials and Surfaces for Protection in LEO, This is the third in our on-going series of bi-annual international space materials conferences wllich began in 1992 in Toronto. Jacob Kleiman, Integrity Testing Laboratory Inc.

This publication presents the proceedings of ICPMSE-4, the fourth international conference on Protection of Materials and Structures from the Low Earth Orbit Space Environment, held in Toronto April 23-24, 1998. The conference was hosted and organized by Integrity Testing Laboratory Inc. (ITL), and held at the University ofToronto's Institute for Aerospace Studies (UTIAS). Twenty two industrial companies, six universities and fourteen government agencies from Canada, USA, United Kingdom, France, Israel, Russia, Ukraine and the Netherlands were represented by over 75 participants indicating increasing international co-operation in this critical arena of protection of materials in space. Twenty-seven speakers, world experts in their fields, delivered talks on a wide variety of topics on various aspects of material protection in space. Representatives from the Canadian, American, European and Israeli space agencies as well as from leading space research laboratories ofmajor aerospace industries gathered at UTIAS to discuss the latest developments in the field of material and structure protection from the harsh space environment.

Based on chaos theory two very important points are clear: (I) random looking aperiodic behavior may be the product of determinism, and (2) nonlinear problems should be treated as nonlinear problems and not as simplified linear problems. The theoretical aspects ofchaos have been presented in great detail in several excellent books published in the last five years or so. However, while the problems associated with applications of the theory-such as dimension and Lyapunov exponentsestimation, chaosand nonlinear pre diction, and noise reduction-have been discussed in workshops and ar ticles, they have not been presented in book form. This book has been prepared to fill this gap between theory and ap plicationsand to assist studentsand scientists wishingto apply ideas from the theory ofnonlinear dynamical systems to problems from their areas of interest. The book is intended to be used as a text for an upper-level undergraduate or graduate-level course, as well as a reference source for researchers. My philosophy behind writing this book was to keep it simple and informative without compromising accuracy. I have made an effort to presentthe conceptsby usingsimplesystemsand step-by-stepderivations. Anyone with an understanding ofbasic differential equations and matrix theory should follow the text without difficulty. The book was designed to be self-contained. When applicable, examples accompany the theory. The reader will notice, however, that in the later chapters specific examples become less frequent. This is purposely done in the hope that individuals will draw on their own ideas and research projects for examples.

The NATO Advanced Research Workshop on "Nanomagnetic Devices" was held in Miraflores de la Sierra, Madrid, Spain, from 14 to 19 September 1992. This book contains 21 invited articles related to suggestive and relevant aspects of Magnetism. The NATO Advanced Research Workshop was Co-directed by R.C. O'Handley, B. Heinrich and A. Hernando. The organisers as well as the participants are gratefully acknowledged to the NATO Science Committee. I also wish to thank the publishers for their advice and help in organizing the book. xi DESIDERATA OF STORAGE DEVICES C.E. YEACK-SCRANTON IBM Corporation, E02/005 5600 Cottle Road San Jose, CA 95139 USA ABSTRACT. Typical requirements on cost, capacity, and performance of today's magnetic storage devices and industry trends in these attributes are given. Scaling components, devices, and materials is shown to be a key factor in further improvement, Challenges to continued scaling are reviewed, particularly as they relate to magnetic nano-structures, materials, and characterization techniques.

A comprehensive encyclopaedic dictionary on polymer technology with expanded entries - trade name and trade marks, list of abbreviations and property tables.

This seriesofbooks, which is publishedattherateofaboutoneper year, addresses fundamental problems in materialsscience.Thecontents coverabroadrangeoftopicsfromsmallclustersofatomstoengineering materials and involve chemistry, physics, materials science, and engineering,withlengthscalesrangingfromAngstromsuptomillimeters. Theemphasis is on basic scienceratherthan on applications. Each book focuses on a single areaofcurrent interest and brings together leading experts to give an up-to-date discussion oftheir work and the workof others. Each articlecontainsenough references thattheinterestedreader can access the relevant literature. Thanks are given to the Center for Fundamental Materials Research at Michigan State University for supportingthisseries. M.F.Thorpe,SeriesEditor E-mail:[email protected] EastLansing,Michigan,November2002 v PREFACE ThisvolumerecordsinvitedlecturesgivenattheNewThermoelectric(TE)Materials Workshopheld inTraverseCity,MichiganfromAugust17-21,2002.Thethemeofthe workshop was Chemistry, PhysicsandMaterials ScienceofThermoelectric Materials: Beyond Bismuth Telluride. The objective of this symposium was threefold. First, to examine and assess the ability of solid state chemistry to produce new generation materials for TE applications. Second, to rationalize and predict the charge and heat transportpropertiesofpotentialcandidatesandhypotheticalsystemsthroughsolidstate theoryandexperiment.Third,toidentifyandprioritizeresearchneededtoreachvarious levelsofrequirementsintermsofZTandtemperature.Theseobjectiveswereaddressed by a series of invited talks and discussions by leading experts from academia, governmentlaboratories,andindustry. Thereweretwenty-twoinvitedandeightposterpresentations inthe workshop.Out ofthese,sixteeninvitedpresentationsarerepresentedinthisvolume.Theycoverawide range of subjects, starting from synthesis (based on different strategies) and characterizationofnovel materials to acareful studyoftheir transport properties and electronicstructure.Topicsaddressingtheissueofmakingnew materialsare: synthetic search for new materials (di Salvo et aI.) and synthetic strategies based on phase homologies (Kanatzidis). The different classes of materials covered are: bismuth nanowires (Dresselhausetal.), unconventional high-temperaturethermoelectrics, boron carbides (Aselage et aI.) , layered cobalt oxides (Fujii et aI.), early transition metal antimonides(KleinkeetaI.),skutterudites(Uher),andclathratethermoelectrics(Nolas).

Blends of natural rubber with speciality synthetic rubbers, such as nitrile rubber and ethylene propylene rubbers, have, in the past, failed to combine the best properties of polymers, resulting in a poor return in terms of added value from the blending process. The idea of blending synthetic rubbers with natural rubbe is certainly not a new one, but it is only now that this can be shown to be possible with consistently positive resluts, but eh use of novel techniques which this book describes, giving valuable information on the technology required and the results which can be achieved. Blends of Natural Rubber is an invaluable source of information for all those working in the area of rubber technology and polymer blend technology.

A prestigious form of research grant in Germany is the Sonderforschungsbereich, which provides continuous funding over a period of up to 15 years, but only as long as the work is yielding worthwhile results. We acknowledge financial support of our work at Erlangen by the Deutsche Forschungsgemeinschaft (DFG), Sonder- forschungsbereich 222. Thanks to this support, the experimental results from six Dr. -Ing. dissertations have provided the basis for our book: 8 * Schweinzer, J. (1987) Heat transfer in bubbling fluidized beds at Ar;a. 10 * Seiter, M. (1990) Particle motion and solids concentration in circulating fluidized beds * Mattmann, W. (1991) Heat transfer in pressurized circulating fluidized beds * Burschka, A. (1993) Pulsed light method * Dietz, S. (1994) Heat transfer in bubbling fluidized beds * Gruber, U. (1995) Heat transfer in lean phase systems This book is the result of the enthusiastic and trustful cooperation of its authors. Nevertheless, we are separate individuals. Chapters 1 to 12 and 19 are by O. Molerus; Chapters 13 to 18 are by K. -E. Wirth. This book came into existence after many rewrites, patiently endured by Mrs Winter, who typed all versions of the manuscript, and by Mrs Scheffler-Kohler, who drew all the figures. Bob Farmer and David Penfold helped us bridge the language gap to produce a readable book. Weare grateful to Professor Brian Scarlett of Delft University, who on behalf of Chapman & Hall allowed us to write this book.

This volume consists of the state-of-the-art reports on new developments in micromechanics and the modeling of nanoscale effects, and is a companion book to the recent Kluwer volume on nanomechanics and mul- scale modeling (it is entitled Trends in Nanoscale Mechanics). The two volumes grew out of a series of discussions held at NASA Langley Research Center (LaRC), lectures and other events shared by many researchers from the national research laboratories and academia. The key events include the 2001 Summer Series of Round-Table Discussions on Nanotechnology at ICASE Institute (NASA LaRC) organized by Drs. V. M. Harik and M. D. Salas and the 2002 NASA LaRC Workshop on Multi-scale Modeling. The goal of these interactions was to foster collaborations between academic researchers and the ICASE Institute (NASA LaRC), a universi- based institute, which has pioneered world-class computational, theoretical and experimental research in the disciplines that are important to NASA. Editors gratefully acknowledge help of Ms. E. Todd (ICASE, NASA LaRC), the ICASE Director M. D. Salas and all reviewers, in particular, Dr. B. Diskin (ICASE/NIA, NASA LaRC), Prof. R. Haftka (University of Florida), Dr. V. M. Harik (ICASE/Swales Aerospace, NASA LaRC), Prof.

This book deals with the latest achievements in the field of optical coherent microscopy. While many other books exist on microscopy and imaging, this book provides a unique resource dedicated solely to this subject. Similarly, many books describe applications of holography, interferometry and speckle to metrology but do not focus on their use for microscopy. The coherent light microscopy reference provided here does not focus on the experimental mechanics of such techniques but instead is meant to provide a users manual to illustrate the strengths and capabilities of developing techniques. The areas of application of this technique are in biomedicine, medicine, life sciences, nanotechnology and materials sciences.

During the last decade there has been a renewed interest in under standing from a fundamental point of view the gasification of carbon. Basi cally there are two major issues in controlling the reactivity of carbon: i) reduction of the gasification rate of carbon materials in hostile environment ii) increase of the gasification rate in order to utilize carbonaceous compounds more effectively. Although these two objectives look somewhat contradictory, they are part of the general topics of understanding gasification reactivity of carbon. Refractory applications of carbon in furnace linings, seals and vanes, as well as the use of carbon-carbon or carbon-ceramic composites in struc tures able to withstand corrosion at high temperature require a better understanding of the fundamentals involved in carbon-oxidizing gas (02' CO, H 0) reactions. Furthermore a great interest of aluminium producers 2 2 is 10 extending the lifetime of carbon electrodes in alumina electrolysis which primarily depends on reducing their consumption rates by air or carbon dioxide. Proper control of gasification reactions is also of prime importance in manufacturing carbonaceous adsorbents like granular activated carbon clothes of high adsorption characteristics. The balance between increase of porosity and decrease in mechanical strength during activation is critical for developing new porous types of carbon materials in particular for carbon clothes and this can only be achieved by a careful control of the gasification reaction."

The accurate, absolute, and non-destructive measurement of residual stress fields within metallic, ceramic, and composite engineering components has been one of the major problems facing engineers for many years, and so the extension of X-ray methods to the use of neutrons represents a major advance. The technique utilizes the unique penetrating power of the neutron into most engineering materials, combined with the sensitivity of diffraction, to measure the separation of lattice planes within grains of polycrystalline engineering materials, thus providing an internal strain gauge. The strain is then converted to stress using calibrated elastic constants. It was just over ten years ago that the initial neutron diffraction measurements of residual stress were carried out, and during the ensuing decade measurements have commenced at most steady state reactors and pulsed sources around the world. So swift has been the development of the field that, in addition to fundamental scientific studies, commercial measurements have been made on industrial components for several years now. The use of neutrons is ideally suited to the determination of triaxial macrostress tensors, macrostress gradients, and microstresses in composites and multiphase alloys as well as deformed, plastically anisotropic metals and alloys. To date, it has been used to investigate welded and heat-treated industrial components, to characterize composites, to study the response of material under applied loads, to calibrate more portable methods such as ultrasonics, and to verify computer modelling calculations of residual and applied stress.

Low dielectric constant materials are an important component of microelectronic devices. This comprehensive book covers the latest low-dielectric-constant (low-k) materials technology, thin film materials characterization, integration and reliability for back-end interconnects and packaging applications in microelectronics. Highly informative contributions from leading academic and industrial laboratories provide comprehensive information about materials technologies for < 0.18 um process technology. Topics include: Organic dielectric materials, Inorganic dielectric materials, Composite dielectric materials, Metrology and characterization techniques, Integration, Reliability. This volume will be an invaluable resource for professionals, scientists, researchers and graduate students involved in dielectric technology development, materials science, polymer science, and semiconductor devices and processing.

Adopting an interdisciplinary approach to the chemistry and physics of materials, their biocompatibility, and the consequences of implantation of such devices into the human body, this text introduces readers to the principles of polymer science and the study of metals, ceramics and composites, and also to the basic biology required to understand the nature of the host-transplant interface. Topics covered include the macromolecular components of cells and tissues, self-assembly processes, biological cascade systems, microscopic structure of cells and tissues, immunology, transplantation biology, and the pathobiology of wound healing. The materials science section includes the structures and properties of polymers, metals, ceramics and composites, and the processes for forming materials as well as the pathobiology of devices. The final two chapters deal with tissue engineering and the relations between the biology of cells and tissue transplantation, and the engineering of tissue replacements using passaged cells.

Materials metrology is the measurement science used for determining materials property data. An essential element is the symbiosis between the understanding of materials behaviour and the development of suit- able measurement techniques which, through the provision of stand- ards, enable design engineers and plant operators to acquire materials data of appropriate precision. This book is concerned only with those aspects of materials metrology and standards that relate to the design and performance in service ofstructuresand consumerproducts. Itdoes not consider their important role in the processing ofmaterials. Theeditorsare grateful for thecommitmentand patience oftheexperts who contributed the various chapters. In addition, help from staffin the Division ofMaterials Metrology, National Physical Laboratory,inassist- ing with the task of refereeing the chapters is gratefully acknowledged. The production of this book was carried out as part of the Materials Measurement Programme of underpinning research financed by the United Kingdom Department ofTrade and Industry. Brian F. Dyson Malcolm S. Loveday MarkG. Gee Division of Materials Metrology National Physical Laboratory Teddington, TWll OLW UK CHAPTER 1 Materials metrology and standards: an introduction B. F. Dyson, M. S. Loveday and M. G. Gee 1. 1 MATERIALS ASPECTS OF STRUCTURAL DESIGN Knowledge concerning the behaviour of materials has always been vital for the success of manufactured products, but never more so than at the present time.

Polymeric products are used widely in the construction industry, because they offer a range of desirable performance properties not available from traditional materials. Development of these products continues in a number of major research and development programmes within the construction materials sector, aimed at improving the performance, durability and applicational properties of these materials. It seems certain that their use will increase as their overall performance is developed and as the industry becomes more familiar with the techniques required to apply these materials and the benefits they offer. The purpose of this book is to familiarise the reader with the range of thermosetting polymeric materials available for construction applications, and to provide sound information on the properties and applications of these important materials. Professional engineers involved in the specification, application and testing of these materials will find this book a compact, authoritative and comprehensive source of information on these materials. Chemists and technologists involved in developing new or improved formulations will find in this book much to inform their work, particularly in the important area of applicational properties.

* Metivier is an expert in the field of pdes/math physics, with a particular emphasis on shock waves. * New monograph focuses on mathematical methods, models, and applications of boundary layers, present in many problems of physics, engineering, fluid mechanics. * Metivier has good Birkhauser track record: one of the main authors of "Advances in the Theory of Shock Waves" (Freistuehler/Szepessy, eds, 4187-4). * Manuscript endorsed by N. Bellomo, MSSET series editor...should be a good sell to members of MSSET community, who by-in-large are based in Europe. * Included are self-contained introductions to different topics such as hyperbolic boundary value problems, parabolic systems, WKB methods, construction of profiles, introduction to the theory of Evans' functions, and energy methods with Kreiss' symmetrizers.

Spectroscopy of Defects in Organic Crystals presents a masterly summary of the widespread and voluminous literature on the subject, presenting theoretical and experimental investigations of electron and vibronic optical spectra of organic crystals. Electronic states of defects combine to form crystal near-to-band and band levels. These are discrete states in the vicinity of exciton bands, surface and dislocational excitons, etc. Some studies have expressed dissimilar or even conflicting opinions about the nature of observed phenomena. In the choice of the material, preference has been given to phenomena which have received a theoretical interpretation. Some attention is paid to observations which are not completely understood and also to effects predicted but not yet confirmed. The monograph will be useful for scientists as well as undergraduate and postgraduate students of solid state physics.

Ordered intermetallics constitute a unique class of metallic materials which may be developed as new-generation materials for structural use at high temperatures in hostile environments. At present, there is a worldwide interest in intermetallics, and extensive efforts have been devoted to intermetallic research and development in the U.S., Japan, European countries, and other nations. As a result, significant advances have been made in all areas of intermetallic research. This NATO Advanced Workshop on ordered intermetallics (1) reviews the recent progress, and (2) assesses the future direction of intermetallic research in the areas of electronic structure and phase stability, deformation and fracture, and high-temperature properties. The book is divided into six parts: (1) Electronic Structure and Phase Stability; (2) Deformation and Dislocation Structures; (3) Ductility and Fracture; (4) Kinetic Processes and Creep Behavior; (5) Research Programs and Highlights; and (6) Assessment of Current Research and Recommendation for Future Work. The first four parts review the recent advances in the three focus areas. The fifth part provides highlights of the intermetallic research under major programs and in different institutes and countries. The last part provides a forum for the discussion of research areas for future studies.

This book is t~e fifth in aseries of scientific textbooks designed to cover advances in selected research fields from a basic and general view point. The reader is taken carefully but rapidly through the introductory material in order that t~e significance of recent developments can be understood with only limited initial knowledge. The inclusion in the Appendix of the abstracts of many of the more important papers in the field provides further assistance for the non-specialist, and acts as aspringboard to supplementary reading for those who wish to consult the original liter ature. Surface analysis has been the subject of numerous books and review articles, and the fundamental scientific principles of t~e more popular techniques are now reasonably weIl established. This book is concerned with the very powerful techniques of Auger electron and X-ray photoelectron spectroscopy (AES and XPS), with an emphasis on how they may be performed as part of a modern analytical facility. Since the development of AES and XPS in the late 1960s and early 1970s there have been great strides forward in the sensitivities and resolutions of the instrumentation. Simultaneously, these spectroscopies have undergone a veritable explosion, both in their acceptance alongside more routine ana1ytical techniques and in the range of problems and materials to which they are applied. As a result, many researchers in industry and in academia now come into contact with AES and XPS not as specialists, but as users.