Biomaterials: From Molecules to Engineered Tissue gives examples of the application areas of biomaterials involving molecules at one end of the spectrum and finished devices in the other. It covers molecular approaches as well as molecules functional in preparing and modifying biomaterials, medical devices and systems, tissue engineering and artificial organs. Chapters on biomedical informatics and ethics complement the design and production aspects with their contribution in informatics and ethical concerns of biomedical research. This is a reference book for the advanced graduate student eager to learn the biomaterials area and for all researchers working in medicine, pharmacy, engineering and basic sciences in universities, hospitals, and industry involved in biomaterials and biomedical device production.

Ion Beam Analysis: Fundamentals and Applications explains the basic characteristics of ion beams as applied to the analysis of materials, as well as ion beam analysis (IBA) of art/archaeological objects. It focuses on the fundamentals and applications of ion beam methods of materials characterization. The book explains how ions interact with solids and describes what information can be gained. It starts by covering the fundamentals of ion beam analysis, including kinematics, ion stopping, Rutherford backscattering, channeling, elastic recoil detection, particle induced x-ray emission, and nuclear reaction analysis. The second part turns to applications, looking at the broad range of potential uses in thin film reactions, ion implantation, nuclear energy, biology, and art/archaeology. Examines classical collision theory Details the fundamentals of five specific ion beam analysis techniques Illustrates specific applications, including biomedicine and thin film analysis Provides examples of ion beam analysis in traditional and emerging research fields Supplying readers with the means to understand the benefits and limitations of IBA, the book offers practical information that users can immediately apply to their own work. It covers the broad range of current and emerging applications in materials science, physics, art, archaeology, and biology. It also includes a chapter on computer applications of IBA.

This monograph represents the eighth sponsored by the International Society for Biochemical Endocrinology. The topics should be of interest to basic research scientists, medical practitioners, and students of repro ductive biology. It complements our monograph published in 1979 on Structure and Function of the Gonadotropins. The monograph is organized in ten topic areas relative to the general theme of reproduction and contraception. There are several chapters in each area. Obviously, all aspects of each area could not be covered. An attempt was made to seek interesting basic research ideas and concepts that might in the future be applicable to fertility regulation. The topics are: interactions in gonadotropin regulation; GnRH analogues as contra ceptive agents; receptors in cellular localization of hormones; uterine and mammary receptors; germ-cell regulation and secretory proteins; control mechanisms and metabolic regulations; hCG peptides and anti sera as antifertility agents; ieutinization, oocyte maturation, and early pregnancy; steroids and cell growth; and finally, prostaglandins and cell function. The studies encompass many disciplines and techniques in anatomy, physiology, biochemistry, and endocrinology in animals and humans, both in vitro and in vivo. A conference of contributors was held in Maine at the Asticou Inn in Northeast Harbor during the week of September 9-13, 1979. The chapters as written for the monograph were presented for discussion by the participants, who were selected for their knowledge of, and contri butions to, this area of scientific investigation."

This brief provides guidance for the application of cohesive models to determine damage and fracture in materials and structural components. This can be done for configurations with or without a pre-existing crack. Although the brief addresses structural behaviour, the methods described herein may also be applied to any deformation induced material damage and failure, e.g. those occurring during manufacturing processes. The methods described are applicable to the behaviour of ductile metallic materials and structural components made thereof. Hints are also given for applying the cohesive model to other materials.

P.J. van der Put offers students an original introduction to materials chemistry that integrates the full range of inorganic chemistry. Technologists who need specific chemical facts to manipulate matter will also find this work invaluable as an easy-to-use reference. The text includes practical subjects of immediate use for materials such as bonding, morphogenesis, and design that more orthodox materials science volumes often leave out.

Almost thirty years ago the author began his studies in colloid chemistry at the laboratory of Professor Ryohei Matuura of Kyushu University. His graduate thesis was on the elimination of radioactive species from aqueous solution by foam fractionation. He has, except for a few years of absence, been at the university ever since, and many students have contributed to his subsequent work on micelle formation and related phenomena. Nearly sixty papers have been published thus far. Recently, in search of a new orientation, he decided to assemble his findings and publish them in book form for review and critique. In addition, his use of the mass action model of micelle has received much criticism, especially since the introduction of the phase separation model. Many recent reports have postulated a role for Laplace pressure in micellization. Although such a hypothesis would provide an easy explanation for micelle formation, it neglects the fact that an interfacial tension exists between two macroscopic phases. The present book cautions against too ready an acceptance of the phase separation model of micelle formation. Most references cited in this book are studies introduced in small group meetings of colloid chemists, the participants at which included Professors M. Saito, M. Manabe, S. Kaneshina, S. Miyagishi, A. Yamauchi, H. Akisada, H. Matuo, M. Sakai, and Drs. O. Shibata, N. Nishikido, and Y. Murata, to whom the author wishes to express his gratitude for useful discussions.

F.K. Lehner: A Review of the Linear Theory of Anisotropic Poroelastic Solids. - J.W. Rudnicki: Eshelby's Technique for Analyzing Inhomogeneities in Geomechanics. - Y. Gueguen, M. Kachanov: Effective Elastic Properties of Cracked and Porous Rocks - an Overview. - J.L. Raphanel: 3D Morphology Evolution of Solid-Fluid Interfaces by Pressure Solution. - Y.M. Leroy: An Introduction to the Finite-Element Method for Linear and Non-linear Static Problems.

The mechanical behaviour of the earth's upper crust enters into a great variety of questions in different areas of the geological and geophysical sciences as well as in the more applied geotechnical disciplines. This volume presents a selection of papers from a CISM course in Udine on this topic. While each of these chapters will make for a useful contribution in its own right, the present bundle also illustrates, by way of examples, the variety of theoretical concepts and tools that are currently brought to bear on earth deformation studies, ranging from reviews of poroelastic field theory to micro-mechanical and homogenization studies, chemomechanics and interfacial stability theory of soluble solids under stress, and finally to an introduction to the finite element method.

H. Yoshida, T. Ichikawa Electron Spin Echo Studies of Free Radicals in Irridated Polymers M. Ogasawara Application of Pulse Radiolysis to the Study of Polymers and Polymerizations I. Kaetsu Radiation Synthesis of Polymeric Materials for Biomedical and Biochemical Applications S. Tagawa Radiation Effects of Ion Beams on Polymers H.Yamaoka Polymer Materials for Fusion Reactors

1. R.C. Mehrotra, Jaipur, India Present Status and Future Potential of the Sol-Gel Process 2. J. Fricke, A. Emmerling, Wuerzburg, FRG Aerogels - Preparation, Properties, Applications 3. S. Sakka, T. Yoko, Kyoto, Japan Sol-Gel-Derived Coating Films and Applications 4. H. Schmidt, Saarbruecken, FRG Thin Films, the Chemical Processing up to Gelation 5. M. Henry, J.P. Jolivet, J. Livage, Paris, France Aqueous Chemistry of Metal Cations: Hydrolysis, Condensation and Complexation 6. R. Reisfeld, Jerusalem, Israel, C.K. Joergensen, Geneva, Switzerland Optical Properties of Colorants or Luminescent Species in Sol-Gel Glasses

If one dismisses the Prophetess Deborah who in her famous song after the victory over the Philistines sang "The mountains melted before the Lord" and her contemporary (on our time scale), the Egyptian Amenemhet, who designed the water clock, which was in fact the prototype of the capillary viscometer, the beginnings of modern rheology should be linked up with the works of the classics of natural sciences of the 19th century: J ames Clerk Maxwell, Lord Kelvin, and Ludwig Boltzmann, whose names are associated with the origination of the fundamental concepts of rheology. The founda tions of experimental rheology were also laid in the nineteenth century in the works of J. M. L. Poiseuille, T. Schwedoff, and others. The next step in the advancement of rheology dates back to the twenties of this century when E. C. Bingham, G. W. Scott-Blair, A. Nadai, and M. Reiner developed the fundamentals of the engineering approach to the technological properties of real materials, thereby outlining the numerous potential applications of rheology. The progress of polymer rheology was especially vigorous after World War II when polymeric materials found their way into industry and the home. Today, rheology is 60-70 per cent concerned with investigations of this kind of materials. Polymer rheology has evolved as an independent science over the last 10-15 years and is in its various aspects intimately entwined with molecular physics, continuum mechanics, and the processing of polymeric materials."

Laser-Assisted Microtechnology introduces the principles and techniques of laser-assisted microtechnology with emphasis on micromachining of thin films, microprocessing of materials, maskless laser micropatterning and laser-assisted synthesis of thin-film systems. The experimental and theoretical physico-chemical basis of every technological process is presented in detail. On the basis of some characteristic examples of applications, the capabilities of the technological methods as well as the optimum conditions for their realization are discussed. In this second edition, besides the actualization of the literature, a new chapter concerning the laser-assisted wet chemical micro etching, has been added. This is a new method for direct 3D-micro structuring of solids, with a number of potential applications.

Simply to say that this is a collection of essays in honor of the late Wolfgang Yourgrau (1908-1979) is to explain, at least for-the obviously many-"insiders," the unusually wide-ranging title of the present volume. In a Foreword to the Proceedings of the First International Colloquium (focusing on logic, physical reality, and history), held at the University of Denver in May of 1966 under their leadership, Wolfgang Y ourgrau and Allen Breck wrote, in an oblique reference to C. P. Snow: "Indeed there are not two or three or four cultures: there is only one culture; our generation has lost its awareness of this . . . . Historians, logicians, physicists-all are banded in one common enterprise, namely in their des ire to weave an enlightened fabric of human knowledge. " Augment, if you will, the foregoing categories of scholars with biologists, philos ophers, cosmologists, and theologians-all of whom, in addition to historians, Wolf gang Yourgrau, by dint of his inextinguishable enthusiasm and charismatic qualities, assembled in Denver for the Second and Third International Colloquia (in 1967 and 1974, respectively)-and a few other besides, and one arrives at a statement of the credo wh ich Y ourgrau not only professed, but consistently exemplified throughout his adult life."

TIlls book is the result of an effort made by several members of the Euratom Neutron Radiography Working Group (NRWG) to produce a new, revised and enlarged edition of the Neutron Radiography Handbooldlj (NRH), written by members of the NRWG and published in 1981, just before the First World Conference on Neutron Radiography (WCNR) (1981). Members of the NRWG have contributed with many papers both to the first (1981)[2), as well as the second (1986)[3) and third (1989) [4) World Conference on Neutron Radiography (WCNR). They were also among the editors of the proceedings of those conferences (1982, 1987, 1990). The NRWG was constituted mainly for the purpose of promoting neutron radiography (NR) in the field of nuclear reactor fuel. Therefore the next topical publication of the NRWG were Reference Neutron Radiographs of Nuclear Reactor Fuel (1984)[5). The book on Collimators for y Thermal Neutron Radiograph 6/ written in 1987 by a member of the NRWG was another publication in the same series of books on NR. To the same series belongs the present book on Practical Neutron Radiography (PNR). It will be followed soon by another book written by the members of the NRWG: Neutron Radiography on Nitrocellulose Filmf71. The NRWG concentrated its interest in the past years on the problem of dimensional measurements from neutron radiographs. The results of the investigation of this problem were summarized in a special EUR report about the Neutron Radiography Working Group Test Program[8/ published in 1989.

This conference offers the opportunity to cover all plastic working operations from primary processes such as rolling, extrusion and drawing to secondary processes such as sheet metal forming, forging, roll forming, stretch forming, spinning, and flow turning. This "horizontal" organization of the conference is overlaid by the "vertical" organization which covers fundamentals such as material science, theory of plasticity, tribology as common scientific and technical disciplines and, furthermore, the role of computers, e.g. in process modelling, process control, process simulation, CAD/CAM/CIM/CAE etc., as well as tools and, machine tools including flexible manufacturing cells and systems.

Among various branches of polymer physics an important position is occupied by that vast area, which deals with the thermal behav ior and thermal properties of polymers and which is normally called the thermal physics of polymers. Historically it began when the un usual thermo-mechanical behavior of natural rubber under stretch ing, which had been discovered by Gough at the very beginning of the last century, was studied 50 years later experimentally by Joule and theoretically by Lord Kelvin. This made it possible even at that time to distinguish polymers from other subjects of physical investigations. These investigation laid down the basic principles of solving the key problem of polymer physics - rubberlike elasticity - which was solved in the middle of our century by means of the statistical thermodynamics applied to chain molecules. At approx imately the same time it was demonstrated, by using the methods of solid state physics, that the low temperature dependence of heat capacity and thermal expansivity of linear polymers should fol low dependencies different from that characteristic of nonpolymeric solids. Finally, new ideas about the structure and morphology of polymers arised at the end of the 1950s stimulated the development of new thermal methods (differential scanning calorimetry, defor mation calorimetry), which have become very powerful instruments for studying the nature of various states of polymers and the struc tural heterogeneity."

DEFECTS AND TRANSPORT IN OXIDES is the proceedings of the eighth Battelle Colloquium in the Materials Sciences, held in Columbus and Salt Fork, Ohio, September 17-22, 1973. It took as its theme the relationship between defects and transport of both mass and charge in oxides. Applications of defect-controlled transport to a number of important processes in oxides also were covered. In selecting this topic, the Organizing Committee thought that 1973 was timely to bring together the leading theoretical and experimental researchers in the oxide transport field to review its status in a critical way, and to consider current major research directions and how research in the future might be guided into fruitful areas. The meeting was highlighted by the presentation of several papers which suggest that major advances in our understanding of transport in oxides appear to be imminent. These papers dealt with the results of new theoretical approaches whereby the energies and configurations of defects may be calculated, and with new experimental techniques for indirectly observing these defects, previously thought to be below the limits of experimental resolving power. Other papers, dealing with the application of defect chemistry to technological processes, served to demonstrate the successes and to point out yet unresolved problems associated with ix x PREFACE understanding the chemistry of imperfect crystals.

Liquid crystal polymers (LCPs) have many strange properties that may be utilized to advantage in the processing of products made from them and their blends with isotropic polymers. This volume (volume 2 in the series Polymer Liquid Crystals) deals with their strange flow behaviour and the models put forward to explain the phenomena that occur in such polymers and their blends. It has been known for some time that small ad ditions of a thermotropic LCP to isotropic polymers not only gives an improvement in the strength and stiffness of the blend but improves the processability of the blend over that of the isotropic polymer. In the case of lyotropic LCPs, it is possible to create a molecular composite in which the reinforcement of an isotropic polymer is achieved at a molecular level by the addition of the LCP in a common solvent. If the phenomena can be fully understood both the reinforcement and an increase in the proces sability of isotropic polymers could be optimized. This book is intended to illustrate the current theories associated with the flow of LCPs and their blends in the hope that such an optimization will be achieved by future research. Chapter 1 introduces the subject of LCPs and describes the ter minology used; Chapter 2 then discusses the more complex phenomena associated with these materials. In Chapter 3, the way in which these phe nomena may be modelled using hamiltonians is fully covered."

The Army Materials and Mechanics Research Center has conducted the Sagamore Army Materials Research Conferences, in cooperation with the Metallurgical Research Laboratories of the Department of Chemical Engineering and Metallurgy of Syracuse University, since 1954. The purpose of the conferences has been to gather together scientists and engineers from academic institutions, industry, and government who are uniquely qualified to explore in depth a subject of importance to the Army, the Department of Defense and the scientific corr.munity. This volume, Surfaces and Interfaces ll: Physical and Mechanical Properties, can be considered a continuation, or perhaps an extension, of the information contained in Surfaces and Interfaces I: Chemical and Physical Characteristics. The emphasis in this volume is focused on: the technological significance of surfaces and interfaces; surface sensitive mechanical properties; environment-sensitive properties; control of grain structure; and composite materials. It is felt that the rather ambitious undertaking of the program committee to place the role of "surfaces and interfaces" in its proper context has been achieved. The balance between basic research findings and more applied research allows the reader a certain degree of latitude in the use of the two volumes. The continued active interest and support of these conferences by Col. C. T. Riordan, Commanding Officer, Dr. E. Scala, Technical Di rector, and J. F. Sullivan, Deputy Technical Director, of the Army Materials and Mechanics Research Center is appreciated."

Electrometallurgy is a broad field but it is not a new one. It was the great Faraday in the 1830s who discovered laws covering the electrodeposition of metals and its relation to the current passed and equivalent weight of the metal undergoing depo- tion. Since that time, applications and developments of his discoveries have spread to many areas of technology. Electrowinning is the most well known, partly because it embraces the process by which aluminum is extracted from its ores. In electrorefining, the impure metal is made into anode and the pure metal dissolved therefrom is deposited on a cathode. Electroplating is exemplified by its use in the manufacture of car bumpers. Finally, in electroreforming, objects may be metallized, often with a very thin layer of the coating desired. The numerous technologies vary greatly in the degree to which they are intell- tualized. Until the work of Popov et al. , electrometallurgy has been regarded as largely empirical, an activity in which there was much art and little science. This will all change with the publication of this book. Several aspects of the background of its senior author, Konstantin Popov, make him uniquely suited to the job of intellectual- ing electrometallurgy. First, he had as his mentor the great surely the leading electrochemist in Eastern Europe since the death of Frumkin. Second, he has had ample experience with the leading electrochemical engineer in America, Ralph White.

In this introductory chemical physics textbook, the authors discuss the interactions, bonding, electron density, and experimental techniques of free molecules, and apply spectroscopic methods to determine molecular parameters, dynamics, and chemical reactions.

I express my sincere gratitude to NATO Science Committee for granting me the financial award to organize and direct the Advanced Research Workshop on "MULTILAYERED and FIBRE-REINFORCED COMPOSITES: PROBLEMS AND PROSPECTS" that was held in Kiev, Ukraine, during the period of June 2 - 6, 1997, in collaboration with Professor S. A. Firstov of the Frantsevich Institute for Problems of Materials Science, National Academy of Sciences, Kiev, Ukraine. In this context I wish to convey special thanks to Dr. J. A. Raussell-Colom, NATO Programme Director for Priority Area on High Technology, for his kind efforts and continuous guidance in the course of organizing the Workshop. I appreciate sincerely the opportunity of working closely with Professor Firstov and acknowledge with deep gratitude his outstanding contribution in co-directing the Workshop. I wish to express my special thanks to Dr. N. Orlovskaya of the Frantsevich Institute, for her outstanding contribution towards both the organization and conduct of the Workshop. I wish to convey my sincere thanks to Professor V. V. Skorohord, Deputy Director of the Frantsevich Institute, on behalf of the same Institute, for hosting the Workshop and welcoming the participants to l{iev. The very kind efforts of the members of the Scientific Advisory Committee, the Local Organizing Committee and the Staff of the Frantsevich Institute towards the organization and conduct of the Workshop, are gratefully appreciated. I convey my full indebtedness to all researchers who participated in the Workshop."

In our earlier monograph "Mlcrohardness of Metals" [1], published in 1962, we attempted to correlate a variety of investigations scattered throughout a number of journals with the gen- eral theme of solving problems of physicochemical analysis and metallography by microhard- ness measurements. The publication of "Microhardness of Metals" promoted the widespread use of this tech- nique in studying physicochemical phenomena in various materials. In recent years the micro- hardness method has been used most extensively in studying semiconducting materials, and this has necessitated the revision of the monograph with the aim of incorporating new experi- mental data relating to both metals and semiconductors. The greater proportion of the material presented in this book reflects the authors' own investigations. other investtgations associated with the use of the microhardness method in tOO physicochemical analysis of metallic and semiconducting systems are also taken into account. The authors are extremely indebted to Academician G. G. Urazov for his great interest in this work at its inception and for a number of valuable comments regarding the possibility of using the microhardness technique in physicochemical analysis. Sincere thanks are extended to Academician A. A. Bochvar and Professors A. N. Krestov- nikov, M. M. Khrushchov, M. V. Mal'tsev, M. V. Zakharov, and I. I. Novikov for their interest in these investigations.

This book is designed for the chemist, formulator, student, teacher, forensic scientist, or others who wish to investigate the composition of polymeric materials. Theinformationwithinthesepagesisintendedtoarmthereaderwiththenecessary workingknowledgetoanalyze,characterize, anddeformulatematerials. ThestructureoftheContentsisintendedtoassistthereaderinquicklylocating the subject of interest and proceed to it with a minimum of expended time and effort. The Contents provides an outline of major topics and relevant materials char- terizedforthereader'sconvenience. Anintroductiontoanalysisanddeformulation is provided in Chapter 1 to acquaint the reader with analytical methods and their applications. Extensive references are provided as additional sources ofinfor- tion. All tables arelocatedin theAppendix, beginning onp. 235. GUIDE FOR USE This is a practical book structured to efficiently use the reader's time with a minimum effort of searching for entries and information by following these brief instructions: 1. Searchthe Contents and/orIndex fora subject withinthe text. 2. Analysis/deformulation principles are discussed at the outset to familiarize the reader with analysis methods and instruments; followed by formu- tions, materials, and analysis ofpaint, plastics, adhesives, and inks; and finally reformulation methods to test the results of analysis. 3. Materials and a wide assortment of formulations are discussed within the text by chapter/section number. 4. Materials are referred toby various names (trivial, trade, and scientific), and these are listed in tables and cross-referenced to aid the reader.

This and its companion Volume 2 chronicle the proceedings of the First Technical Conference on Polyimides: Synthesis, Char acterization and Applications held under the auspices of the Mid Hudson Section of the Society of Plastics Engineers at Ellenville, New York, November 10-12, 1982. In the last decade or so there has been an accelerated interest in the use of polyimides for a variety of applications in a number of widely differing technologies. The applications of polyimides range from aerospace to microelectronics to medical field, and this is attributed to the fact that polyimides offer certain desirable traits, inter alia, high temperature stability. Polyimides are used as organic insulators, as adhesives, as coat ings, in composites, just to name a few of their uses. Even a casual search of the literature will underscore the importance of this class of materials and the high tempo of R&D activity taking place in the area of polyimides. So it was deemed that a conference on polyimides was both timely and needed. This conference was designed to provide a forum for discussion of various ramifications of polyimides, to bring together scientists and technologists interested in all aspects of polyimides and thus to provide an opportunity for cross-pollination of ideas, and to highlight areas which needed further and intensi fied R&D efforts. If the comments from the attendees are a baro meter of the success of a conference, then this event was highly successful and fulfilled amply its stated objectives.