The combination of conductive polymer technology with the ability to produce nanofibres will facilitate major new developments in biotechnology and information technology, benefiting such areas as scaffolds for tissue engineering and drug delivery systems; wires, capacitors, transistors and diodes; sensor technology; biohazard protection; and energy transport, conversion and storage. The work on nanofibrous materials presented here is designed, first of all, to instruct scientists in the most advanced methods for the formation of nanofibres and nanotubes. The second section covers the physics and chemistry of nanofibres, while the third deals with computer simulation and modelling. The applications described in section 4 include biomedical applications, nanotube-based devices, electronic applications of nanotubes and nanofibres, nanofluidics, and composites. Finally, the fifth section discusses recent developments in nanomaterials, nanoparticles and nanostructures.

Drawing a picture of the current situation of this new field, this volume both summarizes the past achievements and analyzes the present unsolved problems.

The state of development of composite materials is quite unique in the scientific world with simultaneous advances being made both in their usage and basic understanding. The complexity and high technology required in manufacturing structural parts with these materials as well as the need for fundamental description of their processing and property characteristics necessitates a close col laboration between industrial and academic researchers. This col laboration has become significant not only in solving specific tech nical problems, but in providing a much needed supply of scientists with training and background focused on anticipated demand for further advances in composite usage. The fact that the transportation industry with its current international character has a vital interest in composite materials for weight savings applications has provided a strong incentive for extending these developments beyond national boundaries. An excel lent example of an established international venture is the building of the new generation commercial aircraft by the Boeing Company with composite parts manufactured by Aerita1ia in Italy. Accordingly, we organized a Joint U. S. -Italy Symposium on Composite Materials in Italy which was successfully held on June 15-19, 1981, under the primary sponsorship of NSF in the U. S. A. and CNR in Italy. The strong support we also received from industrial co-sponsors, both from Italy and the U. S. A., as well as our respective academic insti tutions gave us confidence that we were addressing a timely and important area in Science and Engineering with a unique concept."

This book had its nucleus in some lectures given by one ofus (J. O'M. B. ) in a course on electrochemistry to students of energy conversion at the Vniversity of Pennsylvania. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all ofwhom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry wh ich could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importanee. Thus, conversion to electrochemically powered trans portation systems appears to be an important step by means of which the difficulties of air pollution and the effeets of an increasing concentration in the atmosphere of carbon dioxide may be met. Corrosion is recognized as having an electroehemical basis. The synthesis of nylon now contains an important electroehemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of Ameriean organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the Vnited States."

The production of multi layered thin films with sufficient reliability is a key technology for device fabrication in micro electronics. In the Co/Cu type multi layers, for example, magnetoresistance has been found as large as 80 % at 4. 2 K and 50 % at room temperature. In addition to such gigantic mag netoresistance, these multi layers indicate anti ferromagnetic and ferromag netic oscillation behavior with an increase in the thickness of the layers of the non magnetic component. These interesting properties of the new synthetic flmctional materials are attributed to their periodic and interracial structures at a microscopic level, although the origin of such peculiar features is not fully understood. Information on the surface structure or the number density of atoms in the near surface region may provide better insight. Amorphous alloys, frequently referred to as metallic glasses, are produced by rapid quenching from the melt. The second generation amorphous alloys, called "bulk amorphous alloys," have been discovered in some Pd based and Zr based alloy systems, with a super cooled liquid region at more than 120 K. In these alloy systems, one can obtain a sample thickness of several centime ters. Growing scientific and technological curiosity about the new amorphous alloys has focused on the fundamental factors, such as the atomic scale struc ture, which are responsible for the thermal stability with certain chemical compositions.

F.J. Balta-Calleja, A. Gonzalez Arche, T.A. Ezquerra, C. Santa Cruz, F. Batallan, B. Frick, G.A. Arche, E. Lopez Cabarcos, Structure and Properties of Ferroelectric Copolymers of Poly (vinylidene) Fluoride H.G. Kilian, T. Pieper Packing of Chain Segments: A Method for Describing X-Ray Patterns of Crystalline, Liquid Crystalline and Non-Crystalline Polymers K. Miyasaka PVA-Iodine Complexes: Formation, Structure and Properties

Shunsuke Hirotsu "Coexistence of Phases and the Nature of First-Order Transition in Poly-N-isopropylacrylamide Gels," Masayuki Tokita "Friction between Polymer Networks of Gels and Solvent," Masahiro Irie "Stimuli-Responsive Poly(N-isopropyl- acrylamide), Photo- and Chemicals-Induced Phases Transitions Edward Cussler, Karen Wang, John Burban"Hydrogels as Separation Agents," Stevin Gehrke "Synthesis, Equilibrium Swelling, Kinetics Permeability and Applications of Environmentally Responsive Gels," Pedro Verdugo "Polymer Gel Phase Transition in Condensation- Decondensation of Secretory Products," Etsuo Kokufuta "Novel Applications for Stimulus-Sensitive Polymer Gels in the Preparation of Functional Immobilized Biocatalysts," Teruo Okano "Molecular Design of Temperature-Responsive Polymers as Intelligent Materials," Atsushi Suzuki "Phase Transition in Gels of Sub-Millimeter Size Induced by Interaction with Stimuli," Makoto Suzuki, O. Hirasa "An Approach to Artificial Muscle by Polymer Gels due to Micro-Phase Separation."

Toyiochi Tanaka, Mitsuhiro Shibayama, "Phase Transitions and related Phenomena of Polymer Gels", Akira Onuki "Theory of Phase Transition in Polymer Gels", Alexei Khokhlov, Sergei Starodybtzev, Valentina Vasilevskaya "Conformational Transitions in Polymer Gels: Theory and Experiment", Michal Ilavsky " Effect on Phase Transition on Swellingand Mechanical Behavior of Synthetic Hydrogels", Shozaburo Saito , M. Konno, H. Inomata "Volume Phase Transition of N-Alkylacrylamide Gels", Ronald Siegel "Hydrophobic Weak Polyelectrolyte Gels: Studies of Swelling Equilibria and Kinetics".

During the last decades, continuum mechanics of porous materials has achieved great attention, since it allows for the consideration of the volumetrically coupled behaviour of the solid matrix deformation and the pore-fluid flow. Naturally, applications of porous media models range from civil and environmental engineering, where, e. g. , geote- nical problems like the consolidation problem are of great interest, via mechanical engineering, where, e. g. , the description of sinter materials or polymeric and metallic foams is a typical problem, to chemical and biomechanical engineering, where, e. g. , the complex structure of l- ing tissues is studied. Although these applications are principally very different, they basically fall into the category of multiphase materials, which can be described, on the macroscale, within the framework of the well-founded Theory of Porous Media (TPM). With the increasing power of computer hardware together with the rapidly decreasing computational costs, numerical solutions of complex coupled problems became possible and have been seriously investigated. However, since the quality of the numerical solutions strongly depends on the quality of the underlying physical model together with the experimental and mathematical possibilities to successfully determine realistic material parameters, a successful treatment of porous materials requires a joint consideration of continuum mechanics, experimental mechanics and numerical methods. In addition, micromechanical - vestigations and homogenization techniques are very helpful to increase the phenomenological understanding of such media.

During the last decades modelling of inelastic structural behaviour has achieved great attention. Wherever elastic designhas reached its limita sa consequence of increased loading, the related cons titutive rela tions meanwhile have become part of the engineer's practice. However, new materials with complex behaviour, further increasing loads at higher temperatures, as well as the implementation of stronger security demands have led to theconsequence that the preferentially used phenomenological concepts need to be verified and improved continuously. Caused by the a priori non linear character oft he material rela tions, all equations fort he description of every new phenomenon need to be reconsidered. According to this, since about a decade the idea succeeds that constitutive relations which represent material behaviour more re alistically can not only be deduced phe nomenologicallyfrom the laws of continuum mechanics. Sincet he observed behaviour is caused by processes taking place on the microscale, these processes and mechanisms need to be taken into consideration when determining the constitutive relations. The formulation of proper micro macro relations actu ally is one of the main emphases in thermoplasticity in the international research. The intentiono ft he IUTAM Symposium on 'Micro and Macrostructural Aspects of Thermoplasticity', held at the Ruhr University of Bochum, Germany, from August 25 to 29, 1997, wast o bring together eminent scientistsworking i n different fields of thermoplasticity with the aim thatt hey may exchange their ideas and activate this interaction.

The liquid crystalline state may be identified as a distinct and unique state of matter which is characterised by properties which resembles those of both solids and liquids. It was first recognised in the middle of the last century through the study of nerve myelin and derivatives of cholesterol. The research in the area really gathered momentum, however, when as a result of the pioneering work of Gray in the early 1970's organic compounds showing liquid crystalline properties were shown to be suitable to form the basis of display devices in the electronic products. The study of liquid crystals is truly multidisciplinary and has attached the attention of physicists, biologists, chemists, mathematicians and electronics engineers. It is therefore impossible to cover all these aspects fully in two small volumes and therefore it was decided in view of the overall title of the series to concentrate on the structural and bonding aspects of the subject. The Chapters presented in these two volumes have been organised to cover the following fundamental aspects of the subject. The calculation of the structures of liquid crystals, an account of their dynamical properties and a discussion of computer simulations of liquid crystalline phases formed by Gay Berne mesogens. The relationships between molecular conformation and packing are analysed in some detail. The crystal structures of liquid crystal mesogens and the importance of their X ray scattering properties for characterisational purposes are discussed.

Over 100 scientists met at the IBM Research Laboratory in San Jose. California for a symposium on the Physics and Chemistry of Liquid Crystal Devices. The two-day meeting was intellectually stimulating with excellent oral presentations and with person-to-person discussions. The applications of liquid crystals have developed dramatically in the past ten years. In these few years, they have moved from being a laboratory curiosity to products in the market place. The first commercial application (1940's) of liquid crystals was the preparation of a light polarizer. The second commercial application was their use as temperature sensors. The third major application of liquid crystals dealt with commercial displays. Other current applications include polymeric and graphitic fibers and light attenuators. The future of liquid crystals looks very promising indeed. One can expect to see new fibers of qualities which will be superior to those presently known. Graphitic fibers or other physical forms of graphitic materials will be used as catalytic surfaces for chemical synthesis. In the display area. one can expect to see television screens using liquid crystals. Larger displays than are now used in wrist watches and pocket calculators will become available. Liquid crystals using color displays will become commercially practical. Watches. calculators and television screens will have color.

It was seven years ago this month when I had the pleasure of writing the Foreword to the Proceedings of the Eighth Conference on Thermal Conductivity hosted by TPRC/ Purdue University in 1968. Since then this Conference has developed to the point where one can say it has just entered a new phase. At its meeting in June 1975, the Board of Governors of the International Thermal Conductivity Conferences passed a resolution which formalizes two main policies that were felt to be desirable for a number of years, A key item of the resolution was for CINDAS/Purdue University to become the permanent Sponsor of the Conferences and in this capacity assist the Conferences in all matters which will result in the effective implementation of its goals and mission. In short, CINDAS will serve as a home base for the Conferences thus providing continuity and a permanent point of contact. CINDAS/Purdue University is pleased to accept this respons ibility as it is well within its mission to promote the advancement and dissemination of knowledge on thermophysica properties of matter. A second important aspect of the Conference resolution was the establishment of a policy to publish the Proceedings of future conferences on a continuing and uniform basis effective with this, the Fourteenth Conference."

Natural products like wool, leather or cotton are permeable to water vapor. Their complex fibrous structure makes it difficult to imitate this natural phenomenon by synthesis. This book discusses ways to obtain water vapor permeability by microporosity or through a hydrophilic structure. Various areas of application include the medical sector for implants and dialysis, the industrial sector for filtration or for processes requiring the slow release of substances, and the consumer sector for leather substitutes or performance textiles.

In Number 20 of Modern Aspects of Electrochemistry, we present chapters whose organization is typical for the series: They start with the most fundamental aspects and then work to the more complex. Thus, Jerry Goodisman gives us an interesting contribution on a subject in which he is one of the pioneers, the electron overlap contribution to the double layer potential difference. Closely related to this theme, but not always imbued with knowledge ofit, is the electron transfertheory, treated in this volume by the experienced author A. M. Kuznetsov ofthe Frumkin Institute. H. P. Agarwal is a well-known figure in the field of faradaic rectification, which he originated, and he now teils us about the more recent thinking in the field. On the other hand, Hector D. Abruna comes relatively new to us, and his field, that of X-ray interactions with electrodes, is new, too, but probably augers the trend for the future. The photoelectrochemical reduction of CO2 , described here by Isao Taniguchi from Kumamoto University, is a subject which will have much practical importance as the greenhouse effect continues. Finally, alu mi nu m in aqueous solutions and the physics of its anodic oxide is a subject which seems ever with us, and is described in its latest guise by Aleksandar Despie and Vitaly P. Parkhutik.

Optical Measurements, Modeling, and Metrology represents one of eight volumes of technical papers presented at the Society for Experimental Mechanics Annual Conference on Experimental and Applied Mechanics, held at Uncasville, Connecticut, June 13-16, 2011. The full set of proceedings also includes volumes on Dynamic Behavior of Materials, Mechanics of Biological Systems and Materials, Mechanics of Time-Dependent Materials and Processes in Conventional and Multifunctional Materials; MEMS and Nanotechnology; Experimental and Applied Mechanics, Thermomechanics and Infra-Red Imaging, and Engineering Applications of Residual Stress.

vi on geometric probability is included, students can be expected to create a few simple programs like those shown, but for other geometries. I am indebted to Tom Hare for critical reviews of the material and an endless enthusiasm to debate and derive stereological relationships; to John Matzka at Plenum Press for patiently instructing me in the intricacies of typesetting; to Chris Russ for helping to program many of these measurement techniques; and especially to Helen Adams, both for her patience with my creative fever to write yet another book, and for pointing out that the title, which I had intended to contrast to "theoretical stereology," can also be understood as the antonym of "impractical stereology." John C. Russ Raleigh,NC July, 1986 Chapter 1: Statistics 1 Accuracy and precision 1 The mean and standard deviation 5 Distributions 7 Comparison 13 Correlation 18 Nonlinear fitting 19 Chapter 2: Image Types 23 Planar sections 23 Projected images 25 Finite sections 28 Space-filling structures and dispersed phases 29 Types of images and contrast mechanisms 31 Sampling 32 Chapter 3: Manual Methods 35 Volume fraction 35 Surface density 38 Contiguity 41 Mean intercept length 42 Line density 43 Grain size determination 55 Curvature 48 Reticles to aid counting 49 Magnification and units 51 Chapter4: Size Distributions 53 Intercept length in spheres 53 Nonspherical shapes 57 Corrections for finite section thickness 59 Lamellae 61 Measurement of profile size 62 Nonspherical particles 69 vii Contents viii Chapter 5: Computer Metlwds 73