In our earlier monograph "Mlcrohardness of Metals" [1], published in 1962, we attempted to correlate a variety of investigations scattered throughout a number of journals with the gen- eral theme of solving problems of physicochemical analysis and metallography by microhard- ness measurements. The publication of "Microhardness of Metals" promoted the widespread use of this tech- nique in studying physicochemical phenomena in various materials. In recent years the micro- hardness method has been used most extensively in studying semiconducting materials, and this has necessitated the revision of the monograph with the aim of incorporating new experi- mental data relating to both metals and semiconductors. The greater proportion of the material presented in this book reflects the authors' own investigations. other investtgations associated with the use of the microhardness method in tOO physicochemical analysis of metallic and semiconducting systems are also taken into account. The authors are extremely indebted to Academician G. G. Urazov for his great interest in this work at its inception and for a number of valuable comments regarding the possibility of using the microhardness technique in physicochemical analysis. Sincere thanks are extended to Academician A. A. Bochvar and Professors A. N. Krestov- nikov, M. M. Khrushchov, M. V. Mal'tsev, M. V. Zakharov, and I. I. Novikov for their interest in these investigations.

This monograph written by two Chinese scientists of the younger generation opens a window into the world of thoughts on Mechanical Metallurgy in this fascinating area of our world, characterized by age old cultural heritage as weil as by its dynamic evolution into the future. Based on notions and names all so familiar to the western scientist, and regarding the subject from the point of view of the theoretical mechanical engineer (Yang) as weil as that of the materials and manufacturing engineer (Lee), the authors present a synthesis of both approaches and endeavour to guide the reader from basic theory to engineering applications. Between structural defects in the micrometer scale and the meter-measures of engineering components, the term of mesoplasticity is meant to place the reader right in the center: This is certainly achallenging enterprise, and the editor expresses his sincere wishes as to enrichment and stimulation which will emanate from this interesting book and its creative perspective. Prof. B. Ilschner March, 1993. Preface In the past two decades, enormous advances in materials and manufacturing tech nology have been achieved, which upgrade the material design, processing and precision manufacturing as quantitative and concise scientific disciplines. Rapid improvements on mechanics understanding have been instrumental in the above mentioned development. A topic of great interest and importance in plasticity re search has been the design and processing of materials themselves on the mesoscale to achieve the desired macroscopic properties."

We present an overview of the theoretical background and experimental re sults in the rapidly developing field of semiconductor quantum dots - systems 8 6 of dimensions as small as 10- -10- m (quasi-zero-dimensional) that contain a small and controllable number (1-1000) of electrons. The electronic structure of quantum dots, including the energy quan tization of the single-particle states (due to spatial confinement) and the evolution of these (Fock-Darwin) states in an increasing external magnetic field, is described. The properties of many-electron systems confined in a dot are also studied. This includes the separation of the center-of-mass mo tion for the parabolic confining potential (and hence the insensitivity of the transitions under far infrared radiation to the Coulomb interactions and the number of particles - the generalized Kohn theorem) and the effects due to Coulomb interactions (formation of the incompressible magic states at high magnetic fields and their relation to composite jermions), and finally the spin-orbit interactions. In addition, the excitonic properties of quantum dots are discussed, including the energy levels and the spectral function of a single exciton, the relaxation of confined carriers, the metastable states and their effect on the photoluminescence spectrum, the interaction of an exciton with carriers, and exciton condensation. The theoretical part of this work, which is based largely on original re sults obtained by the authors, has been supplemented with descriptions of various methods of creating quantum-dot structures."

The Army Materials and Mechanics Research Center of Water town, Massachusetts in cooperation with the Materials Science Group of the Department of Chemical Engineering and Materials Science of Syracuse University has conducted the Sagamore Army Materials Research Conference since 1954. The main purpose of these conferences has been to gather together over 150 scientists and engineers from academic institutions, industry and government who are uniquely qualified to explore in depth a subject of importance to the Department of Defense, the Army and the scientific community. This volume, RISK AND FAILURE ANALYSIS FOR IMPROVED PERFORMANCE AND RELIABILITY, addresses the areas of Techniques of Failure Analysis, Risk and Failure Analysis for Design Against Fracture, Risk and Failure Analysis for Design Against Fatigue, Elevated Temperature Effects, Environmental Effects, Systems Approach to Production Reliability Integration and Outlook - Emerging Needs and Techniques. We wish to acknowledge the dedicated assistance of Joseph M. Bernier of the Army Materials and Mechanics Research Center and Helen Brown DeMascio of Syracuse University throughout the stages of the conference planning and finally the publication of this book is deeply appreciated."

Ion Beam Analysis: Fundamentals and Applications explains the basic characteristics of ion beams as applied to the analysis of materials, as well as ion beam analysis (IBA) of art/archaeological objects. It focuses on the fundamentals and applications of ion beam methods of materials characterization. The book explains how ions interact with solids and describes what information can be gained. It starts by covering the fundamentals of ion beam analysis, including kinematics, ion stopping, Rutherford backscattering, channeling, elastic recoil detection, particle induced x-ray emission, and nuclear reaction analysis. The second part turns to applications, looking at the broad range of potential uses in thin film reactions, ion implantation, nuclear energy, biology, and art/archaeology. Examines classical collision theory Details the fundamentals of five specific ion beam analysis techniques Illustrates specific applications, including biomedicine and thin film analysis Provides examples of ion beam analysis in traditional and emerging research fields Supplying readers with the means to understand the benefits and limitations of IBA, the book offers practical information that users can immediately apply to their own work. It covers the broad range of current and emerging applications in materials science, physics, art, archaeology, and biology. It also includes a chapter on computer applications of IBA.

This volume, the proceedings of a 1998 international workshop, provides experimental evidence of the effects of correlation on the physical, chemical, and mechanical properties of materials, as well as the theoretical/computational methodology that has been developed for their study.

The synergism of the mechanics of nondestructive testing and the mechanics of materials response has great potential value in an era of rapid development of new materials and new applications for con ventional materials. The two areas are closely related and an advance in one area often leads to an advance in the other. As our understanding of basic principles increases, nondestructive testing is outgrowing the image of "black box techniques" and is rapidly becoming a legitimate technical area of science and engineering. At the present time, however, an understanding of the mechanics of nondestructive testing is lagging behind other advances in the field. The key to further development in the mechanics of nondestructive testing lies in the mechanics of the phenomena or response being investigated - a better understanding of materials response suggests better nondestructive test methods to investigate the response which, in turn, advances our understanding of materials response, and so on. With this approach in mind, the Materials Response Group of the Engineering Science and Mechanics Department at Virginia Polytechnic Institute and State University hosted a Conference on the Mechanics of Nondestructive Testing on September 10 through 12, 1980. Sponsors of the conference were the Army Research Office, the National Science Foundation, and the Engineering Science and Mechanics Department."

This volume constitutes the Proceedings of the November 7-9, 1977 Conference on PROCESSING OF CRYSTALLINE CERAMICS, held at North Carolina State University in Raleigh. It was the Fourteenth in a series of "University Conferences on Ceramic Science" initiated in 1964 and still coordinated by a founding group of four ceramic related institutions, of which North Carolina State University is a charter member, along with the University of California at Berkeley, Notre Dame University, and the New York State College of Ceramics at Alfred University. In addition, two other ceramic-oriented schools, the University of Florida and Case-Western Reserve University, have also hosted Conferences in the series. These research-oriented conferences, each uniquely concerned with a timely ceramic theme, have been well attended by audiences which typically were both inter national and interdisciplinary in character; their published Proceedings have been well received and are frequently cited. This three day conference was concerned with (a) scientific aspects of all process steps which must be combined and controlled effectively and sequentially in producing crystalline ceramics (both oxides and nonoxides), and (b) utilization of these principles in developing processes for several classes of advanced ceramics critical to present and future technology."

This book reviews recent advances in polymer swelling resulting from the use of novel microporous composite films. It offers a new approach to understanding sorption processes in polymer-liquid systems based on the molecular structures of the sorbed molecules and the repeat unit of the sorbent polymer. It is shown how the adsorption parameters obtained in these studies relate meaningfully with the Flory-Huggins interaction parameters. This implies that these adsorption parameters have relevance not only for swelling and drying of polymers, but also for other phenomena in which molecular sorption plays an important role, such as in chromatography and in membrane permeation.

Nanoindentation, Third Edition gives a detailed account of the most up-to-date research in this important field of materials testing. As in previous editions, extensive theoretical treatments are provided and explained in a clear and consistent manner that will satisfy both experienced and novice scientists and engineers. Additionally, numerous examples of the applications of the technique are provided directly from manufacturers of nanoindentation instruments. A helpful series of appendices provides essential reference information that includes a list of frequently asked questions. The new edition has been restructured to provide results of the latest research and developments in the field of mechanical testing while retaining the essential background and introductory, but authoritative nature, of the previous editions. The new edition also expands on the instrumentation and applications chapters by including material sourced direct from the instrument manufacturers in this field. Aimed at graduate student level, this book is designed to fill a need associated with the use of nanoindentation as a quantitative test method for mechanical properties of small volumes of materials.

The international seminar "Material Behavior and Physical Chemistry in Liquid Metal Systems" was organized by the Institute of Materials and Solid State Research of the Karlsruhe Nuclear Research Center (Karlsruhe, Federal Republic of Germany). The seminar was held at the Nuclear Engineering School of the center on March 24-26, 1981. The aim of the seminar was to give metallurgists, chemists,. and physicists working in different areas of the science and technology of liquid metals an opportunity to discuss the basic work and the need for further work in this field. Since the seminar was held near one of the laboratories which for the last few years has been engaged in liquid alkali metal studies, partic ipants also had an opportunity to observe modern equipment for liquid alkali metal research. Interest in the application of liquid metals as working fluids in energy production, conversion, and storage is increasing. The technology has already demonstrated its high standards, which make possible the operation of large sodium-cooled fast reactors. Past conferences have shown, however, that there is still a lack of basic knowledge and understanding. Therefore, the aim of the present seminar was to discuss basic work in detail, and most of the papers contributed to this objective.

Natural products like wool, leather or cotton are permeable to water vapor. Their complex fibrous structure makes it difficult to imitate this natural phenomenon by synthesis. This book discusses ways to obtain water vapor permeability by microporosity or through a hydrophilic structure. Various areas of application include the medical sector for implants and dialysis, the industrial sector for filtration or for processes requiring the slow release of substances, and the consumer sector for leather substitutes or performance textiles.

Sol--Gel--Optics encompasses numerous schemes for fabricating optical materials from gels -- materials such as bulk optics, optical waveguides, doped oxides for laser and nonlinear optics, gradient refractive index (GRIN) optics, chemical sensors, environmental sensors, and `smart' windows. Sol--Gel--Optics: Processing and Applications provides in-depth coverage of the synthesis and fabrication of these materials and discusses the optics related to microporous, amorphous, crystalline and composite materials. The reader will also find in this book detailed descriptions of new developments in silica optics, bulk optics, waveguides and thin films. Various applications to sensor and device technology are highlighted. For researchers and students looking for novel optical materials, processing methods or device ideas, Sol--Gel--Optics: Processing and Applications surveys a wide array of promising new avenues for further investigation and for innovative applications. (This book is the first in a new subseries entitled `Electronic Materials: Science and Technology).

Awarenes s of the great significance of surface consti- tution in understanding the behavior and perforITlance of ITlaterials has been growing in proportion to the ITleans which have becoITle available for surface study. Recent years have seen iITlportant advances in analytical tools and ITlethods; their applications to date will certainly suggest ITlany other fruitful lines of investigation. The Conference "Surfaces and Interfaces of Glass and CeraITlics" held at the New York State College of CeraITlics at Alfred University under the sponsorship of the U. S. ArITly Research Office, DurhaITl, and the National Aeronautics and Space AdITlinistration, in August 1973, was tenth in the Uni- versity Series in CeraITlic Science, held in rotation aITlong North Carolina State University, the University of California at Berkeley, the University of Notre DaITle and Alfred Uni- versity. The chapters are arranged in order of their particular eITlphasis beginning with those principally concerned with analytical ITlethods. Chapters dealing with friction and wear follow, highly topical in the present-day concern with effi- cient use of energy in finishing processes, on the one hand, and the avoidance of preITlature failure by frictional daITlage to ITloving parts on the other. Surface reactions are then considered, including the iITlportant questions of physiological interactions with ceraITlic candidates for prosthetic applica- tions. Material-ITlaterial interfaces and transition zones are discussed through exaITlples which include grain bound- aries in ceraITlics as well as interfaces aITlong various solid, liquid and gaseous phases.

The Army Materials and Mechanics Research Center has conducted the Sagamore Army Materials Research Conferences, in cooperation with the Metallurgical Research Laboratories of the Department of Chemical Engineering and Metallurgy of Syracuse University, since 1954. The purpose of the conferences has been to gather together scientists and engineers from academic institutions, industry, and government who are uniquely qualified to explore in depth a subject of importance to the Army, the Department of Defense and the scientific corr.munity. This volume, Surfaces and Interfaces ll: Physical and Mechanical Properties, can be considered a continuation, or perhaps an extension, of the information contained in Surfaces and Interfaces I: Chemical and Physical Characteristics. The emphasis in this volume is focused on: the technological significance of surfaces and interfaces; surface sensitive mechanical properties; environment-sensitive properties; control of grain structure; and composite materials. It is felt that the rather ambitious undertaking of the program committee to place the role of "surfaces and interfaces" in its proper context has been achieved. The balance between basic research findings and more applied research allows the reader a certain degree of latitude in the use of the two volumes. The continued active interest and support of these conferences by Col. C. T. Riordan, Commanding Officer, Dr. E. Scala, Technical Di rector, and J. F. Sullivan, Deputy Technical Director, of the Army Materials and Mechanics Research Center is appreciated."

Included is a presentation of configurational forces within a classical context and a discussion of their use in areas as diverse as phase transitions and fracture.

This volume constitutes the written proceedings of the Third International Conference on Materials SCience, held under the sponsorship of the Accademia Nazionale dei Lincei as the XIII summer course of the G. Donegani Foundation at Tremezzo, Italy, on September 4-15, 1972. The course of lectures was designed for scientists and engineers "d th a, wrking knowledge of electronic materials, who sought to extend their knowledge of the newest developments in the field. The rapid pace of research and exploratory development in electronic materials has led to a preSSing need for continuing awareness and assessment of new electronic materials, as well as renewal of information in the more traditional areas. Three classes of electronic materials were selected for the course. Semiconductors provide the foundation for solid state electronics and semiconductor devices represent the most sophisti cated and advanced application of materials science and engineering known to modern technology. Yet, the march of progress in semi conductors continues, unabated - new semiconductor materials are in the research stage, new process technology is being developed, and new devices are being conceived. The second class of materials dealt with in the course, magnetic alloys and insulators, also has a firm application base; for example, computer performance is often measured in terms of the size of the magnetic memory. The tailoring of materials to provide particular combinations of desired magnetic properties is an integral part of the development of the electronics, just as in the case of semiconductors."

Everything flows, so rheology is a universal science. Even if we set aside claims of such width, there can be no doubt of its importance in polymers. It joins with chemistry in the polymerisation step but polymer engineering is supreme in all the succeeding steps. This is the area concerned with the fabrication of the polymer into articles or components, with their design to meet the needs in service, and with the long and short term performance of the article or component. This is a typical area of professional engineering activity, but one as yet without its proper complement of professional engineers. An understanding of polymer rheology is the key to effective design and material plus process selection, to efficient fabrication, and to satisfactory service, yet few engineers make adequate use of what is known and understood in polymer rheology. Its importance in the flow processes of fabrication is obvious. Less obvious, but equally important, are the rheological phenomena which determine the in-service performance. There is a gap between the polymer rheologist and the polymer engineer which is damaging to both parties and which contributes to a less than satisfactory use of polymers in our society. It is important that this gap be filled and this book makes an attempt to do so. It presents an outline of what is known in a concise and logical fashion. It does this starting from first principles and with the minimum use of complex mathematics.

A number of significant changes have occurred in Advances in Solar Energy since Volume 1 appeared in 1982. The delays in publication of the second volume are the result of reorganization of the American Solar Energy Society, and the negotiation of a new publishing arrangement. Beginning with this volume, Advances is now published jointly by the Society and Plenum Press. The Editorial Board has been enlarged to be more representative of the different fields of solar energy conversion. Production of Advances is being expedited through the use of modern word processing equipment and the 'lEX typesetting-editing program. We have gone to a single-column format to ease the problems of presenting long equations, and we expect that the user of the volume will find it easy to read. The use of 'lEX will make last minute updates possible. The external appearance of the volume matches that of Volume 1. We expect that future volumes of this annual will be proceeding on schedule. We invite comments from users and correspondence from prospective authors of critical reviews. Karl W. Boer John A. Duffie CONTENTS CHAPTER 1 The Measurement of Solar Radiation Ronald Stewart, Daniel W. Spencer and Richard Perez 1.1 Abstract 1 1.2 Characteristics of Pyranometers ....................................... . 2 1.3 General Features of a Pyranometer ................................... . 3 1.3.1 Instrument Sensitivity 4 1.3.2 Response with Time 4 1.3.3 Sensitivity 4 1.3.4 Responsivity ................................................. .

The International Thermal Expansion Symposium was started in 1968 with the initiative of Messrs. R. K. Kirby and P. S. Gaa1. These Symposia cover the deve10pments and advances in theoretica1 and experimental studies of the thermal expansion of so lids and its relation to other re1ated properties, and provide a broad1y based forum for researchers active1y working in this fie1d to convene on a regular basis to exchange their ideas and experiences and report their findings and resu1ts. The Symposia have been se1f-perpetuating and are an examp1e of how a technica1 community with a common purpose can transcend the invisible artificia1 barriers between discip1ines and gather togeth- er in increasing numbers without the need of national publicity and continuing funding support, when they see something worthwhi1e going on. Of the first five Symposia on1y three pub1ished formal Pro- ceedings. However, effective with the Sixth Symposium in 1977 when our Center for Information and Numerica1 Data Analysis and Synthesis (CINDAS) of Purdue University became the permanent Spon- sor of the Symposia, a po1icy of pub1ishing formal Proceedings on a continuipg and uniform basis has been estab1ished. Thus, inc1ud- ing the present vo1ume, the fo110wing formal Proceedings have been pub1ished: Publisher Symposium Tit1e of Vo1ume and Year and Year 2nd SYMPOSIUM ON THERMAL EXPANSION OF American Institute SOLIDS, Journal of App1ied Physics, of Physics (1970) (1970) 41 (13), pp. 5043-5154 American Institute 3rd THERMAL EXPANSION - 1971 of Physics (1972) (1971) AlP Conference Proceedings No.

The International Conference on Fracture Mechanics Technology Applied to Material Evaluation and Structure Design was held in Melbourne, Australia, from August 10 to 13, 1982. It was sponsored jointly by the Australian Fracture Group and Institute of Fracture and Solid Mechanics at Lehigh University. Pro fessor G. C. Sih of Lehigh University, Drs. N. E. Ryan and R. Jones of Aeronau tical Research Laboratories served as Co-Chairmen. They initiated the organiza tion of this international event to provide an opportunity for the practitioners, engineers and interested individuals to present and discuss recent advances in the evaluation of material and structure damage originating from defects or cracks. Particular emphases were placed on applying the fracture mechanics tech nology for assessing interactions between material properties, design and opera tional requirements. It is timely to hold such a Conference in Australia as she embarks on technology extensive industries where safeguarding structures from pre mature and unexpected failure is essential from both the technical and economical points. view The application of system-type approach to failure control owes much of its success to fracture mechanics. It is now generally accepted that the discipline, when properly implemented, provides a sound engineering basis for accounting in teractions between material properties, design, fabrication, inspection and op erational requirements. The approach offers effective solutions for design and maintenance of large-scale energy generation plants, mining machineries, oil ex ploration and retrieval equipments, land, sea and air transport vehicles."

The investigation of scattering phenomena is a major theme of modern physics. A scattered particle provides a dynamical probe of the target system. The practical problem of interest here is the scattering of a low energy electron by an N-electron atom. It has been difficult in this area of study to achieve theoretical results that are even qualitatively correct, yet quantitative accuracy is often needed as an adjunct to experiment. The present book describes a quantitative theoretical method, or class of methods, that has been applied effectively to this problem. Quantum mechanical theory relevant to the scattering of an electron by an N-electron atom, which may gain or lose energy in the process, is summarized in Chapter 1. The variational theory itself is presented in Chapter 2, both as currently used and in forms that may facilitate future applications. The theory of multichannel resonance and threshold effects, which provide a rich structure to observed electron-atom scattering data, is presented in Chapter 3. Practical details of the computational implementation of the variational theory are given in Chapter 4. Chapters 5 and 6 summarize recent appli cations of the variational theory to problems of experimental interest, with many examples of the successful interpretation of complex structural fea tures observed in scattering experiments, and of the quantitative prediction of details of electron-atom scattering phenomena."