Significant experimental work is devoted to the preparation of one and zero dimensional semiconductor structures in view of future electronic and optical devices which involve quantum effects. The aim is good control in the realisation of nanometer structures both in vertical and lateral direction. Conventional processing techniques based on lithography face inherent problems such as limited resolution and surface defects caused by reactive ion etching. During the last few years several research groups started working on direct syntheses of semiconductor nanostructures by combining epitaxial growth techniques such as molecular beam epitaxy and chemical vapour deposition with pre patterning of the substrate wafers. Another idea is based on island formation in strained layer heteroepitaxy. Zero and one dimensional structures with dimensions down to a few atomic distances have been realised this way. An important point is that the size of the quantum structures is controlled within the epitaxial deposition in a self-adjusting process. The main subjects of the book are: Theoretical aspects of epitaxial growth, selfassembling nanostructures and cluster formation, epitaxial growth in tilted and non-(001) surfaces, cleaved edge overgrowth, nanostructure growth on patterned silicon substrates, nanostructures prepared by selective area epitaxy or growth on patterned substrates, in-situ etching and device applications based on epitaxial regrowth on patterned substrates. The experimental work mainly concentrated on GaAs/A1GaAs, GaAs/InGaAs, InGaP/InP and Si/SiGe based semiconductor heterostructures. Growth related problems received special attention. The different concepts for preparation of low dimensional structures are presented to allow direct comparison and to identify new concepts for future research work.

This edition of Thermodynamics is a thoroughly revised, streamlined, and cor rected version of the book of the same title, first published in 1975. It is intended for students, practicing engineers, and specialists in materials sciences, metallur gical engineering, chemical engineering, chemistry, electrochemistry, and related fields. The present edition contains many additional numerical examples and prob lems. Greater emphasis is put on the application of thermodynamics to chemical, materials, and metallurgical problems. The SI system has been used through out the textbook. In addition, a floppy disk for chemical equilibrium calculations is enclosed inside the back cover. It contains the data for the elements, oxides, halides, sulfides, and other inorganic compounds. The subject material presented in chapters III to XIV formed the basis of a thermodynamics course offered by one of the authors (R.G. Reddy) for the last 14 years at the University of Nevada, Reno. The subject matter in this book is based on a minimum number of laws, axioms, and postulates. This procedure avoids unnecessary repetitions, often encountered in books based on historical sequence of development in thermodynamics. For example, the Clapeyron equation, the van't Hoff equation, and the Nernst distribution law all refer to the Gibbs energy changes of relevant processes, and they need not be presented as radically different relationships.

Few scientific developments in recent years have captured the popular imagination like the subject of'biodegradable' plastics. The reasons for this are complex and lie deep in the human subconscious. Discarded plastics are an intrusion on the sea shore and in the countryside. The fact that nature's litter abounds in the sea and on land is acceptable because it is biodegradable - even though it may take many years to be bioassimilated into the ecosystem. Plastics litter is not seen to be biodegradable and is aesthetically unacceptable because it does not blend into the natural environment. To the environmentally aware but often scientifically naive, biodegradation is seen to be the ecologically acceptable solution to the problem of plastic packaging waste and litter and some packaging manufacturers have exploited the 'green' consumer with exaggerated claims to 'environmentally friendly' biodegradable packaging materials. The principles underlying environmental degradation are not understood even by some manufacturers of 'biodegradable' materials and the claims made for them have been categorized as 'deceptive' by USA legislative authorities. This has set back the acceptance of plastics with controlled biodegradability as part of the overall waste and litter control strategy. At the opposite end of the commercial spectrum, the polymer manufactur ing industries, through their trade associations, have been at pains to discount the role of degradable materials in waste and litter management. This negative campaign has concentrated on the supposed incompatibility of degradable plastics with aspects of waste management strategy, notably materials recycling."

The integration of top-down lithographic techniques with synthetic organic and inorganic technologies is a key challenge for the development of effective nanosca1e devices. In terms of assembly, nanoparticles provide an excellent tool for bridging the gap between the resolution of electron beam lithography (-60 nm) and the molecular level. Nanoparticles possess an array of unique properties associated with their core materials, including distinctive magnetic, photonic and electronic behavior. This behavior can be controlled and applied through monolayer functionalization and assembly strategies, making nanoparticles both scaffolds and building blocks for nanotechnology. The diverse structures and properties of nanoparticles makes them useful tools for both fundamental studies and pragmatic applications in a range of disciplines. This volume is intended to provide an integrated overview of the synthesis and assembly of nanoparticles, and their applications in chemistry, biology, and materials science. The first three chapters focus on the creation and intrinsic properties of nanoparticles, covering some of the myriad core materials and shapes that have been created. The remaining chapters of the book discuss the assembly of nanoparticles, and applications of both discrete particles and particle assemblies in a wide range of fields, including device and sensor fabrication, catalysis, biology, and nanosca1e electronic and magnetic systems.

Flammability has been recognized as an increasingly important social and scientific problem. Fire statistics in the United States (Report of the National Commission on Fire Prevention and Control. "America Burning: ' 1973) emphasized the vast devastation to life and property--12.000 lives lost annually due to fire. and these deaths are usually caused by inhaling smoke or toxic gases: 300.000 fire injuries: 11.4 billion dollars in fire cost at which 2.7 billion dollars is related to property loss: a billion dollars to burn injury treatment: and 3.3 billion dollars in productivity loss. It is obvious that much human and economic misery can be attributed to fire situations. In relation to this. polymer flammability has been recognized as an in creasingly important social and scientific problem. The development of flame-retardant polymeric materials is a current example where the initia tive for major scientific and technological developments is motivated by sociological pressure and legislation. This is part of the important trend toward a safer environment and sets a pattern for future example. Flame retardancy deals with our basic everyday life situations-housing. work areas. transportation. clothing and so forth-the "macroenvironment" capsule within which "homosapiens" live. As a result. flame-retardant polymers are now emerging as a specific class of materials leading to new and diversified scientific and technological ventures."

A critical, up to date, tutorial review and discussion of the science and technology of nanostructured metallic and ceramic materials. The focus is on the synthesis and processing of nanoparticles, the assembly and stability of nanostructures, characterization and properties, and applications. There is a growing interest in the processing of nanoparticles into consolidated bulk materials and coatings. The metastability of nanoparticles may lead to undesirable grain growth during thermally assisted consolidation or other processing routes, and the retention of nanostructures in a processed part or component continues to attract a great deal of attention. Current activity is concentrating on the deposition of nanostructured coatings using established thermal spray technology and wet chemistry methods. Naturally existing or artificially synthesized templates with unique structures and morphologies have been used to fabricate nanostructured materials with the same structural and morphological characteristics as the templates. Recent advances in characterization techniques have provided information on the structure, the surface and bulk chemistry of nanoparticles, and the structures and chemistry of exposed and buried surfaces of coatings. Contributors are drawn from Canada, France, UK, USA, Belarus, Russia and Ukraine.

This is a book on one of the most fascinating and controversial areas in contemporary science of carbon, chemistry, and materials science. It concisely summarizes the state of the art in topical and critical reviews written by professionals in this and related fields.

Covering both the theoretical and applied aspects of electrochemistry, this well-known monograph series presents a review of the latest advances in the field.

This volume had its birth from a symposium organized by the Macromolecular Secretariat of the American Chemical Society in Atlanta, GA, 1991. Since Macromolecular SeCretariat has five participating divisions-Polymer Chemistry; Polymer Materials: Science and Engineering Division; Colloid and Surface Chemistry Division; Cellulose, Paper and Textile Division; and Rubber Division-the speakers were invited from these disciplinaries and they are truly interdisciplinary in multidisciplinary areas. A number of papers are from the presentations at this symposium. However, some papers were subsequently invited to be sent in. Therefore, many papers have cited references with dates as late as this current year. This book emphasizes applications, and some of the papers were finished in 1993. Therefore, it is timely for scientists and engineers interested in this area of progress. For scientists and engineers who are not familiar with this field, since the development is still youthful, this volume will cover some new frontiers, such as electronics, medical devices, fossil fuels, asphaltics, geochemistry, and environmental engineering. With that in mind, this book can be very useful as a reference. We do include a number of review papers . in this volume. In summary, this book contains sixteen chapters with twenty-eight authors from various organizations and specialties."

In recent years, the technology of cryogenic comminution has been widely applied in the field of chemical engineering, food making, medicine production, and particularly in recycling of waste materials. Because of the increasing pollution of waste tires and the shortage of raw rubber resource, the recycling process for waste rubber products has become important and commercially viable. This technology has shown a great number of advantages such as causing no environmental pollution, requiring low energy consumption and producing high quality products. Hence, the normal crusher which was used to reclaim materials, such as waste tires, nylon, plastic and many polymer materials at atmospheric 12 temperature is being replaced by a cryogenic crusher. * In the cryogenic crusher, the property of the milled material is usually very sensitive to temperature change. When a crusher is in operation, it will generate a great deal of heat that causes the material temperature increased. Once the temperature increases over the vitrification temperature, the material property will change and lose the brittle behavior causing the energy consumption to rise sharply. Consequently, the comminution process cannot be continued. Therefore, it is believed that the cryogenic crusher is the most critical component in the cryogenic comminution system. The research on the temperature increase and energy consumption in the cryogenic crusher is not only to reduce the energy consumption of the crasher, but also to reduce the energy consumption of the cryogenic system.

Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance.

With collaborative product development in a geographically distributed environment and global outsourcing becoming normal for many companies, it is imperative to bring academics, researchers and industrialists together to share research ideas and best practice. The European-Asia Symposium on Engineering Design and Manufacture (EASED 2004) provides such a platform and aims to increase the exchange of ideas and best practice among practitioners and researchers from two major global regions - Europe and Asia. As the manufacturing activities, associated with the design activities in European, American and Japan, are being transferred to Asia, it is timely to organise this International Symposium. The Symposium brings together research experts and industrialists to focus on the issues related to these global changes. This geographical distribution of tasks involved in the whole engineering product realisation process brings great challenge as well as huge benefits. This Symposium provides a platform for academic researchers and industrial practitioners to exchange ideas used to address the challenges presented by this new global economic development. This book presents 75 papers from 185 accepted refereed papers presented at EASED2004.

Superconductors with high critical temperatures are extremely complex and it remains difficult to synthesize high quality samples. In this regard, the materials and crystallographic aspects, drawing together the fields of structural chemistry and physics, solid state chemistry and physics, and applications and properties, both for cuprate and organic superconductors, play a vital role in our understanding of the phenomenon. Among other things, the contributions to local structural elucidation contained in the present work will shatter the reader's prejudices concerning the idealized average structure.

Materials that can mold the ?ow of elastic waves of certain energy in certain directions are called phononic materials. The present thesis deals essentially with such phononic systems, which are structured in the mesoscale (\1 lm), and with their individual components. Such systems show interesting phononic properties in the hypersonic region, i.e., at frequencies in the GHz range. It is shown that colloidal systems are excellent model systems for the realization of such phononic materials. Therefore, different structures and particle architectures are investigated by Brillouin light scattering, the inelastic scattering of light by phonons. Both the mechanical properties of the individual colloidal particles, which manifest in their resonance vibrations (eigenmodes), as well as the acoustic propagation in colloidal structures have been investigated. The measurement of the eigenmodes allows for new insights into physical properties at the mesoscale, e.g., con?nement effects, copolymer behavior, or the non-destructive determination of nanomechanical properties of core-shell particles, supporting the working groups aim to achieve a deeper understanding of 'soft mechanics' at small length scales. Another novel contribution assigned to this thesis is the ?rst experimental rea- zation of a phononic band gap arising from the interaction of these particle - genmodes with the effective medium band (hybridization gap). This ?nding already gave new impulses to the whole ?eld of phononics.

This book presents the proceedings of the Second International Conference on Frontiers of Polymers and Advanced Materials held in Jakarta, Indonesia during January 10-15, 1993. This conference was organized and sponsored by the Indonesian Institute of Sciences (LIPI), the State University of New York (SUNY) at Buffalo, the Agency for Assessment and Application of Technology (BPPT), and the Indonesian Polymer Association. The 244 participants represented a total of 24 countries and a wide variety of academic, industrial and government groups. The inauguration was held in the Royal Palace and was performed by President Soeharto of Indonesia. High level media coverage ensured worldwide recognition. The need for such a conference was emphasized by the fact that polymers have emerged as an important class of materials offering challenging opportunities for both fundamental research and new technological applications. There has been a tremendous growth of interest in the field of polymers, both in academia and in industry, and polymer science offers tremendous opportunities for both fundamental and applied work. This globally represented Second International Conference on Frontiers of Polymers and Advanced Materials was timely, especially given the current heightened enthusiasm for polymers and emerging novel applications.

The Conference on the Science and Technology of Thin Film Superconductors was conceived in the early part of 1988 as a forum for the specialist in thin film superconductivity. The conference was held on November 14-18, 1988, in Co lorado Springs, Co lorado. Al though many excellent superconductivity conferences had been convened in the wake of the 1986-1987 discoveries in high temperature superconductivity, thin film topics were often dispersed among the sessions of a more general conference agenda. The response to the Conference on the Science and Technology of Thin Film Superconductors confirmed the need for an extended conference devoted to thin film superconductors. These proceedings are a major contribution to the technnology of thin film superconductivity because of the breadth and quality of the articles provided by leaders in the field. The proceedings are divided into articles on laser deposition, sputtering, evaporation, metal organic chemical vapor deposition, thick film, substrate studies, characterization, patterning and applications, and general properties. Most of the articles discuss scientific issues for high temperature thin film superconductors, although the conference was to be a forum for technology and scientific questions for both low and high temperature superconductivity. For the first day of the 5 day conference, Lawrence Berkeley Laboratory had organized an excellent set of short courses in superconduc t ing thin film devices.

Polymer Latices, Second Edition is a comprehensive update of the previous edition, High Polymer Latices, taking into account the many developments since it was first published in 1966. It is the only publication to provide such an outstanding and extensive review of latex science and technology, from background theory and principles, to modern day applications. It will prove an invaluable reference source for all those working in the area of latex science and technology, such as colloid chemists, polymer scientists, and materials processors.

The 2001 Dutch Sensor Conference held on 14 -15 May 2001, at the University of Twente in Enschede, The Netherlands, is the fourth in a series ofmeetings. The conference is initiated by the Dutch Technology Foundation (STW) in order to stimulate the industrial application ofsensor research. This MESA Monograph contains a collection oflatest research and development from all major Dutch centers ofsensor research and aspect ofsensor commercialization. Thus it provides an excellent overview ofthe state ofthe art ofDutch Sensor Technology in the new millennium. I should like to acknowledge the work ofthe program committee, the local organizing committee and, ofcourse, the contributors to this volume. All ofthem made the conference a success. Prof. Dr. Miko Elwenspoek Conference Chairman Program Committee: M. Elwenspoek (Chairman) (MESA+) A.van den Berg (MESA+) PJ. French (TV Delft) P.V. Lambeck (MESA+) H. Leeuwis (3T) J.c. Lotters (Bronkhorst) HAC. Tilmans (IMEC) Contents MEASUREMENT SYSTEM FOR BIOCHEMICAL ANALYSIS BASED 1 ON CAPILLARY ELECTROPHORESIS AND MICROSCALE CONDUCTIVITY DETECTION F. Laugere, A. Berthold, R.M Guijt, E. Baltussen, J. Bastemeijer, P.M Sarro, MJ. Vellekoop ELECTRO-OSMOTIC FLOW CONTROL IN MICROFLUIDICS 7 SYSTEMS R.E. Oosterbroek,MH. Goedbloed, A. Trautmann, N.J. van der Veen, S Schlautmann, 1.W Berenschot, A. van den Berg FLOW SENSING USING THE TEMPERATURE DISTRIBUTION 13 ALONG A HEATED MICROBEAM J.J. van Baar, RJ Wiegerink,GJM Krijnen, T.SJ. Lammerink, M.C.

The area of macromolecular and supramolecular science and engineering has gained substantial interest and importance during the last decade and many applications can be envisioned in the future. The rapid developments in this interdisciplinary area justify a snapshot of the state-of-the-art in the research of materials and processes that is given in this monograph. This monograph is based primarily on synthetic architectures and systems covered by the contents of selected plenary and invited lectures delivered at the 1st International Symposium on Macro- and Supramolecular Architectures and Materials (MAM-01): Biological and Synthetic Systems, which was held from 11-14 April 2001 on the international campus of the Kwangju Institute of Science and Technology (K-JIST) in Kwangju, South Korea. In addition, it contains several complementing contributions in this novel field of science dealing with synthetic architectures and represents a unique compilation of reviewed research accounts of the in-depth knowledge of macromolecular and supramolecular materials and processes. It comprises 22 pioneering chapters written by 64 renowned experts from 13 different countries.

Although, carbon is only one of one hundred plus elements, the polymer science lit erature consists primarily of studies on carbon based polymers. In part, this reflects the varied feedstock sources and in part, the type of bonds and bond forming reactions avail able to form organic polymers that are not available to the inorganic and organometallic chemist. However, recent intense interest in polymers with novel optical, electronic or magnetic properties or polymers that can serve as precursors to ceramic, semiconductor, metallic or superconductor materials has served as a driver for the development of novel synthetic routes and characterization techniques that have launched many new inorganic and organometallic oligomers and polymer systems. The following chapters represent an effort to provide an overview of several new and continuing areas of development in inorganic and organometallic polymer science. This book represents the second in a series of books we have edited on inorganic and organometallic polymer chemistry (1. Transformation of Organo-metallics into Common and Exotic Materials, NATO ASI Series Vol 141. 3. Inorganic and Organometallic Polymers with Special Properties, NATO ASI Series in press). In this series, we attempt to develop, for the reader, an understanding of the breadth, depth and potential of inorganic and organometallic polymer science."

Purpose ofthe Workshop In the spirit of enhancing developments in science and technology by facilitating international scientific cooperation, the Science Committee of NATO is sponsoring AR W's in several selected priority areas. The objective of this workshop was to discuss what microbial mediated problems have been experienced in the area of nuclear waste management and spent fuel storage. Long term storage of high-level wastes in repositories is just starting in some countries. However, low and medium level wastes have been stored for several decades. In the area of spent fuel interim, storage has been extended at many locations far beyond the intended time. It was a priority of the workshop to examine and discuss what deleterious effects have been observed under these storage conditions or under conditions used in simulated trial tests for predicting material performance under the storage conditions. For example, one chronic problem that was discussed was possibility that microbial influenced corrosion (MIC) could be taking place in the wet storage of spent fuel thereby initiating or accelerating the process of corrosion. Another discussion in the area of waste forms, focused on the presence ofbiofilms which may be breaking down the structure of the waste form and thereby jeopardizing its integrity. The meeting focused on discussing the observations and data collected relating to problems encountered in the storage of these types of wastes, and sharing this information with others that have not monitored their facilities for similar problems.

This is the first comprehensive resource of power device electrical characteristics in a cryogenic environment. Using theoretical and experimental knowledge from the literature, temperature dependence of fundamental silicon material parameters like intrinsic carrier concentration, carrier mobilities, lifetimes and bandgap narrowing was identified. The temperature dependent model of avalanche breakdown was developed using experimental data on numerous devices. A wide range of power devices, each with its own unique features, was chosen for theoretical and experimental analysis. Using these analyses, Schottky diodes, power MOSFETs, power BJTs, and power JFETs were optimized in the 300-77K temperature range. Cryogenic Operation of Silicon Power Devices presents the different characteristics of power devices operated below -55 C (220K). It provides data and physics based models for power devices operated at temperatures down to 77K for the first time within a single source. All commercially available devices have been included to provide comprehensive coverage.Also, a fundamental analysis of devices identifies the suitability of various devices to applications requiring cryogenic operations. A quantitative analysis of the relative strengths and weaknesses of these devices is also presented.

Modern manufacturing industry is focusing its interests on the potential offered by the laser, in combination with other new technologies such as optical fibres, automation, computing and flexible manufacturing systems, to give new and powerful methods for non-destructive testing, in-process quality assurance, laser material processing and process control, and laser robotics. The greatest opportunities for the laser are in those areas where flexibility, automation, CAD/CAM integration, precision, cost reduction, and time to market are important factors. The examples covered here are mainly drawn from the automotive industry, where all these factors are imperative, and where the CO2, Nd-YAG and excimer laser sources are already making their contribution to the manufacturing process.

Polycrystalline Silicon for Integrated Circuits and Displays, Second Edition presents much of the available knowledge about polysilicon. It represents an effort to interrelate the deposition, properties, and applications of polysilicon. By properly understanding the properties of polycrystalline silicon and their relation to the deposition conditions, polysilicon can be designed to ensure optimum device and integrated-circuit performance. Polycrystalline silicon has played an important role in integrated-circuit technology for two decades. It was first used in self-aligned, silicon-gate, MOS ICs to reduce capacitance and improve circuit speed. In addition to this dominant use, polysilicon is now also included in virtually all modern bipolar ICs, where it improves the basic physics of device operation. The compatibility of polycrystalline silicon with subsequent high-temperature processing allows its efficient integration into advanced IC processes. This compatibility also permits polysilicon to be used early in the fabrication process for trench isolation and dynamic random-access-memory (DRAM) storage capacitors. In addition to its integrated-circuit applications, polysilicon is becoming vital as the active layer in the channel of thin-film transistors in place of amorphous silicon. When polysilicon thin-film transistors are used in advanced active-matrix displays, the peripheral circuitry can be integrated into the same substrate as the pixel transistors. Recently, polysilicon has been used in the emerging field of microelectromechanical systems (MEMS), especially for microsensors and microactuators. In these devices, the mechanical properties, especially the stress in the polysilicon film, are critical to successful device fabrication. Polycrystalline Silicon for Integrated Circuits and Displays, Second Edition is an invaluable reference for professionals and technicians working with polycrystalline silicon in the integrated circuit and display industries.

Gaseous Dielectrics VIII covers recent advances and developments in a wide range of basic, applied, and industrial areas of gaseous dielectrics.