This book is chiefly intended for those who are using microbicides for the protection of materials. Another purpose is to inform teachers and students working on biodeterioration and to show today's technical standard to those engaged in R&D activities in the microbicide field. When trying to classify, or to subclassify, material-protecting microbicides according to their mode of action, e.g. as membrane-active and electrophilic active ingredients, it turned out that a clear assignment was not always possible. For that reason the author has resorted to chemistry's principle of classifying according to groups of substances (e.g. alcohols, aldehydes, ketones, acids, esters, amides, etc.), thus providing the first necessary information about the micro bicides' properties. The description of the various groups of substances includes, whenever possible, an outline of the mode and mechanism of action of the active ingredients involved. The effective use of microbicides presupposes knowledge of their character istics. That is why the microbicides' chemico-physical properties, their toxicity, ecotoxicity, effectiveness, and effective spectrum are described in greater detail. As mentioned before, the characteristics of microbicides play an important role. They have to be suited to the intended application to avoid detrimental effects on the properties and the quality of the material to be protected; also production processes in which microbicides are used to avoid disturbances by microbial action must not be disturbed by the presence of those microbicides."

Since the publication of the first edition of The Physics of Glassy Polymers there have been substantial developments in both the theory and application of polymer physics, and many new materials have been introduced. Furthermore, in this large and growing field of knowledge, glassy polymers are of particular interest because of their homogeneous structure, which is fundamentally simpler than that of crystalline or reinforced materials. This new edition covers all these developments, including the emergence of the polymer molecule with its multiplicity of structure and conformations as the major factor controlling the properties of glassy polymers, using the combined knowledge of a distinguished team of contributors. With an introductory chapter covering the established science in the subject are and summarising concepts assumed in the later chapters, this fully revised and updated second edition is an essential work of reference for those involved in the field.

Purpose ofthe Workshop In the spirit of enhancing developments in science and technology by facilitating international scientific cooperation, the Science Committee of NATO is sponsoring AR W's in several selected priority areas. The objective of this workshop was to discuss what microbial mediated problems have been experienced in the area of nuclear waste management and spent fuel storage. Long term storage of high-level wastes in repositories is just starting in some countries. However, low and medium level wastes have been stored for several decades. In the area of spent fuel interim, storage has been extended at many locations far beyond the intended time. It was a priority of the workshop to examine and discuss what deleterious effects have been observed under these storage conditions or under conditions used in simulated trial tests for predicting material performance under the storage conditions. For example, one chronic problem that was discussed was possibility that microbial influenced corrosion (MIC) could be taking place in the wet storage of spent fuel thereby initiating or accelerating the process of corrosion. Another discussion in the area of waste forms, focused on the presence ofbiofilms which may be breaking down the structure of the waste form and thereby jeopardizing its integrity. The meeting focused on discussing the observations and data collected relating to problems encountered in the storage of these types of wastes, and sharing this information with others that have not monitored their facilities for similar problems.

Modern manufacturing industry is focusing its interests on the potential offered by the laser, in combination with other new technologies such as optical fibres, automation, computing and flexible manufacturing systems, to give new and powerful methods for non-destructive testing, in-process quality assurance, laser material processing and process control, and laser robotics. The greatest opportunities for the laser are in those areas where flexibility, automation, CAD/CAM integration, precision, cost reduction, and time to market are important factors. The examples covered here are mainly drawn from the automotive industry, where all these factors are imperative, and where the CO2, Nd-YAG and excimer laser sources are already making their contribution to the manufacturing process.

An innovative, unified, and comprehensive treatment of the geometric and electronic structure of surfaces. The book emphasizes fundamental aspects, such as the principles of surface crystallography and thermodynamics, the forces driving the rearrangement of the atoms, and the relationship between bonding and electronic structure. It especially illuminates the relationship between surface orientation, chemistry, energetics, and the resulting properties. Principles of Surface Physics develops general physical arguments and methods that enable readers to analyse novel surfaces and interfaces of new materials. This makes the book an indispensable reference to all those studying growth, surface-molecule interactions, self-assembled structures, and materials engineering.

This conference is the second on the Science and Technology of Thin Film Superconductors. It proved to be an excellent forum for these specialists in thin film superconductivity. The conference, held April 30-May 4, 1990, in Denver, Colorado, hosted 170 researchers from 17 countries. The response to the conference again emphasized the need for a meeting devoted to the science and technology of thin film superconductors. The breadth of artic1es and advances made in this technology since the first conference in November 1988, reflect on the maturity of the topic. These proceedings contain artic1es on deposition methods by sputtering, e1ectron beam evaporation, resistive evaporation, laser ablation, chemical vapor deposition and electrodeposition, and on other studies related to substrates, thermodynamics of formation, grain boundaries and weak links, characterization, and some practical applications. The program committee was pleased with the quality of the publications and contributed articles. This conference was highlighted by a fuU day dedicated to presentations from the federallaboratories, discussing a wide range of topics on the fabrication, characterization, and theory of high-temperature superconductor thin films. Other highlights at the conference dealt with (1) critical parameters or problems in measuring critical current density and other important parameters, and (2) problems of scale-up, reproducibility, and amenability to device fabrication. It became evident from the presentations that three issues were developing into critical issues for the ultimate practical application of high temperature superconductor thin films."

The first U. S. Army Natick Research, Development and Engineering Center Atomic Force/Scanning Tunneling Microscopy (AFM/STM) Symposium was held on lune 8-10, 1993 in Natick, Massachusetts. This book represents the compilation of the papers presented at the meeting. The purpose ofthis symposium was to provide a forum where scientists from a number of diverse fields could interact with one another and exchange ideas. The various topics inc1uded application of AFM/STM in material sciences, polymers, physics, biology and biotechnology, along with recent developments inc1uding new probe microscopies and frontiers in this exciting area. The meeting's format was designed to encourage communication between members of the general scientific community and those individuals who are at the cutting edge of AFM, STM and other probe microscopies. It immediately became clear that this conference enabled interdisciplinary interactions among researchers from academia, industry and government, and set the tone for future collaborations. Expert scientists from diverse scientific areas including physics, chemistry, biology, materials science and electronics were invited to participate in the symposium. The agenda of the meeting was divided into three major sessions. In the first session, Biological Nanostructure, topics ranged from AFM ofDNA to STM imagmg ofthe biomoleeule tubulin and bacterialluciferase to the AFM of starch polymer double helices to AFM imaging of food surfaces.

This book is intended to help satisfy an urgent requirement for up-to date comprehensive texts at graduate and senior undergraduate levels on the subjects in non-destructive testing (NDT). The subject matter here is confined to electrical and magnetic methods, with emphasis on the widely used eddy current and magnetic flux leakage methods (including particle inspection), but proper attention is paid to other techniques, such as microwave and AC field applications, which are rapidly growing in importance. Theoretical analyses relating to the various methods are discussed and the depths of presentation are often governed by whether or not the information is readily available elsewhere. Thus, for example, a considerable amount of space is devoted to eddy current theory at what the author considers to be a reasonable standard and not, as usually experienced, in either a too elementary manner or at a level appreciated only by a postgraduate theoretical physicist. The inclusion of the introductory chapter is intended to acquaint the reader with some of the philosophy of NDT and to compare, briefly, the relative performances of the more important methods of testing."

Rail integrity is a current application of engineering fracture mechanics at a practical level. Although railroad rails have been manufactured and used for more than a century, it is only in the last ten years that the effects of their crack propagation and fracture characteristics have been considered from a rational viewpoint. The J, Jractical objectives are to develop damage tolerance delines for rail inspection and to improve the fracture resistance of new rail productiOn. Rail fatigue crack propagation rates and fracture resistance are strongly influenced by residual stresses, which are introduced into the rail both during proouction and in service. Therefore, the rail residual stress field must be well understood before fracture mechanics can be usefully applied to the subject of rail integrity. The three-dintensional character of rail and its stress fields make it essential to apply both experimental and analytical methods in order to twderstand the effects of pro duction and service variables on residual stress and the effects of the stress on fatigue crack propagation and fracture. This volume brings to ether field observations and experimental stress analysis of railroad rails in the Umted States and Europe. The ongoing search for an efficient and accurate technique is emphasized. A companion volume brings together several analytical investigations, based on advanced compu tational mechanics methods, for correlation of the experimental data as well as eval uation of the effects of residual stress on rail integrity."

The aim of the book is to present, in a novel and unified fashion, the elements of Mechanics in Material Space or Configurational Mechanics, with applications to fracture and defect mechanics. This mechanics, in contrast to Newtonian mechanics in physical space, is concerned with defects such as cracks and dislocations, which are embedded in the material and might move in it. The level is kept accessible to any engineer, scientist or graduate student possessing some knowledge of calculus and partial differential equations, and working in the various areas where rational use of materials is essential.

The NATO Advanced Research Workshop on Fundamental Aspects of Inert Gases in Solids, held at Bonas, France from 16-22 September 1990, was the fifth in a series of meetings that have been held in this topic area since 1979. The Consultants' Meeting in that year at Harwell on Rare Gas Behaviour in Metals and Ionic Solids was followed in 1982 by the Jiilich Inter national Symposium on Fundamental Aspects of Helium in Metals. Two smaller meetings have followed-a CECAM organised workshop on Helium Bubbles in Metals was held at Orsay, France in 1986 while in February 1989, a Topical Symposium on Noble Gases in Metals was held in Las Vegas as part of the large TMS/AIME Spring Meeting. As is well known, the dominating feature of inert gas atoms in most solids is their high heat of solution, leading in most situations to an essentially zero solubility and gas-atom precipita tion. In organising the workshop, one particular aim was to target the researchers in the field of inert-gas/solid interactions from three different areas--namely metals, tritides and nuclear fuels-in order to encourage and foster the cross-fertilisation of approaches and ideas. In these three material classes, the behaviour of inert gases in metals has probably been most studied, partly from technological considerations-the effects of helium production via (n, a) reac tions during neutron irradiation are of importance, particularly in a fusion reactor environ ment-and partly from a more fundamental viewpoint."

Integrated Biomaterials Science provides an intriguing insight into the world of biomaterials. It explores the materials and technology which have brought advances in new biomaterials, highlighting the way in which modern biology and medicine are synergistically linked to other key scientific disciplines-physics, chemistry, and engineering. In doing so, Integrated Biomaterials Science contains chapters on tissue engineering and gene therapy, standards and parameters of biomaterials, applications and interactions within the industrial world, as well as potential aspects of patent regulations. Integrated Biomaterials Science serves as a comprehensive guide to understanding this dynamic field, yet is designed so that chapters may be read and understood independently, depending on the needs of the reader. Integrated Biomaterials Science is attractive to a broad audience interested in a deeper understanding of this evolving field, and serves as a key resource for researchers and students of biomaterials courses, providing all with an opportunity to probe further.

TIlls book is the result of an effort made by several members of the Euratom Neutron Radiography Working Group (NRWG) to produce a new, revised and enlarged edition of the Neutron Radiography Handbooldlj (NRH), written by members of the NRWG and published in 1981, just before the First World Conference on Neutron Radiography (WCNR) (1981). Members of the NRWG have contributed with many papers both to the first (1981)[2), as well as the second (1986)[3) and third (1989) [4) World Conference on Neutron Radiography (WCNR). They were also among the editors of the proceedings of those conferences (1982, 1987, 1990). The NRWG was constituted mainly for the purpose of promoting neutron radiography (NR) in the field of nuclear reactor fuel. Therefore the next topical publication of the NRWG were Reference Neutron Radiographs of Nuclear Reactor Fuel (1984)[5). The book on Collimators for y Thermal Neutron Radiograph 6/ written in 1987 by a member of the NRWG was another publication in the same series of books on NR. To the same series belongs the present book on Practical Neutron Radiography (PNR). It will be followed soon by another book written by the members of the NRWG: Neutron Radiography on Nitrocellulose Filmf71. The NRWG concentrated its interest in the past years on the problem of dimensional measurements from neutron radiographs. The results of the investigation of this problem were summarized in a special EUR report about the Neutron Radiography Working Group Test Program[8/ published in 1989.

As recently as 20 years ago, ceramics were widely ignored as potential biomaterials. Interest in bioceramics has increased dramatically over the past decade to the point where it is anticipated they will be the materials of choice for many orthopedic, otologic, maxillofacial and dental applications during the decade of the '90s. Alumina ceramics are being used extensively as articulating comJ1onents in total joint prostheses because of Ithe materials low coefficient of friction and excellent wear resistances. Alumina ceramics are also being used in dental and maxillofacial applica tions because of the materials excellent biocompatibility. Because of its ability to chemically bond to bone, hydroxyapatite is rapidly becoming the material of choice for many dental and maxillofacial applications. For the past decade, one of the most widely researched topics in the field of orthopedics has been the clinical evaluation of joint prostheses based upon stabili zation via tissue ingrowth. It appears that the next generation of joint prostheses will be based upon direct chemically bonding to bone using hydroxyapatite, surface-active glass or surface-active glass ceramics coatings. Resorbable bioceramics are limited to temporary bone space fillers, periodontal pockets treatment and resorbable pharma ceutical delivery systems. Bioceramics is a comprehensive reference textbook covering the history of bio ceramics, present status of bioceramics, and prediction for future use of bioceramics. This book will serve as a major reference for students, as well as experienced bio material researchers. The book presents the state-of-the-art of bioceramics as of 1991."

Considerably simplified models of macroscopic material behavior, such as the idealization for metals of elastic-time independent plastic response with a yield (onset) criterion, have served the engineering profession well for many years. They are still basic to the design and analysis of most structural applications. In the need to use materials more effectively, there are circumstances where those traditional models are not adequate, and constitutive laws that are more physically realistic have to be employed. This is especially relevant to conditions where the inherent time dependence of inelastic deformations, referred to as "viscoplasticity," is pronounced such as at elevated temperatures and for high strain rates. Unified theories of elastic-viscoplastic material behavior, which are primarily applicable for metals and metallic alloys, combine all aspects of inelastic response into a set of time dependent equations with a single inelastic strain rate variable. For such theories, creep under constant stress, stress relaxation under constant strain, and stress-strain relations at constant rates are each special cases of a general formulation. Those equations mayor may not include a yield criterion, but models which do not separate a fully elastic region from the overall response could be considered "unified" in a more general sense. The theories have reached a level of development and maturity where they are being used in a number of sophisticated engineering applications. However, they have not yet become a standard method of material representation for general engineering practice.

The assessment of crack initiation and/or propagation has been the subject of many past discussions on fracture mechanics. Depending on how the chosen failure criterion is combined with the solution of a particular theory of continuum mechanics, the outcome could vary over a wide range. Mod elling of the material damage process could be elusive if the scale level of observation is left undefined. The specification of physical dimension alone is not sufficient because time and temperature also play an intimate role. It is only when the latter two variables are fixed that failure predictions can be simplified. The sudden fracture of material with a pre-existing crack is a case in point. Barring changes in the local temperature,* the energy released to create a unit surface area of an existing crack can be obtained by considering the change in elastic energy of the system before and after crack extension. Such a quantity has been referred to as the critical energy release rate, G e, or stress intensity factor, K Ie. Other parameters, such as the crack opening displacement (COD), path-independent J-integral, etc. , have been proposed; their relation to the fracture process is also based on the energy release concept. These one-parameter approaches, however, are unable simultaneously to account for the failure process of crack initiation, propagation and onset of rapid fracture. A review on the use of G, K I, COD, J, etc. , has been made by Sih [1,2].

The purposes of this book are to provide insight and to draw attention to problems peculiar to heat transfer at low temperatures. This does not imply that the theories of classical heat transfer fail at low temperatures, but rather that many of the approximations employed in standard solutions techniques are not valid in this regime. Physical properties, for example, have more pronounced variations at low temperatures and cannot, as is conventionally done, be held constant. Fluids readily become mixtures of two or more phases and their analysis is different from that for a single-phase fluid. These and other problems which occur more frequently at low temperatures than at standard conditions are discussed in this book. Although the title specifies heat transfer, the book also contains a very comprehensive chapter on two-phase fluid flow and a partial chapter on the flow of fluids in the thermodynamically critical state. Emphasis is placed on those flow phenomena that occur at low temperatures. Flow analyses are, of course, a prerequisite to forced-convection heat transfer analyses, and thus these chapters add continuity to the text. The book is primarily written for the design engineer, but does broach many topics which should prove interesting to the researcher. For the student and teacher the book will serve as a useful reference and possibly as a text for a special topics course in heat transfer.

The present book is devoted to a rapidly developing field of science which studies the behavior of viscoelastic materials under the influence of deformation~the rheology of polymers. Rheology has long been treated as the theoretical foundation of polymer processing, and from this standpoint it is difficult to overesti mate its importance in practice. Rheology plays an important role in developing our ideas on the nature of viscoelastic behavior in connection with the structural features of polymers and composites based on them. This expands the possibilities of employing rheological methods to characterize a variety of materials and greatly magnifies the interest in this field of research. The rheological properties of polymer systems are studied experimen tally, chiefly under conditions of shear and tensile strains. One explana tion is that many aspects of polymer material processing are associated with the stretching of melts or a combination of shear and tensile strains. In scientific investigations, either periodic or continuous conditions of shear deformation are employed. Each mode provides widespread infor mation. In periodic deformation, most attention is generally given to conditions with low deformation amplitudes that do not alter the structure of the polymer system during an experiment (the region of linear deformation conditions). Here the viscoelastic parameters are generally determined with respect to the frequency. Continuous deforma tion involves considerable strains, and may be attended by significant reversible and irreversible changes in the structure of a polymer.

Stuart Wolf This book originated as a series of lectures that were given as part of a Summer School on Spintronics in the end of August, 1998 at Lake Tahoe, Nevada. It has taken some time to get these lectures in a form suitable for this book and so the process has been an iterative one to provide current information on the topics that are covered. There are some topics that have developed in the intervening years and we have tried to at least alert the readers to them in the Introduction where a rather complete set of references is provided to the current state of the art. The field of magnetism, once thought to be dead or dying, has seen a remarkable rebirth in the last decade and promises to get even more important as we enter the new millennium. This rebirth is due to some very new insight into how the spin degree of freedom of both electrons and nucleons can play a role in a new type of electronics that utilizes the spin in addition to or in place of the charge. For this new field to mature and prosper, it is important that students and postdoctoral fellows have access to the appropriate literature that can give them a sound basis in the funda mentals of this new field and I hope that this book is a very good start in this direction.

Microwave testing has been paid only scant attention in the literature as a method for nondestructive testing of materials, yet it offers some attractive features, especially for the testing of composite and other non-metallic materials. Microwave techniques have been used in a large number of applications that can be classified as nondestructive testing applications, ranging from large scale remote sensing to detection of tumors in the body. This volume describes a unified approach to microwave nondestructive testing by presenting the three essential components of testing: theory, practice, and modelling. While recognizing that each of these subjects is wide enough to justify a volume of its own, the presentation of the three topics together shows that these are interrelated and should be practiced together. While few will argue against a good theoretical background, modelling and simulation of the testing environment is seldom part of the NDT training in any method, but particularly so in microwave testing. The text is devided in four parts. The first part presents the field theory background necessary for understanding the microwave domain. The second part treats microwave measurements as well as devices and sources and the third part discusses practical tests applicable to a variety of materials and geometries. The fourth part discusses modelling of microwave testing. Each chapter contains a bibliography intended to expand on the material given and, in particular, to point to subjects which could not be covered either as not appropriate or for lack of space. For engineers, applied physicsts, material scientists.

The First Asilomar Conference on Electron- and Photon-Molecule Collisions was held August 1-4, 1978 in Pacific Grove, California. This meeting brought together forty scientists who are actively involved in theoretical studies of electron scattering by, and photoionization of, small molecules. In this volume, are collected the contributions of the invited speakers, as well as the roundtable and evening discussions condensed from taped recordings of the entire proceedings. The subject matter reflects current activity in the field and describes many of the techniques that are being developed and applied to molecular collision problems. We would like to thank the Air Force Office of Scientific Research (AFOSR) and the Office of Naval Research (ONR) for providing the financial support that made this conference possible. Special thanks are due to Dr. Robert Junker of ONR and Dr. Ralph Kelley of AFOSR for the interest and encouragement they provided in all phases of this meeting. We also thank all the participants whose efforts and contributions made this conference a success. Finally, we thank Ms. Charlotte MacNaughton and Ms. Sara Jackson for the many hours they spent transcribing tapes and preparing this volume for publication.

The Foundation for Advances in Medicine and Science (FAMS), the organizers of SCANNING 98, sponsored its third annual Atomic Force Microscopy/Scanning Tunneling Microscopy Symposium at the Omni Inner Harbor Hotelin Baltimore, Maryland, from May 9 to 12, 1998. This book represents the compilation of papers that were presented at the AFM/STM Symposium as well as a few that were presented at SCANNING 96 and SCANNING 97 meetings that took place in Monterey, California. The purpose of the symposium was to provide an interface between scientists and engineers, representatives of industry, government and academia, all of whom have a common interest in probe microscopies. The meetings offered an ideal forum where ideas could easily be exchanged and where individuals from diverse fields who are on the cutting edge ofprobe microscopy research could communicate with one another. Experts in probe microscopy from around the world representing a wide range of disciplines including physics, biotechnology, nanotechnology, chemistry, material science, etc., were invited to participate. The format of the meeting was structured so as to encourage communication among these individuals. During the first day's sessions papers were presented on general topics such as application of scanning probe microscopy in materials science; STM and scanning tunneling spectroscopy of organic materials; fractal analysis in AFM; and nanomanipulation. Other papers presented included unexpected ordering of a molecule; synthesis ofpeptides and oligonucleotides; and analysis oflunar soils from Apollo 11.