Intensive research on zeolites, during the past thirty years, has resulted in a deep understanding of their chemistry and in a true zeolite science, including synthesis, structure, chemical and physical properties, and catalysis. These studies are the basis for the development and growth of several industrial processes applying zeolites for selective sorption, separation, and catalysis. In 1983, a NATO Advanced Study Institute was organized in Alcabideche (portugal) to establish the State-of-the-Art in Zeolite Science and Technology and to contribute to a better understanding of the structural properties of zeolites, the configurational constraints they may exert, and their effects in adsorption, diffusion, and catalysis. Since then, zeolite science has witnessed an almost exponential growth in published papers and patents, dealing with both fundamentals issues and original applications. The proposal of new procedures for zeolite synthesis, the development of novel and sophisticated physical techniques for zeolite characterization, the discovery of new zeolitic and related microporous materials, progresses in quantum chemistry and molecular modeling of zeolites, and the application of zeolites as catalysts for organic reactions have prompted increasing interest among the scientific community. An important and harmonious interaction between various domains of Physics, Chemistry, and Engineering resulted therefrom.

The Eighth Rochester Conference on Coherence and Quantum Optics was held on the campus of the University of Rochester during the period June 13-16,2001. This volume contains the proceedings of the meeting. The meeting was preceded by an affiliated conference, the International Conference on Quantum Information, with some overlapping sessions on June 13. The proceedings of the affiliated conference will be published separately by the Optical Society of America. A few papers that were presented in common plenary sessions of the two conferences will be published in both proceedings volumes. More than 268 scientists from 28 countries participated in the week long discussions and presentations. This Conference differed from the previous seven in the CQO series in several ways, the most important of which was the absence of Leonard Mandel. Professor Mandel died a few months before the conference. A special memorial symposium in his honor was held at the end of the conference. The presentations from that symposium are included in this proceedings volume. An innovation, that we believe made an important contribution to the conference, was the inclusion of a series of invited lectures chaired by CQO founder Emil Wolf, reviewing the history of the fields of coherence and quantum optics before about 1970. These were given by three prominent participants in the development of the field, C. Cohen-Tannoudji, 1. F. Clauser, and R. I. Glauber.

The authors of this contribution to the literature of resonance spectroscopy in paramagnetic systems are primarily concerned with the properties of the rare earth ions and, as such, the formal derivation of crystal field theory is set out in a manner which reflects this dominant interest. The ions of the 3d transition group are perhaps given too cursory a treatment in Chapter Two for those students of RF spectroscopy who have a somewhat less rare-earth oriented interest in the subject. Since the exam ples cited in the text do include some 3d transition ions, it is perhaps worthwhile in a preface of this sort to extend the broad theoretical concepts and group characteriza tion of Chapter Two to cover, in a somewhat more detailed manner, the derivation of the spin-Hamiltonian for this case. In Chapter Two, mention is made of the fact that for the 4f rare earth ions the spin orbit coupling energy is in general large compared to the crystal field influence of the surrounding ligand matrix. In such a case, the quantum number J is a good quantum number for the rare earth ion in question and the crystal field effects are taken into account within 1M, states. In this formulation, which is pursued in detail in this book, the effects of spin-orbit coupling have been taken care of at the very outset by the d "ining of the 1M, states."

Helium Ion Microscopy: Principles and Applications describes the theory and discusses the practical details of why scanning microscopes using beams of light ions - such as the Helium Ion Microscope (HIM) - are destined to become the imaging tools of choice for the 21st century. Topics covered include the principles, operation, and performance of the Gaseous Field Ion Source (GFIS), and a comparison of the optics of ion and electron beam microscopes including their operating conditions, resolution, and signal-to-noise performance. The physical principles of Ion-Induced Secondary Electron (iSE) generation by ions are discussed, and an extensive database of iSE yields for many elements and compounds as a function of incident ion species and its energy is included. Beam damage and charging are frequently outcomes of ion beam irradiation, and techniques to minimize such problems are presented. In addition to imaging, ions beams can be used for the controlled deposition, or removal, of selected materials with nanometer precision. The techniques and conditions required for nanofabrication are discussed and demonstrated. Finally, the problem of performing chemical microanalysis with ion beams is considered. Low energy ions cannot generate X-ray emissions, so alternative techniques such as Rutherford Backscatter Imaging (RBI) or Secondary Ion Mass Spectrometry (SIMS) are examined.

The study of defects and disorder in solids remains a central topic in solid state science. Developments in the field continue to be promoted by new experimental and theoretical techniques, while further impetus for the study of disorder in solids is provided by the growing range of applications of solid state materials in which disorder at the atomic level plays a crucial rOle. In this book we attempt to present a survey of fundamental and applied aspects of the field. We consider the basic aspects of defective crystalline and amorphous solids. We discuss recent studies of structural, electronic, transport, thermodynamic and spectroscopic properties of such materials. Experimental and theoretical methodologies are reviewed, and detailed consideration is given to materials such as fast ion conductors and amorphous semiconductors that are of importance in an applied context. Any survey of this large field is necessarily selective. We have chosen to emphasise insulating (especially oxidic) and semi-conducting materials. But many of the approaches and techniques we describe apply generally across the entire field of solid state science. This volume is based on a NATO ASI held at the Residencia Santa Teresa de Jesus, Madrid in September 1991. The Editor is grateful to the NATO Scientific Affairs Division for their sponsorship of this School. Thanks are also due to all who participated in and lectured at the school, but especially to the organising committee of A. V. Chadwick, G. N. Greaves, M. Grigorkiewicz, J. H. Harding and S. Kalbitzer. C. R. A.

Polymer science is a technology-driven science. More often than not, technological breakthroughs opened the gates to rapid fundamental and theoretical advances, dramatically broadening the understanding of experimental observations, and expanding the science itself. Some of the breakthroughs involved the creation of new materials. Among these one may enumerate the vulcanization of natural rubber, the derivatization of cellulose, the giant advances right before and during World War II in the preparation and characterization of synthetic elastomers and semi crystalline polymers such as polyesters and polyamides, the subsequent creation of aromatic high-temperature resistant amorphous and semi-crystal line polymers, and the more recent development of liquid-crystalline polymers mostly with n~in-chain mesogenicity. other breakthroughs involve the development of powerful characterization techniques. Among the recent ones, the photon correlation spectroscopy owes its success to the advent of laser technology, small angle neutron scattering evolved from n~clear reactors technology, and modern solid-state nuclear magnetic resonance spectroscopy exists because of advances in superconductivity. The growing need for high modulus, high-temperature resistant polymers is opening at present a new technology, that of more or less rigid networks. The use of such networks is rapidly growing in applications where they are used as such or where they serve as matrices for fibers or other load bearing elements. The rigid networks are largely aromatic. Many of them are prepared from multifunctional wholly or almost-wholly aromatic kernels, while others contain large amount of stiff difunctional residus leading to the presence of many main-chain "liquid-crystalline" segments in the "infinite" network.

Microwave Physics and Techniques discusses the modelling and application of nonlinear microwave circuits and the problems of microwave electrodynamics and applications of magnetic and high Tc superconductor structures. Aspects of advanced methods for the structural investigation of materials and of MW remote sensing are also considered. The dual focus on both HTSC MW device physics and MW excitation in ferrites and magnetic films will foster the interaction of specialists in these different fields.

Despite the significant progress, which has been made in developing of ceramic materials desired for engineering applications, their mass production is still not on expected level. Among the key factors hindering higher exploitation of these materials the problems in processing were identified. The processing comprises powder production, mixing techniques, forming, and sintering. All of them are equally important and all of them can introduce defects into the material. Besides improvement in processing, the properties of ceramic materials can be considerably improved by the creation of composites. Composites formed at micro or macro level are able to form more flaw-tolerant material. Considerable research activities, working on above mentioned phenomena are in progress at industrial laboratories as well as other research centres. This volume presents the contributions to the Advanced Research Workshop "Engineering Ceramics '96" with 65 participants from 21 countries held on 12th - 15th May 1996 at Smolenice Castle, Slovakia, the conference site of Slovak Academy of Sciences. The book covers research activities on engineering ceramic materials and gives an overview with respect to recent developments.

Organic solids exhibit a wide range of electrical and related properties. They occur as crystals, glasses, polymers and thin films; they may be insulators, semiconductors, conductors or superconductors; and they may show luminescence, nonlinear optical response, and complex dynamical behaviour. The book provides a broad survey of this area, written by international experts, one third being drawn from Eastern Europe. Electrical, optical, spectroscopic and structural aspects are all treated in a way that gives an excellent introduction to current themes in this highly interdisciplinary and practically important area. The coverage is especially strong in the areas where electrical and optical properties overlap, such as photoconductivity, electroluminescence, electroabsorption, electro-optics and photorefraction.

This 6th International Symposium on Thermal Expansion, the first outside the USA, was held on August 29-31, 1977 at the Gull Harbour Resort on Hecla Island, Manitoba, Canada. Symposium Chairman was Ian D. Peggs, Atomic Energy of Canada Limited, and our continuing sponsor was CINDAS/Purdue University. We made considerable efforts to broaden the base this year to include more users of expansion data but with little success. We were successful, however, in establishing a session on liquids, an area which is receiving more attention as a logical extension to the high-speed thermophysical property measurements on materials at temperatures close to their melting points. The Symposium had good international representation but the overall attendance was, disappointingly, relatively low. Neverthe less, this enhanced the informal atmosphere throughout the meeting with a resultant frank exchange of information and ideas which all attendees appreciated. A totally new item this year was the presentation of a bursary to assist an outstanding research student to attend the Symposium. We were delighted to welcome Mr. Benedick Fraass from the Univer sity of Illinois to the Symposium, and he responded by making an informal presentation on the topic of his research. We hope this feature will continue. Previous Symposia in the series were: DATE SPONSOR LOCATION CHAIRMEN September 18-20 Gaithersburg, R.K. Kirby Natl. Bureau of 1968 Maryland Standards P.S. Gaal Westinghouse Astronuclear Lab. June 10-12 Santa Fe, R.O. Simmons Materials Res. Lab."

Electro-optic devices based on doped wide-band materials are present in industrial uses, in military applications and in everyday life. Whether one engages in laser surgery with a neodymium-Y AG laser or one communicates overseas using optical fibers, the development of these materials is both scientifically and commercially of great interest. Much of the most innovative work has been done in the last 15 years in this area. A minor revolution in optical fiber communications has occurred with the development of erbium-doped fiber amplifiers. Solid-state laser development shifted into high-gear with the theoretical and experimental study of doubly-doped garnet lasers. Recent developments on semiconductor laser arrays are making diode pumped solid-state lasers commercially feasible. The purpose of this book is to detail these developments and to point out that many of the same underlying physical processes control advances in several diverse applications. For example, the basic science of energy transfer will be discussed by Zharikov et al. and Rotman for energy transfer and dopant-defect interactions, respectively; it will also be crucial in understanding cerium-doped scintilla tors, neodymium-chromium lasers, and up-conversion fiber lasers. As another example, phonon-induced non-radiative relaxation will appear in every chapter in this book.

I express my full indebtedness to all researchers whose work is referenced in this book. Without their outstanding contributions to knowledge, this book would not have been written. I convey my thanks to Professor D. R. Axelrad (McGill University), who was the first person to introduce the fascinating subject of rheology to me and to Professor J. T. Pindera (University of Waterloo) for his kind encouragement and stimulating discussions on the subject matter. I am indebted to Dr J. H. Gittus, Editor-in-Chief Res Mechanica, for originally inviting me to write a book on viscoelasticity. of Permission granted to the author for the reproduction of figures and/or data by the following scientific societies, journals and publishers is gratefully acknowledged: Academic Press, American Chemical Society, American Institute of Physics, British Textile Technology Group, Elsevier Applied Science Publishers, Gebriider Born traeger, Helvetica Chimica Acta, Hermann, International Union of Crystallography, John Wiley & Sons, Pergamon Press, Springer-Verlag Heidelberg, Steinkopff Verlag, Tappi Journal, Taylor and Francis Ltd . . and the Institute of Physics. In the same context, the author wishes to express his sincere thanks and gratitude to Professors M. F. Ashby (University of Cambridge, United Kingdom), N. Davis (The Pennsylvania State University), H. F. Frost (Thayer School of Engineering), F. A. Leckie (University of Illinois at Urbana-Champaigne), E. H. Lee (Stanford University), J. M. Morrison (AT & T Bell Laboratories), A. K. Mukherjee (University of California, Davis) and Dr H. J. Sutherland (Sandia National Laboratories)."

Lo, soul! seest thou not God's purpose from the first? The earth to be spann'd, connected by net-work From Passage to India! Walt Whitman, "Leaves of Grass", 1900. The Internet is growing at a tremendous rate today. New services, such as telephony and multimedia, are being added to the pure data-delivery framework of yesterday. Such high demands on capacity could lead to a "bandwidth-crunch" at the core wide-area network resulting in degra dation of service quality. Fortunately, technological innovations have emerged which can provide relief to the end-user to overcome the In ternet's well-known delay and bandwidth limitations. At the physical layer, a major overhaul of existing networks has been envisaged from electronic media (such as twisted-pair and cable) to optical fibers - in the wide area, in the metropolitan area, and even in the local area set tings. In order to exploit the immense bandwidth potential of the optical fiber, interesting multiplexing techniques have been developed over the years. Wavelength division multiplexing (WDM) is such a promising tech nique in which multiple channels are operated along a single fiber si multaneously, each on a different wavelength. These channels can be independently modulated to accommodate dissimilar bit rates and data formats, if so desired. Thus, WDM carves up the huge bandwidth of an optical fiber into channels whose bandwidths (1-10 Gbps) are compati ble with peak electronic processing speed.

These volumes, 9 and 10, of Fracture Mechanics of Ceramics constitute the proceedings of an international symposium on the fracture mechanics of ceramic materials held at the Japan Fine Ceramics Center, Nagoya, Japan on July 15, 16, 17, 1991. These proceedings constitute the fifth pair of volumes of a continuing series of conferences. Volumes 1 and 2 were from the 1973 symposium, volumes 3 and 4 from a 1977 symposium, and volumes 5 and 6 from a 1981 symposium all of which were held at The Pennsylvania State University. Volumes 7 and 8 are from the 1985 symposium which was held at the Virginia Polytechnic Institute and State University. The theme ofthis conference, as for the previous four, focused on the mechanical behavior ofceramic materials in terms of the characteristics of cracks, particularly the roles which they assume in the fracture processes and mechanisms. The 82 contributed papers by over 150 authors and co-authors represent the current state of that field. They address many of the theoretical and practical problems ofinterest to those scientists and engineers concerned with brittle fracture.

Theoretical and experimental work on solids with low-dimensi onal cooperative phenomena has been rather explosively expanded in the last few years, and it seems to be quite fashionable to con tribute to this field, especially to the problem of one-dimensional metals. On the whole, one could divide the huge amount of recent investigations into two parts although there is much overlap bet ween these regimes, namely investigations on magnetic exchange interactions constrained to mainly one or two dimensions and, secondly, work done on Id metallic solids or linear chain compounds with Id delocalized electrons. There is, of course, overlap from one extreme case to the other with these solids and in some rare cases both phenomena are studied on one and the same crystal. In fact, however, most of the scientific groups in this area could be associated roughly with one of these categories and, in addition, a separation between theoreticians and experimentalists in each of these groups leads to a further splitting of interests although many theories about these solids have been tested by experimenta lists. Nevertheless, more cooperation and understanding between scientists working on low-dimensional cooperative phenomena should appreciably stimulate further development. With a better inderdis ciplinary understanding, new ideas could possibly help chemists in synthesizing tailor-cut solids. This would in return give experi mentalists new phenomena to examine and finally would stimulate new theoretical work."

of Polymer Chemistry, Inc. of the American Chemical Society held its The Division 15th Biennial Polymer Symposium on the topic, "Advances in New Materials," November 17-21, 1990, at the Pier 66 Resort and Marina in Ft. Lauderdale, Florida. A three and one half day program was presented by recognized leaders in major areas of new polymeric materials. The topics of the Biennial Symposium included new high performance polymers, polymers for electronic applications, electrically conducting polymers, nonlinear optics, new polymer systems, and polymers derived from biological media. These are the subject areas of this volume of "Contemporary Topics in Polymer Science." The intent of the Symposium was to focus on recent advances in polymeric materials. The technical sessions were complemented by an initial poster session which augmented the various technical sessions. A particular highlight of the meeting was the presentation to Professor Michael Szwarc of the 1990 Division of Polymer Chemistry Award by Dr. J. L. Benham, Chairman of the T Aymer Division. During his Award address, Professor Szwarc described how he had become a polymer chemist and later developed "living polymers." Without a doubt, Professor Szwarc has made a profound contribution to the polymer field, which has yielded many new forms of living polymerization."

This monograph, which is the outcome of the ASI on High Pressure Chemistry, Biochemistry, and Materials Science, illustrates new developments in the field of high pressure science. In fact, for chemists, biochemists, and materials scientists, pressure as an experimental variable represents a tool which provides unique information about systems of materials studied. It is interesting to note how the growth of the high pressure field is also reflected in the content of the recent ASI's dealing with this field. The ASI High Pressure Chemistry held in 1977 was followed by the ASI High Pressure Chemistry and Biochemistry held in 1986, and the coverage of the present ASI also includes applications to materials science. In view of the teaching character of the ASI, it is natural that main contributions to this volume present overviews of the different subfields or applications of high pressure research. In contrast, contributed papers offer more specialized aspects of various high pressure studies. The various contributions to this volume make clear the impressive range of fundamental and applied problems that can be studied by high pressure techniques, and also point towards a major growth of high pressure science and technology in the near future. This ASI focused mainly on advances achieved in the six years since the previous ASI devoted to the high pressure field. The organization of this volume is as follows.

This volume presents a theoretical and numerical investigation of high index-contrast passive components that can serve as building blocks at the end-points and nodes of WDM communications systems. It presents novel devices for filtering, optical interconnections and coupling to fibres.

Silicon, as an electronic substrate, has sparked a technological revolution that has allowed the realization of very large scale integration (VLSI) of circuits on a chip. These 6 fingernail-sized chips currently carry more than 10 components, consume low power, cost a few dollars, and are capable of performing data processing, numerical computations, and signal conditioning tasks at gigabit-per-second rates. Silicon, as a mechanical substrate, promises to spark another technological revolution that will allow computer chips to come with the eyes, ears, and even hands needed for closed-loop control systems. The silicon VLSI process technology which has been perfected over three decades can now be extended towards the production of novel structures such as epitaxially grown optoelectronic GaAs devices, buried layers for three dimensional integration, micromechanical mechanisms, integrated photonic circuits, and artificial neural networks. This book begins by addressing the processing of electronic and optoelectronic devices produced by using lattice mismatched epitaxial GaAs films on Si. Two viable technologies are considered. In one, silicon is used as a passive substrate in order to take advantage of its favorable properties over bulk GaAs; in the other, GaAs and Si are combined on the same chip in order to develop IC configurations with improved performance and increased levels of integration. The relationships between device operation and substrate quality are discussed in light of potential electronic and optoelectronic applications.

Engineering tasks are supposed to achieve defined goals under certain project constraints. Example goals of software engineering tasks include achieving a certain functionality together with some level of reliability or performance. Example constraints of software engineering tasks include budget and time limitations or experience limitations of the developers at hand. Planning of an engineering project requires the selection of techniques, methods and tools suited to achieve stated goals under given project constraints. This assumes sufficient knowledge regarding the process-product relationships (or effects) of candidate techniques, methods and tools. Planning of software projects suffers greatly from lack of knowledge regarding the process-product relationships of candidate techniques, methods and tools. Especially in the area of testing a project planner is confronted with an abundance of testing techniques, but very little knowledge regarding their effects under varying project conditions. This book offers a novel approach to addressing this problem: First, based on a comprehensive initial characterization scheme (see chapter 7) an overview of existing testing techniques and their effects under varying conditions is provided to guide the selection of testing approaches. Second, the optimisation of this knowledge base is suggested based on experience from experts, real projects and scientific experiments (chapters 8, 9, and 10). This book is of equal interest to practitioners, researchers and students. Practitioners interested in identifying ways to organize their company-specific knowledge about testing could start with the schema provided in this book, and optimise it further by applying similar strategies as offered in chapters 8 and 9.

Building on the extensive coverage of the first volume, Volume 2 focuses on the fundamentals of measurements and computational techniques that will aid researchers in the construction and use of measurement devices.

Approximately half of the world production of the petrochemical industry (more than 100 million tonnes) is in the form of polymers, yet it would probably surprise most people to learn how much their lifestyle depends on polymers ranging, as they do, from detergents, kitchenware and electrical appliances to furnishings and a myriad other domestic goods. Still less are they likely to be aware of the extensive part they play in engineering applications for mechanical machine components and advanced high performance aircraft. This versatility derives from the fact that polymeric materials are made up of a range of molecules of varying length, whose properties are related to molecular structure and the proportions of the chains in the mixture. For example, polypropylene is a commodity polymer which is produced in hun dreds of different grades to meet specific market requirements. This depends on the catalyst as well as the operating conditions and reactor design. A major area for growth is in substituting polymers for conventional materials such as ceramics and metals. Not only can they match these materials in terms of mechanical strength and robustness but they have very good resistance to chemical attack. Polyamides, for example, are widely used for car bumpers and new polymers are being developed for engine manifolds and covers. In 1993 there is, typically, 100 kg of various polymers used in cars and this is continually increasing, giving a net weight reduction and hence better fuel economy."

Summary of the recent progress in ceramics research. Several novel concepts for materials selection and microstructural design are presented, as are experimental results that substantiate the ideas.

It is almost self-evident that surface and interface science, coupled with the electronic structure of bulk materials, playa fundamental role in the understanding of materials properties. If one is to have any hope of understanding such properties as catalysis, microelectronic devices and contacts, wear, lubrication, resistance to corrosion, ductility, creep, intragranular fracture, toughness and strength of steels, adhesion of protective oxide scales, and the mechanical properties of ceramics, one must address a rather complex problem involving a number of fundamental parameters: the atomic and electronic structure, the energy and chemistry of surface and interface regions, diffusion along and across interfaces, and the response of an interface to stress. The intense need to gain an understanding of the properties of surfaces and interfaces is amply attested to by the large number of conferences and workshops held on surface and interface science. Because of this need, the fields of surface and interface science have been established in their own right, although their development presently lags behind that of general materials science associated with bulk, translationally invariant systems. There are good reasons to expect this situation to change rather dramatically in the next few years. Existing techniques for investigating surfaces and interfaces have reached maturity and are increasingly being applied to systems of practical relevance. New techniques are still being created, which drastically widen the scope of applicability of surface and interface studies. On the experimental side, new microscopies are bearing fruit.

In recent years remarkable progress has been made in the development of materials for ultrasonic transducers. There is a continuing trend towards increasingly higher frequency ranges for the application of ultrasonic trans ducers in modern technology. The progress in this area has been especially rapid and articles and papers on the subject are scattered over numerous technical and scientific journals in this country and abroad. Although good books have appeared on ultrasonics in general and ultrasonic transducers in particular in which, for obvious reasons, materials play an important part, no comprehensive treatise is available that represents the state-of-the-art on modern ultrasonic transducer materials. This book intends to fill a need for a thorough review of the subject. Not all materials are covered of which, theoretically, ultrasonic trans ducers could be made but those that are or may be of technical impor tance and which have inherent electro acoustic transducer properties, i.e., materials that are either magnetostrictive, electrostrictive, or piezoelectric. The book has been devided into three parts which somewhat reflect the historic development of ultrasonic transducer materials for important tech nical application. Chapter 1 deals with magnetostrictive materials, magnetostrictive met als and their alloys, and magnetostrictive ferrites (polycrystalline ceramics). The metals are useful especially in cases where ruggednes of the transducers are of overriding importance and in the lower ultrasonic frequency range."