After epoxy resins and polyimides, cyanate esters arguably form the most well-developed group of high-temperature, thermosetting polymers. They possess a number of desirable performance characteristics which make them of increasing technological importance, where their somewhat higher costs are acceptable. The principal end uses for cyanate esters are as matrix resins for printed wiring board laminates and structural composites. For the electronics markets, the low dielectric loss characteristics, dimen sional stability at molten solder temperatures and excellent adhesion to conductor metals at temperatures up to 250 DegreesC, are desirable. In their use in aerospace composites, unmodified cyanate esters offer twice the frac ture toughness of multifunctional epoxies, while achieving a service tem perature intermediate between epoxy and bis-maleimide capabilities. Applications in radome construction and aircraft with reduced radar signatures utilize the unusually low capacitance properties of cyanate esters and associated low dissipation factors. While a number of commercial cyanate ester monomers and prepoly mers are now available, to date there has been no comprehensive review of the chemistry and recent technological applications of this versatile family of resins. The aims of the present text are to present these in a com pact, readable form. The work is primarily aimed at materials scientists and polymer technologists involved in research and development in the chemical, electronics, aerospace and adhesives industries. It is hoped that advanced undergraduates and postgraduates in polymer chemistry and technology, and materials science/technology will find it a useful introduc tion and source of reference in the course of their studies.

In many cases rheological measurements are carried out in the simplest of geometries, but the interpretation involved in obtaining the rheological parameters of the test fluids from these measurements is surprisingly complex. The purpose of this book is to emphasise the points on which most workers in the field agree, and to let the authors deal with the contentious points according to their own beliefs and experience. This work represents a summary of the current thought on rheological meas urement by experts in the various techniques. When making measurements and obtaining from them parameters that describe the flow behaviour of the test fluids, it is essential that the experimentalist understands the underlying theory and shortcomings of the measurement technique, that he is aware of the likely microstructure of the fluid, and that from this he can appreciate how the fluid and the measuring system will interact with each other. It is this interaction that gives both the required rheological parameters of the fluids and the artefacts that confuse the issue. This book covers the main rheological measurement techniques from capillary, slit and stretching flows to rotational and oscillatory rheometry in various geometries including sliding plate measurements. These topics are backed up by chapters on more practical aspects, such as commercial instruments, and on computer control and data acquisition. The chapters deal with the basic methods, how the measurements are taken, and what assumptions and interpretations are made to obtain valid data on the test fluids."

Toyiochi Tanaka, Mitsuhiro Shibayama, "Phase Transitions and related Phenomena of Polymer Gels", Akira Onuki "Theory of Phase Transition in Polymer Gels", Alexei Khokhlov, Sergei Starodybtzev, Valentina Vasilevskaya "Conformational Transitions in Polymer Gels: Theory and Experiment", Michal Ilavsky " Effect on Phase Transition on Swellingand Mechanical Behavior of Synthetic Hydrogels", Shozaburo Saito , M. Konno, H. Inomata "Volume Phase Transition of N-Alkylacrylamide Gels", Ronald Siegel "Hydrophobic Weak Polyelectrolyte Gels: Studies of Swelling Equilibria and Kinetics".

The modeling of minerals and silicated materials is a. difficult challenge faced by Solid StatePhysics, Quantum Chemistry and Molecular Dynamics communities. The difficulty of such a modeling is due to the wide diversity of elements, including heavy atoms, and types of bonding involved in such systems. Moreover, one has to consider infinite systems: either perfect cr- tals or glasses and melts. In the solid state a given chemical composition gives rise to numerous polymorphs, geometricallycloselyrelated. These polymorphs have very similar energies and related thermodynamical pr- erties which explain the complexity of their phase diagrams. The modeling of silicates and minerals covers a wide field of applications ranging from basic research to technology, from Solid State Physics to Earth and Planetary science. The use of modeling techniques yields information of different nature. In the case of chemical studies, we can mention inv- tigations on catalytic processes occurring on surfaces and in zeolite cages. These calculations find possible applications in chemical engineering, in particular in the oil industry

Shunsuke Hirotsu "Coexistence of Phases and the Nature of First-Order Transition in Poly-N-isopropylacrylamide Gels," Masayuki Tokita "Friction between Polymer Networks of Gels and Solvent," Masahiro Irie "Stimuli-Responsive Poly(N-isopropyl- acrylamide), Photo- and Chemicals-Induced Phases Transitions Edward Cussler, Karen Wang, John Burban"Hydrogels as Separation Agents," Stevin Gehrke "Synthesis, Equilibrium Swelling, Kinetics Permeability and Applications of Environmentally Responsive Gels," Pedro Verdugo "Polymer Gel Phase Transition in Condensation- Decondensation of Secretory Products," Etsuo Kokufuta "Novel Applications for Stimulus-Sensitive Polymer Gels in the Preparation of Functional Immobilized Biocatalysts," Teruo Okano "Molecular Design of Temperature-Responsive Polymers as Intelligent Materials," Atsushi Suzuki "Phase Transition in Gels of Sub-Millimeter Size Induced by Interaction with Stimuli," Makoto Suzuki, O. Hirasa "An Approach to Artificial Muscle by Polymer Gels due to Micro-Phase Separation."

This volume of the series gives an overview on Rigid Polymer Networks written by two reputed experts in the field. A broad range of densely-branched, highly-crosslinked aromatic networks and gels of increasing rigidity are discussed, with special emphasis on aromatic rigid liquid-crystal polymer networks. The synthetic procedures to create the networks are briefly described and extensively referenced. Features of one-step and two-step rigid networks in their pre-gel and post-gel states are discussed. Some first steps are then taken in the theoretical treatment of LCP networks with long aromatic segments of decreasing stiffness. The current state of theory dealing with the broader class of highly-crosslinked rigid aromatic networks and gels is finally mentioned.

This book had its nucleus in some lectures given by one ofus (J. O'M. B. ) in a course on electrochemistry to students of energy conversion at the Vniversity of Pennsylvania. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all ofwhom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry wh ich could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importanee. Thus, conversion to electrochemically powered trans portation systems appears to be an important step by means of which the difficulties of air pollution and the effeets of an increasing concentration in the atmosphere of carbon dioxide may be met. Corrosion is recognized as having an electroehemical basis. The synthesis of nylon now contains an important electroehemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of Ameriean organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the Vnited States."

Drawing a picture of the current situation of this new field, this volume both summarizes the past achievements and analyzes the present unsolved problems.

The combination of conductive polymer technology with the ability to produce nanofibres will facilitate major new developments in biotechnology and information technology, benefiting such areas as scaffolds for tissue engineering and drug delivery systems; wires, capacitors, transistors and diodes; sensor technology; biohazard protection; and energy transport, conversion and storage. The work on nanofibrous materials presented here is designed, first of all, to instruct scientists in the most advanced methods for the formation of nanofibres and nanotubes. The second section covers the physics and chemistry of nanofibres, while the third deals with computer simulation and modelling. The applications described in section 4 include biomedical applications, nanotube-based devices, electronic applications of nanotubes and nanofibres, nanofluidics, and composites. Finally, the fifth section discusses recent developments in nanomaterials, nanoparticles and nanostructures.

This book contains the proceedings of the Symposium on FT-IR Characterization of Polymers, which was held under the auspices of the Division of Polymer Chemistry, American Chemical Society (ACS) during the annual ACS meeting in Philadelphia, August, 1984. The content of each paper has been substantially extended from the papers presented during the conference. Due to the accidental, irrecoverable loss of the entire contents of the book by the computer system used for editorial purposes, the publication of this book has been delayed more than one year over the initial scheduled date. It has been a continuous, frustrating experience for the editor as well as for the authors. An extended Murphy's law, -anything can go wrong goes multiply wrong- has been demonstrated in editor's office. It necessitated, otherwise unnecessary, repeated proof reading during which time the editor had valuable experience ~n familiarizing himself with each paper much more than usual. The papers in this book are state-of-the-art even after such a delay. It is the authors pride and integrity toward the quality of each paper that makes the value of this book long lasting, while responsibility of the loss of any timeliness rests at the editor's hand. For the purpose of official records, submission and acceptance dates must be stated. All papers had been submitted by September, 1984, and had been accepted for publication by November, 1984, after the critical review processes.

This book deals with the application of grazing angle x-ray and neutron scattering to the study of surface-induced critical phenomena. With the advent of even more advanced synchrotron radiation sources and new sophisticated instrumentation this novel technique is expected to experience a boom. The comprehensive and detailed presentation of theoretical and experimental aspects of the scattering of evanascent x-ray and neutron waves inside a solid makes this book particularly useful for tutorial courses. Particular emphasis is put on the use of this technique to extract microscopic information (correlation functions) from the real structure of a surface, from buried and magnetic interfaces and from surface roughness.

This book is concerned with the configuration of polymers at the interfacial zone between two other phases or immiscible components. In recent years, developments in technology combined with increased attention from specialists in a wide range of fields have resulted in a considerable increase in our understanding of the behavior of polymers at interfaces. Inevitably these advances have generated a wealth of literature and although there have been numerous reviews, a critical treatment with adequate descriptions of both theory and experiment, including detailed analysis of the two, has been missing. This text hopes to fill this gap, providing a timely and comprehensive account of the field as it stands today. This long needed work will be invaluable to experts as well as newcomers in the broad field of polymers, interfaces and colloids, both in industry and academia. Whilst industrial laboratories involved in this field will find it indispensable, it will be equally important to anyone with an interest in interfacial polymer or colloidal research.

During the last decades, continuum mechanics of porous materials has achieved great attention, since it allows for the consideration of the volumetrically coupled behaviour of the solid matrix deformation and the pore-fluid flow. Naturally, applications of porous media models range from civil and environmental engineering, where, e. g. , geote- nical problems like the consolidation problem are of great interest, via mechanical engineering, where, e. g. , the description of sinter materials or polymeric and metallic foams is a typical problem, to chemical and biomechanical engineering, where, e. g. , the complex structure of l- ing tissues is studied. Although these applications are principally very different, they basically fall into the category of multiphase materials, which can be described, on the macroscale, within the framework of the well-founded Theory of Porous Media (TPM). With the increasing power of computer hardware together with the rapidly decreasing computational costs, numerical solutions of complex coupled problems became possible and have been seriously investigated. However, since the quality of the numerical solutions strongly depends on the quality of the underlying physical model together with the experimental and mathematical possibilities to successfully determine realistic material parameters, a successful treatment of porous materials requires a joint consideration of continuum mechanics, experimental mechanics and numerical methods. In addition, micromechanical - vestigations and homogenization techniques are very helpful to increase the phenomenological understanding of such media.

Over 100 scientists met at the IBM Research Laboratory in San Jose. California for a symposium on the Physics and Chemistry of Liquid Crystal Devices. The two-day meeting was intellectually stimulating with excellent oral presentations and with person-to-person discussions. The applications of liquid crystals have developed dramatically in the past ten years. In these few years, they have moved from being a laboratory curiosity to products in the market place. The first commercial application (1940's) of liquid crystals was the preparation of a light polarizer. The second commercial application was their use as temperature sensors. The third major application of liquid crystals dealt with commercial displays. Other current applications include polymeric and graphitic fibers and light attenuators. The future of liquid crystals looks very promising indeed. One can expect to see new fibers of qualities which will be superior to those presently known. Graphitic fibers or other physical forms of graphitic materials will be used as catalytic surfaces for chemical synthesis. In the display area. one can expect to see television screens using liquid crystals. Larger displays than are now used in wrist watches and pocket calculators will become available. Liquid crystals using color displays will become commercially practical. Watches. calculators and television screens will have color.

In recent years, a growing number of engineering applications of light weight and energy efficient plastics can be found in high quality parts vital to the func tioning of entire equipments and structures. Improved mechanical properties, especially balance of stiffness and toughness, are among the most frequently desired features of the new materials. In addition, reduced flammability is con sidered the single most important requirement for further expansion of plastics into large volume and demanding markets such as construction and mass trans port. Production of power cables also requires flame retardant cable jacketing plastics to replace or at least to reduce consumption of environmentally unsound PVC. The two principal ways to achieve the goals mentioned above include the development of completely new thermoplastic polymers and various modifica tions of the existing ones. Development and commercialization of a new ther moplastic require mobilization of large human and financial resources, the lat ter being within the range from $100 million to $10 billion, in comparison to $100 thousand to $10 million needed to develop and commercialize polymeric mate rial with prescribed end use properties using physical or chemical modification of an existing plastic. In addition, the various markets utilizing thermoplastics demand large flexibility in material properties with only moderate volumes, at the best.

vi on geometric probability is included, students can be expected to create a few simple programs like those shown, but for other geometries. I am indebted to Tom Hare for critical reviews of the material and an endless enthusiasm to debate and derive stereological relationships; to John Matzka at Plenum Press for patiently instructing me in the intricacies of typesetting; to Chris Russ for helping to program many of these measurement techniques; and especially to Helen Adams, both for her patience with my creative fever to write yet another book, and for pointing out that the title, which I had intended to contrast to "theoretical stereology," can also be understood as the antonym of "impractical stereology." John C. Russ Raleigh,NC July, 1986 Chapter 1: Statistics 1 Accuracy and precision 1 The mean and standard deviation 5 Distributions 7 Comparison 13 Correlation 18 Nonlinear fitting 19 Chapter 2: Image Types 23 Planar sections 23 Projected images 25 Finite sections 28 Space-filling structures and dispersed phases 29 Types of images and contrast mechanisms 31 Sampling 32 Chapter 3: Manual Methods 35 Volume fraction 35 Surface density 38 Contiguity 41 Mean intercept length 42 Line density 43 Grain size determination 55 Curvature 48 Reticles to aid counting 49 Magnification and units 51 Chapter4: Size Distributions 53 Intercept length in spheres 53 Nonspherical shapes 57 Corrections for finite section thickness 59 Lamellae 61 Measurement of profile size 62 Nonspherical particles 69 vii Contents viii Chapter 5: Computer Metlwds 73

Optical Measurements, Modeling, and Metrology represents one of eight volumes of technical papers presented at the Society for Experimental Mechanics Annual Conference on Experimental and Applied Mechanics, held at Uncasville, Connecticut, June 13-16, 2011. The full set of proceedings also includes volumes on Dynamic Behavior of Materials, Mechanics of Biological Systems and Materials, Mechanics of Time-Dependent Materials and Processes in Conventional and Multifunctional Materials; MEMS and Nanotechnology; Experimental and Applied Mechanics, Thermomechanics and Infra-Red Imaging, and Engineering Applications of Residual Stress.

This book presents a method for replicating natural butterfly wing scales using a variety of metals for state-of-the-art applications requiring high surface-enhancement properties. During the past decade, three dimensional (3D) sub-micrometer structures have attracted considerable attention for optical applications. These 3D subwavelength metallic structures are, however, difficult to prepare. By contrast, the 3D superstructures of butterfly wing scales, with more than 175 000 morphologies, are efficiently engineered by nature. Natural butterfly wing scales feature 3D sub-micrometer structures that are superior to many human designs in terms of structural complexity, reproducibility, and cost. Such natural wealth offers a versatile chemical route via the replication of these structures into functional metals. A single versatile chemical route can be used to produce butterfly scales in seven different metals. These synthesized structures have the potential for catalytic (Au, Pt, Pd), thermal (Ag, Au, Cu), electrical (Au, Cu, Ag), magnetic (Co, Ni), and optical (Au, Ag, Cu) applications. Plasmon-active Au, Cu, Ag butterfly scales have exhibited excellent properties in surface-enhanced Raman scattering (SERS). The Au scales as SERS substrates have ten times the analyte detection sensitivity and are one-tenth the cost of their human-designed commercial counterparts (KlariteTM). Preliminary mechanisms of these surface-enhancement phenomena are also reviewed.

This book describes clearly various research topics investigated for these 10 years in the Research Center of Advanced Structural and Functional Materials Design in Osaka University, Japan. Every chapter is aimed at understanding most advanced researches in materials science by describing its fundamentals and details as much as possible. Since both general explanations and cutting-edge commentaries are given for each topic in this book, it provides a lot of useful information for ordinary readers as well as materials scientists & engineers who wish to understand the future development in materials science fields of metals, alloys, ceramics, semiconductors etc. In particular, this book deals with special fusion area of structural and functional materials such as medical bone materials, of which contents are very unique features as materials science textbook.

C axis Current I ~ . The (11 0) thick homoepitaxial film of 320 nm -------~ ~-=-=--==---==--==--==--- shows a very good surface flatness, which --------** sJ;1 0] suggests the unique (110) atomic plane helps 2- A [1 1 OJ dimensional epitaxial growth of YBCO films, and shows excellent high Tc. The resultant 1. 0 surface morphology of YBCO is quite different Q ,. -- R(270)=1. 60 m 0 from the (110) heteroepitaxial films of similar 0 0. 0 " thickness [11). In the case of heteroepitaxy ~ . ,,_. 1. 0 irrespective of c-axis [ 12] or a-axis oriented ~ ~. . ,. R(270)=3. 71 m 0 films [5), only thin films show flat surfaces, g 0. 0 . . Tc=92. 3K "' which, however, give usually a degraded Tc due -~ 1. 0 v v I - to lattice mismatching. In conclusion, we have ::1. ,. . . . . R(270)=31. 9 mO succeeded to grow high-quality (11 0) YBCO ~ YBCO film . . Tc=90. 7 K 0. 0 *;:: YBCO(IIO) 1 0 *d*--~ YBCO thinfilms on (11 0) YBCO single crystal substrate ~Xtt=u 1. 0 substra substrates with very flat surfaces and high Tc's. :GBP R(270)=40. 1 m 0 0. 0 LLLLL. J. . . . LL~. t-J' L-Tc=9LWO. L-! L-K LLLLL. . . . L. . I. . . . l. . . . L. L. L. J. . . . . L. L. l. . . J 50 100 150 200 250 300 0 ACKNOWLEDGMENTS Temperature (K) One of the authors (T. U. ) would like to thank Fig.