Dr A.R. BUNSELL President de l'Association Europeenne des Materiaux Composites Apres Ie succes des deux precedentes editions, Ie troisieme Congres Europeen sur les Materiaux Composites, ECCM-3, s'annonce de tres haut niveau. La premiere reunion s'est tenue a BORDEAUX en septembre1985 tandis que la seconde, jumelee avec Ie sixieme Congres International sur les Materiaux Composites, ICCM-6 eut lieu a LONDRES en juillet 1987. Ces deux reunions ont clairement montre I'importance de la recherche sur les materiaux composites en Europe. Elles ont pu rassembler les chercheurs venus de toute l'Europe et du monde entier. Ce troisieme congres nous ramene a BORDEAUX et souligne I'interet porte aux materiaux composites a BORDEAUX et en Aquitaine, haut lieu d'application des technologies de pointe. La creation a BORDEAUX de l'Association Europeenne des Materiaux Composites, A.E.M.C., a ete Ie fait a la fois d'une volonte politique et d'une prise de conscience locales ainsi que de la presence d'un tissu industriel favorable au developpement de celie activite. Le travail assidu du comite scientifique, compose de specialistes europeens, grace a qui les sujets traites et les articles sont varies et de haut niveau, nous assure de la qualite du compte rendu de ECCM-3 qui comptera desormais parmi les ouvrages de reference. Plus notable encore, est Ie fait que ECCM-3 contribue a la construction d'une grande communaute internationale des composites, composee de chercheurs venus du monde entier.

This book contains the proceedings of the NATO Advanced Study Institute on Surfaces and Interfaces of Ceramic Materials, held on the Oleron island, France, in September 1988. This Institute was organized in nine months after receiving the agreement of the NATO Scientific Affairs Division. Despite this very short time, most of the lecturers contacted have accepted our invitation to prepare a specific talk. The meeting was held at "La Vieille Perrotine" on the Oleron island. This holiday village of the French CNRS is located near the Ocean in a natural area which contributed to create a very pleasant atmosphere favourable to develop interaction between the 91 participants in this Institute. First of all, the Institute was aimed at diffusing the foremost results on the characterization of and the role played by surfaces, grain boundaries and interfaces in preparation and overall properties of ceramic materials, mainly of oxide ceramics. Through its interdisciplinary character, the Institute was also aimed at developing interaction between scientists and engineers interested in basic and practical aspects of processing and use of ceramics.

One of the key aspects of this volume is to cut across the traditional taxonomy of disciplines in the study of alloys. Hence there has been a deliberate attempt to integrate the different approaches taken towards alloys as a class of materials in different fields, ranging from geology to metallurgical engineering. The emphasis of this book is to highlight commonalities between different fields with respect to how alloys are studied. The topics in this book fall into several themes, which suggest a number of different classification schemes. We have chosen a scheme that classifies the papers in the volume into the categories Microstructural Considerations, Ordering, Kinetics and Diffusion, Magnetic Considerations and Elastic Considerations. The book has juxtaposed apparently disparate approaches to similar physical processes, in the hope of revealing a more dynamic character of the processes under consideration. This monograph will invigorate new kinds of discussion and reveal challenges and new avenues to the description and prediction of properties of materials in the solid state and the conditions that produce them.

This is the second edition of Melt Rheology and its Role in Plastics Processing, although the title has changed to reflect its broadened scope. Advances in the recent years in rheometer technology and polymer science have greatly enhanced the usefulness of rheology in the plastics industry. It is now possible to design polymers having specific molecular structures and to predict the flow properties of melts having those structures. In addition, rheological properties now provide more precise information about molecular structure. This book provides all the information that is needed for the intelligent application of rheology in the development of new polymers, the determination of molecular structure and the correlation of processability with laboratory test data. Theory and equations are limited to what is essential for the use of rheology in the characterization of polymers, the development of new plastics materials and the prediction of plastics processing behavior. The emphasis is on information that will be of direct use to practitioners. Extensive references are provided for those wishing to pursue certain issues in greater depth. While the primary audience is applied polymer scientists and plastics engineers, the book will also be of use to postgraduate students in polymer science and engineering and as a text for a graduate course.

The idea of this monograph is to present the latest results related to design and analysis of materials and engineering structures. The contributions cover the field of mechanical and civil engineering, ranging from automotive to dam design, transmission towers and up to machine design and exmaples taken from oil industry. Well known experts present their research on damage and fracture of material and structures, materials modelling and evaluation up to image processing and visualization for advanced analyses and evaluation

"Polymeric and Nanostructured Macromolecules" presents the recent advances made in the synthesis, characterization, and applications of polymeric macromolecules. This book provides an excellent overview of the recent breakthroughs in the science of macromolecules, with an emphasis on nanostructured macromolecules and the perspectives that these versatile materials offer to different fields such as optoelectronics and biotechnology. Advanced undergraduate, graduate students and researchers alike will find the topics concerning physical and chemical properties of advanced macromolecular materials of great interest.

This book provides essential information on metal forming, utilizing a practical distinction between bulk and sheet metal forming. In the field of bulk forming, it examines processes of cold, warm and hot bulk forming, as well as rolling and a new addition, the process of thixoforming. As for the field of sheet metal working, on the one hand it deals with sheet metal forming processes (deep drawing, flange forming, stretch drawing, metal spinning and bending). In terms of special processes, the chapters on internal high-pressure forming and high rate forming have been revised and refined. On the other, the book elucidates and presents the state of the art in sheet metal separation processes (shearing and fineblanking). Furthermore, joining by forming has been added to the new edition as a new chapter describing mechanical methods for joining sheet metals. The new chapter "Basic Principles" addresses both sheet metal and bulk forming, in addition to metal physics, plastomechanics and computational basics; these points are complemented by the newly added topics of metallography and analysis, materials and processes for testing, and tribology and lubrication techniques. The chapters are supplemented by an in-depth description of modern numeric methods such as the finite element method. All chapters have been updated and revised for the new edition, and many practical examples from modern manufacturing processes have been added.

In the past few decades, research in the science of electrodeposition of metals has shown the important practical applications of electronic, magnetic, energy devices and biomedical materials. The aim of this new volume is to review the latest developments electrodeposition and present them to teachers, professionals, and students working in the field.

The ELFNET Book on Failure Mechanisms, Testing Methods, and Quality Issues of Lead-Free Solder Interconnects is the work of the European network ELFNET which was founded by the European Commission in the 6th Framework Programme. It brings together contributions from the leading European experts in lead-free soldering. The limited validity of testing methods originating from tin-lead solder was a major point of concern in ELFNET members' discussions. As a result, the network's reliability group decided to bring together the material properties of lead-free solders, as well as the basics of material science, and to discuss their influence on the procedures for accelerated testing. This has led to a matrix of failure mechanisms and their activation and, as a result, to a comprehensive coverage of the scientific background and its applications in reliability testing of lead-free solder joints. The ELFNET Book on Failure Mechanisms, Testing Methods, and Quality Issues of Lead-Free Solder Interconnects is written for scientists, engineers and researchers involved with lead-free electronics.

Heterogeneously catalyzed selective oxidations of alcohols is a highly topical field. The first chapter of this brief describes the importance of the selective oxidation of alcohols and advantages of heterogeneous catalysts over conventional catalysts, use of environmentally benign oxidants, and the design of selective catalysts by tailoring of polyoxometalates at the molecular level. Chapter 2 describes synthesis, characterization 11-molybdophosphate based supported materials and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite H were used as supports. Chapter 3 describes synthesis, characterization of transition metals (Mn, Co, Ni, Cu)- substituted phosphomolybdates and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. Chapter 4 describes conclusive remarks for present catalytic systems.

The field of Atomic and Molecular Physics (AMP) has reached significant advances in high-precision experimental measurement techniques. The area covers a wide spectrum ranging from conventional to new emerging multi-disciplinary areas like physics of highly charged ions (HCI), molecular physics, optical science, ultrafast laser technology etc. This book includes the important topics of atomic structure, physics of atomic collision, photoexcitation, photoionization processes, Laser cooling and trapping, Bose Einstein condensation and advanced technology applications of AMP in the fields of astronomy, astrophysics, fusion, biology and nanotechnology. This book is useful for researchers, professors, graduate, postgraduate and PhD students dealing with atomic and molecular physics. The book has a wide scope with applications in neighboring fields like plasma physics, astrophysics, cold collisions, nanotechnology and future fusion energy sources like ITER (international Thermonuclear Experimental Reactor) Tokomak plasma machine, which need accurate AMP data.

One distinct feature of human society since the dawn of civilization is the systematic use of inorganic building materials, such as natural stone, unburnt and burnt soil, adobe and brick, inorganic binders like lime and cement, and reinforced concrete. Our heritage has cultural, architectural and technological value and preserving such structures is a key issue today. Planners and conservation scientists need detailed site surveys and analyses to create a database that will serve to guide subsequent actions. One factor in this knowledge base is an understanding of how historic materials were prepared and the crucial properties that influence their long-term behaviour. Any assessment of the way such materials perform must crucially be based on an understanding of the methods used for their analysis. The editors here add to the knowledge base treating the materials used in historic structures, their properties, technology of use and conservation, and their performance in a changing environment. The book draws together 18 chapters dealing with the inorganic materials used in historic structures, such as adobe, brick, stone, mortars, concrete and plasters. The approach is complex, covering material characterisation as well as several case studies of historic structures from Europe, including Germany, Ireland, Italy, Poland, Portugal, Scotland, Slovenia and Spain, and the My Son Temples in Vietnam. An equally important component of the book covers the analysis of materials, together with a treatment of sustainable development, such as the protection of monuments from earthquakes and climate change. The authors are all leading international experts, drawn from a variety of backgrounds: architecture, civil engineering, conservation science, geology and material science, with close links to professional organisations such as ICOMOS or universities and research centres throughout Europe. Audience: This book will be of interest to geologists, engineers, restorers, consulting engineers, designers and other professionals dealing with cultural heritage and sustainable development. Also graduate students in applied geo-science (mineralogy, geochemistry, petrology), architecture and civil engineering will find interesting information in this book.

Thematerialsusedinmanufacturingtheaerospace,aircraft,automobile,andnuclear parts have inherent aws that may grow under uctuating load environments during the operational phase of the structural hardware. The design philosophy, material selection, analysis approach, testing, quality control, inspection, and manufacturing are key elements that can contribute to failure prevention and assure a trouble-free structure. To have a robust structure, it must be designed to withstand the envir- mental load throughout its service life, even when the structure has pre-existing aws or when a part of the structure has already failed. If the design philosophy of the structure is based on the fail-safe requirements, or multiple load path design, partial failure of a structural component due to crack propagation is localized and safely contained or arrested. For that reason, proper inspection technique must be scheduled for reusable parts to detect the amount and rate of crack growth, and the possible need for repairing or replacement of the part. An example of a fail-sa- designed structure with crack-arrest feature, common to all aircraft structural parts, is the skin-stiffened design con guration. However, in other cases, the design p- losophy has safe-life or single load path feature, where analysts must demonstrate that parts have adequate life during their service operation and the possibility of catastrophic failure is remote. For example, all pressurized vessels that have single load path feature are classi ed as high-risk parts. During their service operation, these tanks may develop cracks, which will grow gradually in a stable manner.

The reader is provided with information about methods of calibration of light sources and photodetectors as well as responsiveness of spectral instruments ranging from near infrared to vacuum UV spectral, 1200 - 100 nm, and radiation intensities of up to several quanta per second in absolute and arbitrary units. The author describes for the first time original methods of measurements they created and draws upon over 40 years of experience in working with light sources and detectors to provide accurate and precise measurements. This book is the first to cover these aspects of radiometry and is divided into seven chapters that examine information about terminology, units, light sources and detectors, methods, including author's original ones, of absolute calibration of detectors, spectral instruments responsiveness, absolute measurements of radiation intensity of photoprocesses, and original methods of their study. Of interest to researchers measuring; luminescence spectra, light intensities from IR to vacuum UV, spectral range in wide-light intensity ranges, calibrate light sources and detectors, absolute or relative quantum yields of photoprocess determination.

This book describes the design of the first functioning single-sided tomograph, the related measurement methods, and a number of applications in medicine, materials science, and chemical engineering. It will be the first comprehensive account of this new device and its applications. Among the key advances of this method is that images can be obtained in much shorter times than originally anticipated, and that even vector maps of flow fields can be measured although the magnetic fields are highly inhomogeneous. Furthermore, the equipment is small, mobile and affordable to small and medium enterprises and can be located in doctors' offices.

Carbon nanotubes (CNTs) and Boron nitride nanotubes (BNNTs) are part of the so-called B-C-N material system, which includes novel nanostructures of carbon (C), doped-carbon, boron (B), boron nitride (BN), carbon nitride (CNx), boron-carbon nitride (BxCyNz), and boron carbide (BxCy). BNNTs and CNTs are structurally similar and share extraordinary mechanical properties, but they differ in chemical, biological, optical, and electrical properties. Therefore, hybrid nanotubes constructed of B, C, N elements are expected to form a new class of nanotubes with tunable properties between those of CNTs and BNNTs. In addition, these B-C-N nanostructures will further enhance and complement the applications of CNTs and BNNTs. With contributions from leading experts, B-C-N Nanotubes and Related Nanostructures is the first book to cover all theoretical and experimental aspects of this emerging material system, and meets the need for a comprehensive summary of the tremendous advances in research on B-C-N materials in recent years.

There is a growing need in both industrial and academic research to obtain accurate quantitative results from continuous wave (CW) electron paramagnetic resonance (EPR) experiments. This book describes various sample-related, instrument-related and software-related aspects of obtaining quantitative results from EPR expe- ments. Some speci?c items to be discussed include: selection of a reference standard, resonator considerations (Q, B ,B ), power saturation, sample position- 1 m ing, and ?nally, the blending of all the factors together to provide a calculation model for obtaining an accurate spin concentration of a sample. This book might, at ?rst glance, appear to be a step back from some of the more advanced pulsed methods discussed in recent EPR texts, but actually quantitative "routine CW EPR" is a challenging technique, and requires a thorough understa- ing of the spectrometer and the spin system. Quantitation of CW EPR can be subdivided into two main categories: (1) intensity and (2) magnetic ?eld/mic- wave frequency measurement. Intensity is important for spin counting. Both re- tive intensity quantitation of EPR samples and their absolute spin concentration of samples are often of interest. This information is important for kinetics, mechanism elucidation, and commercial applications where EPR serves as a detection system for free radicals produced in an industrial process. It is also important for the study of magnetic properties. Magnetic ?eld/microwave frequency is important for g and nuclear hyper?ne coupling measurements that re?ect the electronic structure of the radicals or metal ions.

This collection of recent activities provides researchers and scientists with the latest trends in characterization and developments of composed materials and structures. Here, the expression 'composed materials' indicates a wider range than the expression 'composite material' which is many times limited to classical fibre reinforced plastics. The idea of composed structures and materials is to join different components in order to obtain in total better properties than one of the single constituents can provide. In this collection, well known experts present their research on composed materials such as textile composites, sandwich plates, hollow sphere structures, reinforced concrete as well as classical fibre reinforced materials.

This book outlines, with the help of several specific examples, the important role played by absorption spectroscopy in the investigation of deep-level centers introduced in semiconductors and insulators like diamond, silicon, germanium and gallium arsenide by high-energy irradiation, residual impurities, and defects produced during crystal growth. It also describes the crucial role played by vibrational spectroscopy to determine the atomic structure and symmetry of complexes associated with light impurities like hydrogen, carbon, nitrogen and oxygen, and as a tool for quantitative analysis of these elements in the materials.

Preparation of Liquid Crystalline Elastomers, by F. Broemmel, D. Kramer, H. Finkelmann Applications of Liquid Crystalline Elastomers, by C. Ohm, M. Brehmer und R. Zentel Liquid Crystal Elastomers and Light, by Peter Palffy-Muhoray Electro-Opto-Mechanical Effects in Swollen Nematic Elastomers, by Kenji Urayama The Isotropic-to-Nematic Conversion in Liquid Crystalline Elastomers, by Andrija Lebar, George Cordoyiannis, Zdravko Kutnjak und Bostjan Zalar Order and Disorder in Liquid-Crystalline Elastomers, by Wim H. de Jeu und Boris I. Ostrovskii

Dynamic Failure of Materials and Structures discusses the topic of dynamic loadings and their effect on material and structural failure. Since dynamic loading problems are very difficult as compared to their static counterpart, very little information is currently available about dynamic behavior of materials and structures. Topics covered include the response of both metallic as well as polymeric composite materials to blast loading and shock loadings, impact loadings and failure of novel materials under more controlled dynamic loads. These include response of soft materials that are important in practical use but have very limited information available on their dynamic response. Dynamic fragmentation, which has re-emerged in recent years has also been included. Both experimental as well as numerical aspects of material and structural response to dynamic loads are discussed. Written by several key experts in the field, Dynamic Failure of Materials and Structures will appeal to graduate students and researchers studying dynamic loadings within mechanical and civil engineering, as well as in physics and materials science.

The idea for putting together a tutorial on zeolites came originally from my co-editor, Eric Derouane, about 5 years ago. I ?rst met Eric in the mid-1980s when he spent 2 years working for Mobil R&D at our then Corporate lab at Princeton, NJ. He was on the senior technical staff with projects in the synthesis and characterization of new materials. At that time, I managed a group at our Paulsboro lab that was responsible for catalyst characterization in support of our catalyst and process development efforts, and also had a substantial group working on new material synthesis. Hence, our interests overlapped considerably and we met regularly. After Eric moved back to Namur (initially), we maintained contact, and in the 1990s, we met a number of times in Europe on projects of joint interest. It was after I retired from ExxonMobil in 2002 that we began to discuss the tutorial concept seriously. Eric had (semi-)retired and lived on the Algarve, the southern coast of Portugal. In January 2003, my wife and I spent 3 weeks outside of Lagos, and I worked parts of most days with Eric on the proposed content of the book. We decided on a comprehensive approach that ultimately amounted to some 20+ chapters covering all of zeolite chemistry and catalysis and gave it the title Zeolite Chemistry and Catalysis: An integrated Approach and Tutorial.

This book offers systematic and up-to-date treatment of the whole area of magnetic domains. It contains many contributions that have not been published before. The comprehensive survey of this important area gives a good introduction to students and is also interesting to researchers.

"Semiconductor-On-Insulator Materials for NanoElectronics Applications" is devoted to the fast evolving field of modern nanoelectronics, and more particularly to the physics and technology of nanoelectronic devices built on semiconductor-on-insulator (SemOI) systems. The book contains the achievements in this field from leading companies and universities in Europe, USA, Brazil and Russia. It is articulated around four main topics: 1. New semiconductor-on-insulator materials; 2. Physics of modern SemOI devices; 3. Advanced characterization of SemOI devices; 4. Sensors and MEMS on SOI. "Semiconductor-On-Insulator Materials for NanoElectonics Applications" is useful not only to specialists in nano- and microelectronics but also to students and to the wider audience of readers who are interested in new directions in modern electronics and optoelectronics.

From October 15 to 19, 1995 a Workshop on Hetero- structureEpitaxyandDeviceswasheldatSmoleniceCastlenear Slovakia'scapital Bratislava. The intention ofthisWorkshop was toestablishandstrengthentiesbetweenscientistsoftheformerly Socialist East and Middle-European states with their colleagues fromtheWesterncountries. WiththisaimtheWorkshopfoundthe financialsupportbyNATOwhichtremendouslyhelpedtofacilitate organizingthemeeting That the Workshop was also a scientific success is evidenced by the present volume comprising a selection of the contributed papers. We are confident that the reader of these Proceedings can convincehimselfofthe highqualityofthe work whose results are presented here. We hope that this and the numerousdiscussionsbetweenthe participants ofthe Workshop will promote cooperations among scientists from the countries representedatthemeeting. It is a pleasure to express our gratitude to NATO and, as representatives ofthe institutions involved in the organization, to Lubomir Malacky (Institute of Electrical Engineering, Slovak Academy of Sciences) and Hergo-Heinrich Wehmann (Institute for Semiconductor Technology, Technical University Braun- schweig) whose dedicated work was most essential for the Workshop. A. Schlachetzki J. Novak November1995 xiii SIMULATIONOFIII-VLAYERGROWTH y. ARIMA DepartmentofPhysics, Gakushuin University 1-5-1 Mejiro, Toshima-ku, Tokyo 171, Japan AND T. IRISAWA ComputerCenter, Gakushuin University 1-5-1 Mejiro, Toshima-ku, Tokyo 171, Japan 1. Introduction Since it was reported [1] that the intensities of RHEED for the growing surface of aGaAs crystal in the process of MBE oscillate with a period correspondingto the completion of a monolayer, this phenomenon has been applied to the thin layer growth of man-made superlattices.